• 대한환경공학회지
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• 제37권4호
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• pp.228-233
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• 2015

본 연구에서는 회분식 실험 및 $A^2/O$ 공법의 연속식 실험으로 아연이 생분해, 산소 소모율, 질산화 및 탈질에 미치는 영향을 검토하였다. 본 연구의 결과를 요약하면 다음과 같다. 아연 영향 실험 결과 유기물 분해는 회분식 실험의 경우 아연 농도 12 mg/L까지 영향을 미치지 않았으며, 연속식 실험의 경우 아연 농도 3.0 mg/L 이상일 때 생분해성이 낮아졌다. 질산화 및 질소 제거의 경우 회분식은 아연 농도 6.0 mg/L 이상일 때 질산화율이 낮아졌으며, 연속식의 경우 아연 농도 3.0 mg/L 이상일 때는 질소 제거율이 낮아졌다. 인 제거의 경우 회분식은 아연 농도 6.0 mg/L, 연속식은 아연 농도 3.0 mg/L 이상일때 인 제거율이 낮아지는 것으로 나타났다. 산소 소모율의 경우 연속식의 아연 농도가 3.0 mg/L 이상이면 미생물 활성에 영향을 주어 산소 소모율이 낮아졌다.

• 유체기계공업학회:학술대회논문집
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• 유체기계공업학회 2002년도 유체기계 연구개발 발표회 논문집
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• pp.493-498
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• 2002

The letdown system of pressurized water reactor (PWR) nuclear fewer plants had experienced instabilities in letdown system due to unacceptable flow characteristics of control valves. The Korean Standard Nuclear Power Plants (KSNPs) have three flow paths in parallel for letdown new control. Each flow path consists of two offices and one isolation valve. This study evaluates the effect of orifice arrangement and valve stroke time of letdown isolation valve on the system transients because sudden flow changes due to valve actuation can generate high pressure peaks in letdown line. A pressure transient analysis has been preformed to evaluate the impact of dynamic transients. This analysis uses MMS which is a simulation code developed by EPRI based on the method of characteristics. The result shows that the pressure peak is reduced in the continuous arrangement but negligible. Additionally, it shows that the stroke time of linear type flog valve greater than 15 seconds can give more stable performance.

• 환경위생공학
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• 제15권2호
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• pp.58-64
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• 2000

The photocatalytic removal of Ag(I) in water by $TiO_2$ at a various conditions, which are initial Ag(I) concentration, circulation flow rate, $TiO_2$ dosage and methanol concentration, was studied. A continuous flow system with a circular type reactor of the TiO2 suspensions with UV light through an photoreactor column was applied. The major results of this study were as follows; 1. First order kinetics was observed from the result at different initial concentration of Ag(I). As the initial Ag(I) concentration was incereased, the reaction rate was decreased. 2. The removal efficiency of Ag(I) increased with increasing the circulation flow rate and $TiO_2$ dosage. However, over $4{\ell}/min$ of circulation flow rate and $1.5g/{\ell}$ of $TiO_2$ dosage, increasing of the efficiency reached a plateau. 3. The addition of methanol as hole scavenger enhanced the removal efficiency of Ag(I) but the removal efficiency reached a plateau over some level of methanol. 4. It was found that $TiO_2$ photocatalysis was effective method to remove of Ag(I) from aqueous solution.

• Korean Chemical Engineering Research
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• 제58권2호
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• pp.235-247
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• 2020

