• Structural Engineering and Mechanics
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• 제73권3호
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• pp.319-330
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• 2020

This paper investigates the free vibrations of cylindrical shells made of time-dependent materials for different viscoelastic models under various boundary conditions. During the extraction of equations, the displacement field is estimated through the first-order shear deformation theory taking into account the transverse normal strain effect. The constitutive equations follow Hooke's Law, and the kinematic relations are linear. The assumption of axisymmetric is included in the problem. The governing equations of thick viscoelastic cylindrical shell are determined for Maxwell, Kelvin-Voigt and the first and second types of Zener's models based on Hamilton's principle. The motion equations involve four coupled partial differential equations and an analytical method based on the elementary theory of differential equations is used for its solution. Relying on the results, the natural frequencies and mode shapes of viscoelastic shells are identified. Conducting a parametric study, we examine the effects of geometric and mechanical properties and boundary conditions, as well as the effect of transverse normal strain on natural frequencies. The results in this paper are compared against the results obtained from the finite elements analysis. The results suggest that solutions achieved from the two methods are ideally consistent in a special range.

• Bulletin of the Korean Chemical Society
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• 제24권6호
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• pp.723-727
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• 2003

Recently the ab initio effective valence shell Hamiltonian method $H^v$ has been extended to treat spin-orbit coupling in atoms or molecules. The quasidegenerate many-body perturbation theory based $H^v$ method has an advantage of determining the spin-orbit coupling energies of all valence states for both the neutral species and its ions with a similar accuracy from a single computation of the effective spin-orbit coupling operator. The new spin-orbit $H^v$ method is applied to calculating the fine structure splittings of the valence states of SiH, $SiH^+$, and $SiH^{2+}$ not only to assess the accuracy of the method but also to investigate the spin-orbit interaction of highly excited states of SiH species. The computed spin-orbit splittings for ground states are in good agreement with experiment and the few available ab initio computations. The ordering of fine structure levels of the bound and quasi-bound spin-orbit coupled valence states of SiH and its ions, for which neither experiment nor theory is available, is predicted.

• 한국정밀공학회지
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• 제25권3호
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• pp.115-125
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• 2008

Recently, Exhaust Gas Recirculation (EGR) system which re-flow a cooled exhaust gas from vehicles burning diesel as fuel to a combustion chamber of engine has been used to solve the serious air pollution. For the design and mass production of EGR system, it is essential to ensure structural integrity evaluation. The EGR system consisted of ten dimpled oval core rectangular tubes, two fix-plates, two coolant pipes, shell body and two flanges in this study. To confirm the safety of the designed system, finite element modeling about each component such as the dimpled oval core tube with the dimpled shape and others was carried out. The reliability of EGR system against exhaust gas flow with high temperature was investigated by flow and pressure analysis in the system. Also, thermal and strength analysis were verified the safety of EGR system against temperature change in the shell and tubes. Furthermore, modal analysis using ANSYS was also performed. From the results of FE analysis, there were confirmed that EGR system was safe against the flow of exhaust gas, temperature change in EGR system and vibration on operation condition, respectively.

• Coupled systems mechanics
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• 제6권3호
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• pp.273-286
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• 2017

We present a simple and easy-to-implement lumped stiffness model to elucidate the load transfer mechanism among all individual tube shells and intertube van der Waals (vdW) interactions in transversely compressed multi-walled carbon nanotubes (CNTs). Our model essentially enables theoretical predictions to be made of the relevant transverse mechanical behaviors of multi-walled tubes based on the transverse stiffness properties of single-walled tubes. We demonstrate the validity and accuracy of our model and theoretical predictions through a quantitative study of the transverse deformability of double- and triple-walled CNTs by utilizing our recently reported nanomechanical measurement data. Using the lumped stiffness model, we further evaluate the contribution of each individual tube shell and intertube vdW interaction to the strain energy absorption in the whole tube. Our results show that the innermost tube shell absorbs more strain energy than any other individual tube shells and intertube vdW interactions. Nanotubes of smaller number of walls and outer diameters are found to possess higher strain energy absorption capacities on both a per-volume and a per-weight basis. The proposed model and findings on the load transfer and the energy absorption in multi-walled CNTs directly contribute to a better understanding of their structural and mechanical properties and applications, and are also useful to study the transverse mechanical properties of other one-dimensional tubular nanostructures (e.g., boron nitride nanotubes).

• Bulletin of the Korean Chemical Society
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• 제34권11호
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• pp.3362-3366
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• 2013

A simple and quick separation technique for selenite in natural water was developed using $TiO_2$@$SiO_2/Fe_3O_4$ nanoparticles. For the synthesis of nanoparticles, a polymer-assisted sol-gel method using hydroxypropyl cellulose (HPC) was developed to control particle dispersion in the synthetic procedure. In addition, titanium butoxide (TBT) precursor, instead of the typical titanium tetra isopropoxide, was used for the formation of the $TiO_2$ shell. The synthesized nanoparticles were used to separate selenite ($Se^{4+}$) in the presence of $Se^{6+}$ or selenium anions for the photocatalytic reduction to $Se^0$ atom on the $TiO_2$ shell, followed by magnetic separation using $Fe_3O_4$ nanoparticles. The reduction efficiency of the photocatalytic reaction was 81.4% at a UV power of 6W for 3 h with a dark adsorption of 17.5% to the nanoparticles, as determined by inductively coupled plasma-mass spectrometry (ICP-MS). The developed separation method can be used for the speciation and preconcentration of selenium cations in environmental and biological analysis.

