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Effect of Electrolytic Condition on Composition of Zn-Co Alloy Plating (Zn-Co 합금도금의 조성에 미치는 전해조건의 영향)

  • Kang, Soo Young
    • Journal of the Korea Convergence Society
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    • v.8 no.11
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    • pp.287-292
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    • 2017
  • The electrodeposition of Zn on the automotive parts has been adapted However, because Zn electrodeposit needs to increase thickness for corrosion protection, it has problem of destruction of electrodeposit Zn-based electrodeposit have teen studied for corrosion protection and decreasing electrodeposit thickness. Especially; Zn-Co electrodeposit have much attention In this study, the Composition of Zn-Co electrodeposit in various manufacturing condition such as temperature, current density and electrolyte content was investigated to understand effect of electrolysis condition on Co content of specimen. The results were explained by cathode overvoltage and diffusion coefficient. As the current density increases, the electrolyte temperature decreases, and as the electrolyte concentration decreases, the overvoltage of the cathode increases. As the overvoltage of the cathode increases, the concentration polarization becomes more important than the activation polarization. Concentration polarization is determined by the diffusion of the mass transfer in the diffusion layer. In a constant concentration polarization, a large amount of elements with a large diffusion coefficient is diffused. That is, as the overvoltage of the cathode increases, the Zn content having a large diffusion coefficient increases.

Processing and Flexural Properties of Chopped Jute Fiber Reinforced PLA Sandwich Composites (황마 단섬유 강화 폴리유산 샌드위치 복합재의 제작 및 굽힘 특성)

  • Lee, Gyu Hee;Roh, Jeong U;Lee, Woo Il
    • Composites Research
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    • v.27 no.3
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    • pp.96-102
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    • 2014
  • In this study, we fabricated jute fiber reinforced polylactic acid (PLA) composite in the form of sandwich panel structure which includes core foam of chopped jute fiber reinforced PLA and outer skin layer of continuous glass fiber reinforced PLA. Flexural properties of the composite were assessed for different jute fiber weight fractions. Density of the core foam ranged from 0.31 to 0.67 $g/cm^3$ and void content fraction 0.51 to 0.71. The maximum flexural strength was 92.7 MPa at 12.5 wt.% of jute fiber content, and the maximum flexural modulus was 7.58 GPa at 30.0 wt.%. Cost analysis was also conducted. The cost to enhance the flexural strength of the applied structure was estimated to be $0.010USD/m^3/MPa$ for 12.5 wt.% fiber content.

Comparative Performance of Hens Fed Diets Containing Korean, Japanese and Chinese Green Tea

  • Uuganbayar, D.;Shin, I.S.;Yang, C.J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.8
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    • pp.1190-1196
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    • 2006
  • This experiment was carried out to investigate the effects of Korean, Japanese and Chinese green tea on laying performance and egg quality in hens. A total of 168 "Tetran Brown" hens aged 40 weeks were assigned to 7 treatments in a completely randomized design. Each treatment had 4 replicates accommodating 6 layers per replication. The seven dietary treatments were: 1) control diet with no green tea added, 2) diet containing 1.0% Korean green tea (1.0% KGT), 3) diet containing 2.0% Korean green tea (2.0% KGT), 4) diet containing 1.0% Japanese green tea (1.0% JGT), 5) diet containing 2.0% Japanese green tea (2.0% JGT), 6) diet containing 1.0% Chinese green tea (1.0% CGT), and 7) diet containing 2.0% Chinese green tea (2.0% CGT). Egg production rate of the layers fed diets containing 1.0 or 2.0% green tea powders were significantly increased compared to that of the control (p<0.05). The egg weight of layers was significantly reduced in layers fed 1.0% CGT (p<0.05). The feed intake was significantly decreased in KGT and CGT groups at 2.0% inclusion levels (p<0.05). The egg shell thickness and shape index of JGT treatment was significantly lower than that of the control (p<0.05). There were no significant differences in albumen index, yolk index and Haugh unit of eggs for layers fed diets containing green tea powders regardless of origin (p>0.05). Green tea feeding to layers tended to reduce the overall cholesterol content of egg yolk. Particularly, 1.0 or 2.0% CGT significantly depressed the total cholesterol content of egg yolk (p<0.05). In conclusion, incorporation of 1.0 or 2.0% Korean, Japanese and Chinese green tea into layer diets regardless of origin had favorable effects on laying performance and egg quality profiles. Among the three green tea sources, the Chinese green tea powder had the highest reducing effect on cholesterol content in egg yolk.

