• 제목/요약/키워드: Corrosion characteristic

검색결과 206건 처리시간 0.02초

MgNi계 수소흡장합금의 충방전특성 (Charge-discharge Characteristic of the Mg-Ni Hydrogen Storage Alloy System)

  • 오명학;정원섭;김인곤
    • 한국수소및신에너지학회논문집
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    • 제10권3호
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    • pp.177-184
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    • 1999
  • The charge-discharge characteristics of the $Mg_2Ni-x$ wt.%Nd (x = 0~3) electrodes were investigated. The electrodes were prepared by the mechanical grinding of the induction-melted $Mg_2Ni$ alloy powders with Ni and/or Nd using planetary ball mill apparatus. The discharge capacity of the $Mg_2Ni$ alloy increased with the increase in the nickel content. The electrode possessing 100 wt.% nickel powder showed the initial capacity of 760 mAh/g and the capacity decay with the cycle number was less than that of the 55 wt.% nickel powder. The Nd was added to this composition. It was found that the $Mg_2Ni-100$ wt.%Ni -0.2 wt.%Nd alloy showed an excellent charge-discharge cycle characteristics compared with the other reported Mg-Ni alloy system. The discharge capacity was 400 mAh/g after 70 cycles. Such an improved cycle life seems to be attributed to the improvement in the corrosion characteristics of the alloy. The anodic polarization curve of the $Mg_2Ni-100$ wt.%Ni-0.2 wt.%Nd alloy exhibited better passivating behavior than that of the $Mg_2Ni-100$ wt.%Ni.

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0.2% N을 첨가한 수퍼 2상 스테인리스강의 열처리 조건에 따른 특성 평가 - 제2보: 피로균열진전 거동 (Characteristic Evaluation according to Heat Treatment Conditions of Super Duplex Stainless Steel with Additive 0.2% N - Part 2: Fatigue Crack Propagation Behavior)

  • 안석환;강흥주;서현수;남기우;이건찬
    • 한국해양공학회지
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    • 제23권5호
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    • pp.79-84
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    • 2009
  • Super duplex stainless steel has long life in severe environments by showing the enough strength and corrosion resistance. Therefore, the fracture mechanics approach needs to support the structural strength integrity for the used material. In this study, fatigue crack propagation behavior was investigated to super duplex stainless steel with 0.2% nitrogen. The various volume fraction and distribution of austenite structure for applied specimen in test were obtained by changing the heat treatment temperature and cycle. From test results, fatigue crack propagation rate showed two kinds of tendency between da/dN and ${\Delta}K$ according to distribution of austenite structure and structure anisotropy.

자동차용 컨트롤 암 알루미늄 열간 압출을 위한 포트홀 금형개발 (Development of porthole Die on Aluminum Extrusion for the Automobile Control Arm)

  • 조영준;이상곤;오개희;박상우;이우식;장계원;김병민
    • 한국정밀공학회지
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    • 제24권4호
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    • pp.102-108
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    • 2007
  • The characteristic properties of aluminum, high strength stiffness to weight ratio, good formability, good corrosion resistence, and recycling potential make it the ideal candidate to replace heavier materials in the car to respond to the weight reduction demand within the automotive industry. In this paper, FE simulation was carried out to design an appropriate extrusion die for the automobile control arm. Based on the FE simulation result, a new die design has been proposed for uniform material flow in the cross section of extruded product. And then the welding pressure, extrusion load, and the tendency of mandrel deflection were estimated to verify high quality. In the extrusion experiment, it was possible to produce sound product without defects.

평판 예혼합 세라믹 버너의 분포판 변화에 따른 연소화염특성과 안정성 분석 (Combustion Characteristic and Stability of Flat Premixed Ceramic Burner with Different Porous Baffle Plates)

  • 이재영;이필형;박창수;박봉일;황상순
    • 한국연소학회지
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    • 제14권4호
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    • pp.7-16
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    • 2009
  • Porous metal plates (Metal fiber, muti-hole metal plate) using mainly in surface burner are known to have a corrosion and durability problem under high temperature condition. In this study, premixed flat flame with perforated ceramic tile of more durable cordierite material was examined with respect to combustion stability and emission. The flat premixed ceramic burner consists of perforated ceramic tile and various type of baffle plates to form stable surface flame. The results show that most stable flat flame is generated using baffle plate with open ratio of 0.193. In downward flat flame mode which is widely used in condensing boiler, CO is measured below 50ppm from equivalence ratio 0.755 to 0.765 and $NO_X$ is measured below 12ppm from equivalence ratio 0.75 to 0.79. It is also found that the range of blue flame in flame stability curve becomes wider with increasing heat capacity.

