• Journal of the Korean institute of surface engineering
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• v.36 no.1
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• pp.9-13
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• 2003

Plasma polymerized organic thin films were deposited on Si(100), glass and metal substrates at $25∼100 ^{\circ}C$ using thiophene and toluene precursors by PECVD method. In order to compare physical and electrochemical properties of the as-grown thin films, the effects of the RF plasma power in the range of 30∼100 W and deposition temperature on both corrosion protection efficiency and physical properties were studied. We found that the corrosion protection efficiency ($P_{k}$), which is one of the important factors for corrosion protection in the interlayer dielectrics of microelectronic devices application, was increased with increasing RF power. The highest $P_{k}$ value of plasma polymerized toluene film (85.27% at 70 W) was higher than that of the plasma polymerized thiophene film (65.17% at 100 W), indicating inhibition of oxygen reduction. The densely packed and tightly interconnected toluene film could act as an efficient barrier layer to the diffusion of molecular oxygen. The result of contact angle measurement showed that the plasma polymerized toluene films have more hydrophobic surface than those of the plasma polymerized thiophene films.

• Nuclear Engineering and Technology
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• v.54 no.12
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• pp.4481-4490
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• 2022

In this study, a new rupture disk corrosion test (RDCT) method was developed for real-time detection of stress corrosion cracking (SCC) initiation of Alloy 600 in a primary water environment of pressurized water reactors. In the RDCT method, one side of a disk specimen was exposed to a simulated primary water at high temperature and pressure while the other side was maintained at ambient pressure, inducing a dome-shaped deformation and tensile stress on the specimen. When SCC occurs in the primary water environment, it leads to the specimen rupture or water leakage through the specimen, which can be detected in real-time using a pressure gauge. The tensile stress applied to the disk specimen was calculated using a finite element analysis. The tensile stress was calculated to increase as the specimen thickness decreased. The SCC initiation time of the specimen was evaluated by the RDCT method, from which result it was found that the crack initiation time decreased with the decrease of specimen thickness owing to the increase of applied stress. After the SCC initiation test, many cracks were observed on the specimen surface in an intergranular fracture mode, which is a typical characteristic of SCC in the primary water environment.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.4
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• pp.2391-2400
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• 2015

Weather proof steels are used for steel bridges due to its high corrosion resistance under atmospheric conditions. However, instead of forming stabilized rust layers, general rust occurs on weather proof steels under high humidity condition close to seawater or shady places. In Japan, therefore, they perform rust stabilization treatment instead of unpainted treatment due to severe atmospheric conditions. However, most of domestic weather proof steels were constructed unpainted in the form of closed box-girder, which makes the periodical repetition of dry and wet hard to occur. For the steel bridges constructed on the Han river, the evaporation of water, dew condensation due to temperature change, and stagnant water due to rain affect harmfully on the formation of passive film on weather proof steels. Thus, in this research, in order to analyze corrosion properties inside the closed box-girder for the unpainted weather proof steel bridge in the waterworks safety zone, multiple ways of analysis such as observation with eyes, cellophane-tape test, steel thickness measurement, surface corrosion potential measurement, electron microscope analysis, and X-ray diffraction analysis of the rust were performed. As a result, unstable rust layer was observed inside the closed box-girder, and severe corrosion was observed on the top and bottom of the flanges due to the effects of stagnant water caused by rain, dew condensation, and de-icing materials.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.2
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• pp.191-199
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• 2021

In this study, the correlation between the influencing factors on corrosion and Half Cell Potential(HCP) measurement was analyzed considering the three levels of W/C ratio, cover depth, and chloride concentration. The HCP increased with enlarged cover depth, so it was confirmed that the increment of cover depth was effective for control of corrosion. Based on the criteria, the case of 60mm cover depth showed excellent corrosion control with under -200mV, indicating increase of cover depth is an effective method for reducing intrusion of external deterioration factors. When fresh water was injected to the upper part of specimens, very low level of HCP was monitored, but in the case that concentrations of chloride were 3.5% and 7.0%, HCP dropped under -200mV. In addition, the case with high volume of unit binder showed lower HCP measurement like increasing cover depth. Multiple regression analysis was performed to evaluate the correlation between the corrosive influence factors and HCP results, showing high coefficient of determination of 0.97. However, there were limitations such as limited number of samples and measuring period. Through the additional corrosion monitoring and chloride content evaluation after dismantling the specimen, more reasonable prediction can be achieved for correlation analysis with relevant data.

• Analytical Science and Technology
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• v.14 no.4
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• pp.364-370
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• 2001

The corrosion behaviors of reinforcing steels were investigated under chloride ion contained in cement mortar including gypsum by the implementation of half cell potential measurement, EPMA analysis, exterior features, weight loss and extraction experiment. The acceleration test equipment accelerated corrosion of mild steel bar in a short period of time. From observing the exterior features and weight loss, we could evaluate the measure of corrosion. Also, from the extraction experiment of ${SO_4}^{2-}$ with $Cl^-$ ions contained in the ceramic mortar, we concluded that ${SO_4}^{2-}$ ion affected more on the corrosion mechanism in comparison to pH.

