• 제목/요약/키워드: Copper(I)

검색결과 599건 처리시간 0.028초

2차원 구리 배위 고분자: [$Cu_2Cl_2$(4,4'-dipyen)] (Two-dimensional Cu Coordination Polymer: [$Cu_2Cl_2$(4,4'-dipyen)])

  • 허현수;이순원
    • 한국결정학회지
    • /
    • 제18권1_2호
    • /
    • pp.16-20
    • /
    • 2007
  • 수열 반응 조건 하에서, [$Cu(OAc)_2]{\cdot}H_2O$, 4,4-dipyen, 그리고 KCl로부터 2차원 구리 배위 고분자 [$Cu_2Cl_2$(4,4'-dipyen)] (1)이 합성되었다. 고분자 1 내에서, 구리 원자들이 4,4-dipyen 리간드들로 대략 b-축 방향으로 연결되고, 또한 Cl 리간드들로 대략 a-축 방향으로 연결되어 직사각형 그물 망 형태의 2차원 층이 형성된다.

$F_{16}CuPC$를 활성층으로 사용한 유기전계효과트랜지스터의 바이폴라 특성연구 (Bipolar Characteristics of Organic Field-effect Transistor Using F16CuPc with Active Layer)

  • 이호식;박용필;천민우;김태곤;김영표
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
    • /
    • pp.303-304
    • /
    • 2009
  • We fabricated organic field-effect transistors (OFETs) based a fluorinated copper phthalocyanine. ($F_{16}CuPc$) as an active layer. And we observed the surface morphology of the $F_{16}CuPc$ thin film. The $F_{16}CuPc$ thin film thickness was 40nm, and the channel length was $50{\mu}m$, channel width was 3mm. We observed the typical current-voltage (I-V) characteristics and capacitance-voltage (C-V) in $F_{16}CuPc$ FET and we calculated the effective mobility.

  • PDF

$NO_2$Gas Detection Characteristics of Octa-dodecyloxy Copper-phthalocyanine Langmuir-Blodgett(LB) Films

  • Koo, Ja-Ryong;Kim, Young-Kwan;Kim, Jung-Soo
    • E2M - 전기 전자와 첨단 소재
    • /
    • 제11권10호
    • /
    • pp.78-80
    • /
    • 1998
  • Metallo-phthalocyanines(MPcs) are very sensitive to toxic molecules such as electron affinitive NO2 gas and also chemically and thermally stable since losts of MPcs have been studied for the potential chemcial gas sensors for $NO_2$ using their electrical conductivity. In this study, thin films of octa-dodecyloxy copper -phthalocyanine were prepared by Langmuir-Blodgett(LB) method and characterized by using UV/Vis absorption spectroscopy, and ellipsometry. It was found that the proper transfer surface pressure for the film deposition was 25mN/m and the limiting area per molecule was $112\AA$/molecule. The film thickness of one layer was $64\AA$. Current-voltage(I-V) characteristics of these films were investigated as a function of film thickness.

  • PDF

SHS공정에 의한 TiC-Ni-Mo 분말 합성 및 소결체 제조 (A Study on Self-Propagating High-Temperature Synthesis of TiC-Ni-Mo Based Cermet)

  • 송인혁;전재호;한유동
    • 한국세라믹학회지
    • /
    • 제35권7호
    • /
    • pp.749-756
    • /
    • 1998
  • TiC-Ni and TiC-Ni-Mo cermet powders were produced by Self-propagating High temperature Synthesis (SHS) process. The cooling rate of synthesized powders were controlled by using the V-shaped copper jig and the carbide size decreased with increasing the cooling rate I. e decreasing the width of copper jig Round shape carbide particles were produced after SHS reaction in TiC-Ni as well as TiC-Ni-Mo powders. Local segregation of Mo rich phases was observed in SHS powder of TiC-Ni-Mo and the uneven dis-triobution of Mo promoted the faster growth rate of carbide particles during sintering compared to the same composition specimen with commercial TiC powder. Howogeneous microstructure of TiC-Ni-Mo cermet was obtained when the elemental Mo powder was mixed with the SHS powder of TiC-Ni.

  • PDF

F16CuPc를 이용한 Field Effect Transistor의 전기적 특성 연구 (Electrical Properties of Field Effect Transistor using F16CuPc)

  • 이호식;박용필;천민우
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
    • /
    • pp.389-390
    • /
    • 2008
  • We fabricated organic field-effect transistors (OFETs) based a fluorinated copper phthalocyanine ($F_{16}CuPc$) as an active layer. And we observed the surface morphology of the $F_{16}CuPc$ thin film. The $F_{16}CuPc$ thin film thickness was 40nm, and the channel length was $50{\mu}m$, channel width was 3mm. We observed the typical current-voltage (I-V) characteristics and capacitance-voltage (C-V) in $F_{16}CuPc$ FET and we calculated the effective mobility.

