• Economic and Environmental Geology
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• v.47 no.1
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• pp.71-85
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• 2014

To study biogeochemical characteristics and origin organic matter, sediment samples were taken from Site of 1249C and Stie 1251B of ODP Leg 204. Data of Rock-Eval, isotope, and element analysis generally indicate dominance of marine organic matter in sediments deposited under marine sedimentary environment. Only Rock-Eval data are somewhat different from those of others owing to under-maturation of organic matter. Samples of Site 1249C show high content of gas hydrate, whereas Site 1251B low content of gas hydrate in some intervals of the core. This result may be accounted to different location of two cores and presence of transportation passage (Horizon A, BSR 2) of thermogenic gas in the core, 1249 C. However, Site 1251B Located in the basin of low accumulation of gas hydrate is presumed to be limited in the gas hydrate production. Because not only transportation passage is limited to move thermogenic gas from the core, but also gas supply was not enough. Therefore, the biogenic gas that resulted from diagenesis of there sediment is superior.

• Journal of Environmental Science International
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• v.2 no.1
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• pp.43-49
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• 1993

Concentrations of sulfate and 6-values of sulfate, $({\delta}^{34}SO_4_){pw}$, dissolved In pore waters were measured from the sediment cores of the two different marine environments : deep northeast Pacific (57-1) and coastal Kyunggi Bay of Yellow Sea (57-2) . Sulfate concentration in pore waters decreases with depth at both cores, reflecting sulfate reduction in the sediment columns. However, much higher gradient of pore water sulfate at 57-2 than 57-1 indicates more rapid sulfate reduction at 57-2, because of high sedimentation rate at the coastal area compared to the deep-sea. The measured 6-values, $({\delta}^{34}SO_4_){pw}$, follow extremely well the predicted trend of the Rayleigh fractionation equation. The range of 26.756 to 61.35% at the coastal core 57-2 is not so great as that of 32.4$\textperthousand$ to 97.8$\textperthousand$ at the deep-sea core 57-1. Despite greater graclient of pore water sulfate at 57-2, the 6-values become lower than those of the deep- sea core 57-1. This inverse relation between the 6-values and the gradients of pore water sulfate could be explained by the combination of the two subsequent factors : the kinetic effect by which the residual pore water sulfate becomes progressively enriched with respect to the heavy isotope of $^{34}S$ as sulfate reduction proceeds, and the intrinsic formulation effect of the Rayleigh fractionation equation in which the greater becomes the fractionation factor, the more diminished values of $({\delta}^{34}SO_4_){pw}$ are predicted.

• Geophysics and Geophysical Exploration
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• v.15 no.2
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• pp.102-115
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• 2012

The purpose of this paper is to review several different methods calculating gas hydrate saturations. There are three methods using downhole log data, core data (including pressure core), and seismic velocity data. Archie's equation using electrical resistivity of downhole log data is widely used for saturation calculation. In this case, Archie's parameters should be defined accurately. And the occurrence types of gas hydrate significantly affect to saturation calculation. Thus saturation calculation should be carefully conducted. The methods using chlorinity and pressure core data are directly calculated from core sample. So far, the saturation calculated from pressure core gives accurate and quantitative values. But this method is needed much more time and cost. Thus acquisition of the continuous data with sediment depth is realistically hard. The recent several results show that the saturation calculated from resistivity data is the highest values, while the value calculated from pressure core is the lowest. But this trend is not always absolutely. Thus, to estimate accurate gas hydrate saturation, the values calculated from several methods should be compared.

• Economic and Environmental Geology
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• v.54 no.1
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• pp.151-160
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• 2021

