• Title/Summary/Keyword: Continuous Flow Reaction

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A Numerical Analysis of the Abatement of VOC with Photocatalytic Reaction in a Flow Reactor (연속흐름 반응기에서 광촉매 반응에 의한 VOC 물질제거 특성에 대한 수치적 연구)

  • 최우혁;김창녕;정석진
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.7
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    • pp.637-646
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    • 2001
  • VOC(Volatile Organic Compound) removal characteristics in continuous flow reactors have been numerically investigated. The photocatalytic reaction have been simulated with the binding constant and the reaction rate constant obtained from experimental data for the constant-volume batch reactor, and then VOC abatement in continuous flow reactors with the same conditions as those of batch reactor has been analyzed. The standard 4\kappa-\varepsilon$ model and mass conservation equation have been employed for numerical calculation, and heterogeneous reaction rate has been used in terms of the boundary condition of the conservation equation. in the case of the continuous flow reactor, reaction characteristics have been estimated with various inlet velocities and with different number of baffles. The result shows that the concentration distribution and flow patterns are strongly affected by the inlet velocity, and that with the increased inlet velocity, VOC removal rate is increased, while removal efficiency is decreased. This result may be useful in the design of reactors with improved VOC removal efficiency.

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Design of Continuous-flow Micro-PCR System (연속류형 Micro-PCR 시스템의 설계)

  • Kim, Duck-Jong;Kim, Jae-Yun;Park, Sang-Jin;Heo, Pil-Woo;Yoon, Eui-Soo
    • 유체기계공업학회:학술대회논문집
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    • 2003.12a
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    • pp.115-120
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    • 2003
  • In this work, a continuous-flow micro-PCR system is systematically designed. From the numerical simulation based on the finite volume method, adapting oneself to a new environmental temperature without an external temperature controller is shown to be possible and a cooler as well as a heater is shown to be necessary to obtain three individual temperature zones for polymerase chain reaction. In addition, appropriate geometry of a heat sink for the cooler is determined by using a compact modeling method, the porous medium approach.

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Characteristics of Indium-Tin-Oxide Electrode for Continuous-flow PCR Chip (연속흐름 중합효소연쇄반응칩 제작을 위한 인듐 산화막 전극의 특성분석)

  • Joung, Seung-Ryong;Kim, Jun-Hyeok;Yi, In-Je;Kang, C.J.;Kim, Yong-Sang
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.3
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    • pp.561-565
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    • 2007
  • We propose glass and PDMS (polydimethylsiloxane) chips for DNA amplification with continuous-flow PCR (polymerase chain reaction). The PDMS microchannel was fabricated using a negative molding method for sample injection. Three heaters and sensors of ITO (indium-tin-oxide) thin films were fabricated on glass chip. ITO heaters and sensors were calibrated accurately for the temperature control of the liquid flow. ITO heater generated stable heat versus applied power. ITO sensor resistance was changed linearly versus temperature increase as a RTD (resistance temperature detector) sensor. As a result, we enable precision temperature control of continuous-flow PCR chip. Using the continuous-flow PCR chip DNA plasmid pKS-GFP 720 bp was successfully amplified.

Thermodynamic Analysis of Solid Electrolyte $CO_2$ Sensor in Continuous and Discontinuous Flow Systems (연속 기체흐름계 및 일시 기체흐름계에서의 고체 전해질 $CO_2$ 가스센서의 열역학적 분석)

  • Choi, Soon-Don
    • Journal of Sensor Science and Technology
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    • v.7 no.5
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    • pp.319-326
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    • 1998
  • Anodic half-reaction in the $Na^+$ ionic sensors using $Na_2CO_3$ and $MCO_3$ ($M=Cs_2,K_2,Li_2,Ca$) as a sensitive membrane is derived in continuous flow system to explain $CO_2$ sensing characteristics. For various gas-sensitive membranes, a well known overall reaction, $MCO_3\;=\;MO\;+\;CO_2$, cannot be applied for the EMF behaviors of these kinds of sensors. So, the anodic reaction is found to involve $Na_2CO_3$ and $M^{++}$-containing oxide phases by employing the ion exchange reaction at the interface of solid electrolyte and the sensitive membrane to maintain ionic balance in the whole cell. Based on the electrode reaction derived in flow system, differences of cell potentials between continuous and discontinuous flow systems were also discussed. These EMF differences were considerably caused by the partial pressures of oxygen and $CO_2$ as well as irreversible chemical reactions between electrode materials and $CO_2$ atmosphere.

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A Study of Forging Equipment for One Body Crankshaft of Medium Sized Marine Engine (선박 중형엔진용 일체형 Crankshaft 단조장치에 관한 연구)

  • 박승희;윤성만;신상엽;박래원;박종국;이응기;김대두
    • Transactions of Materials Processing
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    • v.8 no.3
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    • pp.237-244
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    • 1999
  • The purpose of this research is for the development of a new type forging equipment. H.C.G.(Hyundai Continuous Grain-Flow), by using two virtual build-up tools, rigid viscoplastic FEM and downsized plasticine experiment. This forging method consists of only vertical pressuree. Therefore, high quality crankshafts can be forged with this method as it can maintain a continuous grain flow. The factors considered in the development of equipment are die geometry for flawless deformed shape, die reaction forces, stress/strain distributions and continuous material flow. We carried out several numerical simulations and downsized plasticine experiments for the proper design of the forging equipment. The validity of those simulation results is confirmed by checking with the actual test results. Based on these simulation results, the proper design of the H.C.G. forging equipment is enabled.

