• 제목/요약/키워드: Corrosion measurement

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22APU 스테인리스강의 용접부위의 부식특성에 관한 전기화학적 평가 (Electrochemical Evaluation on Corrosion Property of Welding Zone of 22APU Stainless Steel)

  • 문경만;김윤해;이성열;김종도;이명훈;김진경
    • Journal of Advanced Marine Engineering and Technology
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    • 제33권8호
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    • pp.1162-1169
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    • 2009
  • 22APU 스테인리스강에 대해서 두가지의 용접법이 적용 되었으며, 그중 한 방법은 레이저 용접법이며 다른 하나는 TIG 용접법이다. 이 경우 상기한 두 용접을 적용할 경우 용접부의 부식특성의 차이점에 대해서 전기화학적인 방법 예를 들면 부식전위, 분극곡선 및 사이클릭볼타모그램 등의 측정에 의해서 고찰되어졌다. 레이저용접의 경우 모든 용접부(용접금속,열영향부, 모재부)의 경도가 TIG용접의 경우에 비해서 상대적으로 높은 값을 나타내었다. 더욱이 모든 용접부의 부식전류밀도 역시 TIG용접에 비해서 낮은 값이 관찰되었다. 특히 모재부의 부식전류밀도는 용접방법에 관계없이 가장 낮은 값을 나타내었다. 그리고 레이저용접의 경우 부식된 모든 용접부에서 입계부식이 관찰 되지 않았으나, TIG용접에서는 용접금속부와 열영향부에서 입계부식이 관찰되었는데 이것은 크롬카바이드의 형성에 의한 크롬결핍이 감수성온도영역에 있는 용접금속부와 열영향부에 나타났기 때문으로 사료된다. 따라서 이들 영역은 더욱 활성화된 양극으로 부식되기쉽다. 결과적으로 22APU 스테인리스강의 용접부의 내식성은 레이저용접에 의해서 확실히 개선될 수 있다는 사실을 알 수 있다.

용접재료 별 주강 피스톤 크라운 용접부위의 부식 특성에 대한 평가 (Evaluation of the Corrosion Property on the Welded Zone of Cast Steel Piston Crown with Types of Electrode)

  • 문경만;김윤해;이명훈;백태실;김진경
    • 한국해양공학회지
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    • 제28권4호
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    • pp.356-362
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    • 2014
  • Wear and corrosion of the engine parts surrounded with combustion chamber is more serious compared to the other parts of the engine because temperature of the exhaust gas in a combustion chamber is getting higher and higher with increasing of using the heavy oil of low quality. Therefore, an optimum repair weldment as well as an available choice of the base metal for these parts are very important to prolong their lifetime in a economical point of view. It reported that there was an experimental result for repair weldment on the forged steel which would be generally used with piston crown material, however, it is considered that there is no study for the repair weldment on the cast steel of piston crown material. In this study, four types of electrodes such as 1.25Cr-0.5Mo, 0.5Mo Inconel 625 and 718 were welded with SMAW and GTAW methods on the cast steel which would be generally used with piston crown material. And the corrosion properties of weld metal, heat affected zone and base metal were investigated using electrochemical methods such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% $H_2SO_4$ solution. In the cases of Inconel 625, 718, the weld metals and base metals exhibited the best and worst corrosion resistance respectively, however, 1.25Cr-0.5Mo and 0.5Mo indicated that corrosion resistance of the base metal was better than the weld metal. And the weld metal welded with electrodes of Inconel 625 revealed the best corrosion resistance among the electrodes, and Inconel 718 followed the Inconel 625. Hardness relatively also indicated higher value in the weld metal compared to heat affected zone and base metal. In particular, Inconel 718 indicated the highest value of hardness compared to other electrodes in the heat affected zone.