• Advances in nano research
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• 제6권4호
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• pp.299-321
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• 2018

A layerwise shear deformation theory is applied in this paper for buckling analysis of piezoelectric truncated conical shell. The core is a multiphase nanocomposite reinforced by carbon nanotubes (CNTs) and carbon fibers. The top and bottom face sheets are piezoelectric subjected to 3D electric field and external voltage. The Halpin-Tsai model is used for obtaining the effective moisture and temperature dependent material properties of the core. The proposed layerwise theory is based on Mindlin's first-order shear deformation theory in each layer and results for a laminated truncated conical shell with three layers considering the continuity boundary condition. Applying energy method, the coupled motion equations are derived and analyzed using differential quadrature method (DQM) for different boundary conditions. The influences of some parameters such as boundary conditions, CNTs weight percent, cone semi vertex angle, geometrical parameters, moisture and temperature changes and external voltage are investigated on the buckling load of the smart structure. The results show that enhancing the CNTs weight percent, the buckling load increases. Furthermore, increasing the moisture and temperature changes decreases the buckling load.

• Steel and Composite Structures
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• 제44권3호
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• pp.371-388
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• 2022

The present study tackles the problem of forced vibration of imperfect axially functionally graded shell structure with truncated conical geometry. The linear and nonlinear large-deflection of the structure are considered in the mathematical formulation using von-Kármán models. Modified coupled stress method and principle of minimum virtual work are employed in the modeling to obtain the final governing equations. In addition, formulations of classical elasticity theory are also presented. Different functions, including the linear, convex, and exponential cross-section shapes, are considered in the grading material modeling along the thickness direction. The grading properties of the material are a direct result of the porosity change in the thickness direction. Vibration responses of the structure are calculated using the semi-analytical method of a couple of homotopy perturbation methods (HPM) and the generalized differential quadrature method (GDQM). Contradicting effects of small-scale, porosity, and volume fraction parameters on the nonlinear amplitude, frequency ratio, dynamic deflection, resonance frequency, and natural frequency are observed for shell structure under various boundary conditions.

• 한국지반공학회논문집
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• 제21권6호
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• pp.19-30
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• 2005

. 본 연구에서는 지반의 비선형을 고려한 하부구조(말뚝지반말뚝캡)의 복잡한 거동과 상부 피어구조와 연계된 상$\cdot$하부 일체화 해석을 수행할 수 있는 3차원 해석기법을 개발하였다. FBPier 3.0과 Croup 6.0의 중간단계에 해당하는 해석기법으로 각 해석기법의 장점을 취하고 단점을 보완하였다. 군말뚝기초 중 말뚝은 말뚝두부 강성행렬을 이용하여 모델링하였으며, 지반은 비선형 하중전이곡선(t-z, q-z, p-y곡선)으로 나타내었다. 말뚝캡은 6개의 자유도를 갖는 개선된 4절점 평면쉘(Flat shell)요소루 교각(피어)은 3차원 보(Beam)요소로 모델링 하여 상$\cdot$하부 일체해석이 가능하게 하였다. 말뚝두부 강성행렬의 하중크기에 따른 비선형성을 고려하기 위하여 점증하중-할선계수법을 제안하였다. 기존의 비선형 해석기법과의 비교$\cdot$분석 결과, 본 해석기법이 말뚝을 FBPier 5.0과 달리 말뚝두부 강성행렬을 이용하여 모델링 하였어도 말뚝두부 및 교각 상단에서의 변위를 비교적 정확히 산정 가능하였다.

• Advances in nano research
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• 제12권1호
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• pp.81-99
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• 2022

The aim of current work is to evaluate thermo-electrical characteristics of graphene nanoplatelets Reinforced Composite (GNPRC) coupled with magneto-electro-elastic (MEE) face sheet. In this regard, a cylindrical smart nanocomposite made of GNPRC with an external MEE layer is considered. The bonding between the layers are assumed to be perfect. Because of the layer nature of the structure, the material characteristics of the whole structure is regarded as graded. Both mechanical and thermal boundary conditions are applied to this structure. The main objective of this work is to determine critical temperature and critical voltage as a function of thermal condition, support type, GNP weight fraction, and MEE thickness. The governing equation of the multilayer nanocomposites cylindrical shell is derived. The generalized differential quadrature method (GDQM) is employed to numerically solve the differential equations. This method is integrated with Deep Learning Network (DNN) with ADADELTA optimizer to determine the critical conditions of the current sandwich structure. This the first time that effects of several conditions including surrounding temperature, MEE layer thickness, and pattern of the layers of the GNPRC is investigated on two main parameters critical temperature and critical voltage of the nanostructure. Furthermore, Maxwell equation is derived for modeling of the MEE. The outcome reveals that MEE layer, temperature change, GNP weight function, and GNP distribution patterns GNP weight function have significant influence on the critical temperature and voltage of cylindrical shell made from GNP nanocomposites core with MEE face sheet on outer of the shell.

• 청정기술
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• 제30권1호
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• pp.55-61
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• 2024

연료전지의 산소환원반응용 백금 촉매의 높은 비용을 극복하기 위하여 나노 구조 제어를 통한 고성능의 백금 합금 촉매 개발 연구가 활발히 수행되고 있다. 본 연구에서는 탄소에 담지된 니켈-니켈 질화물 복합체와 백금 이온 간의 갈바닉 치환 반응 시 용액의 pH 조절을 통한 촉매의 나노구조를 중공형이나 코어-쉘 구조로 제어하는 방법을 제시하였다. X선 회절 분석과 투과전자현미경, 유도결합 플라즈마를 이용한 분석을 통해 합성 조건에 따른 금속의 상태와 함량 및 합금 입자의 형상에 대한 물리적 특성 평가를 수행하였다. 제조된 촉매를 산소환원반응 촉매로 적용하였으며 상용 백금 촉매 대비 1.7배(중공형 촉매) 및 1.9배(코어-쉘 구조 촉매) 개선된 전기화학적 활성 면적 당 활성을 나타내었다.