• Title/Summary/Keyword: Corrosion performance

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CO2/CH4 Separation in Metal-organic Frameworks: Flexibility or Open Metal Sites? (금속-유기 골격체를 이용한 CO2/CH4 분리: 플렉서블 효과와 강한 흡착 사이트 비교 연구)

  • Jung, Minji;Oh, Hyunchul
    • Membrane Journal
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    • v.28 no.2
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    • pp.136-141
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    • 2018
  • Carbon dioxide ($CO_2$) exists not only as a component of natural gas, biogas, and landfill gas, but also as a major combustion product of fossil fuels which leads to a major contributor to greenhouse gases. Hence it is essential to reduce or eliminate carbon dioxide ($CO_2$) in order to obtain high fuel efficiency of internal combustion engine, to prevent corrosion of gas transportation system, and to cope with climate change preemptively. In recent years, there has been a growing interest in not only conventional membrane-based separation but also new adsorbent-based separation technology. Particularly, in the case of metal-organic frameworks (MOFs), it has been received tremendous attentions due to its unique properties (eg : flexibility, gate effect or strong binding site such as open metal sites) which are different from those of typical porous adsorbents. Therefore, in this study, stereotype of two MOFs have been selected as its flexible MOFs (MIL-53) representative and numerous open metal sites MOFs (MOF-74) representative, and compared each other for $CO_2/CH_4$ separation performance. Furthermore, varying and changeable separation performance conditions depending on the temperature, pressure or samples' unique properties are discussed.

Evaluation on Mechanical Properties of Organic of Fiber Reinforced Concrete Using Macro Forta Fiber (매크로 포타 섬유를 사용한 섬유 보강 콘크리트의 역학적 특성 평가)

  • Ryu, Hwa-Sung;Kim, Deuck-Mo;Shin, Sang-Heon;Ryu, Il-Hwan;Joe, Ji-Min
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.4
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    • pp.321-329
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    • 2017
  • Concrete is a semi-brittle material, so its compressive strength is high but its tensile strength is low. The use of fiber-reinforced concrete to improve the disadvantages of such concrete can be an effective way to toughen effective toughness, and the performance is improved by using steel fiber reinforced concrete for structures that are vulnerable to bending forces. However, alternative materials are required due to corrosion of steel fiber and lowering of workability. The purpose of this study is to evaluate the availability of replacing steel fiber reinforced concrete by evaluating physical properties, mechanical properties and drying shrinkage properties of concrete using macro forta fiber with excellent diffusibility. Experimental results show that the macro forta fiber has better fluidity and mechanical performance than the steel fiber reinforced concrete. It was also confirmed that the crack resistance of concrete using Macro Forta fiber is effective in improving structural cracking and drying shrinkage resistance compared to steel fiber reinforced concrete.

Evaluation of Static and Fatigue Performances of Decks Reinforced with GFRP Rebar for Reinfocement Ratio (GFRP 보강근으로 보강된 바닥판의 보강비에 따른 정적 및 피로성능 평가)

  • You, Young-Jun;Park, Young-Hwan;Choi, Ji-Hun;Kim, Jang-Ho Jay
    • Journal of the Korea Concrete Institute
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    • v.26 no.4
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    • pp.491-497
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    • 2014
  • The corrosion of steel reinforcement in reinforced concrete bridge decks significantly affects the degradation of the capacity. Due to the advantageous characteristics such as high tensile strength and non-corrosive property, fiber reinforced polymer (FRP) has been gathering much interest from designers and engineers for possible usage as a alternative reinforcement for a steel reinforcing bar. However, its application has not been widespread, because there data for short- and long-term performance data of FRP reinforced concrete members are insufficient. In this paper, seven full-scale decks with dimensions of $4000{\times}3000{\times}240mm$ were prepared and tested to failure in the laboratory. The test parameter was the bottom reinforcement ratio in transverse direction. The decks were subjected to various levels of concentrated cyclic load with a contact area of $577{\times}231mm$ to simulate the vehicle loading of DB-24 truck wheel loads acting on the center span of the deck. It was observed that the glass FRP (GFRP) reinforced deck on a restraint girder is strongly effected to the level of the applied load rather than the bottom reinforcement ratio. The study results showed that the maximum load less than 58% of the maximum static load can be applied to the deck to resist a fatigue load of 2 million cycles. The fatigue life of the GFRP decks from this study showed the lower and higher fatigue performance than that of ordinary steel and CFRP rebar reinforced concrete deck. respectively.

