Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Hydrothermal Synthesis of Nanosized Sulfated Zirconia as an Efficient and Reusable Catalyst for Esterification of Acetic Acid with n-Butanol

  • Yu, Shengjian (School of Chemical and Material Engineering, Jiangnan University) ;
  • Jiang, Pingping (School of Chemical and Material Engineering, Jiangnan University) ;
  • Dong, Yuming (School of Chemical and Material Engineering, Jiangnan University) ;
  • Zhang, Pingbo (School of Chemical and Material Engineering, Jiangnan University) ;
  • Zhang, Yue (School of Chemical and Material Engineering, Jiangnan University) ;
  • Zhang, Weijie (School of Chemical and Material Engineering, Jiangnan University)
  • Received : 2011.09.30
  • Accepted : 2011.12.08
  • Published : 2012.02.20
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Abstract

A kind of nanosized sulfated zirconia was prepared by a hydrothermal method, and full characterized by XRD, TEM, BET, TGA, and FTIR. Its catalytic activity was evaluated in the esterification reactions, including the testing of the catalytic reusability and the optimization of reaction conditions. The obtained catalyst was revealed to be highly efficient solid catalyst for the esterification of acetic acid with n-butanol, presenting the advantages of high conversion and selectivity, easy recovery, and steady reusability.

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References

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