• Title/Summary/Keyword: Content layer

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Effect of Treatment Temperature and Gas Content on the Characteristics of Surface Layer of Low Temperature Plasma Nitrided Duplex Stainless Steel. (Duplex Stainless Steel (2205)의 Low Temperature Plasma Nitriding 처리시 처리온도 및 가스함량에 따른 S-phase 거동)

  • Lee, In-Seop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.291-292
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    • 2015
  • Duplex Stainless Steel의 Plasma Nitriding 처리 시 가스량과 처리온도가 표면 특성에 미치는 영향을 조사하였다. $N_2$함량 및 처리 온도가 각각 10%에서 25%로 $400^{\circ}C$에서 $430^{\circ}C$로 증가함에 따라서 질소가 과고용된 S-phase의 두께 및 표면 경도가 증가하였으나, 내부 식성은 $Cr_2N$$(Fe,Cr)_4N$이 석출하여 감소하였다. 질소를 10%로 고정하고 $CH_4$함량을 증가시키면 1%일 때 S-phase의 두께가 최대가 되며 그이후로 감소하였다. 처리온도 $400^{\circ}C$일 때 질소함량이 10%, $CH_4$ 함량이 5%일 경우 내식성이 모재보다 증가하였다.

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Electroless Ni-P layer Characteristics in accordance with the plating process conditions (무전해 Ni-P 도금의 공정조건에 따른 도금피막 특성변화)

  • Lee Hong-Kee;Jeon Jun-Mi;Park Hae-Duck
    • Journal of Surface Science and Engineering
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    • v.36 no.3
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    • pp.263-271
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    • 2003
  • Optimal conditions of electroless nickel plating in acid baths has been studied for industrial applications of a developed EN solution. The phosphorus content in the deposition ranges from 8 to $12\;wt.\%$. The investigated EN plating parameters are ion concentrations of nickel and hypophosphite, concentration of reducing and complexing agent, temperature, and pH. The average plating rate of Ni-P deposition was ca. $14{\mu}m/h$. The EN solution used shows a deposition rate of $10{\mu}m/h$ up to seven metal turnovers.

Interfacial Reaction of Galvanized Steel in Ni Added Zn-0.18Al Bath (Zn-0.18Al 도금욕에서 Ni첨가에 따른 아연 도금강의 계면반응)

  • 이경구;기회봉;이도재
    • Journal of Surface Science and Engineering
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    • v.32 no.4
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    • pp.547-554
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    • 1999
  • The interfacial reaction, spangle and coating thickness of galvanized steel in Ni added Zn-0.18Al bath have been investigated. The size of spangle and thickness of reaction layer were observed under an optical microscope, SEM and EDS. Analysing the experimental results concerning spangle size of galvanized steel it was found that Ni addition in Zn-0.18Al bath tended to be minimized spangle size. For Zn-0.18Al bath, addition of 0.1Ni suppressed the formation of Fe-Zn intermetallic compounds but increased with Ni content above 0.1%. The coating thickness of galvanized steel was reduced with Ni addition in Zn-0.18Al bath, especially in Zn-0.18Al-0.05Ni bath. Addition of Al in Ni containing bath resulted in forming the Al-Ni intermetallic compounds such as $Al_3$Ni$_2$ and $Al_2$Ni which consist most of top precipitates.

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Preparation and Characterization of Insoluble Anodes for Electrodeposition of Ni-W Alloys in Ammoniacal Citrate Bath (Ni-W 합금도금용 불용성 양극의 제조 및 특성 연구)

  • 장도연;강성군
    • Journal of Surface Science and Engineering
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    • v.32 no.6
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    • pp.686-694
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    • 1999
  • Insoluble anodes of the Ta/Ir mixed metal oxide for electrodeposition of Ni-W alloy in ammoniacal citrate bath were prepared by thermal decomposition method. Ti plate was etched in boiling oxalic acid solution and coated with ethanol solution of $TaCl_{5}$ and $IrCl_4$ mixed in a fixed ratio, followed by drying and treating at various temperatures. The coating layer of these insoluble anode was characterized by SEM, EDX, XRD and DSC. The decomposition rate of citric acid in plating bath was determined by measuring the $CO_2$ gas evolved at the anodes with Gas Chromatography. Evolution of $CO_2$ gas from Ta/Ir oxide anodes decreased about 5% compared with that of Pt. The $CO_2$ gas evolution was increased with the amount of Ir-oxide in the coatings. The coatings which have more than 40% ratio of Ta content and heat-treated at the temperature higher than $400^{\circ}C$ showed better efficiency

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Immobilization of Leuconostoc oenos Cells for Wine Deacidification (포도주의 신맛 조절을 위한 Leuconostoc oenos 세포의 고정화)

  • Lee, S.O.;Park, M.Y.
    • Korean Journal of Food Science and Technology
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    • v.12 no.4
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    • pp.299-304
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    • 1980
  • By using whole cells of Leuconostoc oenos ML-34 immobilized in polyacrylamide gel, deacidification of grape juice and wine was attempted. The immobilization did not destroy the original malo-lactic fermentation ability of the cells. However, the speed of malic acid decomposition by the immobilized cells was slow due to the slow transportation of the substrate through the gel layer. By reducing malic acid content in grape juice to a desired degree one may control the level of acid taste in wine fermented with the treated grape juice.

