• Title/Summary/Keyword: Conversion Energy

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Parametric Numerical Study on the Performance of Helical Tidal Stream Turbines (헬리컬 터빈의 설계인자에 따른 성능 연구)

  • Han, Jun-Sun;Choi, Da-Hye;Hyun, Beom-Soo;Kim, Moon-Chan;Rhee, Shin-Hyung;Song, Mu-Seok
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.14 no.2
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    • pp.114-120
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    • 2011
  • The characteristics of a helical turbine to be used for tidal stream energy conversion have been numerically studied with varying a few design parameters. The helical turbines were proposed aiming at mitgating the well known poor cut-in characteristics and the structural vibration caused by the fluctuating torque, and the basic concept is introducing some twisting angle of the vertical blade along the rotation axis of the turbine. Among many potential controling parameters, we focused, in this paper, on the twisting angle and the height to diameter ratio of the turbine, and, based on the numerical experiment, We tried to propose a configuration of such turbine for which better performance can be expected. The three-dimensional unsteady RANS equations were solved by using the commercial CFD software, FLUENT with k-${\omega}$ SST turbulence model, and the grid was generated by GAMBIT. It is shown that there are a range of the twisting angle producing better efficiency with less vibration and the minimum height to diameter ratio above which the efficiency does not improve considerably.

Effect of alkali pretreatment on bioconversion of waste money bill to glucose for bio-ethanol production

  • Sheikh, M. Mominul Islam;Kim, Chul-Hwan;Park, Hyun-Jin;Kim, Sung-Ho;Kim, Gyeong-Chul;Lee, Ji-Yong;Kim, Jae-Won
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.10a
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    • pp.167-177
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    • 2011
  • Renewable energy resources and technologies have the potential to provide long-lasting solutions of the global energy-requirements faced by the economic and environmental sectors of a nation. Therefore, waste money bills were used as renewable energy source for the production of bio-ethanol. In this study, different concentrated NaOH 0.5%. 1.0%, 2.0%, 3.0% and 0.0% (as a control) were used for 10, 20 and 30 mins at $121^{\circ}C$/15 psi in an autoclave. Saccharification and fermentation (aerobic and anaerobic) were carried out through commercial enzyme Celluclast 1.5 L, Novozymes 188 and Saccharomyces cerevisiae KCCM 11304 respectively. The results of pretreatment showed that the NaOH pre-treated substrate enhanced enzyme action and released more amount of glucose. The amount of glucose was found with the increasing concentration of NaOH and time $44996.95{\pm}6.30$, $46763.10{\pm}3.56$, $53421.32{\pm}4.72$, $63431.25{\pm}6.95$ and $56850.98{\pm}6.75\;ng/{\mu}l$ for 30 min respectively. As for bioethanol, the conversion rate of NaOH resulted $1010.08{\pm}4.71$, $1050.25{\pm}4.37$, $1109.49{\pm}4.39$, $1139.25{\pm}3.26$ and $1020.77{\pm}3.89$ ppm for aerobic; $16730.54{\pm}6.67$, $17076.45{\pm}6.25$, $17516.17{\pm}4.49$, $19782.68{\pm}6.19$ and $17973.39{\pm}7.50$ ppm for anaerobic and $18935.02{\pm}4.59$, $19895.45{\pm}5.39$, $21912.95{\pm}4.83$, $24895.21{\pm}6.72$ and $18961.21{\pm}4.90$ ppm for anaerobic condition with benzoic acid for respective condition. Thus, the results of the present work clearly revealed that with the increasing of alkali concentration might be more effective for bio-ethanol production from waste money bill, which is economic and environmental friendly.

