• Title/Summary/Keyword: Corrosive Resistance

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Corrosion Behavior Optimization by Nanocoating Layer for Low Carbon Steel in Acid and Salt Media

  • Ahmed S. Abbas;Bahaa Sami Mahdi;Haider H. Abbas;F.F. Sayyid;A.M. Mustafa;Iman Adnan Annon;Yasir Muhi Abdulsahib;A.M. Resen;M. M. Hanoon;Nareen Hafidh Obaeed
    • Corrosion Science and Technology
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    • v.22 no.1
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    • pp.21-29
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    • 2023
  • In this paper, a SiC nano electroless nickel plating layer with excellent corrosion resistance was fabricated using the Taguchi method. The electroless plated low carbon steel was subjected to tests to examine the influence of corrosive media, microhardness, and corrosion rate on the corrosion resistance of this alloy. Three different corrosive media (HCl, Na2SO4, and NaCl) at various temperatures (80, 90, and 100 ℃) were used, and at three different times (40, 80, and 120 min.) with a speed of stirring equal to 500 rpm. The results of microhardness were found from 134.276 HV to 278.578 HV at various conditions, while the corrosion rate results were obtained from 0.89643 mpy to 7.12571 mpy at different circumstances. Corrosion, and mechanical characteristics were explained using Taguchi design. Taguchi technique was used to account for all possible combinations of elements in order to conduct a complete study. Models that link the response and procedure parameters were developed using the results of these tests, and the analysis of variance was utilized to validate these models (ANOVA). For maximum efficiency, a function called "desirability" was applied to all responses at once.

A Study on Anti-Oxidation of Stainless Steel Spot Weld (스테인리스강 Spot 용접부의 산화방지에 관한 연구)

  • Huh, Dong-Woon;Rhee, Se-Hun
    • Journal of Welding and Joining
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    • v.29 no.5
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    • pp.58-62
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    • 2011
  • Stainless steels are alloy steels with a nominal chromium content of at least 11 percent, with other alloy additions. The stainlessness and corrosion resistance of these alloy steels are attributed to the presence of a passive oxide film on the surface. When exposed to conditions like Resistance Spot Welding (RSW) process that remove the passive oxide film, stainless steels are subject to corrosive attack. And exposure to elevated temperatures causes oxidation (discoloration) of areas around indentation in Spot welding. In this paper, deal with the effect of shielding gas (Ar) preventing the corrosion, oxidation of stainless steel. And find the optimal shielding gas flow rate. In addition, suggest effective purging method for direct/indirect spot welding process.

Corrosion Resistance and Low Friction Property of Sintered Steel Parts via Chromizing Treatment (크로마이징 처리 된 철계 소결 부품의 내식성 및 저 마찰특성)

  • Kim, Sang-Gweon;Park, Yong-Jin;Yeo, Kuk-Hyun;Lee, Jae-Hoon
    • Korean Journal of Metals and Materials
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    • v.50 no.11
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    • pp.809-815
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    • 2012
  • Recently, as the interest in improving energy efficiency has grown, the demand for vehicle and machine parts that are resistant in high temperature corrosive conditions and abrasive environments has increased. Pack chromizing treatment of sintered steels is a profitable method that satisfies both corrosion resistance and low friction properties. Since austenitic stainless steels have good corrosion resistance but low mechanical hardness, if they are replaced by sintered steel parts with pack chromizing treatment, all the desirable properties such as low price, easy molding, high hardness, low frictional coefficient, and high corrosion resistance, can be obtained. The higher corrosion resistance of the chromized parts over that of the austenitic stainless steels was acquired by coating chromium carbides and a thin chromium oxides layer on the surface. Moreover, the surface morphology of chromized parts, which were composed of chromium rich phases and hardened chromium carbides by diffusing and alloying, had a peak-and-valley shape so that the dimple effect by the wrinkled morphology and high hardness induced a low friction coefficient.

