• Title/Summary/Keyword: Conversion Energy

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Synthesis of Renewable Jet Fuel Precursors from C-C Bond Condensation of Furfural and Ethyl Levulinate in Water

  • Cai, Chiliu;Liu, Qiying;Tan, Jin;Wang, Tiejun;Zhang, Qi;Ma, Longlong
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.519-526
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    • 2016
  • Biomass derived jet fuel is proven as a potential alternative for the currently used fossil oriented energy. The efficient production of jet fuel precursor with special molecular structure is prerequisite in producing biomass derived jet fuel. We synthesized a new jet fuel precursor containing branched $C_{15}$ framework by aldol condensation of furfural (FA) and ethyl levulinate (EL), where the latter of two could be easily produced from lignocellulose by acid catalyzed processes. The highest yield of 56% for target jet fuel precursor could be obtained at the optimal reaction condition (molar ratio of FA/EL of 2, 323 K, 50 min) by using KOH as catalyst. The chemical structure of $C_{15}$ precursor was specified as (3E, 5E)-6-(furan-2-yl)-3-(furan-2-ylmethylene)-4-oxohex-5-enoic acid ($F_2E$). For stabilization, this yellowish solid precursor was hydrogenated at low temperature to obtain C=C bonds saturated product, and the chemical structure was proposed as 4-oxo-6-(tetrahydrofuran-2-yl)-3-(tetrahydrofuran-2-yl)-methyl hexanoic acid ($H-F_2E$). The successful synthesis of the new jet fuel precursors showed the significance that branched jet fuel could be potentially produced from biomass derived FA and EL via fewer steps.

PSCAD/EMTDC BASED MODELING AND ANALYSIS OF A GRID-CONNECTED VARIABLE SPEED WIND ENERGY CONVERSION SCHEME (계통연계형 가변속 풍력발전방식의 PSCAD/EMTDC 모의 및 해석)

  • 김슬기;김응상
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.52 no.8
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    • pp.413-419
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    • 2003
  • The paper presents a simulation model and analysis of a grid-connected variable speed wind energy conversion scheme (VSWECS) using the PSCAD/EMTDC software. The modeled system uses a variable speed drive, a fixed pitch angle, a synchronous generator as a wind generator and an AC-DC-AC conversion scheme, which facilitates the wind generation to efficiently operate under varying wind speed while connected to the distribution network. The power output of the WECS is controlled by the AC-DC-AC conversion scheme, the objective of which is to capture the maximum active power under varying wind conditions and to keep the voltage magnitude of the terminal bus at a specific level. Aerodynamic models are applied for a wind turbine model. An simulation analysis of the scheme in terms of its responding to wind variations is also presented.

Design and Characteristic of Electromagnetic Energy Conversion Devices Using magnetic materials (자성재료를 이용한 전자에너지변환기기의 설계 및 특성)

  • Hong, Jung-Pyo;Ha, Kyung-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.04a
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    • pp.83-87
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    • 2002
  • In order to improve the capability of magnetic circuit, magnetic materials are used for all kinds of electromagnetic energy-conversion devices. This paper presents the analysis method considering magnetic properties of the magnetic material and analyzes that the effects of magnetic materials. In addition, it is described that the requirements of magnetic materials for the improvement of electric machines. Several application examples using a metal powder in electromagnetic energy conversion devices is introduced.

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The optimum conversion efficiency in nile blue arabinose system by photogalvanic cell

  • Lal, Mohan;Gangotri, K.M.
    • Advances in Energy Research
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    • v.3 no.3
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    • pp.143-155
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    • 2015
  • The Nile blue has been used as a photosensitizer with Arabinose as a reductant in photogalvanic cell for optimum conversion efficiency and storage capacity. Reduction cost of the photogalvanic cell for commercial utility. The generated photopotential and photocurrent are 816.0 mV and $330.0{\mu}A$ respectively. The maximum power of the cell is $269.30{\mu}W$ where as the observed power at power point is $91.28{\mu}W$. The observed conversion efficiency is 0.6095% and the fill factor 0.2566 has been experimentally found out at the power point of the photogalvanic cell, whereas the absolute value is 1.00. The photogalvanic cell so developed can work for 120.0 minutes in dark if it is irradiated for 200.0 minutes that is the storage capacity of photogalvanic cell is 60.00%. The effects of different parameters on the electrical output of the photogalvanic cell have been observed. A mechanism has also been proposed for the photogeneration of electrical energy.

