• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.129-136
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• 2003

Numerical study with momentum-balanced boundary conditions has been conducted to grasp chemical effects of added $CO_{2}$ and $H_{2}O$ to fuel- and oxidizer-sides on flame structure and NO emission behavior in $CH_{4}$/Air counterflow diffusion flames. The dilution with $H_{2}O$ results in significantly higher flame temperatures and NO emission, but dilution with $CO_{2}$ has much more chemical effects than that with $H_{2}O$. Maximum reaction rate of principal chain branching reaction due to chemical effects decreases with added $CO_{2}$. but increases with added $H_{2}O$. The NO emission behavior is closely related to the production rate of OH, CH and N. The OH radical production rate increases with added $H_{2}O$ but those of CH, N decrease. On the other hand the production rates of OR CH and N decrease with added $CO_{2}$. It is found that NO emission behavior is considerably affected by chemical effects of added $CO_{2}$ and $H_{2}O$.

• Journal of the Korean Society of Combustion
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• v.8 no.4
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• pp.9-14
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• 2003

High temperature air combustion technology has been utilized by using preheated air over 1100 K and excessive exhaust gas recirculation. Numerical analysis was performed to investigate the combustion characteristics with high temperature deficient oxygen air combustion by adopting a counterflow as a model problem accounting for detailed chemical kinetics. Methane($CH_4$) was used as a test fuel and calculated oxidizer conditions were low temperature high oxygen (300K, $X_{O2}=0.21$) and high temperature low oxygen (1300K, $X_{O2}=0.04$) conditions. The latter case showed that the flame temperature is lower than the former case and its profile showed monotonic decrease from oxidizer to fuel side, without having local maximum flame temperature at high stretch rate. Also, heat release rate was one order lower and it has one peak profile because of low oxygen concentration and heat release rate integral is almost same for stretch rate. High temperature low oxygen air combustion shows low NO emission characteristics.

• Journal of the korean Society of Automotive Engineers
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• v.11 no.3
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• pp.37-48
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• 1989

The effects of burnt gas mixing, which can be caused by turbulent eddy mixing, on the interaction and extinction characteristics of premixed flames are analyzed using large activation energy asymptotics adopting counterflow as a model problem. The results show that the burnt gas mixing, preferential diffusion and heat loss affect the fuel consumption rate, flame temperature and the oxidizer concentration at the flame which influence the flame behavior and the extinction characteristics.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.9 s.252
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• pp.905-912
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• 2006

Experiments in low strain rate methane-air counterflow diffusion flames diluted with $CO_2$ have been conducted to investigate the flame extinction behavior and edge flame oscillation in which flame length is less than the burner diameter and thus lateral conductive heat loss in addition to radiative loss could be remarkable at low global strain rates. The critical mole fraction at flame extinction is examined in terms of velocity ratio and global strain rate. It is seen that flame length is closely relevant to lateral heat loss, and this sheets flame extinction and edge flame oscillation considerably. Lateral heat loss causes flame oscillation even at fuel Lewis number less than unity. Edge flame oscillations are categorized into three: a growing-, a harmonic- and a decaying-oscillation mode. Onset conditions of the edge flame oscillation and the relevant modes are examined with global strain rate and $CO_2$ mole fraction in fuel stream. A flame stability map based on the flame oscillation modes is also provided at low strain rate flames.

• Journal of the Korean Society of Combustion
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• v.17 no.3
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• pp.9-16
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• 2012

Nonlinear dynamics of pulsating instability in radiating counterflow diffusion flames is numerically investigated by imposing Damk$\ddot{o}$hler number perturbation. Stable limit-cycle solutions occur in small ranges of Damk$\ddot{o}$hler numbers past bifurcation point of instability. Period doubling cascade and chaotic behaviors appear just before dynamic extinction occurs. Nonlinear dynamics is also studied when large disturbances are imposed to flames. For weak steady flames, the dynamic extinction range shrinks as the magnitudes of disturbances are increased. However, strong steady flames can overcome relatively large disturbances, thereby the dynamic extinction range extending. Stable limit-cycle behaviors reappears prior to dynamic extinction when the steady flames are strong enough.