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Determination of Aqueous Ammonia with Indophenol Method : Comparision and Evaluation for the Reaction-Rate, Equilibrium and Flow-Injection Analysis Methods (인도페놀법을 이용한 수용액 중 암모니아 정량에 관한 연구 : 평형법, 반응속도법, 흐름주입분석법의 비교와 평가)

  • 정형근;김범식
    • Journal of Environmental Science International
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    • v.4 no.1
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    • pp.91-103
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    • 1995
  • The reaction rate, equilibrium, and flow injection analysis methods were fundamentally evaluated for the determination of aqueous ammonia. The selected indophenol blue method was based on the formation of indophenol blue in which ammonium ion reacted with hypochlorite and phenol in alkaline solution. In the optimized reaction condition, the reaction followed 1st order reaction kinetics and the final product was stable. The absorbance measurements before and after the equilibrium were utilized for the reaction rate and equilibrium methods. The reaction rate methods, based on the relative analytical signals for the possibility of eliminating interferents, were shown to have good linear calibration curves but the detection limit and the calibration sensitivity were poorer than those in the equilibrium method. The detection limits were 32-49 pub and 24 pub for the reaction rate and equilibrium methods, respectively In the flow injection analysis, the absorbance was measured before the equilibrium reached and thus resulted in 30% reduction of calibration sensitivity. However, the detection limit was 11 ppb, indicating that the peak-to-peak noise for the blank was remarkably improved. Compared to the manual methods, the optimized experimental condition in a closed reaction system reduced the blank absorbance and the inclusion of ammonia from the atmosphere was prevented. In addition, highly reproducible mixing of sample and reagents and analytical data extracted from continuous recording showed excellent reproducibility.

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A study on the synthesis of fine nickel hydroxide crystalline powder using the taylor fluid flow

  • Park, Il-Jeong;Kim, Dae-Weon;Jung, Hang-Chul
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.5
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    • pp.268-273
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    • 2017
  • In this study, nickel hydroxide crystalline powders were synthesized by continuous reaction in the taylor fluid flow using nickel chloride, nickel sulphate and sodium hydroxide as raw materials and compared with those prepared by a conventional batch type reaction. The crystallinity of nickel hydroxide prepared by the Taylor fluid flow reaction was higher than that of nickel hydroxide obtained by batch reaction. The particle size of nickel hydroxide decreased about 2.5 to 3.6 times, and the specific surface area was increased.

A Study of Forging Equipment for One Body Crankshaft of Medium Sized Marine Engine (선박 중형엔진 일체형 Crankshaft 제작용 형단조장치 기술개발에 관한 연구)

  • 윤성만
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.03b
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    • pp.107-110
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    • 1999
  • The purpose of this research is for the development of a new type forging equipment H.C.G(Hyundai Continuous Grain-flow) by using two virtual build-up tools rigid viscoplastic FEM and downsized plasticine experiment. This forging equipment consists of consecutive horizontal and vertical pressure while the traditional forging method consists of only vertical pressure. Using this method high quality crankshafts can be forged as it can maintain a continuous grain flow. The factors considered in the development of equipment are die geometry for flawless deformed shape die reaction forces stress/strain distributions and continuous material flow. We carried out several numerical simulations and downsized plasticine experiments for the proper design of the forging equipment. The validity of those simulation results is confirmed by checking with the actual test results. Based on these simulation results the proper design of the H.C.G for ging equipment is enabled.

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Continuous Production of Lactosucrose by Immobilized Sterigmatomyces elviae Mutant

  • Lee, Jong-Ho;Lim, Jung-Soo;Park, Chul-Hwan;Kang, Seong-Woo;Shin, Hyun-Yong;Park, Seung-Won;Kim, Seung-Wook
    • Journal of Microbiology and Biotechnology
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    • v.17 no.9
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    • pp.1533-1537
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    • 2007
  • In this study, in order to develop a continuous production process of lactosucrose in a packed-bed reactor, Sterigmatomyces elviae ATCC 18894 was selected and mutated. The mutant strain of S. elviae showed 54.3% higher lactosucrose production than the wild type. Reaction conditions such as temperature, pH, substrate concentration and flow rate were also optimized. Under optimized reaction conditions ($50^{\circ}C$, pH 6.0, 25% sucrose and 25% lactose as substrate, flow rate 1.2 ml/min), the maximum concentration of lactosucrose (192 g/l) was obtained. In a packed-bed reactor, continuous production of lactosucrose was performed using S. elviae mutant immobilized in calcium alginate, and about 180 g/l of lactosucrose production was achieved for 48 days.