2:1 clay minerals such as smectite incorporating ammonium were extracted to investigate the ammonium behavior and nitrogen isotope characteristics for two different sediment cores which were collected from shimmering sites on seafloor of the Wakamiko crater, southwestern Japan. Inorganic nitrogen contents in clay fraction were estimated by calibration curve based on consistently decreasing carbon and nitrogen ratio during the treatment to decompose organic materials, after removing inorganic carbon. The results show that the proportions of inorganic nitrogen for total nitrogen in clay fraction of SWS site(Core#1094MR: av. 18.2%) are higher than those in SES site(Core#1093MG: av. 11.5%). Relatively good crystallinity of the former suggests that exchangeable ammonium was transformed to non-exchangeable ammonium during more evolving diagenetic process. Nitrogen isotope variance of clay fraction(SES site: Core#1093MG: -4.4 ~ +0.2 ‰, av. -2.4 ‰; SWS site: Core#1094MR: -0.7 ~ +3.0 ‰, av. +1.5 ‰) during sequential decomposition of exchangeable ammonium suggests that heat flow derived from deep magma led to nitrogen isotope fractionation between dissolved ammonium and ammonia in the fluids involved in the formation of 2:1 clay mineral incorporating ammonium with local temperature variation.

• Ocean and Polar Research
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• v.24 no.4
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• pp.391-398
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• 2002

Trace organic contaminants in deep-sea sediments near Dokdo were analyzed. Total PAMs concentration ranged 14.8-314 ng/g dry weight and high molecular weight PAHs were dominant. The highest PAHs concentration was detected at A19 which located at Ulleung Basin. Most of organochlorines were under detection limit. Among the detected organochlorines, DDT compounds were dominant and followed by HCHs and HCB. Butyltin compounds and most of organophosphorus pesticides were not detected. Vertical distribution of PAHs showed typical sub-surface maximum and decreasing trends depending on depth. The highest PAHs concentration reached 454ng/g. Some organochlorines, DDT, HCH was detected and also showed decreasing trends. Other target organic pollutants were not detected in core sediments. Abnormally high level of PAHs concentration in A19 was discussed and the input sources were inferred to be the transport of sludge derived pollutant dumped at dumping site 'Byung' by deep current.

• Proceedings of the Korean Quaternary Association Conference
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• 2005.10a
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• pp.34-39
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• 2005

A 120-cm core recovered from Lake Hovsgol, the northern Mongolia provides evidence for climate variability since the Marine Isotope Stage 3, representing a sharp lithological change. The lowermost part of the core consists of diatom-barren calcareous silty clay without coarse sands, framboidal pyrite, and biogenic components deposited during the MIS 3. Following the last glacial maximum, in-situ moss is included in the sediments, as lake-level was retreated by cold and dry environment with low precipitation. The AMS radiocarbon ages of the plant fragments match a marked lithologic boundary between 14,060 and 14,325 $^{14}C$ yr BP. The contents of coarse sands abruptly increase, indicating probably wind-derived sandy dust or coarse grains contributed from floating icebergs. And abundant framboidal pyrite grains were deposited in an anoxic environment, as reflected by high accumulation of organic matters at a low lake stand. During the deglaciation, quantities of coarse sands, ostracod, shell fragments, framboidal pyrite, and diatom markedly varies by regional and global scale climate regimes. Some allochthonous coarse sands were probably ice-rafted debris derived from floating icebergs. A rapid increase in diatom productivity probably marked the onset of Bolling-Allerodwarming. Subsequent high concentration of framboidal pyrite probably represents a dry and cold condition, such as Younger Drays events. Consistent warm period with high precipitation at Holocene is documented by diatomaceous clayey ooze without framboidal pyrite, coarse sands, and ostracod.

• The Journal of the Acoustical Society of Korea
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• v.25 no.2E
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• pp.49-55
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• 2006

Compressional wave velocity (Vp), shear wave velocity (Vs), elastic and physical properties, and electrical resistivity for two core sediments obtained from Southeastern Yellow Sea Mud (SEYSM) were measured and computed. The sediments consist of homogeneous mud (mostly silt and clay) with shells and shell fragments. As a result, the mean grain size is uniform ($7.5-8.5{\Phi}$ throughout the core sediments. However, physical properties such as wet bulk density and porosity show slightly increasing and decreasing patterns with depth, compared to the mean grain size. The compressional (about 1475 m/s in average) and shear wave (about 60 m/s in average) velocities with depth accurately reflect the pattern of wet bulk density and porosity. Electrical resistivity is more closely correlated with compressional wave velocity than physical properties. The computed Vp/Vs and Poisson's ratios are relatively higher (more than 10) and lower (approximately 0.002) than Hamilton's (1979) data, respectively, suggesting the typical characteristics of soft and fully water-saturated marine sediments. Thus, the Vp/Vs ratio in soft and unconsolidated sediments is not likely sufficient to examine lithology and sediment properties. Relationships between the elastic constant and physical properties are correlated well. The elastic constants (Poisson's ratio, bulk modulus, shear modulus) given in this paper can be used to characterize soft marine sediments saturated with seawater.