시멘트 복합체 내부 철근 부식에 양생 용액과 철근 사전 부식이 미치는 영향 (Effect of Curing Solution and Pre-Rust Process on Rebar Corrosion in the Cement Composite)

  • 두여준;장인동;이혜린;이종구
    • 한국구조물진단유지관리공학회 논문집
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    • 제26권2호
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    • pp.1-8
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    • 2022
  • 철근 콘크리트 구조물 수명 저하의 주요한 원인은 콘크리트 내부 철근의 부식이다. 이때 사전 부식된 구조물 내부 철근은 다른 철근에 비해 더 쉽게 부식되며, 특히 구조물이 습기 또는 염화 환경에 노출된 경우 부식의 진행속도가 매우 빠른 것으로 알려져 있다. 본 연구에서는 시멘트 복합재 내부의 사전 부식 철근에 대한 서로 다른 양생 용액이 부식에 미치는 영향을 탐구하였다. 철근의 사전 부식을 촉진하기 위해 HCl(3%)용액과 CaCl2(10%)용액을 활용하였으며, 대조군(RE)을 포함한 3종의 사전 부식 철근 모르타르 실린더를 타설하였다. 철근 모르타르 실린더는 CaCl2(3%) 용액과 수돗물에서 각각 120일 동안 양생하며 실험을 진행하였다. 사전 부식 철근의 모르타르 내부 부식 거동에 대한 양생 용액의 영향을 평가하기 위해 전기화학적 분극저항(Electrochemical Polarization)과 반전지 전위 측정법(Half-cell potential)을 활용하였으며, 전자주사현미경(SEM)과 X선 회절 분석(X-ray Diffraction Analysis)을 통해 부식된 철근의 표면 상태와 성분을 분석하였다. 실험 결과 두 종류의 양생 용액에서 사전 부식된 철근의 부식률은 사전 부식되지 않은 시료의 부식률보다 높은 것으로 나타났으며, CaCl2 용액 양생 120일의 RE, CaCl2, HCl 사전 부식 시편의 최종 부식 속도가 수돗물에 양생한 경우보다 각각 8.14, 4.48, 13.81배로 높았다.

Experimental Study on CO2 Diffusivity in Cementitious Materials

  • Jung, Sang-Hwa;Lee, Myung-Kue;Kim, Jee-Sang
    • Corrosion Science and Technology
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    • 제4권2호
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    • pp.69-74
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    • 2005
  • The carbonation of concrete is one of the major factors that cause durability problems in concrete structures. The rate of carbonation depends largely upon the diffusivity of carbon dioxide in concrete. The purpose of this study is to identify the diffusion coefficients of carbon dioxide for various concrete mixtures. To this end, several series of tests have been planned and conducted. The test results indicate that the diffusion coefficient increases with the increase of water-cement ratio. The diffusion coefficient decreases with the increase of relative humidity at the same water-cement ratio. The diffusion of carbon dioxide reached the steady state within about five hours after exposure. The content of aggregates also influences the diffusivity of carbon dioxide in concrete. It was found that the diffusion coefficient of cement paste is larger then that of concrete or mortar. The quantitative values of diffusivity of carbon dioxide in this study will allow more realistic assessment of carbonation depth in concrete structures.

원자력 발전소 STUD BOLT의 자동초음파 주사장치 개발 (Development of Automatic Ultrasonic Testing Equipment for Pressure-Retaining Studs and Bolts in Nuclear Power Plant)

  • 서동만;박문호;홍순신
    • 비파괴검사학회지
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    • 제9권1호
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    • pp.106-110
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    • 1989
  • Bolting degradation problems in primary coolant pressure boundary applications have become a major concern in the nuclear industry. In the bolts concerned, the failure mechanism was either corrosion wastage(loss of bolt diameter) or stress-corrosion cracking.(3) Here the manual ultrasonic testing of RPV(Reactor Pressure Vessel) and RCP(Reactor Coolant Pump) stud has been performed. But it is difficult to detect indications because examiner can not exactly control the rotation angle and can not distinguish the indication from signals of bolt. In many cases, the critical sizes of damage depth are very small(1-2 mm order). At critical size, the crack tends to propagatecompletly through the bolt under stress, Resulting in total fracture.(3) Automatic stud scanner for studs(bolts) was developed because the precise measurement of bolt diameter is required in this circumstance. By use of this scanner, the rotation angle of probe was exactly controlled and the exposure time of radiations was reduced.

