• Journal of the Korean Solar Energy Society
• /
• v.26 no.4
• /
• pp.93-100
• /
• 2006

An experimental study of a counterflow heat exchanger was performed. The heat exchanger had an effective heat transfer length of 1000mm and was operated in a counterflow arrangement with hot water($30{\pm}0.5^{\circ}C$, $Re_i=3500{\sim}20000$) in the inner tube(copper tube, $d_0=9.52mm$) and cold water($15{\pm}0.5^{\circ}C$, $Re_{DH}=10700{\sim}39000$) in the annulus(copper tube, $D_0=19.05mm$). Overall heat transfer coefficients were calculated and heat transfer coefficients in the inner tube and the annulus were determined using Wilson plots. The inner Nusselt number was compared with that of Gnielinski's correlation and they agreed within ${\pm}10%$ error. The trends were typical for a fluid-to-fluid heat exchanger with the overall heat transfer coefficient increasing with both inner and annulus flow rates. In the range of this experiment, Nusselt numbers for the inner tube flow were almost identical with those of the annulus flow at the same Reynolds number.

• Journal of the Korean Society of Clothing and Textiles
• /
• v.13 no.2 s.30
• /
• pp.128-136
• /
• 1989

In order to investigate a practical application of fibrous adsorbents to heavy metal ions, amidoxime fibers, as a particular class of solid chelate agents, were prepared by hydroxylamine treatment for acrylic fibers in a recipe of neutralization. Among the important problems from plant effluents are toxic concentrations of heavy metals such as copper. Accordingly, the properties of Cu (II) adsorption and its chelates were studied. The results obtained are as follows; The fibrous adsorbents have the property of increasing the swelling volumes by amidoximation. The adsorption of Cu (II) ion is characterized by an endothermic reaction, which is estimated as the plus values in the enthalpy change ($\delta$H=1.30 Kcal/mol. and 3.14 Kcal/mol.). The Cu (II) ions are adsorbed in the range of pH $3\~8$ and the maximum adsorptions are occurred about pH 8. Owing to the anions $(NO_3^-,\;Cl^-)$ of copper salts, amidoxime fibers form 1:1 and 2:1 (ligand: metal) chelating complexes with Cu (II). The nitrate anion chelates to amide I (NH) of amidoxime groups and the chlorine anion does to nitrosyl (NO). These effects relate to the crystallization of the complex and the thermal property.

• Nuclear Engineering and Technology
• /
• v.8 no.2
• /
• pp.69-76
• /
• 1976

This experiment has been carried out for the removal of long-lived radioactive-nuclides (Sr-90, Ru-106, Cs-137 and Ce-144) contained in the low-level radioactive effluents from the spent fuel reprocessing plant and nuclear power plant, in order to determine the decontaminability of various chemical coagulants and domestic clay mineral (montmorillonite). Phosphate process showed prominent efficiency for the removal of Ce-144, and lime-soda process did good removal efficiency for Sr-90. About Cs-137 copper-ferrocyanide process is much desirable. In phosphate or lime-soda process, most favorable removal efficiency was obtained at more than pH 11. The montmorillonite treated with sodium chloride showed a considerable improvement in the removal of the radioactive-nuclides. By a combined chemicals-montmorillionite process, the radioactive-nuclides could be more effectively removed than by the only chemicals process.

• Economic and Environmental Geology
• /
• v.14 no.1
• /
• pp.1-25
• /
• 1981

This paper is a literature review on the following subjects: 1) relationships between porphyry molybdenum and copper systems; 2) hydrothermal environments of molybdenite depositions; 3) genetic significance of molybdenite polyforms; and 4) trace element patterns in molybdenite useful as an exploration guide. The geologic similarities between porphyry molybdenum (e. g. Climax) and porphyry copper (e. g. Bingham) systems exist, and similar techniques can be applied for exploring deposits of either type. Several features suggest that tungsten and tin may form porphyry-like systems (i. e. lowgrade, large tonnage). The clustering of porphyry-like systems in geophysically distinctive batholithic provinces is well documented and provides larger targets for reconnaissance exploration. Geochemical studies suggest that uranium should often occur in close proximity to molybdenum ores in igneous as well as sedimentary environments.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.08a
• /
• pp.376-376
• /
• 2011

I-III-VI2 chalcopyrite compounds, particularly copper, indium, gallium selenide(Cu(InxGa1-x)Se2, CIGS), are effective light-absorbing materials in thin-film solar application. They are direct band-gap semiconductors with correspondingly high optical absorption coefficients. Also they are stable under long-term excitation. CIS (CIGS) solar cell reached conversion efficiencies as high as 19.5%. Several methods to prepare CIS (CIGS) absorber films have been reported, such as co-evaporation, sputtering, selenization, and electrodeposition. Until now, co-evaporation is the most successful technique for the preparation of CIS (CIGS) in terms of solar efficiency, but it seems difficult to scale up. CIS solar cells have been hindered by high costs associated with a fabrication process. Therefore, inorganic colloidal ink suitable for a scalable coating process could be a key step in the development of low-cost solar cells. Here, we will present the preparation of CIS photo absorption layer by a solution process using novel metal precursors. Chalcopyrite copper indium diselenide (CuInSe2) nanocrystals ranging from 5 to 20nm in diameter were synthesized by arrested precipitation in solution. For the fabrication of CIS photo absorption layer, the CuInSe2 colloidal ink was prepared by dispersing in organic solvent and used to drop-casting on molybdenum substrate. We have characterized the nanoparticless and CIS layer by XRD, SEM, TEM, and ICP.