Rosary : Topology-Aware Structured P2P Overlay Network for CDN System (Rosary : CDN 시스템을 위한 구조화된 토폴러지-인식 P2P 오버레이 네트워크)

  • Shin Soo-Young;Namgoong Jung-ll;Park Soo-Hyun
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.30 no.12B
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    • pp.818-830
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    • 2005
  • Recently, Peer-to-Peer (P2P) overlay networks like CAN, Chord, Pastry and Tapestry offer a novel platform for scalable and decentralized distributed applications. These systems provide efficient and fault-tolerant routing, object location, and load balancing within a self-organizing overlay network. Content Delivery Network (CDN) is an intermediate layer of infrastructure that helps to efficiently deliver the multimedia content from content providers to clients. In this paper, We propose a topology-aware P2P overlay network for CDN, Rosary, in which CDN servers perform Intra-Pastry and Inter-Pastry routing based on a two-level structured overlay network. This proposed system extends pastry by adapting itself to CDN environments, where a semi-hashing based scheme for Intra-Pastry routing is introduced, and dynamic landmark technology is used to construct the topology-aware overlay network. Through simulations on NS-2, it is shown that Rosary is scalable, efficient, and flexible.

Effects of the Variables in the Fabrication of Anode on the Performance of DMFC (직접 메탄올 연료전지용 산화극 제조 변수가 성능에 미치는 영향)

  • Kim, Joon-Hee;Ha, Heung-Yong;Oh, In-Hwan;Hong, Seong-Ahn;Lee, Ho-In
    • Journal of the Korean Electrochemical Society
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    • v.6 no.1
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    • pp.18-22
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    • 2003
  • Single cell performance has been investigated and characterized with variables in the fabrication of DMFC anode. The performance was checked as a function of ionomer content which affects ion conductivity in the catalyst layer, and catalyst slurry solvent which determines structure of agglomerates consisting of an ionomer and a catalyst. Anode with total ionomer to catalyst ratio of 0.6 showed the best performance and the lowest polarization resistance. Also, electrochemically effective surface area increased with ionomer content. As solubility of the ionomer decreases with decreasing solvent polarity, the size of agglomerates consisting of a catalyst and an ionomer became larger in the less polar solvent. The anode using DPK $(\varepsilon=12.60)$ as a solvent, which is less polar than generally-used water or alcohol species, showed the maximum performance and the lowest polarization resistance.

The Rheology of the Silica Dispersion System with Single and Mixed Solvent (단일 및 혼합 용매계 실리카 분산체의 점도 특성 및 유변학적 거동)

  • Ahn, Jae-Beom;Noh, Si-Tae
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.685-691
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    • 2009
  • Dispersions of fumed silica are made in 6 kinds of mono-solvents and mixed solvents which have hydroxyl group, non hydroxyl group, different polarity, and different molecular size. The viscosity and rheology behaviors of the each dispersion are investigated according to the viewpoint of solvent characteristic. The silica dispersion in polar solvent with hydroxyl group is stable and low viscous sol. The silica dispersion in non-polar solvent with non-hydroxyl group is high viscous gel. When the solvent with hydroxyl group is added to the silica dispersions with non-polar solvents, they show the reduction of viscosity with solvent content. They have minimum critical content which shows no viscosity change. The minimum critical solvent content is decreased according to the polarity of solvents with no hydroxyl group. The solvation layer which is formed on the silica surface through hydrogen bonding between hydroxyl-containing solvent and the silanol group of silica surface is the reason of stable and low viscous sol. In case of non-polar solvent, silanol on adjacent silica particles interacted directly by hydrogen bonding show high viscous and flocculated gel.