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A Study Based on Molecular Orbital Theory of Polymerization of Oxetane High Explosives (옥세탄 고폭 화약류의 중합반응에 관한 분자 궤도론적 연구)

  • Kim, Joon-Tae
    • Applied Chemistry for Engineering
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    • v.20 no.2
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    • pp.159-164
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    • 2009
  • Monomers of oxetane high explosives were theoretically examined in terms of reactivity, reaction mechanism and process of polymerization substituted by azido $(-CH_2N_3)$, nitrato $(-CH_2ONO_2)$ and hydrazino $(-CH_2N_2H_3)$ which belong to the 5th class hazardous materials and have explosiveness under acid catalyst using MINDO/3, MNDO, and AMI methods for formal charge, heat of formation, and energy level. Nucleophilicity and base of oxetane high explosives could be explained by negative charge size of oxetane oxygen atom and reactivity of oxetane in the growth stage of polymerization under acid catalyzer could be expected to be governed by positive charge size of axial carbon atom and low LUMO energy of electrophile. It could be estimated that carbenium ion was more beneficial in the conversion process of oxetane high explosives than that of stabilization energy (13.90~31.02 kcal/mole) of oxonium ion. In addition, concentration of oxonium ion and carbenium ion in equilibrium state influenced mechanism and it was also estimated that $S_N1$ mechanism reacts faster than that of $S_N2$ in prepolymer growth stage considering quick equilibrium based on form and calculation of polymerization under acid catalyzer.

Photovoltaic performance evaluation of the bonded single crystalline silicon solar cell on composite specimens under mechanical loading (기계적 하중 하에서 복합재료 시험편에 접착된 단결정 실리콘태양전지의 성능평가)

  • Kim, Jong-Cheon;Choi, Ik-Hyeon;Kim, Dae-Hyun;Jeong, Seong-Kyun
    • Composites Research
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    • v.24 no.6
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    • pp.56-63
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    • 2011
  • The objective of this study is to investigate appropriate bonding methods of solar cells in order to apply solar cells, which have been receiving particular attention as a renewable energy due to fossil energy depletion and environment issues, to composite structures. Back-contact solar cells with approximately 24.2% energy conversion efficiency were used in this study. Since silicon-based solar cells are mechanically fragile, the secondary-bonding methods using adhesive were examined in this study. The experiment was conducted with three kinds of bonding materials such as EVA film, Resin film and elastic adhesive. The performance of solar cells for three types of adhesives under mechanical loading on test specimens is conducted. In addition, the measuring equipment was designed to evaluate the performance of the solar cells under mechanical loading in real time and the fracture characteristics depending on bonding materials were evaluated. The reason decreasing solar cells efficiency were analyzed and considered by Fractography. The results show that the solar cell performance is largely affected by bonding techniques. Moreover, the bonding method using elastic adhesive shows best solar cell efficiency.

A Kinetic Study of Steam Gasification of Woodchip, Sawdust and Lignite (나무칩, 톱밥 바이오매스와 갈탄의 수증기 가스화반응 특성 연구)

  • Kim, Kyungwook;Bungay, Vergel C.;Song, Byungho;Choi, Youngtai;Lee, Jeungwoo
    • Korean Chemical Engineering Research
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    • v.51 no.4
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    • pp.506-512
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    • 2013
  • Biomass and low-grade coals are known to be better potential sources of energy compared to crude oil and natural gas since these materials are readily available and found to have large reserves, respectively. Gasification of these carbonaceous materials produced syngas for chemical synthesis and power generation. Woodchip, sawdust and lignite were gasified with steam in a thermobalance reactor under atmospheric pressure in order to evaluate their kinetic rate information. The effects of gasification temperature ($600{\sim}900^{\circ}C$) and partial pressure of steam (20~90 kPa) on the gasification rate were investigated. The three different types of gas-solid reaction models were applied to the experimental data to predict the behavior of the gasification reactions. The modified volumetric model predicted the conversion data well, thus the model was used to evaluate kinetic parameters in this study. The observed activation energy of biomass, sawdust and lignite gasification reactions were found to be in reasonable range and their rank was found to be sawdust > woodchip > lignite. The expression of apparent reaction rates for steam gasification of the three solids was proposed to provide basic information on the design of coal gasification processes.