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Characterization of Fatty Acids Extracted from Brachionus rotundiformis Using Lipase-catalyzed Hydrolysis

  • Lee, Jung-Kwon;Kim, Se-Kwon;Byun, Hee-Guk
    • Fisheries and Aquatic Sciences
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    • v.12 no.1
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    • pp.16-23
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    • 2009
  • Lipids were extracted from marine rotifer, Brachionus rotundiformis in order to examine the functionality of lipid enzymatic modification. The fatty acids, palmitic, linoleic, oleic and stearic acids were the dominant forms accounting for approximately 35.8%, 21.5%, 15.9% and 7.7% of the total lipid content, respectively. Lipid fractions were categorized as neutral lipids (38.5%), glycolipids (45.9%) and phospholipids (17.6%), and after extraction from the rotifer were isolated by thin-layer chromatography (TLC) as free fatty acids (FFA), monoacylglycerol (MAG), diacylglycerol (DAG) and triacylglycerol (TAG). The production of polyunsaturated fatty acid (PUFA) concentrate from rotifer lipids was studied using lipase-catalyzed hydrolysis. In addition, rotifer lipids were modified by hydrolysis using lipases such as porcine pancreas, Candida rugosa and Rhizomucor miehei. The lipase from Rhizomucor miehei was effective in extracting linoleic acid (C 18:2), while the lipase from Candida rugosa was effective in palmitic acid (C16:0) extraction.

Infiltration and Drainage Capacity of Unsaturated Soil-Aggregate Foundation System (조립질 지반재료로 이루어진 기초의 불포화 침투 및 배수성능 평가)

  • Sung, Yeoul-Jung;Park, Seong-Wan;Tae, Doo-Hyung
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.03a
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    • pp.966-972
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    • 2009
  • Soil-aggregate system in pavement foundations exist in unsaturated conditions. However, change in water content on foundation layers due to joint and structural cracks during rainfall may cause problems like layer deformations or partial settlements. Therefore, a need exist to evaluate the infiltration and drainage capacity of soil-aggregate foundation system under both saturated and unsaturated conditions. To do that, a laboratory soil-water characteristic curve and permeability under unsaturated conditions are assessed to establish hydraulic properties of geomaterials and limited numerical analysis are performed respectively. As a result, it was found that suction profiles and drainage process was greatly influenced by the initial suction of soil-aggregate system at the time of infiltration, soil water characteristics curves, and hysteresis effects.

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Chemically Induced High Pretilt Angle by CN-Containing Polyimide

  • Lee, Myong-Hoon;You, Kwon-Il;Lee, Chang-Jin;Woo, Tae-Ha
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.191-192
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    • 2000
  • New copolyimides containing nitrile side group were synthesized from copolymerization of pyromellitic dianhydride, m-phenylene diamine and 3,5-diaminobenzonitrile and subsequent thermal imidization of the resulting poly(amic acid). Crystallinity, glass transition temperature and initial decomposition temperature of copolyimides were almost identical to those of homo polyimide prepared from PMDA and m-PDA. Change of pretilt angle induced by the orientation layer of resulting copolyimide was investigated by using a nitrile-containg nematic liquid crystal cell after rubbing. As the content of polar nitrile group was increased in the copolymer, pretilt angle was increased from $3.65^{\circ}$ to $6.49^{\circ}$. The mechanism of this was speculated as the dipolar interaction between the liquid crystal and nitrile groups in copolyimide.

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Effect of Additives on the PTCR Characteristics of La3+ Doped(Ba1-xCax)TiO4 Ceramics (La3+ doped (Ba1-x Cax) TiO3의 PTCR 특성에 미치는 첨가제의 영향)

  • 강원호;오봉인;김재현;이경희
    • Journal of the Korean Ceramic Society
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    • v.25 no.1
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    • pp.42-48
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    • 1988
  • Commercially available PTCR (Postive Temperature Coefficient of Resistivity) ceramics which have low room temperature resistance, high PTC effect and temperature coefficient were prepared by La3+ doped semiconducting barium calcium titanate soild solutions. PTCR characteristics were remarkably improved by addition of AST (1/3 Al2O3$.$3/4SiO2$.$1/4TiO2) and MnCl2. That can be explained by formation of liquid phase during sintering and acceptor level on the intergranular layer. Resistivity anormaly increased with decreasing cooling rate. Optimum manufacturing conditions were cooling rate below 100$.$C/hr, Ca and Mn content of 4 mol% &, 0.09-0.12mol% respectively.

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Changes of Activities of Oxygen Free Radical, Generating and Scavenging Enzymes in Rat Liver Induced by Scald Burn Injury (피부화상에 의한 간 조직의 oxygen free radical 생성계 효소와 해독계 효소의 활성변화)

  • Kim Han-Soo;Cho Hyun-Gug;Kim Sang-Soo;Bae Ju-Han;Seo Hyun-Kyu
    • The Journal of Korean Physical Therapy
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    • v.11 no.3
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    • pp.115-121
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    • 1999
  • The effects of scald bum Injury ($40-45\%$ of total body surface area), there were not inhalation and secondary infection, on the histological changes and the levels of oxygen free radical generating and scavenging enzymes have been determined in liver tissue of rat models. It was found that dermal epithelium was left out with edema of dermis layer and hydorpic swelling of hepatocytes, Burn injury increased liver weight (L.W./B.W.) and serum aspartate aminotransferase content (pThe data of this study suggest that liver damage Induced by scald burn injury leads to dysbalance of oxygen free radical generating and scavenging enzymes.

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