• Title/Summary/Keyword: Conversion material

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Single Nanoparticle Photoluminescence Studies of Visible Light-Sensitive TiO2 and ZnO Nanostructures

  • Yoon, Minjoong
    • Rapid Communication in Photoscience
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    • v.2 no.1
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    • pp.9-17
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    • 2013
  • Visible light-sensitive $TiO_2$ and ZnO nanostructure materials have attracted great attention as the promising material for solar energy conversion systems such as photocatalysts for water splitting and environmental purification as well as nano-biosensors. Success of their applications relies on how to control their surface state behaviors related to the exciton dynamics and optoelectronic properties. In this paper, we briefly review some recent works on single nanoparticle photoluminescence (PL) technique and its application to observation of their surface state behaviors which are raveled by the conventional ensemble-averaged spectroscopic techniques. This review provides an opportunity to understand the temporal and spatial heterogeneities within an individual nanostructure, allowing for the potential use of single-nanoparticle approaches in studies of their photoenergy conversion and nano-scale optical biosensing.

Characterization of TiO2 Nanocrystalline Films for High Performance Dye-Sensitized Solar Cells

  • Jung, Heung-Joe
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.3
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    • pp.123-126
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    • 2011
  • Titanium dioxide ($TiO_2$) thin films were deposited by the sol-gel method with a surfactant-assisted mechanism. Its application for dye-sensitized solar cells (DSSCs) was investigated. Brunauer-Emmett-Teller, X-ray diffraction and field emission scanning electron microscopy techniques were used to characterize the surface characteristics of thin films. Photovoltaic-current density measurements were performed to determine the photoelectrochemical properties of the thin films and the performance of DSSCs. Energy conversion efficiency of about 6.1% was achieved for cells with conductive glass under illumination with AM 1.5 (100 $mWcm^{-2}$) simulated sunlight. Investigation showed higher photo-energy conversion efficiency for mesoporous $TiO_2$ nanocrystalline films used in DSSCs relative to commercially available Degussa P25 films.

Comparison of enzymatic hydrolysis characteristics of mushroom culutured waste (MCW) and Cork oak by alkali treatment (알칼리 처리에 따른 폐골목 및 굴참나무의 효소당화 특성 비교)

  • Yoon, Su-Young;Seung, Hyun-A;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.3
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    • pp.44-49
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    • 2014
  • The mushroom cultured waste(MCW) from cork oak was evaluated as the raw material for bioethanol production. For enzymatic hydrolysis, cellulase cocktails (Celluclast 1.5L and Novozym 188) was used for polysaccharides to monosaccharides conversion. Compared with sound cork oak woodmeal, woodmeal from MCW showed higher cellulose to glucose conversion. To improve polysaccharides to monosaccharides conversion, pretreatment by sodium hydroxide was applied. Even though more xylan and lignin were removed in woodmeal of MCW than that of cork oak, concentration of glucose was higher from sodium hydroxide treated cork oak woodmeal (51.3 g/L) than treated MCW woodmeal (41.6 g/L).

Analysis of the Temperature Dependence of Phosphor Conversion Efficiency in White Light-Emitting Diodes

  • Ryu, Guen-Hwan;Ryu, Han-Youl
    • Journal of the Optical Society of Korea
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    • v.19 no.3
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    • pp.311-316
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    • 2015
  • We investigate the temperature dependence of the phosphor conversion efficiency (PCE) of the phosphor material used in a white light-emitting diode (LED) consisting of a blue LED chip and yellow phosphor. The temperature dependence of the wall-plug efficiency (WPE) of the blue LED chip and the PCE of phosphor are separately determined by analyzing the measured spectrum of the white LED sample. As the ambient temperature increases from 20 to $80^{\circ}C$, WPE and PCE decrease by about 4.5% and 6%, respectively, which means that the contribution of the phosphor to the thermal characteristics of white LEDs can be more important than that of the blue LED chip. When PCE is decomposed into the Stokes-shift efficiency and the phosphor quantum efficiency (QE), it is found that the Stokes-shift efficiency is only weakly dependent on temperature, while the QE decreases rapidly with temperature. From 20 to $80^{\circ}C$ the phosphor QE decreases by about 7% while the Stokes-shift efficiency changes by less than 1%.

Life Cycle Cost Comparative Analysis for Main Conversion System in 8200 Series Electric Locomotive (8200호대 전기기관차 주변환장치 LCC 비교 분석)

  • Kim, Wan-il;Chang, Yoon-Woo;Kim, Dong-Man;Kim, Jae-Moon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.12
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    • pp.1717-1722
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    • 2018
  • Parts and units of 8200 series electric locomotive are aging, but and source technology is not secured. As a results, maintenance costs are increasing steadily due to using expensive substitute parts. Therefore, various studies have been conducted to reduce maintenance costs. In this paper, the life cycle cost(LCC) of the developed and conventional products were compared and analyzed about main conversion system in 8200 Series electric locomotive. As a result of analysis, the material cost was the highest in the conventional product among the various item costs. On the other hand, it is confirmed that preventive cost was the highest among the costs about the developed product.

