• Title/Summary/Keyword: Corrosion measurement

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Strain Distribution Measurement for Wall Thinning Defect in Pipe Bends by ESPI (ESPI 를 이용한 곡관 감육 결함부의 변형률 분포 측정)

  • Naseem, Akhter;Kim, Koung-Suk;Jung, Sung-Wook;Park, Jong-Hyun;Choi, Jung-Suk;Jung, Hyun-Chul
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.120-125
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    • 2007
  • Put Abstract text here The strain distribution measurement for wall thinned pipe bends by ESPI is presented. Defect types observed in the steel piping in the nuclear power plants (NPP) are the crack at the weld part and the wall thinning defect in the pipe bends. Especially, the wall thinning defects in the pipe bends due to the flow-accelerated corrosion (FAC) is a main type of defects observed in the carbon steel piping system. ESPI is one of the optical non-destructive testing methods and can measure the stress and the strain distribution of the object subjected by the tensile loading or the internal pressure. In this paper, the strain distribution of the wall thinned pipe bends due to the internal pressure will be measured by ESPI technique and the results are discussed. From the results, the size of the wall thinning defect can also be measured approximately.

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Preliminary Study of the Measurement of Foreign Material in Galvanic Corrosion Using Laser Ultrasonic

  • Hong, Kyung Min;Kang, Young June;Park, Nak Kyu;Choi, In Young
    • Journal of the Optical Society of Korea
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    • v.17 no.4
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    • pp.323-327
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    • 2013
  • A laser ultrasonic inspection system has the advantage of nondestructive testing. It is a non-contact mode using a laser interferometer to measure the vertical displacement of the surface of a material caused by the propagation of ultrasonic signals with the remote ultrasonic generated by laser. After raising the ultrasonic signal with a broadband frequency range using a pulsed laser beam, the laser beam is focused to a small point to measure the ultrasonic signal because it provides an excellent measurement resolution. In this paper, foreign materials are measured by a non-destructive and non-contact method using the laser ultrasonic inspection system. Mixed foreign material on the corroded part is assumed and the laser ultrasonic experiment is conducted. An ultrasonic wave is generated by pulse laser from the back of the specimen and an ultrasonic signal is acquired from the same location of the front side using continuous wave laser and Confocal Fabry-Perot Interferometer (CFPI). The characteristic of the ultrasonic signal of existing foreign material is analyzed and the location and size of foreign material is measured.

Determination of Knoop Indentation Stress Conversion Factors for Measuring Equibiaxial Residual Stress (인장 및 압축 등방 잔류응력 측정을 위한 누프 압입시험의 응력환산계수 결정)

  • Jeong, Min Jae;Kim, Young-Cheon
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.484-490
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    • 2021
  • Instrumented indentation testing has been widely used for residual stress measurement. The Knoop indentation is mainly selected for determining anisotropic mechanical properties and non-equibiaxial residual stress. However, the measurement of equibiaxial stress state and compressive residual stress on a specimen surface using Knoop indentation is neither fully comprehended nor unavailable. In this study, we investigated stress conversion factors for measuring Knoop indentation on equibiaxial stress state through indentation depth using finite element analysis. Knoop indentation was conducted for specimens to determine tensile and compressive equibiaxial residual stress. Both were found to be increased proportionally according to indentation depth. The stress field beneath the indenter during each indentation test was also analyzed. Compressive residual stress suppressed the in-plane expansion of stress field during indentation. In contrast, stress fields beneath the indenter developed diagonally downward for tensile residual stress. Furthermore, differences between trends of stress fields at long and short axes of Knoop indenter were observed due to difference in indenting angles and the projected area of plastic zone that was exposed to residual stress.