  • PDF

F16CuPc를 활성층으로 사용한 FET의 특성 연구 (Properties of FET using Activative Materials with F16CuPc)

  • 이호식;박용필
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2009년도 춘계학술대회 논문집
    • /
    • pp.43-44
    • /
    • 2009
  • We fabricated organic field-effect transistors (OFETs) based a fluorinated copper phthalocyanine ($F_{16}CuPc$) as an active layer. And we observed the surface morphology of the $F_{16}CuPc$ thin film. The $F_{16}CuPc$ thin film thickness was 40nm, and the channel length was $50{\mu}m$, channel width was 3mm. We observed the typical current-voltage (I-V) characteristics and capacitance-voltage (C-V) in $F_{16}CuPc$ FET and we calculated the effective mobility.

  • PDF

New Tridentate Ligands with Mixed Donor Atoms for Cu-Based Atom Transfer Radical Polymerization

  • Cho, Hong-Youl;Han, Byung-Hui;Kim, Il;Paik, Hyun-Jong
    • Macromolecular Research
    • /
    • 제14권5호
    • /
    • pp.539-544
    • /
    • 2006
  • 2-Furancarboxaldehyde-2-pyridinylhydrazone (FPH) and 5-methyl-2-furancarboxaldehyde-2-pyridinylhydrazone (MFPH) were synthesized and used as tridentate ligands of copper (I) bromide for the atom transfer radical polymerization of methyl methacrylate (MMA) and styrene. The polymerization of methyl methacrylate achieved high conversion and yielded polymers with a good control of molecular weight and low polydispersity (PDI=1.33). Higher PDI were observed in the polymerization of styrene. Using 1-phenyl ethylbromide (PEBr) and ethyl 2-bromoisobutyrate (EBiB) as model compounds for the polymeric chain ends, the activation rate constants of the new catalytic systems were measured. These results were correlated with the polymerization results and compared with another catalytic system previously reported.

F16CuPc를 이용한 FET의 전기적 특성 연구 (Electrical Properties of FET using F16CuPc)

  • 이호식;박용필
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
    • /
    • pp.504-505
    • /
    • 2008
  • We fabricated organic field-effect transistors (OFETs) based a fluorinated copper phthalocyanine ($F_{16}CuPc$) as an active layer. And we observed the surface morphology of the $F_{16}CuPc$ thin film. The $F_{16}CuPc$ thin film thickness was 40nm, and the channel length was $50{\mu}m$, channel width was 3mm. We observed the typical current-voltage (I-V) characteristics and capacitance-voltage (C-V) in $F_{16}CuPc$ FET and we calculated the effective mobility.

  • PDF

The Effect of Manipulating Package Construct and Leadframe Materials on Fracture Potential of Plastically Encapsulated Microelectronic Packages During Thermal Cycling

  • Lee, Seong-Min
    • Transactions on Electrical and Electronic Materials
    • /
    • 제2권3호
    • /
    • pp.28-32
    • /
    • 2001
  • It was studied in the present work how the thermal cycling performance of LOC (lead on chip) packages depends on the package construct or leadframe materials. First, package body thickness and Au wire diameter were manipulated for the selection of proper package design. Secondly, two different types of leadframe materials (i.e. copper and 52%Fe-48%Ni alloy) were tested to determine the better material for improved reliability margin of plastically encapsulated microelectronic packages. This work shows that manipulating package body thickness was more effective than an increase of Au wire from 23$\mu\textrm{m}$ to 33$\mu\textrm{m}$ for the prevention of wire debonding failure. Further, this work indicates that the LOC packages including the copper leadframes can be more susceptible to thermal cycling reliability degradation due to chip cracking than those including the alloy leadframes.

  • PDF

송배전용 Al-Cu접속 금구의 신뢰도 향상일 관한 연구(I) 알루미늄 및 동의 부식 특성 (Study on the Improvement of the Reliability of Al-Cu Connections in Power Distribution Systems)

  • 하윤철;배정효;김대경;하태현;이현구
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2003년도 하계학술대회 논문집 A
    • /
    • pp.488-490
    • /
    • 2003
  • As aluminum becomes more widely used in power distribution systems, so the corrosion caused by bimetallic contacts of aluminum and copper becomes more serious problem. In particular, the poor contact of the commonly used compression type bimetal connections may bring about the disastrous interruption of the power supply resulted from the increased corrosion within the joints, which is accelerated by the permeation of water and electrolyte into the interface. In this paper, the corrosion characteristics of aluminum and copper are investigated to improve the reliability of Al-Cu connectons.

  • PDF