Challenges and Design Strategies for Conversion-Based Anode Materials for Lithium- and Sodium-Ion Batteries

  • Kim, Hyunwoo;Kim, Dong In;Yoon, Won-Sub
    • Journal of Electrochemical Science and Technology
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    • v.13 no.1
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    • pp.32-53
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    • 2022
  • Although lithium-ion batteries are currently the most reliable power supply system for various mobile applications, further improvement in energy density is still required as the need for batteries in large energy-consuming devices is rapidly growing. However, in the anode, the most widely commercialized graphite-based anode materials almost face theoretical limitations. In addition, sodium-ion batteries have been actively studied to replace expensive charge carriers with cheaper ones. Accordingly, conversion-based materials have been extensively studied as high-capacity anode materials in both lithiumion batteries and sodium-ion batteries because their theoretical capacity is twice or thrice higher than that of insertion-based materials. This review will provide a comprehensive understanding of conversion-based materials, including basic charge storage behaviors, critical drawbacks that should be overcome, and practical material design for high-performance.

Hydrothermal Synthesis of Nanosized Sulfated Zirconia as an Efficient and Reusable Catalyst for Esterification of Acetic Acid with n-Butanol

  • Yu, Shengjian;Jiang, Pingping;Dong, Yuming;Zhang, Pingbo;Zhang, Yue;Zhang, Weijie
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.524-528
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    • 2012
  • A kind of nanosized sulfated zirconia was prepared by a hydrothermal method, and full characterized by XRD, TEM, BET, TGA, and FTIR. Its catalytic activity was evaluated in the esterification reactions, including the testing of the catalytic reusability and the optimization of reaction conditions. The obtained catalyst was revealed to be highly efficient solid catalyst for the esterification of acetic acid with n-butanol, presenting the advantages of high conversion and selectivity, easy recovery, and steady reusability.

Inversion of Material Coefficients for Numerical Analysis of Piezoelectric Actuators Using a Three-Dimensional Finite Element Method

  • Joo, Hyun-Woo;Lee, Chang-Hwan;Park, Jong-Seok;Jung, Hyun-Kyo
    • KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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    • v.3B no.2
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    • pp.67-73
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    • 2003
  • In this paper, the impedance of a piezoelectric transducer is calculated using the three-dimensional finite element method. The validity of numerical routine is confirmed experimentally. Using this numerical routine, the effects of material coefficients on piezoelectric actuators characteristics are analyzed. The material constants, which make significant effects, are selected and the relations between material constants are studied. Using these processes, three variables of material constants for a piezoelectric transducer are selected and the design sensitivity method is adopted as an inversion scheme. The validity of the inversion scheme for a piezoelectric transducer is confirmed by applying the proposed method to the sample piezoelectric transducer.

Fabrication of Nanopatterned PDMS Elastic Stamp Mold Using Surface Treatment of Nanotemplate (나노템플레이트 표면처리를 통한 나노패턴이 형성된 PDMS 탄성 스탬프 몰드 제작)

  • Park, Yong Min;Seo, Sang Hyun;Seo, Young Ho;Kim, Byeong Hee
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.24 no.1
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    • pp.38-42
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    • 2015
  • Polydimethylsiloxane (PDMS) is a widely used material for replicating micro-structures because of its transparency, deformability, and easy fabrication. At the nanoscale, however, it is hard to fill a nanohole template with uncured PDMS. This paper introduces several simple methods by changing the surface energy of a nanohole template and PDMS elastomer for replicating 100nm-scale structures. In the case of template, pristine anodic aluminum oxide (AAO), hydrophobically treated AAO, and hydrophillically treated AAO are used. For the surface energy change of the PDMS elastomer, a hydrophilic additive and dilution solvent are added in the PDMS prepolymer. During the molding process, a simple casting method is used for all combinations of the treated template and modified PDMS. The nanostructured PDMS surface was investigated with a scanning electron microscope after the molding process for verification.

Thermal Stress Analysis by Field Data Conversion between FDM and FEM (FDM과 FEM의 해석 데이터 변환에 의한 탄소성 열응력 해석)

  • Kwahk, S.Y.;Cho, C.D.
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.4
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    • pp.228-234
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    • 2001
  • The present study was an attempt for systematic data conversion between FDM and FEM in order to evaluate the thermal stress distribution during quenching process. It has been generally recognized that FDM is efficient in flow and temperature analysis and FEM in that of stress. But it induced difficulty and tedious work in analysis that one uses both FDM and FEM to take their advantages because of the discrepancy of nodes between analysis tools. So we proposed field data conversion procedure from FDM to FEM in 3-dimensional space, then applied this procedure to analysis of quenching process. The simulation procedure calculates the distributions of temperature and microstructure using FDM and microstructure evolution equations of diffusion and diffusionless transformation. FEM was used for predicting the distributions of thermal stress. The present numerical code includes coupled temperaturephase transformation kinetics and temperature-microstructure dependent material properties. Calculated results were compared with previous experimental data to verify the method, which showed good agreements.

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