• Title/Summary/Keyword: Corrosion characteristics

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The Magnetic Properties of Co-Ni-Fe-N Soft Magnetic Thin Films

  • Kim, Y. M.;Park, D.;Kim, K. H.;Kim, J.;S. H. Han;Kim, H. J.
    • Journal of Magnetics
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    • v.5 no.4
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    • pp.120-123
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    • 2000
  • Co-Ni-Fe-N thin films were fabricated by a $N_2$ reactive rf magnetron sputtering method. The nitrogen partial pressure ($P_{N2}$) was varied in the range 0~10% . As$P_{N2}$ increases in this range, the saturation magnetization $B_s$ linearly decreases from 19.8 kG to 14 kG and the electrical resistivity ($\rho$) increases from 27 to 155 $\mu\Omegacm$. The coercivity $H_c$ exhibits the minimum value at 4% $P_{N2}$. The magnetic anisotropy fields ($H_k$) are in the range of 20$\sim$50 Oe. High frequency characteristics of $(Co_{22.2}Ni_{27.6}Fe_{50.2})_{100-x}N_x$ films are excellent in the range of 3$\sim$5% of $P_{N2}$. In particular, the effective permeability of the film fabricated at 4% $P_{N2}$ is 800, which is maintained up to 600 MHz. This film also shows Bs of 17.5 kG, $H_c$/ of 1.4 Oe, resistivity of 98$\mu\Omegacm$ and $H_k$ of about 25 Oe. Also, the corrosion resistance of $(Co_{22.2}Ni_{27.6}Fe_{50.2})_{100-x}N_x$ films was imp roved with increasing N concentration.

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Electrical resistivity and capillarity of self-compacting concrete with incorporation of fly ash and limestone filler

  • Silva, Pedro;de Brito, Jorge
    • Advances in concrete construction
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    • v.1 no.1
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    • pp.65-84
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    • 2013
  • Electrical resistivity is a property associated with both the physical and chemical characteristics of concrete. It allows the evaluation of the greater or lesser difficulty with which aggressive substances penetrate the concrete's core before the dissolution of the passive film process and the consequent reinforcement's corrosion begin. This work addresses the capillary absorption of self-compacting concrete (SCC) with various types and contents of additions, correlating it with its electrical resistivity. To that effect, binary and ternary mixes of SCC were produced using fly ashes (FA) and limestone filler (LF). A total of 11 self-compactable mixes were produced: one with cement (C) only; three with C + FA in 30%, 60% and 70% substitution ratios; three with C + LF in 30%, 60% and 70% substitution ratios; four with C + FA + LF in combinations of 10-20%, 20-10%, 20-40% and 40-20% substitution ratios, respectively; and four reference mixes according to the LNEC E 464 specification, which refers to the NP EN 206-1 norm. The evaluation of the capillarity of the mixes produced was made through the determination of the water absorption by capillarity coefficient according to the LNEC E 393 specification. The electrical resistivity was evaluated using the European norm proposal presented by the EU-Project CHLORTEST (EU funded research Project under 5FP GROWTH programme) and based on the RILEM TC-154 EMC technical recommendation. The results indicate that SCC's capillarity is strongly conditioned by the type and quantity of the additions used. It was found that FA addition significantly improves some of the properties studied especially at older ages.

The Selection of Optimum Measurement Method of Antimicrobial Activity and Constituent Phase of Yuggi Alloy according to Heat Treatment Condition (유기합금의 열처리조건에 따른 구성상의 제어와 최적 항균특성 측정방법의 선정)

  • Park, Kyu-Ha;Hwang, Dae Youn;Son, Hong-Joo;Choi, Ji Woong;Kim, Hye Sung
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.5
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    • pp.233-238
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    • 2021
  • The mechanical, anti-tarnishing, and corrosion characteristics of Yuggi (Cu-22wt%Sn) alloy are greatly affected by fraction of constituent phases according to heat treatment method. The Yuggi heat-treated at 750℃ has a β1' phase of 98% or more, which is a high-temperature disordered beta phase, on the other hand, cast Yuggi that Sn is solid-solutioned into Cu consists with α-phase over 60v/o. This difference of constituent phases of Yuggi may cause a difference in dissolution of Cu under antimicrobial test condition. Nonetheless, few studies have been conducted on the effect of fraction of constituent phases and constituent phases in antimicrobial activity. In addition, few studies have also been conducted on the suitable method measuring the antimicrobial activity of Yuggi. Hence, the purpose of this study is to provide an optimum measurement method of antimicrobial activity, and to evaluate quantitatively the effect of constituent phases on antimicrobial activity.