• The Journal of the Korea Contents Association
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• v.15 no.8
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• pp.397-407
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• 2015

Concrete is a attractive construction material, however durability problem occur due to steel corrosion, which leads propagation to structural safety problem. The recently developed FRP (Fiber Reinforced Plastic) Hybrid Bar has an engineering merit of both structural steel and FRP. Accelerated corrosion test for RC (Reinforced Concrete) samples with normal steel and FRP Hybriud Bar are performed and their flexural capacity is evaluated. Furthermore UV(Ultrasonic Velocity) measurement is attempted for analysis of variation of UV due to corrosion condition. After corrosion test, there is no significant reduction in RC beam with FRP hybrid bar but 11.5% of reduction in the case of normal steel is evaluated with 3.3% of UV reduction. For commercial production of FRP hybrid bar, bond strength evaluation through long-term submerged corrosion is required.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.22 no.4
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• pp.241-247
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• 2010

Corrosion of steel embedded in concrete is one of the foremost factors that affect the durability of concrete structures in marine environments. This paper presents an application technique of anode-ladder-system to evaluate corrosion behaviours of marine concrete structure. In order to investigate the behaviours quantitatively, the measurement of potential and current was performed on the concrete elements subjected to the penetration and diffusion of chloride ions. The main variable was the heights from seawater level; namely 3.7, 6.0 and 8.2 m. As a result of the monitoring, it was found that the corrosion characteristics differently behaved with the increasing height. Additionally, through migration test, the relationship between compressive strength of concrete and diffusivity of chloride ions was observed. It is suggested, ultimately, that in order to reduce or mitigate steel corrosion, both appropriate concrete cover depth and high-quality of concrete in early ages should be done.

• Journal of the Korean institute of surface engineering
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• v.50 no.4
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• pp.251-258
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• 2017

This study was carried out with solution temperature variables of $75^{\circ}C$ and $90^{\circ}C$ for STS 304, which is a nuclear equipment material, in order to determine the corrosion damage behavior in chemical decontamination process using permanganic acid and oxalic acid. Then electrochemical polarization experiment, weight loss measurement, surface morphology observation and surface damage depth were measured every cycle of the decontamination process to analyze the degree of corrosion damage. As a result, the corrosion current density, weight loss, and surface damage increased as the decontamination process cycle increased, and the corrosion damage of STS 304 tended to increase. Few ${\mu}m$ pitting damage was observed on the surface observation. In 5 cycle, the elongated wormhole-type pitting damage appeared, leading to relatively large surface damage. However, there was no significant difference in the degree of surface damage resulting from the increase in the temperature of the chemical decontamination solution.

• Journal of Korea Foundry Society
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• v.35 no.6
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• pp.155-162
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• 2015

The effect of Sr addition on mechanical and bio-corrosion properties of as-cast Mg-3wt.%Zn-0.5wt.%Ca-xwt.%Sr (x = 0.3, 0.6, 0.9) alloys were examined for application as biodegradable implant material. The microstructure, mechanical properties and corrosion resistance of the as-cast Mg-Zn-Ca-Sr alloys were characterized by using optical microscopy, scanning electron microscopy, tensile testing and electrochemical measurement in Hank's solution. The as-cast alloys contained ${\alpha}$-Mg and eutectic $Ca_2Mg_6Zn_3$ phases, while the alloys contained ${\alpha}$-Mg, $Ca_2Mg_6Zn_3$ and Mg-Zn-Ca-Sr intermetallic compound when the Sr addition was more than 0.3 wt.%. The yield strength, ultimate tensile strength and elongation increased with the increasing of Sr content up to 0.6 wt.% but decreased in the 0.9 wt.% Sr-added alloy, whereas the corrosion resistance of 0.3 wt.% Sr-added alloy was superior to other alloys. It was thought that profuse Mg-Zn-Ca-Sr intermetallic compound deteriorated both the mechanical properties and corrosion resistance of the as-cast alloy.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.40 no.5
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• pp.974-980
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• 2015

Arc thermal spray coating using Al-3%Mg thermal spray wire was carried out to prevent steel from corrosion damage under the marine environment. Post-sealing was applied to Al-3%Mg spray coating treatment using organic/inorganic composite ceramics in order to improve the corrosion resistance of the as-sprayed coating. The results of various electrochemical experiments with sealing treatment indicated that the improvement in corrosion resistance was observed due to low current density in all applied potential range during anodic and cathodic polarization experiments. Futhermore, the natural potential measurement exhibited severe potential fluctuation due to influence of micro-crack presence on the surface of sealed thermal spray coating layer. In addition, the sealed layer was easily eliminated during anodic polarization. Nevertheless, Al-3%Mg spray coating layer improved corrosion resistance by sealing treatment because the sealed coating efficiency was determined to be 92.11%, indicating the exterior environment barrier effect which is based on the Tafel analysis.