• Journal of the korean society of oceanography
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• v.34 no.3
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• pp.151-166
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• 1999

Both benthic and planktonic foraminifera from Core 97-02 obtained in the northern East China Sea are quantitatively analyzed for reconstructing the paleocenography of late Quaternary. Since the earliest time of the core sediment (last not older than 18000 yr B.P.), the paleo-water depth has changed from less than 20 m to near 100 m at present, which is reflected by the benthic foraminiferal assemblages: before 14000 yr B.P., the water depth was shallower than 20 m; from 14000 to 7500 yr B.P., water depth was 20-50 m; and after 7500 yr B.P., water depth was 50-100 m. The foraminiferal fauna also disclose the water mass history: during the last glacial maximum, the water that dominated the study area might be the coastal water; at the end of the last glacial maximum(14000-9500 yr B.P.), the Yellow Sea Cold Water mostly affected this area; then it gave way to the Yellow Sea Warm Current after 9500 yr B.P.; and finally, the warm water has dominated this area since 9500 yr B.P. because of the westward shift and enhancement of the Kuroshio Current.

• Ocean and Polar Research
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• v.21 no.2
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• pp.149-157
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• 1999

Surface sediment samples collected from the eastern half of the Yellow Sea proper in 1998 were analyzed for polycyclic aromatic hydrocarbons (PAHs), ubiquitous pollutants. Total PAHs concentrations varied from 1.0 to $320.5ng\;g^{-1}$ dw. Relatively high concentrations of PAHs were found in the muddy central part of the Yellow Sea. Sedimentary total PAHs concentrations in the Yellow Sea proper were similar to those of Californian offshores and the central Mediterranean Sea, albeit an order of magnitude lower than the Yellow Sea nearshore areas. Phenanthene/Anthracene concentration ratio of PAHs in bottom sediments suggested that pyrolytic PAHs might be dominant over petrogenic ones in the eastern Yellow Sea. Downcore depth distributions of PAHs from the relatively undisturbed core samples of the central Yellow Sea showed decreasing PAHs concentrations with core depths and suggested that the Yellow Sea has been increasingly exposed to PAH for decades. Annual total PAH flux to these sediments was estimated to be $166{\mu}gm^{-2}yr^{-1}$ in the central part of the Yellow Sea for the recent decade.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.5 no.4
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• pp.320-334
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• 2000

Deep-sea surface sediment were analyzed for their geotechnical properties, and the sediment samples were collected with a multiple-corer from 31 stations along the track line (131$^{\circ}$30'W, 5-12$^{\circ}$N) in the northeast equatorial Paciflc. Most of the sediments from the northern part (8-12$^{\circ}$N) showed typical properties of siliceous sediments, whereas the southern part (5-6$^{\circ}$N) showed calcareous characteristics due to high biogenic carbonate productivity in the surface waters, where its water depth was shallower than the carbonate compensation depth (CCD: 4,400 m). Geotechnical properties changed sharply at the boundary of 7$^{\circ}$N. Calcareous sediments from the southern part had low water contents, low porosity, low shear strength, high bulk density and high specific grain density, whereas siliceous sediments from the northern part attained high water content, high porosity, high shear strength, low bulk density and low specific grain density. Higher sediment activities were observed in the northern sediment samples than the southern sediment samples. The core samples of the northern sediments were divided into a semi-liquid upper layer and a consolidated lower layer with a boundary at 5-8 cm. These sediment samples showed a rapid increasing pattern along the downcore in original shear strength when an opposite trend was observed in the southern samples. The results showed that sediment variabilities in geotechnical properties between the northern and southern parts such as productivities of surface water, grain solubility due to water depth variation, sedimentation rate, erosion and redistribution of sediment, and combined sedimentary processes were distinctly different along the latitude.