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$P_2O_5$의 첨가가 $B_2O_3-SiO_2$$Al_2O_3-SiO_2$ 박막의 화학적내구성에 미치는 영향 (Influence on the Chemical Durability of $B_2O_3-SiO_2$ and $Al_2O_3-SiO_2$ Thin Films at the Addition of $P_2O_5$)

  • 황규석;김병훈;최석진
    • 한국세라믹학회지
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    • 제30권8호
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    • pp.615-622
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    • 1993
  • In order to increase chemical durability of thin films in binary system B2O3-SiO2 and Al2O3-SiO2 on the slide glass by the dip-coating technique from TEOS(Tetraethyl Orthosilicate) and boric acid or aluminum nitrate, phosphoric acid(5~20mol%) was added, respectively. Corrosion of acid and alkali of samples treated with 1N, HCl, NaOH and distilled water at 10$0^{\circ}C$ for 15 minute, were measured IR transmittance and variance of transmittance at visible range. Surface structure of thin film was investigated with SEM and formation of crystal phase according to additiion of phosphoric acid was measrued with XRD. In Al2O3-SiO2 system, change of remarkable characteristic was not obtained at the addition of P2O5 but transmittance of thin film was decreased with addition of P2O5 in B2O3-SiO2 system.

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케이블 부재의 방청성능 특성에 관한 연구 (A Study on the Characteristic of Anti-corrosive Performance for the Cable Members)

  • 안승환;한상을;이상주
    • 한국공간구조학회:학술대회논문집
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    • 한국공간구조학회 2006년도 춘계 학술발표회 논문집 제3권1호(통권3호)
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    • pp.66-72
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    • 2006
  • 최근 건축물 및 교량 건설에 있어 연성 재료를 사용함으로써 구조형식의 다양화가 적극적으로 이뤄지고 있는 실정이다. 그 중 하나인 케이블 부재는 인장력의 도입으로 인한 전체 구조물의 강성을 증대시킬 수 있으며 흥미로운 연구 대상이라 할 수 있다. 국내에서도 건축물 또는 교량에 케이블 부재를 사용하는 시공 방법이 점차 증가하고 있고 그에 따라 설계 및 시공 기술도 장족의 발전을 이루고 있다 할 수 있다. 설계에 반영된 케이블 부재가 영구적으로 성능을 유지하기 위해서는 케이블 부재의 방청성능이 가장 중요하나, 이에 대한 기술자들의 인식이 다소 부족한 점을 느껴 본 논문에서 케이블의 방청성능에 대해 고찰 하고자 한다.

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금속 디알킬디티오인산염이 윤활유에 미치는 영향 (Effects of Metallaic Dialkyldithiophosphates on Lubricating Oil)

  • 문탁진;권오관
    • 대한화학회지
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    • 제23권1호
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    • pp.52-58
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    • 1979
  • 금속 디알킬디티오인산염은 윤활유의 산화방지 및 내마모 첨가제로 널리 사용되고 있다. 특히 아연 DDTP가 윤활유 첨가제로서 가장 많이 사용되고 있다. 1차 및 2차 알킬기를 가진 아연, 납, 주석 및 코발트 디알킬디티오인산염을 각각 합성하였다. 합성된 각각의 금속 디알킬디티오인산염에 대하여 윤활유에서의 산화안정성, 열안정성, 금속부식성 및 내마모성을 실험검토하였다. 실험결과, 코발트 DDTP가 크롬합금강에 미치는 내마모성은 다른 화합물에 비하여 극히 우수하였으며 또한 코발트 DDTP는 일정온도 이상에서는 다갈색으로부터 청색으로 변하며 온도의 환원과 더불어 색상도 환원되는 특이한 색상의 온도 감도변화 성질이 있는 것을 알았다. 또한 모든 금속 디알킬디티오인산염은 일정 유효산 농도에 도달되어야만 윤활유의 산화 방지작용을 개시한다는 결과를 얻었다.