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Clark Cell을 이용한 ppb단위 용존산소 측정기술개발 (Development of pub Level Dissolved Oxygen Measuring Technology using Clark Cell)

  • 정경열;류길수
    • Journal of Advanced Marine Engineering and Technology
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    • 제26권3호
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    • pp.375-381
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    • 2002
  • Measuring of the dissolved oxygen is widely used for the environmental control of natural waters, sewage waste treatment, medical and biochemical studies, soil husbandry, food and drug process control, and prevention of corrosion in boilers. Especially, a power plants need special management for preventing accidents from corrosion, therefore, it is essential to measure the concentration of dissolved oxygen in real-time. In this paper we present a method of measuring dissolved oxygen very accurately up to pub units. This method, called polarograph method, is based on the measures of the electric current generated by the oxidation process in cathode and de-oxidation process in anode, assuming that the amount of the current is proportional to the density of dissolved oxygen.

자기누설탐상시스템에서 밀집된 다수의 결함에 의한 탐상 신호 왜곡에 관한 연구 (Study on the Distortion of Detecting Signals with the Multi-Defects in Magnetic Flux Leakage System)

  • 서강;김덕건;한재만;박관수
    • 전기학회논문지
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    • 제56권5호
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    • pp.876-883
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    • 2007
  • The magnetic flux leakage(MFL) type nondestructive testing(NDT) method is widely used to detect corrosion, defects and mechanical deformation of the underground gas pipelines. The object pipeline is magnetically saturated by the magnetic system with permanent magnet and yokes. Hall sensors detect the leakage fields in the region of the defect. The defects are sometimes occurred in group. The accuracy of the detecting signals in this defect cluster become lowered because of the complexity of the defect cluster. In this paper, the effects of the multi -defects are analyzed. The detecting signals are computed by 3-dimensional finite element method and compared with real measurement. The results say that, rather than the size of the defects, the effects of the relative position of the multi-defects are very important on the detecting signals.

점열탄소성 이론에 의한 용접후열처리에 대한 수치해석 (Numerical analysis of post welding heat treatment base on the thermal creep elastic-plastic theory)

  • 방한서;차용훈;오율권;노찬승;김종명
    • 한국해양공학회지
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    • 제11권1호
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    • pp.113-123
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    • 1997
  • The welding residual stresses produced by welding frequently cause a crack and promote stress corrosion etc. in heat affected zone contained with external load and weakness of material. For the purpose pof relaxation of welding residual stress, post welding heat teratment(PWHT) is widely used. In this paper, the computer program which is based on Thermal-Elasto-plastic-creep theory for plane deformation on developed by finite element method (F.E.M) and verified its propriety by experimental measurement and also by using the developed computer program. The mechanical behavior of butt welding joint is clairfied during PWHT.

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배관감육 관리를 위한 고정식 및 탈착식 보온재 설치 경제성 분석 (Economic Analysis of Installing Fixed and Removable Insulation for Pipe Wall Thinning Management)

  • 황경모;윤훈
    • Corrosion Science and Technology
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    • 제15권6호
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    • pp.320-325
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    • 2016
  • To perform ultrasonic testing (UT) thickness measurement of the secondary side piping installed in nuclear power plants, the insulation for preventing heat loss should be removed. The type of insulation can be divided into fixed and removable insulation. Fixed and removable insulation have their own strengths and weaknesses. Removable insulation has been installed in the components susceptible to wall thinning caused by FAC and erosion from Shin-Kori unit 1, which commenced its commercial operation in 2011. In this paper, the number of repeated inspections of components and the number of replacements of fixed insulation were estimated and a more economical way was identified based on the manufacturing and installation costs for fixed and removable insulation.

Clark Cell을 이용한 ppb Level 용존산소 측정기술 개발에 관한 연구 (A Study on the Development of ppb Level Dissolved Oxygen Measuring Technology using Clark Cell)

  • 정경열;이후락;동은석;이수태;류길수
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2001년도 춘계학술대회 논문집
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    • pp.197-201
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    • 2001
  • Measuring of the dissolved oxygen is widely used for the environmental control of natural waters, sewage waste treatment, medical and biochemical studies, soil husbandry, food and drug process control, and prevention of corrosion in boilers. Especially, a power plants need special management for preventing accidents from corrosion, therefore, it is essential to measure the concentration of dissolved oxygen in real-time. In this paper we present a method of measuring dissolved oxygen very accurately up to ppb units. This method, called polarographic method, is based on the measures of the electric current generated by the oxidation process in cathode and de-oxidation process in anode, assuming that the amount of the current is proportional to the density of dissolved oxygen.

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