Development of Wall-Thinning Evaluation Procedure for Nuclear Power Plant Piping-Part 1: Quantification of Thickness Measurement Deviation

  • Yun, Hun;Moon, Seung-Jae;Oh, Young-Jin
    • Nuclear Engineering and Technology
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    • v.48 no.3
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    • pp.820-830
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    • 2016
  • Pipe wall thinning by flow-accelerated corrosion and various types of erosion is a significant and costly damage phenomenon in secondary piping systems of nuclear power plants (NPPs). Most NPPs have management programs to ensure pipe integrity due to wall thinning that includes periodic measurements for pipe wall thicknesses using nondestructive evaluation techniques. Numerous measurements using ultrasonic tests (UTs; one of the nondestructive evaluation technologies) have been performed during scheduled outages in NPPs. Using the thickness measurement data, wall thinning rates of each component are determined conservatively according to several evaluation methods developed by the United States Electric Power Research Institute. However, little is known about the conservativeness or reliability of the evaluation methods because of a lack of understanding of the measurement error. In this study, quantitative models for UT thickness measurement deviations of nuclear pipes and fittings were developed as the first step for establishing an optimized thinning evaluation procedure considering measurement error. In order to understand the characteristics of UT thickness measurement errors of nuclear pipes and fittings, round robin test results, which were obtained by previous researchers under laboratory conditions, were analyzed. Then, based on a large dataset of actual plant data from four NPPs, a quantitative model for UT thickness measurement deviation is proposed for plant conditions.

Characteristics Evaluation on Welding Metal Zones Welded with Inconel 625 Filler Metal to Cast Steel for Piston Crown Material

  • Jeong, Jae-Hyun;Moon, Kyung-Man;Lee, Sung-Yul;Lee, Myeong-Hoon;Baek, Tae-Sil
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.5
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    • pp.542-547
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    • 2015
  • Since the oil price has been significantly jumped for several years, a heavy oil of low quality has been mainly used in the diesel engine of the merchant ship. Thus, a combustion chamber of the engine has been often exposed to severely corrosive environment more and more because temperature of the exhaust gas of the combustion chamber has been getting higher and higher with increasing of using the heavy oil of low quality. As a result, wear and corrosion of the engine parts such as exhaust valve, piston crown and cylinder head surrounded with combustion chamber are more serious compared to the other parts of the engine. Therefore, an optimum repair welding for these engine parts is very important to prolong their lifetime in a economical point of view. In this study, Inconel 625 filler metal were welded with GTAW method in the cast steel which would be generally used with piston crown material. And the corrosion properties of weld metal, heat affected and base metal zones were investigated using electrochemical methods such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% $H_2SO_4$ solution. The weld metal and base metal zones exhibited the highest and lowest values of hardness respectively. Furthermore, the corrosion current density of the weld metal zone revealed the lowest value, having the highest value of hardness. The corrosive products with red color and local corrosion like as a pitting corrosion were considerably observed at the base metal zone, while these morphologies were not wholly observed in the weld metal zone. In particular, the polarization characteristics such as impedance, polarization curve and cyclic voltammogran associated with corrosion resistance property were well in good agreement with each other. Consequently, it is suggested that the mechanical and corrosion characteristics of the piston crown can be predominantly improved by repair welding method using the Inconel 625 electrode.

ELECTROCHEMICAL STUDY ON THE CORROSION BEHAVIOUR OF DENTAL AMALGAM IN ARTIFICIAL SALIVA (인공타액에서 아말감의 부식거동에 관한 전기화학적 연구)