Characterization of Tribocorrosion Behaviour of CoCr Alloy by Electrochemical Techniques in Several Corrosive Media

  • Escudero, M.L.;Diaz, I.;Martinez Lerma, J.F.;Montoya, R.;Garcia-Alonso, M.C.
    • Corrosion Science and Technology
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    • v.17 no.2
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    • pp.68-73
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    • 2018
  • Substitution of hip and knee joints by CoCr alloys is in great demand due to their high wear resistance and good biocompatibility. Understanding of tribocorrosion in joint replacements requires study of variables such as coefficient of friction and the choice of a proper corrosive medium in wear-corrosion tests carried out in the lab. The objective of this study was to characterize tribocorrosion behaviour of CoCr alloy with low (LCCoCr) and high carbon (HCCoCr) contents in several corrosive media: NaCl, Phosphate Buffer Solution (PBS), and PBS with hyaluronic acid (PBS-HA). Tribocorrosion tests were carried out on a pin-on-disk tribometer with an integrated electrochemical cell. A normal load of 5N was applied on the alumina ball counterpart at a rotation rate of 120 rpm. Coefficient of friction (COF) was measured and tribocorrosion behaviour was characterized by in situ application of electrochemical techniques. HCCoCr alloy immersed in PBS-HA showed the best tribocorrosion behaviour with the lowest COF. In this case, in situ measurement of corrosion potential and the impedance data under wear corrosion process showed an active state while passive film was continuously destroyed without possibility of regeneration.

Corrosion of the non-beryllium dental casting Ni-Cr alloys for the denture base framework metal and the porcelain-fused-to-metal crown (베릴륨 불포함 치과 주조용 니켈-크롬 합금 중 금속의치상용 합금과 금속소부도재관용 합금의 부식에 관한연구)

  • Kim, Hong-Sik;Song, Jae-Sang;Park, Soo-Chul
    • Journal of Technologic Dentistry
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    • v.34 no.4
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    • pp.337-344
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    • 2012
  • Purpose: This study examined the corrosion level by alloy type and pH, and used the corrosion levels as the dental health data. The study utilized one Ni-Cr alloy for the full and removable partial denture metal frameworks and two Ni-Cr alloys for porcelain-fused-to-metal crown, among the non-beryllium dental casting non-precious Ni-Cr alloys. Methods: The alloy specimens were manufactured in $10cm^2$ and stored in the corrosive solution(pH 2.2-4.4) in the electrical water bath($37^{\circ}C$) for seven days. Afterwards, the metal ions were quantitatively analyzed using the ICP. Results: Of the three metal alloys, Bellabond-Plus$^{(R)}$alloy and SOLIBOND N$^{(R)}$alloy, with 22% or higher chrome chemical contents, had higher corrosion resistance than Jdium-100$^{(R)}$alloy with 20% chrome chemical content. In all three alloys, the corrosion of Ni was highest, and metal ion corrosion was higher in the pH 2.2 corrosive solution. Conclusion: Although Ni-Cr alloy was not very corrosive, a Ni-allergic patient should not have Ni-Cr alloy prosthesis. The Ni-Cr alloy for porcelain-fused-to-metal crown should be designed for the dental porcelain to cover the whole crown.

Study on the Effect of Corrosion Gas and Acidic Falling Materials for Conservational Wax on the Copper based Sculpture (동(銅)이 주종을 이루는 조형물 보존용 왁스의 산성강하물 및 부식 가스에서의 영향성 연구)

  • Oh, Seung-Jun;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.26 no.4
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    • pp.437-443
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    • 2010
  • The influence of noxious corrosive gas, which is the product of fossil fuel, and the acidic descent material, which becomes the reason for such reaction, on wax which protects the cultural assets, and the habitat factor were researched. It could be viewed that corrosion occurred rapidly due to the acidic descent material, which have the long staying on the material, rather than harmful corrosive gas. Also, it could be figured out that such corrosion began from whitening phenomenon of coated wax. As the acidity increased, more whitening phenomenon occurred, and eventually, it could be found out that whitening effect began due to the acidic descent material, corrosive gas and various 0.1 M acid solution, which lead to the exposure of internal metal, and corrosion occurred. The wax with the greatest resistance to the acidity due to its least changing aspect seemed to be Renaissance wax, except sulfuric acid.

Durability of Various Anti-Corrosive Organic Coatings in Marine Environment for Twelve Years

  • Yamamoto, Mashiro;Kajiki, Toshitaka;Kamon, Toshikuni;Yoshida, Kotaro
    • Corrosion Science and Technology
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    • v.3 no.1
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    • pp.20-25
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    • 2004
  • In order to clarify the durability of protective coatings for maritime steel structures, various anti-corrosive organic coated steel samples were exposed for twelve years in semitropical marine environment at Miyakojima Island, Okinawa, JAPAN. Samples were various organic coated steel pipes, 4.0 m in length and 150 mm in diameter. While the bare steel pipe entirely corroded in 4.5 mm thickness in four and half years, these organic coated steel pipes exhibited protective appearances after twelve-year-exposure except for the defect in the coatings. Polyethylene (PE) lining pipe exhibited a good protective performance. Urethane painted pipe was also good but some barnacles stuck to its surface. A combination of petrolatum tape and FRP cover showed sufficient corrosion resistance for steel surface. The correlation in results between exposure and laboratory acceleration test was examined. It was found that salt spray test (SST) results corresponded to rusted area of scratched portion and that adhesion change of coating layer corresponded to the rotating immersion test result. Among the on-site measured data, volume resistivity is utilized for the index of corrosion protection performance of organic coating.