Effect of Organo Nanoclay and Catalyst on the Polyesterification between Adipic Acid and Diethylene Glycol (Adipic Acid와 Diethylene Glycol의 Polyesterification에 대한 유기나노점토와 촉매의 영향)

  • Park, Kyung-Kyu;Shin, Sung-Wook;Oh, Min-Ji;Lee, Sang-Ho
    • Elastomers and Composites
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    • v.46 no.1
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    • pp.37-44
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    • 2011
  • Effect of organo nanoclay (Cloisite 30B) on the polyesterification of adipic acid (AA) with diethylene glycol(DEG) was investigated with p-toluene sulfonic acid (p-TSA) (Br${\phi}$nsted acid) and butylchlorotin dihydroxide (Lewis acid) catalyst at 383 and 423 K. The initial [OH]/[COOH] molar ratio was two and the concentration of the catalysts in the reactants was 0.14 mol% based on the total reactants. The kinetics of the polyesterification was interpreted with the conversion data that was calculated from the acid values of the reactant-product mixture. The reaction rate of the polyesterification, which was catalyzed with p-TSA, exhibited the second-order dependency on AA concentration. When Butylchlorotin dihydroxide was used, the reaction rate revealed the first-order dependency on AA concentration. The activation energy of the reactions catalyzed with p-TSA and Butylchlorotin dihydroxide were calculated at 42.2 and 63.8 kJ/mol, respectively. Addition of 5 wt% Cloisite 30B to the reactant significantly diminished the activity of p-TSA, so the reaction rate decreased and the activation energy was calculated at 72.9 kJ/mol. Butylchlorotin dihydroxide catalyst maintained its activity regardless of the addition of Cloisite 30B to the reactant and the activation energy was calculated to 61.8 kJ/mol. Lewis acid catalyst, butylchlorotin dihydroxide, was more effective than Br${\phi}$nsted acid catalyst for the esterification of AA with DEG.

A study on the oxide semiconductor $[(I_{n2}O_3)_x{\cdot}(S_nO_2)_{1-x}]_{(n)}/Silicon(p)$, solar cells fabricated by two source evaporation (이가열원(二加熱源) 증착법(蒸着法)에 이한 산화물(酸化物) 반도체(半導體) $[(I_{n2}O_3)_x{\cdot}(S_nO_2)_{1-x}]_{(n)}/Silicon(p)$, 태양전지(太陽電池)에 관한 연구(硏究))

  • Jhoon, Choon-Saing;Kim, Yong-Woon;Lim, Eung-Choon
    • Solar Energy
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    • v.12 no.2
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    • pp.62-78
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    • 1992
  • The solar cells of $ITO_{(n)}/Si_{(p)}$, which are ITO thin films deposited and heated on Si wafer 190[$^{\circ}C$], were fabricated by two source vaccum deposition method, and their electrical properties were investigated. Its maximum output is obtained when the com- position of the thin film consist of indium oxide 91[mole %] and thin oxide 9[mole %]. The cell characteristics can be improved by annealing but are deteriorated at temperature above 600[$^{\circ}C$] for longer than 15[min]. Also, we investigated the spectral response with short circuit current of the cells and found that the increasing of the annealing caused the peak shifted to the long wavelength region. And by experiment of the X-ray diffraction, it is shown to grow the grains of the thin film with increasment of annealing temperature. The test results from the $ITO_{(n)}/Si_{(p)}$ solar cell are as follows. short circuit current : Isc= 31 $[mW/cm^2]$ open circuit voltage : Voc= 460[mV] fill factor : FF=0.71 conversion efficiency : ${\eta}$=11[%]. under the solar energy illumination of $100[mW/cm^2]$.

