• 제목/요약/키워드: Conventional mixed oxide method

검색결과 118건 처리시간 0.025초

Ce첨가에 따른 MST 세라믹스의 마이크로파 유전특성 (Microwave Dielectric Properties of the MST Ceramics with Addition of Ce)

  • 최의선;박인길;배선기;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.430-433
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    • 2001
  • The 0.96MgTiO$_3$-0.04SrTiO$_3$+xCe(x=0∼1.6 wt%) ceramics were fabricated by the conventional mixed oxide method. The sintering temperature and time were 1300$^{\circ}C$, 2hr., respectively. From the X-ray diffraction patterns, it was found that the perovskite SrTiO$_3$ and ilmenite MgTiO$_3$ structures were coexisted in the 0.96MgTiO$_3$-0.04SrTiO$_3$+xCe(x=0∼1.6 wt%) ceramics. The dielectric constant($\varepsilon$$\sub$r/) was increased with addition of Ce. The temperature coefficient of resonant frequency($\tau$$\sub$f/) was gradually varied from positive value to the negative value with increasing the Ce. The temperature coefficient of resonant frequency of the 0.96MgTiO$_3$-0.04SrTiO$_3$+0.2Ce ceramics was near zero, where the dielectric constant, quality factor, and $\tau$$\sub$f/ were 20.68, 50, 272 and -0.5pm/$^{\circ}C$, respectively.

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$BaTiO_{3}+xNb_{2}O_{5}$ 세라믹스의 구조 및 유전특성 (The structural and dielectric properties of the $BaTiO_{3}+xNb_{2}O_{5}$ ceramics)

  • 이상철;류기원;이성갑;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.426-429
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    • 2001
  • The BaTiO$_3$+xNb$_2$O$_{5}$[x=6,8 , 10wt%] ceramics were prepared by conventional mixed oxide method. The structural properties of the BaTiO$_3$+xNb$_2$O$_{5}$ ceramics with the sintering temperature and addition of Nb$_2$O$_{5}$ were investigated by XRD and SEM. Increasing the sintering temperature, the 2$\theta$ value of BT (110) peak was shifted to the lower degree and intensity of the BN (310) peak was increased. Increasing the addition of Nb$_2$O$_{5}$, the intensity of BN (100) Peak was decreased and BN (310), (110) peaks were increased. The grain size of the BaTiO$_3$+Nb$_2$O$_{5}$ ceramics sintered at 135$0^{\circ}C$ were almost uniform. In the BaTiO$_3$+Nb$_2$O$_{5}$ ceramics sintered at 135$0^{\circ}C$, the dielectric constant and dielectric loss were 5424, 0.02 respectively.espectively.

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소결온도에 따른 $0.7Mg_4Ta_2O_9-0.3TiO_2$ 세라믹스의 마이크로파 유전특성 (Microwave Dielectric Properties of $0.7Mg_4Ta_2O_9-0.3TiO_2$ Ceramics with Sintering Temperature)

  • 김재식;최의선;이성갑;배선기;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 센서 박막재료 반도체 세라믹
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    • pp.249-252
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    • 2003
  • The microwave dielectric properties of $0.7Mg_4Ta_2O_9-0.3TiO_2$ ceramics were investigated. All samples were prepared by the conventional mixed oxide method. The structural properties were investigated with sintering temperature by X-ray Diffractor meter. According to. the X-ray diffraction patterns of the $0.7Mg_4Ta_2O_9-0.3TiO_2$ ceramics, major phase of the hexagonal $Mg_4Ta_2O_9$ were appeared. In the case of $0.7Mg_4Ta_2O_9-0.3TiO_2$ ceramics sintered at $1400^{\circ}C$, dielectric constant, quality factor and temperature coefficient of resonant frequency were 11.72, 126,419GHz, $-31.82ppm/^{\circ}C$, respectively.