Review on the oxidation stability of biodiesel (바이오디젤의 산화 안정성 특성에 관한 고찰)

  • Lee, Mi-Eun;Hwang, In-Ha;Kim, Jae-Kon;Na, Byung-Ki
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1013-1030
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    • 2018
  • Biodiesel is a fuel produced in the form of a fatty acid methyl ester by using raw materials such as animal fat, vegetable oil and its by-products, and is being seen as a biofuel that can replace petroleum energy. However unsaturated fatty acid methyl esters in biodiesel causes to oxidize during storage and distribution, resulting in poor fuel quality and corrosion of vehicle engine components. In this study, the influence of quality and oxidation characteristics of biodiesel on the oxidation stability is investigated and the evaluation method related it is described. We also propose a method to improve the drawback of oxidation stability in biodiesel.

Convergence Study on FTO Film Etchant (FTO 필름 식각액에 관한 융합연구)

  • Han, Doo-Hee;Yang, Ui-Dong
    • Journal of Convergence for Information Technology
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    • v.8 no.6
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    • pp.43-48
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    • 2018
  • An etchant capable of forming a circuit in an FTO film that can replace ITO, which depends on full imports, was prepared. The etching solution is composed of 1 to 30% by weight of fluoride, 1 to 20% by weight of acid, 0.5 to 5% by weight of surfactant, 5 to 20% by weight of solvent, 0.5 to 10% by weight of corrosion inhibitor and the balance of water. This etchant can be etched using a dry film, thereby reducing the cost, and is free from bubbles and residue of the etchant. The characteristics of the etchant were etched in a time of 2 minute with a 100 nm thick FTO, and the etchant temperature was maintained at $50^{\circ}C$. An undercut of -0.00364% was obtained when put into a 2 minute etching solution. No harmful substances such as Cd, Pb, Hg and Cr components were measured. The use of FTO in Korea where rare earths do not exist can achieve localization and import substitution effect.

A Study on Coating Film Thickness Measurement in vehicle Using Eddy Current Coil Sensor (와전류 코일 센서를 통한 차량용 코팅막 측정에 관한 연구)

  • Park, Hwa-Beom;Kim, Young-Kil
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.23 no.9
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    • pp.1131-1138
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    • 2019
  • The importance of coatings has been increasing for different purposes such as prevention of static electricity of auto parts or products, improvement of abrasion and corrosion resistance, and enhancement of esthetics. As a method for measuring the thickness of a coating film, a contact method with probe is commonly used. However, it is problematic that accuracy of the sensor is degraded due to sensor output distortion or load phenomenon, which is caused by a change in magnetic permeability of the core. In this study, we propose a method to reduce the measurement error of the coating film by applying the optimized circuit design and the thickness measurement algorithm to the problems caused by the nonlinear characteristics. The tests result which have been taken with different thickness coating samples show that the measurement accuracy is within ${\pm}2%$.

Comparison of stress distribution in bone and implant-supported dental prosthesis with zirconia and titanium implants: a 3-dimensional finite element analysis (지르코니아 및 티타늄 임플란트를 사용한 지지골 및 임플란트 유지 수복물의 응력 분포 비교: 3차원 유한 요소 분석)

  • Hong, Min-Ho
    • Journal of Technologic Dentistry
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    • v.42 no.4
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    • pp.348-354
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    • 2020
  • Purpose: Zirconia is differentiated from other ceramics because of its high resistance to corrosion and wear, excellent flexural strength (900~1400 MPa), and high hardness. Dental zirconia with proven mechanical/biological stability is suitable for the manufacture of implants. However, there are limited in vivo studies evaluating stress distribution in zirconia compared with that in titanium implants and studies analyzing finite elements. This study was conducted to evaluate the stress distribution of the supporting bone surrounding zirconia and titanium implants using the finite element analysis method. Methods: For finite element analysis, a single implant-supported restoration was designed. Using a universal analysis program, eight occlusal points were set in the direction of the occlusal long axis. The occlusal load was simulated at 700 N. Results: The zirconia implant (47.7 MPa) von Mises stress decreased by 5.3% in the upper cortical bone compared with the titanium implant (50.2 MPa) von Mises stress. Similarly, the zirconia implant (20.8 MPa) von Mises stress decreased by almost 4% in the cancellous bone compared with the titanium implant (21.7 MPa) von Mises stress. The principal stress in the cortical and cancellous bone exhibited a similar propensity to von Mises stress. Conclusion: In the supporting bone, the zirconia implant is able to reduce bone resorption caused by mechanically transferred stress. It is believed that the zirconia implant can be a potential substitute for the titanium implant by reinforcing aesthetic characteristics and improving stress distribution.