Study of lubrication and rheological properties of urea grease with respect to PTFE powder addition (PTFE 분말 첨가에 따른 우레아 그리스의 윤활 및 유변학 특성 연구)

  • Son, Kihun;Lee, Dongkyu;Lee, Youngseok;Woo, Jaegu;Ha, KiRyong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.2
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    • pp.634-643
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    • 2020
  • In this study, the rheological and tribological properties of urea grease were studied according to the type and amount of polytetrafluoroethylene (PTFE) powders added to the urea grease, which is the most widely used among solid lubricants, to develop an optimal lubrication system. Urea grease was synthesized using 4,4'-methylenebis(phenyl isocyanate)(MDI), oleylamine, and cyclohexylamine, and PTFE powders prepared by dispersion or suspension polymerization process were then added. The basic rheological and tribological properties of the prepared greases were compared. The worked penetration numbers of urea grease decreased with increasing amount of PTFE powders, but both PTFE powders caused no significant changes in heat resistance and copper corrosion resistance. The shear viscosity increased with increasing PTFE powder content, and the dispersion-type PTFE powder was more effective in increasing the viscosity. In the value of the loss coefficient = 1, the shear stress was higher for the grease containing PTFE powders than the non-PTFE added grease, and the dispersion-type PTFE-added grease showed higher viscosity than the suspension-type PTFE-added grease. Finally, urea grease was found to have a low-performance improvement in terms of wear reduction effects by adding PTFE powders, but the load-bearing performance was up to 2.5 times higher for the dispersion-type PTFE and five times higher for the suspension-type PTFE.

Structural performance evaluation of precast concrete segment using synthetic fibres (프리캐스트 콘크리트 세그먼트의 합성섬유 보강재 적용에 따른 구조적 성능 평가)

  • Lee, Hoseong;Kim, Changyong;Lee, Sean S.;Kim, Seungjun;Lee, Kyeongjin
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.20 no.2
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    • pp.469-483
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    • 2018
  • Steel bars have been widely used as the primary reinforcement for Precast Segmental Concrete Lining for TBM Tunnels. Previously, studies have been carried out to gauge the potential for steel fiber reinforcement to replace the use of steel bar reinforcements in the segmental lining to reduce the amount of the steel bar reinforcement. Steel fiber reinforcements have been investigated and widely applied to SFRC TBM linings to improve the constructability of SFRC TBM linings worldwide. However, the steel fiber reinforcement often caused punctures to the water membranes inside tunnel lining and had long-term durability deterioration issues caused by steel corrosion, as well as cosmetic problems. Therefore, this paper sought to gauge the potential of synthetic fiber reinforcements, which have proven to be very attractive substitutes for steel fiber reinforcements. This study analyzed the performance of both steel and synthetic fiber reinforcements in segmental linings and evaluated the applicability of the fiber reinforcements to the TBM Precast Concrete Segmental Linings of TBM tunnels. As a conclusion, this study demonstrates that the potential use of steel and synthetic fibers in various combination, can substitute the rebar reinforcement in the concrete mix for segmental concrete linings.

Technology Development of Entry-Level MiC Smart Photovoltaic System based on SOC (SoC 기반 보급형 MiC 스마트 태양광발전시스템 기술개발)

  • Yoon, Yongho
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.20 no.3
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    • pp.129-134
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    • 2020
  • Moisture infiltration inside the solar cell module, filling of EVA sheet, melting of the frame seal, and deterioration of power generation performance in the module one year after installation are occurring. Whitening phenomenon, electrode corrosion phenomenon, and dielectric breakdown phenomenon are appearing in solar cell module installed in Korea before 5-7 years, leading to deterioration of power generation performance, and big problems for long-term reliability and long life technology are emerging. Therefore, in order to solve these problems, the development of a micro inverter (MiCrco Inverter Converter, MiC) including the function of securing the durability of the solar cell module and monitoring the aging progress and the solar cell based on the monitoring data from the MiC smart monitoring programs have been proposed to determine the aging of modules. In addition, in order to become a highly efficient solar smart monitoring system through systematic operation management through IT convergence with MiC that has enhanced monitoring function of solar cell module, SoC(System On Chip) in micro inverter is the environment for solar cell module. There is a demand for functions that can detect information in a complex manner and perform communication and control when necessary. Based on these requirements, this paper aims to develop SoC-based low-cost MiC smart photovoltaic system technology.