The Effect of Additives on Properties of Sintered $ZrSiO_4$ ($ZrSiO_4$ 소결체의 특성에 미치는 첨가제의 영향에 관한 연구)

  • 박금철;차명진
    • Journal of the Korean Ceramic Society
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    • v.22 no.5
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    • pp.71-75
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    • 1985
  • This study deals with sintering and corrosive behavior of sintered zircons mixed with 5wt% of clay $Cr_2O_3$ $CrO_3-MgO$ aqueous solution and $CrO_3-Mg(OH)_2$ aqueous solution. Measurements were conducted by firing specimens at 135$0^{\circ}C$ 145$0^{\circ}C$ and 155$0^{\circ}C$ 1$650^{\circ}C$ for 3hrs in oxidized and reduced atmospheric conditions. Following results were obtained. 1. Sintered zircon with 5 wt% clay showed that highest compressive strength and the lowest apparent porosity and the other showed less positive result than above specimen in order of zircon with $CrO_3-MgO$ aqueous solution $CrO_3-Mg(OH)_2$ aqueous solution and $Cr_2O_3$. 2. The more firing temperature increased the more its strength improved and porosity decreased and specimen which was fired over 155$0^{\circ}C$ and in reduced atmospheric condition showed better results. 3. Zircon with additives which was fired over 155$0^{\circ}C$ showed the evidence of thermal dissociation but it was not rebonded completely during cooling. 4. Zircon with $CrO_3-MgO$ aqueous solution and $CrO_3-Mg(OH)_2$ aqueous solutiion showed more corrosive resistance than zircon itself and zircon-clay system.

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An Eight-directional Airborne Chloride Collection Method for the Application of an Appropriate Anti-corrosive Material for Each Side of a Building

  • Cho, Gyuhwan;Yeo, Inhwan;Park, Dongcheon
    • Architectural research
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    • v.18 no.2
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    • pp.75-82
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    • 2016
  • To secure the anticorrosive performance of structures in the oceanic environment it is necessary to select appropriate finishing materials and thickness of cover. However, airborne chloride deposition varies depending on the collector used, and it is difficult to select appropriate finishing materials. For this reason, an eight-directional collector is proposed in this study through reviewing the differences between existing airborne chloride collectors and the new one. To analyze airborne chloride deposition according to the direction from which it flows and verify the performance of the collector proposed in this study, airborne chlorides were deposited on the collector for one year at five different locations in an oceanic environment. From the experiment, it was verified that in terms of direction, there were differences in airborne chloride deposition of up to more than 1.5 times. Based on these research findings, the anti-corrosive method applied can be different for each side of a building's structure, and this is believed to serve as an effective and systemic chloride resistance design.

AN EXPERIMENTAL STUDY ON RESISTANCE OF DENTAL GOLD ALLOYS WITH LESS THAN 30% GOLD IN SALIVA AND CHEMICAL AGENTS (시판치과용 합금류의 타액등에 대한 내성실험)

  • Seo, Chang-Hwan
    • The Journal of the Korean dental association
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    • v.16 no.2 s.105
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    • pp.107-112
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    • 1978
  • The followings are dealing with 10 dental alloys with less then 30% gold, manufactured by S company 7, and by H company 3. We could find several noticable things by examining them about tarnish and corrosion with human saliva and several other chemicals, and through metal microscopy. 1) After the samples were submerged in human saliva for 3 months, the colour of the samples were no remarkable change. 2) taking a consideration of the error of santorius balance, also there had been little corrosive changes in human saliva. 3) The colour of A-4 was changed into red in 0.05% HCI solution, while that of P-B was changed into black in 0.1% Na₂S solution and severely corroded samples, P-B, X, and Z lost their original colour and turned black. 4) In case of submerging in H₂NO₃reagent, 50%, it caused serious diminishing changes in weight, that is, X 2.7%, Pb 31.0%, Z 40.5%, and there happened tremble corrosive reaction. 5) Seeing them through metal microscopy, we can obserre the corroded samples changed into the shape of.

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