Sulfur-Iodine cycle (SI cycle)은 요오드와 황을 첨가하여 최종적으로 물을 열화학적으로 분해하여 산소와 수소를 생산하는 공정으로 황산분해, 요오드화 수소 분해, 분젠반응 등 세가지 반응들로 이루어져 있다. 분젠 반응은 두가지 공정 중간에 존재하므로 두 반응에 필요한 화학물을 조달하는 역할로 이에 대한 상분리 및 반응기에 대한 분석이 중요하다. 본 연구에서는 50 L/hr 수소를 생산하는 pilot scale의 Sulfur-Iodine Cycle 중 분젠 공정에 대한 모사, 민감도 분석, 민감도 분석을 토대로한 각각 상분리기와 분젠 반응기에 대한 최적 조건을 제시하였다. 열역학 물성치의 계산을 위해 Electrolyte Non-Random Two Liquid (ELECNRTL) model 사용하였다. 모델에 대한 신뢰도 확보를 위해서 실제 pilot scale의 공정 데이터와 검증을 수행하였다. 반응기의 종류를 선정하기 위해 Continuous Stirred Tank Reactor (CSTR)과 Plug Flow Reactor (PFR) 동일한 온도 및 부피 변화에서 SO₂ 전환율을 비교하였다. 상분리기 선정을 위해 3상 분리 시스템(기체-액체-액체)과 액체-기체 분리 후 액체-액체 구조에서 H₂SO₄ 상과 HI_X 상에서의 불순물들을 비교하였다. PFR에서 온도, 지름, 길이를 결정 변수로 SO₂ 전환율을 최대화 하기 위한 최적화를 수행하였는데, 온도 121 ℃와 PFR의 지름이 0.20 m 및 길이 7.6 m 일 때 SO₂ 전환율이 98% 최적 결과임을 확인하였다. 기존 pilot scale과 동일한 운전 조건 하에 PFR의 지름 3/8 inch, 길이 3.0 m, 120 ℃ 일 때 인입 몰량인 I₂ 및 H₂O를 결정 변수로 SO₂ 전환율에 대한 최적화를 수행하였을 때, SO₂ 전환율이 10% 일때 H₂O 및 I₂ 의 인입 몰량은 각각 17%와 22%로 감소하였다. 앞선 조업 조건 최적화 조건 (121 ℃, 지름 0.20 m, 길이: 7.6 m) 경우에는 SO₂ 전환율이 98% 일 때 H₂O가 1% 그리고 I₂가 7% 감소하였다. 상분리기에서 HI_X 상내 H₂SO₄ 최소화하는 목적함수에서 그에 상응하는 온도, I₂와 H₂O를 결정 변수로 설정하였을 때, H₂O 몰량이 기존공정보다 17% 감소하고 I₂ 몰량이 24% 감소하였을 때 최소 불순물이 생성하였다.

• 상하수도학회지
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• 제21권3호
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• pp.331-339
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• 2007

The purpose of this study was to investigate the biodegradability and performance of organic removal and methane production rate when treating piggery wastewater using a pilot scale two-phase anaerobic system operated up to a volumetric rate of $10m^3/day$. The pilot scale two-phase anaerobic process is consisted of a continuous-flow stirred-tank reactor (CFSTR) for the acidification phase and an Upflow Anaerobic Sludge Blanket reactor (UASB) for the methanogenesis. The acidogenic reactor played key roles in reducing the periodically applied shock-loading and in the acidification of the influent organics. The acidogenic CFSTR was operated at organic loading rates (OLR) between 1.8 and $14.4kgCOD/m^3{\cdot}day$, and the UASB reactor was operated between 0.5 and $5.6kgCOD/m^3{\cdot}day$. A stable maximum biogas production rate was $81m^3/day$ and the methane conversion rate of the organic matter varied from 0.30 to $0.42L\;CH_4/g\;COD_{removed}$(0.40) at hydraulic retention time (HRT) above 3.5days. The methane contents ranged from 73 to 82% during the experimental period. It is known that most of the removed organic matter was converted to methane gas, and the produced biogas might be high quality for its subsequent use.