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CuO와 ZnO 첨가에 따른 NKN-BZT 세라믹스의 압전 특성 (Piezoelectric Properties of NKN-BZT Ceramics Sintered with CuO and ZnO Additives)

  • 이승환;백상돈;이동현;이성갑;이영희
    • 한국전기전자재료학회논문지
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    • 제24권8호
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    • pp.636-640
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    • 2011
  • The lead-free $0.98(Na_{0.5},K_{0.5})NbO_3-0.02Ba(Zr_{0.52},Ti_{0.48})O_3$-(hereafter NKN-BZT) CuO, ZnO-doped ceramics were prepared using a conventional mixed oxide method. NKN-BZT ceramics doped CuO, ZnO have superior structural and electrical properties than pure NKN-BZT ceramics. For the NKN-BZT-ZnO ceramics sintered at $1,120^{\circ}C$, piezoelectric constant ($d_{33}$) of sample showed the optimum values of 172 pC/N. The $0.98(Na_{0.5},K_{0.5})NbO_3-0.02Ba(Zr_{0.52},Ti_{0.48})O_3$-ZnO ceramics are a promising candidate for lead-free piezoelectric materials.

$CaF_2$ 첨가에 따른 $TiTe_3O_8$ 세라믹스의 마이크로파 유전특성 (Microwave Dielectric Properties of $TiTe_3O_8$ Ceramics with addition at $CaF_2$)

  • 이문기;김재식;최의선;류기원;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 하계학술대회 논문집 C
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    • pp.1589-1591
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    • 2003
  • The microwave dielectric properties of $TiTe_3O_8-CaF_2$ ceramics were investigated. All sample of $TiTe_3O_8-CaF_2$ ceramics were prepared by the conventional mixed oxide method, and sintered in the temperature of $730^{\circ}C{\sim}750^{\circ}C$. The structural properties of $TiTe_3O_8-CaF_2$ ceramics were investigated by the X-ray diffractor meter. According to the X-ray diffraction patterns of $TiTe_3O_8-CaF_2$ ceramics, the major phase of the cubic $TiTe_3O_8$ were presented. In the case of $1molTiTe_3O_8-0.1molCaF_2$ ceramics sintered at $740^{\circ}C$ for 5hr., the bulk density, dielectric constant, quality factor were $2.8g/cm^3$, 39.1, 36.100GHz, respectively.

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소결은도에 따른 $0.6Mg_4Ta_2O_9-0.4TiO_2$ 세라믹스의 마이크로파 유전특성 (Microwave Dielectric Properties of $0.6Mg_4Ta_2O_9-0.4TiO_2$ Ceramics with Sintering Temperature)

  • 김재식;최의선;박인길;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 하계학술대회 논문집 C
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    • pp.1541-1543
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    • 2003
  • The microwave dielectric properties of $0.6Mg_4Ta_2O_9-0.4TiO_2$ ceramics were investigated. All sample of $0.6Mg_4Ta_2O_9-0.4TiO_2$ ceramics were prepared by the conventional mixed oxide method, and sintered in the temperature of $1350^{\circ}C{\sim}1450^{\circ}C$. The structural properties of $0.6Mg_4Ta_2O_9-0.4TiO_2$ ceramics were investigated by the X-ray diffraction meter. According to the X-ray diffraction patterns of $0.6Mg_4Ta_2O_9-0.4TiO_2$ ceramics, the major phase of the hexagonal $0.6Mg_4Ta_2O_9-0.4TiO_2$ were presented, In the case of $0.6Mg_4Ta_2O_9-0.4TiO_2$ ceramics sintered at $1400^{\circ}C$ for 5hr., the dielectric constant, quality factor and temperature coefficient of resonant frequency were 12.19, 109.411GHz, -17.21ppm/$^{\circ}C$, respectively.