  • Kim, Yeoung-Nam;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.13 no.2
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    • pp.221-235
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    • 1988
  • The purpose of this study was to observe characteristic properties through the polarization curves and EMPA images from 4 different types of amalgam obtained by using the potentiostats (EG & G PARC) & EPMA (Jeol JSM-35), to investigate the degree of corrosion of each phase of amalgam on the oxidation peak, and to identify corrosion products from the corroded amalgam by use of X-ray diffractometer(Rigaku). After each amlgam alloy and Hg were triturated as the direction of the manufacturer by means of the mechanical amalgamator(Shofu), the triturated mass was inserted into the cylindrical metal mold which was 12mm in diameter and 10mm in height and was condensed by means of routine manner. The specimen was removed from the mold and stored at room temperature for about 7 days. The standard surface preparation was routinely carried out. Anodic polarization measurement was employed to compare the corrosion behaviours of the amalgams in 0.9% saline solution(pH6.8~7.0) and artificial saliva (pH6.8~7.0) at $37^{\circ}C$. The open circuit potential was determined after 30 minutes' immersion of specimen in electrolyte and the potential scan was begun at the potential of 100mV cathodic from the corrosion potential. The scan rate was 1mV/sec and the surface area of amalgam exposed to the solution was 0.64$cm^2$ for each specimen. All the potentials reported are with respect to a saturated calomel electrode (SCE). EPMA images on the determined oxidation peaks of each amalgam in artificial saliva were observed. X-ray diffraction patterns of each sample were recorded before and after polarization in artificial saliva (Aristaloy, Caulk Spherical, Dispersalloy and Tytin: at +770mV, +585mV, +8.10m V and +680m V respectively) by use of a recording diffractometer. Nickel filtered Cu $K_{{\alpha}_1}$ radiation was used and sample was scanned at $4^{\circ}(2{\theta})/min.$ from $25^{\circ}$ to $80^{\circ}$. The following results were obtained. 1. Oxidation peak potential in artificial saliva shifted to more anodic direction than that in saline solution. 2. The corrosion potential of high copper amalgam was more anodic than the potential of low copper amalgam. 3. The current density was lower in artificial saliva than in saline solution. 4. One of the corrosion products, AgCl was identified by X-ray diffraction analysis. 5. ${\gamma}_2$ phase was the most susceptible to corrosion and e phase was stable in low copper amalgam and ${\eta}$' phase and Ag-Cu eutectic were susceptible to corrosion in high copper amalgam.

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A Study on the Measurement of Foreign Material in Dissimilar Metal Contact Using Pulse Laser and Confocal Fabry-Perot Interferometer (펄스 레이저와 CFPI를 이용한 이종금속 접촉부의 이물질 측정에 관한 연구)

  • Hong, Kyung-Min;Kang, Young-June;Park, Nak-Kyu
    • Journal of the Korean Society for Nondestructive Testing
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    • v.33 no.2
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    • pp.160-164
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    • 2013
  • A laser ultrasonic inspection system is a non-contact inspection device which generates and measures ultrasonics by using laser beam. A laser ultrasonic inspection system provides a high measurement resolution because the ultrasonic signal generated by a pulse laser beam has a wide-band spectrum and the ultrasonic signal is measured from a small focused spot of a measuring laser beam. In this study, galvanic corrosion phenomenon was measured by non-destructive and non-contact method using the laser. The case of mixed foreign material on the part of corrosion was assumed and laser ultrasonic experiment was conducted. Ultrasonic was generated by pulse laser from the back side of the specimen and ultrasonic signal was acquired from the same location of the front side using continuous wave laser and Confocal Fabry-Perot Interferometer(CFPI). The characteristic of the ultrasonic signal of exist foreign material part was analyzed and the location and size of foreign material was measured.

A Study on Characteristic Analysis of Shaft Electromotive Force in SAEYUDAL (새유달호 축기전력의 특성 분석에 관한 연구)

  • Ahn, Byong-Won;Im, Myeong-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.1
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    • pp.28-31
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    • 2015
  • Electromotive forces (EMF) are generated by electrical equipment and engine shafting with a number of reasons. The shaft and bearing which is insulated by lubricating oil acts as a condenser, being able to store this EMFs. The electromotive force on the hull and shaft, with very few exceptions, has anode voltage on it. Electrical spark of the anode voltage on the shaft may lead to corrosion. Hence, in order to prevent ship's shaft and propeller corrosion, shaft grounding system are installed and operated. The shaft EMF voltage measurement methods was measured using 24bit 2 channels A/D converter of NI company and Labview software. 1 channel was propeller shaft's voltage and the other was M/E engine rpm gauge. In this paper, the generated electromotive force was analyzed and modeled with result of the analysis. As a result, the main shaft's electromotive force was in direct proportion to the main engine's revolution. However, over the specific R.P.M., it was reduced gradually. In addition, higher electromotive force on the shaft was identified during engine's ahead direction than the astern direction. The generated electromotive force is only minor compared to the shaft grounding system.