• 한국물환경학회지
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• 제26권5호
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• pp.781-788
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• 2010

A pilot study was performed to examine the feasibility of multiple stage of constructed wetland (CW) for nutrient removal. The system is composed of six wetland cells connected with water-ways. The hydraulic of wetland cells is designed as free water surface flow. The treatment capacity was $25m^3d^{-1}$ at HRT of about one day for each cell. The magnitude of nutrient removal was related with the length of wetlands and plant density. Total N and P removal rates were 1353 and $246mg\;m^{-2}d^{-1}$ respectively. The pilot-scale reactor was model as continuous flow system containing contribution of CSTR and PFR typed-reactors. The $k-C^*$ model equation was applied to predict N and P reduction. The result indicated the equation was well guided to estimate reduction of $NO_3-N$ and $PO_4-P$.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2009년도 추계학술발표대회
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• pp.23.2-23.2
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• 2009

Atomic layer deposition (ALD)have been proven to be a very attractive technique for the fabrication of advanced gate dielectrics and DRAM insulators due to excellent conformality and precise control of film thickness and composition, However, one major disadvantages of ALD is its relatively low deposition rate (throughput) because the deposition rate is typically limited by the time required for purging process between the introduction of precursors. In order to improve its throughput, many efforts have been made by commercial companies, for example,the modification reactor and development of precursors. However, any promising solution has not reported to date. We developed a new concept ALD system(Lucida TM S200) with high-throughput. In this process, a continuous flow of ALD precursor and purging gas are simultaneously introduced from different locations in the ALD reactor. A cyclic ALD process is carried out by moving the wafer holder up and down. Therefore, the time required for ALD reaction cycle is determined by speed of the wafer holder and vapor pressure of precursors. We will present the operating principle of our system and results of deposition.

• 한국수소및신에너지학회논문집
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• 제28권4호
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• pp.384-391
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• 2017

Effects of operating variables on solid circulation rate were measured and discussed using two-interconnected circulating fluidized bed system at ambient temperature and pressure. OCN 706-1100 particles were used as oxygen carrier. The measured solid circulation rates increased as the lower loop seal gas flow rates and the solid height in the fuel reactor increased. Suitable operating conditions to avoid choking of the air reactor were confirmed. Continuous long-term operations of steady-state solid circulation were also demonstrated at two different conditions based on the operating window.

• 한국수산과학회지
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• 제47권5호
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• pp.622-629
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• 2014

This study induced biological denitrification and nitrification via a biofiltration process with the view of removing nitrogen from land-based fish farm effluent. To achieve this, we operated an aquaculture nitrogen-removal system that includes a denitrification and nitrification reactor [working volume 40 L, flow rate 64.8 L, HRT (hydraulic retention time) 14.8 h, HRT considering recycling of NOx 7.4 h]. In the continuous process, the nitrification rate of ammonium nitrogen exceeded 90% at a steady state and the denitrification efficiency exceeded 80% with recycling to a pre-anoxic reactor. In addition, the pH in the final effluent was lower with a low influent water alkalinity averaging 100 mg/L (as $CaCO_3$). For effective denitrification reactions, carbon must be supplied via particulate organic matter (POM) hydrolysis because of the low C/N (carbon/nitrogen) ratio in the water.

• 한국환경보건학회지
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• 제23권3호
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• pp.85-90
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• 1997

The objective of this study was to investigate biodegradation of TPA(terephthalic acid) and EG (ethylene glycol), treatment efficiency of polyester weight loss wastewater and microbial characteristics by aerated submerged biolfilm(ASB) p.rocess. In a batch reactor, pH increased from 7.0 to 8. 5 in the biodegradation of TPA. Whereas, in case of EG, decreased from 7.0 to 5.2. COD concentration rapidly decreased within 24hr in the biodegradation of TPA and EG. COD removal velocity constant(k) were 0.065-0.088 hr$^{-1}$. The biodegradation velocity of TPA was 1.4 times faster than that of EG. The ratio of suspended biomass to the total biomass in the reactor was 18.3-33.3%, increased as a high ratio of EG content. Biofilm thickness, biofilm dry density and attached biomass were 346-432 $\mu$m, 41.8-61.9 mg/cm$^3$, 1.45-2.67 mg/cm$^2$, respectively. There values increased as a high ratio of TPA content. In the hydraulic retention time of 36 hr, organic loading rate of 4 kgCOD/m$^3\cdot$ day and packing ratio of 70%, the effluent concentrations of TCOD, SCOD in a continuous flow reator were 1,388 mg/l, 147 mg/l and removal efficiencies were 77%, 97.6%, respectively.