Microstructural Characteristics of Oxidation Resistant Cr-Si-Al alloys in Cast State and after High Temperature Heating (내산화성 Cr-Si-Al합금의 주조상태 및 고온가열 후의 미세조직 특성)

  • Kim, Jeong-Min;Kim, Chae-Young;Yang, Won-Chul;Park, Joon-Sik
    • Korean Journal of Materials Research
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    • v.31 no.3
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    • pp.156-161
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    • 2021
  • Cr-Si based alloys are not only excellent in corrosion resistance at high temperatures, but also have good wear resistance due to the formation of Cr3Si phase, therefore they are promising as metallic coating materials. Aluminum is often added to Cr-Si alloys to improve the oxidation resistance through which stable alumina surface film is formed. On the other hand, due to the addition of aluminum, various Al-containing phases may be formed and may negatively affect the heat resistance of the Cr-Si-Al alloys, so detailed investigation is required. In this study, two Cr-Si-Al alloys (high-Si & high-Al) were prepared in the form of cast ingots through a vacuum arc melting process and the microstructural changes after high temperature heating process were investigated. In the case of the cast high-Si alloy, a considerable amount of Cr3Si phase was formed, and its hardness was significantly higher than that of the cast high-Al alloy. Also, Al-rich phases (with the high Al/Cr ratio) were not found much compared to the high-Al alloy. Meanwhile, it was observed that the amount of the Al-rich phases reduced by the annealing heat treatment for both alloys. In the case of the high temperature heating at 1,400 ℃, no significant microstructural change was observed in the high Si alloy, but a little more coarse and segregated AlCr phases were found in the high Al alloy compared to the cast state.

Neuro PID Control for Ultra-Compact Binary Power Generation Plant (초소형 바이너리 발전 플랜트를 위한 Neuro PID 제어)

  • Han, Kun-Young
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.25 no.11
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    • pp.1495-1504
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    • 2021
  • An ultra-compact binary power generation plant converts thermal energy into electric power using temperature difference between heat source and cooling source. In the actual power generation environment, the characteristic value of the plant changes due to any negative effects such as environmental condition or corrosion of related equipment. If the characteristic value of the plant changes, it may lead to unstable output of the turbine in a conventional PID control system with fixed PID parameters. A Neuro PID control system based on Neural Network adaptively to adjust the PID parameters according to the change in the characteristic value of the plant is proposed in this paper. Discrete-time transfer function models to represent the dynamic characteristics near the operating point of the investigated plant are deduced, and a design strategy of the proposed control system is described. The proposed Neuro PID control system is compared with the conventional PID control system, and its effectiveness is demonstrated through the simulation results.

Evaluation on De-Icing Salts Laden Environment of Road in Seoul (제설제에 노출된 서울시내 도로 시설물의 열화 환경 분석)

  • Yoon, In-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.1
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    • pp.1-9
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    • 2022
  • De -icing salts have been used commonly in areas where snow or ice is a seasonal safety hazard for roadway, however, the salts is one of main causes on serious deterioration of road infrastructures in crowded urban city like Seoul. In order to establish maintenance strategy of road infrastructures under de-icing salts laden environment, it is necessary to examine environmental characteristics and its response to the existing facilities. The purpose of this study is to evaluate the deterioration environment of road infrastructures. Additional purpose is to develop a design model and details for durability design of infrastructures under de-icing salts laden environment, considering mainly a build-up rate of surface chlorides. Concentration of external chloride solution and surface chloride content were calculated at the level of average de-icing salts for 5 years, ratio of auxiliary road of 17.5 to 30%, and effective exposure area to snow 50 to 80%. The chloride build-up rate was 0.073 ~ 0.077% / year and the maximum surface chloride content was calculated to be 2.2 ~ 2.31% by concrete wt. This study is expected to be used for establishing integrated strategy of road infrastructures, such as predicting chloride profiles or degree of chemical corrosion to exposure concrete.