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소결온도에 따른 $Ba_{5}Nb_{4}O_{15}$ 세라믹스의 구조 및 마이크로파 유전특성 (Structural and Microwave Dielectric Properties of the $Ba_{5}Nb_{4}O_{15}$ Ceramics with Sintering Temperature)

  • 이승준;박인길;이성갑;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 제38회 하계학술대회
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    • pp.238-239
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    • 2007
  • In this study, the structural and microwave dielectric properties of the $Ba_{5}Nb_{4}O_{15}$ cation-deficient perovskite ceramics with sintering temperature were investigated. All sample of the $Ba_{5}Nb_{4}O_{15}$ ceramics were prepared by the conventional mixed oxide method and sintered at $1325^{\circ}C{\sim}1500^{\circ}C$. The bulk density, dielectric constant and quality factor of the $Ba_{5}Nb_{4}O_{15}$ ceramics were increased in the range of $1325^{\circ}C{\sim}1400^{\circ}C$ and decreased above the sintering temperature of 1400$^{\circ}C$. In the case of the $Ba_{5}Nb_{4}O_{15}$ ceramics sintered at 1400$^{\circ}C$ for 5h, the dielectric constant, quality factor and temperature coefficient of the resonant frequency (TCRF) were 39.55, 28,052GHz, 5.7ppm/$^{\circ}C$, respectively.

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MgTiO$_3$-SrTiO$_3$세라믹스의 마이크로파 유전특성 (Microwave Dielectric Properties of the MgTiO$_3$-SrTiO$_3$Ceramics)

  • 최의선;이문기;정장호;김강;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.843-846
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    • 2000
  • The (1-x)MgTiO$_3$-xSrTiO$_3$(x=0.02∼0.08) ceramics were fabricated by conventional mixed oxide method. The sintering temperature and time were 1250$^{\circ}C$∼1400$^{\circ}C$, 2hr., respectively. The structural and microwave dielectric properties were investigated by varying sintering temperature and composition ratio. In the (1-x)MgTiO$_3$-xSrTiO$_3$(x=0.02) ceramics, the cubic SrTiO$_3$and hexagonal MgTiO$_3$phases were coexisted. The dielectric constant was increased and the temperature coefficient of resonant frequency( $\tau_f$) was decreased with addition of SrTiO$_3$. The temperature coefficient of resonant frequency($\tau_f$) was gradually varied from negative value to positive value with increasing the SrTiO$_3$.

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불순물 첨가에 따른 $Al_2O_3$세라믹스의 구조적 특성 (Structural Properties of $Al_2O_3$Ceramics with impurities)

  • 우원석;김지헌;임성수;박인길;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.387-390
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    • 2000
  • The $Al_2$O$_3$specimens were prepared by the conventional mixed oxide method with addition La$_2$O$_3$, Bi$_2$O$_3$. The specimens were sintered at 15$25^{\circ}C$, 5hr., in air. The structural properties of the specimens were investigated by XRD and SEM. The $Al_2$O$_3$ceramics with dopants had hexagonal structure and didn't show secondary phases. In the case of specimens with 0.25wt% La$_2$O$_3$and 0.25wt% Bi$_2$O$_3$bulk densities and lattice parameter of c/a were 3.818g/cm$^3$, 3.783g/cm$^3$and ca=2.725, c/a=2.723, respectively. The bulk densities of $Al_2$O$_3$ceramics were decreased with dopants.

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$Y_2O_3$ 첨가에 따른 $BaTi_4O_9$ 세라믹스의 마이크로파 유전특성 (Microwave Dielectric Properties of $BaTi_4O_9$ Ceramics with addition of $Y_2O_3$)

  • 김정훈;김지헌;정장호;박인길;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.88-90
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    • 2002
  • The $BaTi_4O_9$ ceramics with $Y_2O_3$(0.5wt%) were prepared by the conventional mixed oxide method. The structural properties were investigated with sintering temperature by XRD. The microwave dielectric properties also were investigated as a function of sintering temperature. According to the X-ray diffraction pattern of the $BaTi_4O_9$ ceramics with $Y_2O_3$(0.5wt%), the orthorhombic $BaTi_4O_9$ were appeared. In the case of $BaTi_4O_9+Y_2O_3$(0.5wt%) ceramics sintered $1400^{\circ}C$, dielectric constant. quality factor and temperature coefficient of resonant frequency were 41.3, 41,600, $+3.2ppm/^{\circ}C$, respectively.

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