Simulation of Neutron irradiation Corrosion of Zr-4 Alloy Inside Water Pressure reactors by Ion Bombardment

  • Bai, X.D.;Wang, S.G.;Xu, J.;Chen, H.M.;Fan, Y.D.
    • Journal of the Korean Vacuum Society
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    • v.6 no.S1
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    • pp.96-109
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    • 1997
  • In order to simulate the corrosion behavior of Zr-4 alloy in pressurized water reactors it was implanted (or bombarded) with 190ke V $Zr^+\; and \;Ar^+$ ions at liquid nitrogen temperature and room temperature respectively up to a dose of $5times10^{15} \sim 8\times10^{16} \textrm{ions/cm}^2$ The oxidation behavior and electrochemical vehavior were studied on implanted and unimplanted samples. The oxidation kinetics of the experimental samples were measured in pure oxygen at 923K and 133.3Pa. The corrosion parameters were measured by anodic polarization methods using a princeton Applied Research Model 350 corrosion measurement system. Auger Electron Spectroscopy (AES) and X-ray Photoelectric Spectroscopy (XPS) were employed to investigate the distribution and the ion valence of oxygen and zirconium ions inside the oxide films before and after implantation. it was found tat: 1) the $Zr^+$ ion implantation (or bombardment) enhanced the oxidation of Zircaloy-4 and resulted in that the oxidation weight gain of the samples at a dose of $8times10^{16}\textrm{ions/cm}^2$ was 4 times greater than that of the unimplantation ones;2) the valence of zirconium ion in the oxide films was classified as $Zr^0,Zr^+,Zr^{2+},Zr^{3+}\; and \;Zr^{4+}$ and the higher vlence of zirconium ion increased after the bombardment ; 3) the anodic passivation current density is about 2 ~ 3 times that of the unimplanted samples; 4) the implantation damage function of the effect of ion implantation on corrosion resistance of Zr-4 alloy was established.

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Resistance of Cementitious Binders against a Fall in the pH at Corrosion Initiation

  • Song, Ha-Won;Jung, Min-Sun;Ann, Ki Yong;Lee, Chang-Hong
    • Corrosion Science and Technology
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    • v.8 no.3
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    • pp.110-115
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    • 2009
  • At the onset of corrosion of steel in concrete, hydrogen ions usually evolve in the process of electrochemical reaction, thereby decreasing the pH of the pore solution, which can be buffered by cement hydration products, as being representatively illustrated by calcium hydroxide. Hence, a fall in the pH is dependent on properties of cement hydration (i.e. hydration products and degree of hydration). The present study tested acid neutralization capacity (ANC) of cementitious binders of OPC(Ordinary Portland Cement), 30% PFA(Pulverized Fuel Ash), 60% GGBS(Ground Granulated Blast Furnace Slag), 10% SF(Silica Fume) to quantify the resistance of cement matrix to a pH fall. Cement pastes were cast at 0.4 of a free W/C ratio with 1.5% chlorides by weight of binder in cast. Powder samples obtained crushed and ground specimen after 200 days of curing were diluted in still water combined with different levels of 1M nitric acid solution, ranging from 0.5 to 20 mol/kg. Then, the pH of diluted solution was monitored until any further change in the pH did not take place. It was seen that the pH of the diluted solution gradually decreased as the molar amount of nitric acid increased. At some particular values of the pH, however, a decrease in the pH was marginal, which can be expressed in the peak resistances to a pH fall in the ANC curve. The peaks occurred at the variations in the pH, depending on binder type, but commonly at about 12.5 in the pH, indicate a resistance of precipitated calcium hydroxide. The measurement of water soluble chloride at the end of test showed that the amount of free chloride was significantly increased at the pH corresponding to the peaks in the ANC curve, which may reflect the adsorption of hydration products to chlorides.