Strength and Resistance to Chloride Penetration in Concrete Containing GGBFS with Ages (GGBFS를 혼입한 콘크리트의 재령에 따른 강도 및 염소이온 침투 저항성)

  • Park, Jae-Sung;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korea Concrete Institute
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    • v.29 no.3
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    • pp.307-314
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    • 2017
  • Concrete is a durable and cost-benefit construction material, however performance degradation occurs due to steel corrosion exposed to chloride attack. Penetration of chloride ion usually decreases due to hydrates formation and reduction of pores, and the reduced chloride behavior is considered through decreasing diffusion coefficient with time. In the work, HPC (High Performance Concrete) samples are prepared with 3 levels of W/B (water to binder) ratios of 0.37, 0.42, and 0.27 and 3 levels of replacement ratios of 0%, 30% and 50%. Several tests containing chloride diffusion coefficient, passed charge, and compressive strength are performed considering age effect of 28 days and 180 days. Chloride diffusion is more reduced in OPC concrete with lower W/B ratio and GGBFS concrete with 50% replacement ratio shows significant reduction of chloride diffusion in higher W/B ratio. At the age of 28 days, GGBFS concrete with 50% replacement ratio shows more rapid reduction of chloride diffusion than strength development, which reveals that abundant GGBFS replacement has effective resistance to chloride penetration even in the early-aged condition.

A study on the development and field application of SP-Rockbolt with high-strength steel pipe (고강도 강관을 적용한 SP-록볼트 개발 및 현장 적용을 위한 연구)

  • Shin, Hyunkang;Jung, Hyuksang;Ahn, DongWook
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.4
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    • pp.651-668
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    • 2017
  • For initial stability of the tunnel, the primary support, Shotcrete and rockbolt shall be placed in the most appropriate time. This is because the role of such support plays a vital role in long-term and short-term tunnel stability. In this study, the rock bolt is an important supporting system that receives the external pressure generated by the stress relaxation during tunnel excavation as axial force and transmits it to the shotcrete on the tunnel excavation surface. Until now, most of the materials of rock bolts have been used in the field, but there have been many problems such as uncertain quality of Chinese materials entering the market, poor packing due to falling down of rock bolts when filled with mortar, and corrosion due to water. Therefore, in this study, we have developed a high strength steel pipe rock bolt using Autobeam material to solve and improve various problems of existing rock bolts. In order to evaluate the performance of the developed bolt, field tests were carried out and the existing mortar filler in order to improve the performance of the rock bolt, the design and construction criteria were studied and the results were included in this paper.

Developing of Sound Absorption Composite Boards Using Carbonized Medium Density Fiberboard (탄화 중밀도섬유판을 이용한 목재흡음판 개발)

  • Lee, Min;Park, Sang-Bum;Byeon, Hee-Seop;Kim, Jong-In
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.6
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    • pp.714-722
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    • 2014
  • In the previous study, a variety of wood-based panels was thermally decomposed to manufacture carbonized boards that had been proved to be high abilities of insect and fungi repellence, corrosion and fire resistant, electronic shielding, and formaldehyde adsorption as well as sound absorption performance. Based on the previous study, carbonized medium density fiberboard (c-MDF) was chosen to improve sound absorption performance by holing and sanding process. Three different types of holes (cross shape, square shape, and line) with three different sanding thickness (1, 2, and 3 mm) were applied on c-MDF and then determined sound absorption coefficient (SAC). The control c-MDF without holes had 14% of SAC, however, those c-MDFs with holes had 16.01% (square shape), 15.68% (cross shape), and 14.25% (line) of SAC. Therefore, making holes on the c-MDF did not significantly affect on the SAC. As the degree of sanding increased, the SAC of c-MDF increased approximately 65% on sanding treated c-MDFs (21.5, 21.83, and 19.37%, respectively) compared to the control c-MDF (13%). Based on these results, composite sound absorbing panel was developed with c-MDF and MDF (11 mm). The noise reduction coefficient of composite sound absorbing panel was 0.45 which was high enough to certify as sound absorbing material.

Evaluation on the Mechanical Performance of Concrete Using Entanglement Polyamide Fiber (다발형 폴리아미드섬유 보강 콘크리트의 역학적 성능평가)

  • Jeon, Joong Kyu;Kim, Gyu Yong;Jeon, Chan Ki;Lee, Soo Choul
    • Journal of the Society of Disaster Information
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    • v.8 no.3
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    • pp.223-233
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    • 2012
  • Steel fiber is high stiffness and large weight. So, Pumping hose to rupture of the safety management is difficult. Steel fiber caused by corrosion of the deterioration of durability and high-rebound losses are needed for the improvements. Thus, the revised regulations in 2009 by a steel fiber to reinforce other materials is possible. Variety of fiber reinforcement material for concrete review of applicability is needed. Steel fiber strength than the other fibers is large and by the geometry of the fibers are attached to improve performance. However, compared to steel fiber organic fibers and low modulus of elasticity and tensile strength of fiber and agglomeration occurs in the concrete to be used as reinforcement material is difficult. In this regard, the present study as a single object in the micro-fiber bouquet sharp entanglement through make muck attach surface area, distributed fibers from surfactant of the surface enhanced polyamide fibers, steel fiber and PP fiber reinforced concrete by comparing the scene to provide a basis for the use.