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지상탱크의 부식감지를 위한 음향방출시험에서 발생한 전자기간섭신호의 특성 연구 (A Study on the Characteristics of Electronic Magnetic Interference(EMI) in Acoustic Emission Testing for Corrosion Detection of Ground Tank)

  • 김승대;정우광
    • 한국재료학회지
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    • 제17권5호
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    • pp.239-243
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    • 2007
  • The evaluation and comparison have been made for the EMI noise which was included in the signal from the sensors in the acoustic emission testing for the bottom plate of ground tank at full. The EMI signal has been classified into two types. One is the signal with very short AE count, and this signal possibly can be filtered by front end filter setting of the channel count with low level of 4 and high level of $10^8$. The other EMI signal occurred from CH 1, CH 3 and CH 10, and had high and constant duration with high energy and count (maximun duration > $10^5\;{\mu}s$), and has characteristic gradient of accumulation amplitude distribution. This signal should be removed in the AE signal evaluation by filtering, because this may affect to the total gradient.

기계적 혼합에 의한 플라즈마 용사용 ZrO2-Y2O3 분말의 제조 및 특성 (Fabrication and Characteristic of ZrO2-8%Y2O3 Powder for Plasma Spray Coating Manufactured by Mechanical Mixing Method)

  • 한진원;곽찬원;우기도
    • 한국재료학회지
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    • 제24권7호
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    • pp.357-362
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    • 2014
  • Thermal barrier coatings(TBCs) are being applied in many industrial fields such as thermal power generation, aviation and seasonal fields. $ZrO_2-Y_2O_3$(8%) thermal spray coating powders are commercially used as thermal-barrier coating materials to protect against oxidation and corrosion of heat-resistant alloys at elevated temperatures. Currently, $ZrO_2-Y_2O_3$(8%) thermal-spray powder is made using the industrial co-precipitation process, which is very complex and requires a lot of time. In this study, orthorhombic $ZrO_2$ and $Y_2O_3$ powders were fabricated by mechanical mixing, which is more economical than the co-precipitation process. A tetragonal, yttria-stabilized zirconia(YSZ) coating-layer was produced by plasma spraying, using orthorhombic $ZrO_2-Y_2O_3$(8%) powder. Our experimental results indicate that $ZrO_2-Y_2O_3$(8%) mixed powder can be used economically in industry because it is no longer necessary to make this powder by liquid and gas-phase methods.

세라믹 코팅이 기계 주조용 알루미늄합금(7075 T6)의 마찰ㆍ마모특성에 미치는 영향에 관한 연구 (A Study on the Influence of Ceramic Coating on Characteristics of Friction and Abrasion of Aluminum Alloy(7075 T6) Used in Mechanical Casting)

  • 류성기;정광조;로룡
    • 한국안전학회지
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    • 제18권3호
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    • pp.14-21
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    • 2003
  • This study deals with the influence of ceramic coating on characteristics of friction and abrasion of aluminum allot(7075 T6) used in mechanical casting. In this research, frictional wear characteristic of ceramic coating materials such as $A1_2O_3$, $Si_3N_4$, SiC was investigated using aluminum alloy(7075 T6) and stainless 403 cast iron under room temperature and normal air pressure. The coating layer was observed using SEM. The conclusions are as follows: 1) Friction coefficients of $A1_2O_3$, SiC and $Si_3N_4$ are obtained 0.63 0.56 and 0.54 respectively. 2) Abrasion resistance of stainless 403 cast iron with $Si_3N_4$ is the best among the ceramic coating materials. 3) Abrasion mechanism of aluminum alloy(7075 T6) coaled with ceramic material and stainless 403 cast iron is caused by brittle fracture. 4) Coating the ceramic material on the aluminum alloy(7075 T6) can effectively increase the antiwear, impact properties, and corrosion resistance.