• Journal of the Korean Society of Combustion
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• v.18 no.2
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• pp.42-50
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• 2013

Linear stability analysis of radiating counterflow diffusion flames is numerically conducted to examine the instability characteristics of cellular patterns. Lewis number is assumed to be 0.5 to consider diffusional-thermal instability. Near kinetic limit extinction regime, growth rates of disturbances always have real eigen-values and neutral stability condition of planar disturbances perfectly falls into quasi-steady extinction. Cellular instability of disturbance with transverse direction occurs just before steady extinction. However, near radiative limit extinction regime, the eigenvalues are complex and pulsating instability of planar disturbances appears prior to steady extinction. Cellular instability occurs before the onset of planar pulsating instability, which means the extension of flammability.

• Journal of the Korean Society of Combustion
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• v.13 no.4
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• pp.16-25
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• 2008

Experiments have been conducted to clarify impacts of curtain flow and velocity ratio on low strain rate flame extinction, and to further display transition of shrinking flame disk to flame-hole. Critical mole fractions at flame extinction are examined in terms of velocity ratio, global strain rate, and nitrogen curtain flow rate. It is shown that multi-dimensional effects at low strain rate flames through global strain rate, velocity ratio, and curtain flowrate dominantly contribute to flame extinction and transition of shrinking flame disk to flame hole. Our concerns are particularly focused on the dynamic behavior of an edge flame in shrinking flame disk.

• Fire Science and Engineering
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• v.26 no.4
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• pp.55-62
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• 2012

The suppression mechanisms of carbon dioxide ($CO_2$) as a representative fire suppression agent were revisited using a counterflow diffusion flame which could be applied the concept of a local application system. To end this, the low strain rate $CH_4$/air counterflow diffusions with $CO_2$ addition in either fuel or oxidizer stream were examined numerically using detailed-kinetic chemistry. Radiative heat loss due to radiating gas species including $CO_2$ added was considered by the optically thin model (OTM). As a result, the critical $CO_2$ volume fractions in the oxidizer stream required to extinguish the flame were in good agreement with the experimental data reported in the literature, while somewhat under-prediction was observed with $CO_2$ added in the fuel stream. The surrogate agents were adopted to estimate the quantitative contribution with changing in global strain rate ($a_g$) on the flame extinguishment among pure dilution effect, thermal effects including radiation heat loss and chemical effect due to the $CO_2$ fire suppression agent.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.9
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• pp.859-866
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• 2010

Nonlinear dynamics of pulsating instability-diffusional-thermal instability with Lewis numbers sufficiently higher than unity-in counterflow diffusion flames, is numerically investigated by imposing a Damkohler number perturbation. The flame evolution exhibits three types of nonlinear behaviors, namely, decaying pulsating behavior, diverging behavior (which leads to extinction), and stable limit-cycle behavior. The stable limit-cycle behavior is observed in counterflow diffusion flames, but not in diffusion flames with a stagnant mixing layer. The critical value of the perturbed Damkohler number, which indicates the region where the three different flame behaviors can be observed, is obtained. A stable simple limit cycle, in which two supercritical Hopf bifurcations exist, is found in a narrow range of Damkohler numbers. As the flame temperature is increased, the stable simple limit cycle disappears and an unstable limit cycle corresponding to subcritical Hopf bifurcation appears. The period-doubling bifurcation is found to occur in a certain range of Damkohler numbers and temperatures, which leads to extend the lower boundary of supercritical Hopf bifurcation.

• Fire Science and Engineering
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• v.28 no.3
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• pp.20-28
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• 2014

Effect of radiation models on the suppression limits in counterflow $CH_4$/air diffusion flame was numerically investigated with fundamental experiments for the numerical validation. $N_2$ and $CO_2$ were considered as extinguishing agents. The differences in extinguishing concentration between OTM and SNB radiation models which have different accuracy levels were examined. As a result, there is no considerable difference in extinguishing concentration for the $N_2$ dilution as the radiation models with different accuracy levels were used. As the $CO_2$ having strong radiative effect was diluted in the low strain flames, however, the radiation model with high predictive accuracy such as SNB should be used. In particular, the $CO_2$ dilution in fuel stream leads to the significant difference in extinguishing concentration between OTM and SNB models. Therefore, it is necessary that the radiation model should be reasonably chosen with the consideration of numerical accuracy and computational time for the prediction of extinguishing concentration.