• Proceedings of the KIEE Conference
• /
• 1994.07a
• /
• pp.150-152
• /
• 1994

In this paper, the optimum shape design of stator slot of induction motors for iron loss reduction is proposed. To obtain the flux distribution in induction motors, 2-D finite element method with voltage source is employed. The iron loss is calculated from the iron loss data given by the iron manufacturer. To calculate the sensitivity of iron loss to shape variation, the sensitivity analysis of discrete approach is used. The proposed algorithm is applied to a 3-phase squirrel cage induction motor. The nodes at stator slot boundary of the induction motor are defined as design parameters. By controlling these parameters under the constant volume of iron, we can minimize the iron loss. Furthermore, the stator copper loss is reduced by increasing the slot area. So the stator slot area is determined at the point that the summation of iron loss and copper loss of stator is minimized. Since the constraint of constant volume of iron is nonlinear to the design parameters, the Gradient Projection method is used as an optimization algorithm.

• Journal of Powder Materials
• /
• v.25 no.4
• /
• pp.291-295
• /
• 2018

A conductive additive is prepared by dispersing multi-walled carbon nanotubes (MWCNTs) on Cu powder by mechanical milling and is distributed in epoxy to enhance its electrical conductivity. During milling, the MWCNTs are dispersed and partially embedded on the surface of the Cu powder to provide electrically conductive pathways within the epoxy-based composite. The degree of dispersion of the MWCNTs is controlled by varying the milling medium and the milling time. The MWCNTs are found to be more homogeneously dispersed when solvents (particularly, non-polar solvent, i.e., NMP) are used. MWCNTs gradually disperse on the surface of Cu powder because of the plastic deformation of the ductile Cu powder. However, long-time milling is found to destroy the molecular structure of MWCNTs, instead of effectively dispersing the MWCNTs more uniformly. Thus, the epoxy composite film fabricated in this study exhibits a higher electrical conductivity than 1.1 S/cm.

• Journal of Microbiology and Biotechnology
• /
• v.26 no.11
• /
• pp.1983-1992
• /
• 2016

Pseudomonas strains isolated from the heavily contaminated Lubin copper mine and Zelazny Most post-flotation waste reservoir in Poland were screened for the presence of integrons. This analysis revealed that two strains carried homologous DNA regions composed of a gene encoding a DNA_BRE_C domain-containing tyrosine recombinase (with no significant sequence similarity to other integrases of integrons) plus a three-component array of putative integron gene cassettes. The predicted gene cassettes encode three putative polypeptides with homology to (i) transmembrane proteins, (ii) GCN5 family acetyltransferases, and (iii) hypothetical proteins of unknown function (homologous proteins are encoded by the gene cassettes of several class 1 integrons). Comparative sequence analyses identified three structural variants of these novel integron-like elements within the sequenced bacterial genomes. Analysis of their distribution revealed that they are found exclusively in strains of the genus Pseudomonas.

• Journal of the Korean institute of surface engineering
• /
• v.39 no.6
• /
• pp.276-281
• /
• 2006

In order to improve the performance of PPFs (Pre-Plated Frames), a PPF that employed a Cu-Sn alloy instead of conventionally used Ni was developed and then its properties were investigated. It was found that the electoplated Cu-Sn alloy layer was a mixture of uniformly distributed fine crystallites, resulting In better wettability and crack resistance than those of Ni PPF. Moreover, as in Cu/Ni/Pd/Au PPF, migration of copper atoms from the base metal to the top of the Cu/Cu-Sn/Pd/Au PPF surface was not found although the Cu-Sn layer itself contained considerable amount of copper. It was expected that, by using the newly developed Cu-Sn PPF, any possible heat generation and signal interrupt caused by an external electro-magnetic field could be reduced because the Cu-Sn layer was paramagnetic, i.e., nonmagnetic.

• Bulletin of the Korean Chemical Society
• /
• v.23 no.12
• /
• pp.1702-1708
• /
• 2002

The synthesis and catalytic application of a new class of a new class of planar chiral ferrocenes, 1,2-ferrocenediylazaphosphinines (1 and 2) are described. They are powerful ligands for the copper(I)-catalyzed asymmetric cyclopropanation of a range of alkenes with diazo esters to exhibit an exceptionally high degree of diastereoselectivity(~100% de) in favor of trans isomers, regardless the structure of the olefins and the diazo compounds. Comparative studies between 1 and 2 reveal that the former works better in terms of diastereocontrol. In contrast, however, enantioselectivity is low with both 1 and 2 as a whole although, in certain cases with a proper combination of the olefin and the diazo ester, high optical yields (up to 100% ee) can be achieved. Other reaction parameters such as the reaction temperature and the structure of the ligand do exhibit some influence, although infinitestimal, on both chemical and optical yields.