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Performance Analysis on the Multi Stage Reheater Regeneration Cycle for Ocean Geothermal Power Generation (해양지열발전용 다단재열재생사이클 성능해석)

  • Lee, Ho Saeng;Cha, Sang Won;Jung, Young Kwon;Kim, Hyeon Ju
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.17 no.2
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    • pp.116-121
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    • 2014
  • In order to study the improvement of the multi stage regeneration cycles, muti-stage processes were applied to the cycles, respectively or together. The kinds of the cycles are multi stage reheater cycle (MS) and multi stage reheater regeneration cycle (MSR). Working fluid used was R134a and R245fa. Temperature of the heat source was $65^{\circ}C$, $75^{\circ}C$, and $85^{\circ}C$, and temperature of the heat sink was $5^{\circ}C$. Optimization simulation was conducted for improving the gross power and efficiency with multi stage reheater regeneration cycle for ocean thermal energy conversion(OTEC) with changing of a heat source, kind of the working fluid, and type of the cycle. Performance analysis of the various components was simulated by using the Aspen HYSYS for analysis of the thermodynamic cycle. R245fa shows better performance than R134a. This paper showed the most suitable working fluid with changing of a heat source and the kinds of working cycle. Compared to each other, MS showed better performance at gross power and MSR showed higher cycle efficiency.

A Study on the Utilization of Soy-Lecithin in Broiler Ration (Broiler에 있어서 대두 Lecithin의 사료적 가치에 관한 연구)

  • 김대진;김영길
    • Korean Journal of Poultry Science
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    • v.7 no.1
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    • pp.23-29
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    • 1980
  • The research was conducted to study the feeding value of crude soylecithin produced as by-products of soybean oil manufacturing in broiler ration. The results obtained were as follows. 1. The chemical composition, mineral composition, Vitamine contents and gross energy values of crude soy-lecithin were determined 2. No significant difference was observed for the body weight gain of broiler between control and lecithin groups of 3%, 6%, 9o/e and 12% addition. 3. Significant difference (P<0.05) was observed for feed intake lecithin 12% composed with lecithin 6% and 9% group, However, no significant difference was found among control, lecithin 3%, 6%, and 9% groups. 4. No significant difference was found for feed conversion between treatments. However, the lowest figure 2.32 for lecithin 9% treatments, followed by 2.40 of lecithin 6% and 2.41 of lecithin 3% orderly. 5. The composition of moisture, crude protein and ether extract in broiler carcas ranged from 71.2 to 72.15%, from 15.93 to 16.45% and from 6.19 to 7.05% respectively. 6. The weight of abdominal fat and live fat in broiler caress ranged from 42.4 to 63.7 gm, and from 2.2 to 2.4gm respectively. difference between abdominal and live fat weight was showing in significant statistically. 7. The present data reveal that soy-lecithin as by-product of soybean oil manufacturing was valuable energy source.

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12-bit SAR A/D Converter with 6MSB sharing (상위 6비트를 공유하는 12 비트 SAR A/D 변환기)

  • Lee, Ho-Yong;Yoon, Kwang-Sub
    • Journal of IKEEE
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    • v.22 no.4
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    • pp.1012-1018
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    • 2018
  • In this paper, CMOS SAR (Successive Approximation Register) A/D converter with 1.8V supply voltage is designed for IoT sensor processing. This paper proposes design of a 12-bit SAR A/D converter with two A / D converters in parallel to improve the sampling rate. A/D converter1 of the two A/D converters determines all the 12-bit bits, and another A/D converter2 uses the upper six bits of the other A/D converters to minimize power consumption and switching energy. Since the second A/D converter2 does not determine the upper 6 bits, the control circuits and SAR Logic are not needed and the area is minimized. In addition, the switching energy increases as the large capacitor capacity and the large voltage change in the C-DAC, and the second A/D converter does not determine the upper 6 bits, thereby reducing the switching energy. It is also possible to reduce the process variation in the C-DAC by proposed structure by the split capacitor capacity in the C-DAC equals the unit capacitor capacity. The proposed SAR A/D converter was designed using 0.18um CMOS process, and the supply voltage of 1.8V, the conversion speed of 10MS/s, and the Effective Number of Bit (ENOB) of 10.2 bits were measured. The area of core block is $600{\times}900um^2$, the total power consumption is $79.58{\mu}W$, and the FOM (Figure of Merit) is 6.716fJ / step.