Electrocatalytic Activity of Sulfamic Acid Doped Polyaniline Nanofiber Counter Electrode for Dye Sensitized Solar Cell

  • Jo, Chul-Gi;Ameen, Sadia;Akhtar, M.Shaheer;Kim, Young-Soon;Yang, O-Bong;Shin, Hyung-Shik
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.385-385
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    • 2009
  • Uniform polyaniline nanofibers (PANI NFs), and chemically doped sulfamic acid(SFA) PANI NFs, synthesized via template free interfacial polymerization process, were used as new counter electrodes materials for the fabrication of the highly-efficient dyesensitized solar cells (DSSCs). The PANI NFs based fabricated DSSCs exhibited a solarto-electricity conversion efficiency of ~ 4.02% while, the SFA doped PANI NFs based DSSC demonstrated ~ 27% improvement in the solar-to-electricity conversion efficiency. The obtained solar-to-electricity conversion efficiency for SFA doped PANI NFs based DSSC was 5.47% under 100mW/$cm^2$(AM1.5). The enhancement in the conversion efficiency was due to the incorporation of SFA into the PANI NFs which resulted to the higher electrocatalytic activity for the $I^{3-}/I^-$ redox reaction.

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Effect of Pre-treatment Method on Reactivity of WGS Catalyst for SEWGS System (SEWGS 시스템을 위한 WGS 촉매의 반응성에 미치는 수소 전 처리 방법의 영향)

  • Ryu, Hojung;Park, Jihye;Lee, Dongho;Shun, Dowon;Rhee, Youngwoo
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.4
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    • pp.355-363
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    • 2014
  • Thermal shock or overheating of WGS catalyst for SEWGS system during hydrogen pre-treatment can cause reactivity decay of the catalyst. To select appropriate pre-treatment condition, temperature profiles of catalyst bed (or outside fluidized particle bed of bed insert) during pre-treatment were measured and then CO conversions of those catalysts during WGS reaction were also measured and compared. Drastic overheating of catalyst took place when we reduce catalyst at fixed bed condition and these catalysts showed low CO conversion during WGS reaction. On the contrary, there was no overheating of catalyst at fluidized bed condition not only physical mixing case but also bed insert case. Spring type bed insert showed acceptable CO conversion even at low WGS content. Consequently, feasibility of high CO conversion without decay of reactivity of catalyst and holding the WGS catalyst inside the SEWGS reactor as tablet shape were confirmed using spring type bed insert.

Characteristics of Photo-conversion Glass with $Eu^{3+}$ and Its Use 2 (Effect of Photo-conversion on Vegetables Growth) ($Eu^{3+}$가 첨가된 광변환 유리의 특성과 효과연구 2(유리의 채소재배 효과))

  • Chung, Hun-S.;Ahn, Yang-K.
    • Journal of the Korean Solar Energy Society
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    • v.22 no.4
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    • pp.62-67
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    • 2002
  • Energy conversion soda-lime-silica glasses doped with Eu3+ were produced and they were used to build small scale modules of $100\times100cm$ simulating the roof of glass house with which the rearing state of a small number of young and grown vegetables was observed. The vegetables selected for the study were eggplant, kale, and pimento. The width and length of their leaves along with the photosynthesized ability and chlorophyl content were measured to observe the growing state of the vegetables in the given periods of time. It was found that the vegetables grown under the photo-conversion glass made panels had higher values of the leaf width and length by 5 to 30% than them under the commercially available ordinary glass panels depending on the kind of vegetables. The photosynthesized abilities were also shown much higher for the vegetables under the conversion glass panels than for the non-conversion ones.

실리콘 박막 태양전지를 위한 CdSe계 양자점 광변환구조체

  • Sin, Myeong-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.135.2-135.2
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    • 2014
  • Photon conversion technology for thin film solar cells is reviewed. The high-energy photons which are hardly absorbed in solar cells can be transformed the low energy photon by the photon conversion process such as down conversion or down shift, which can improve the solar cell efficiency over the material limit. CdSe-based quantum dot materials commonly used in LED can be used as the photon conversion layer for Si thin film solar cells. The photon conversion structure of CdSe-based quantum dot for Si thin film solar cells will be presented and the pros and cons for the Si thin film solar cells integrated with the photon conversion layers will be discussed.

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