Silicon 기판과 SiON 박막 사이의 계면 결함 감소를 위한 $NH_3$ Plasma Treatment 방법에 관한 연구

  • Gong, Dae-Yeong;Park, Seung-Man;Lee, Jun-Sin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.131-131
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    • 2011
  • 이종접합 태양전지 제작을 위해 기판의 buffer layer로 사용되는 기존의 a-Si 박막을 SiON 박막으로 대체하려는 연구가 진행 중이다. 기존의 a-Si 박막은 대면적에서 균일도를 담보하기 어렵고, 열적 안정성에 취약한 문제점이 있다. 이에 반해 SiON 박막은 일종의 화학 반응인 oxidation 방법으로 형성이 되기 때문에 막의 균일도를 담보 할 수 있고, $400^{\circ}C$이상의 온도에서 형성되기 때문에 열적 안정성이 우수한 장점이 있다. 이러한 장점에도 불구하고 기판위에 직접 형성이 되기 때문에 기판과 SiON 계면 사이의 pssivation이 무엇보다 중요하다. 본 연구에서는 비정질 실리콘 이종접합 태양전지에 적용키 위한 SiON 박막을 형성하고, 기판과 SiON 계면에서의 passivation 향상을 위한 계면 결함 감소에 대한 연구를 진행하였다. 실험을 위한 SiON 박막은 공정온도 $450^{\circ}C$, 공정압력 100 mTorr, 증착파워 120 mW/cm2에서 5분간 증착하였으며, 이때 50 sccm의 N2O 가스를 주입하였다. 증착된 박막은 2~4 nm의 두께로 증착이 되었으며, 1.46의 광학적 굴절률을 가지는 것으로 분석되었다. 계면의 결함을 줄이기 위해 PECVD를 이용한 NH3 plasma treatment를 실시하였다. 공정온도 $400^{\circ}C$, 공정압력 150mTorr~450 mTorr, 플라즈마 파워 60mW/cm2에서 30분간 진행하였으며, 50 sccm의 N2O 가스를 주입하였다. 계면의 결함이 줄었는지 확인하기 위해 C-V 측정을 위한 시료를 제작하여 분석을 하였다. 실험 결과 VFB가 NH3 plasma treatment 이후 positive 방향으로 shift 됨을 알 수 있었다. Dit 분석을 통해 공정 압력 450 mTorr에서 $4.66{\times}108$[cm2/eV]로 가장 낮은 계면 결함 밀도를 확인 할 수 있었다. 결과적으로 NH3 plasma 처리를 통해 positive charge를 갖는 N-content가 형성되었음을 예측해 볼 수 있으며, N-content가 증가하면, 조밀한 Si-N 결합을 형성하면서, boron 및 phosphorus diffusion을 막는데 효과적이다. 또한, plasma treatment 과정에서 H-content에 의한 passivation 효과를 기대할 수 있다.

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Effects of Forest Practices on the Changes of Characteristics of Forest Stand, Mesopore Ratio and Soil Water Contents in Pinus koraiensis Stands (산림시업이 잣나무림의 생장, 토양조공극 및 토양함수능에 미치는 영향)

  • Jun, Jaehong;Jeong, Yongho;Choi, Hyung Tae;Yoo, Jae-Yun
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.11 no.3
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    • pp.20-27
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    • 2008
  • This study was conducted to investigate the influence of thinning and pruning on characteristics of forest stand, mesopore ratio and soil water content at the Pinus koraiensis stands in Gwangneung, Gyeonggido. The Pinus koraiensis had been planted in 1976 and thinning and pruning were carried out in 1996. A sample area survey was conducted at experimental plots (thinned and unthinned) in 1998 and 2005, and mesopore ratio and soil water content have been monitored from 2000 to present. Average tree height of the thinned plot increased from 10.9m to 13.2m and from 10.3m to 12.8m for the unthinned plot. Average D.B.H of the thinned plot increased from 15.9cm to 21.1cm and from 14.5cm to 16.7cm for the unthinned plot during the period 1998-2005. Crown density at the thinned plot increased from 81.5% to 95.0% and from 89.5% to 95.0% for the unthinned plot during the period 1998-2005. Mesopore ratio (pF2.7) of A layer soil at the thinned plot was 40.1% while that of the unthinned plot was 37.3%. Changes of mesopore ratio at unthinned plot were not associated with stand age, but those at thinned plot had increased and then decreased, showing declining of the practice effect. Average soil water content at the thinned plot were 23.7% and 22.4% for the unthinned plot. Soil watercontents at both plots have been increased with increase in stand age. But the difference of soil watercontent at each plot has been decreased, especially at the depth of 10cm.

Influence of Microstructure on Corrosion Property of Mg-Al-Zn Alloy

  • Lee, Jeong Ja;Na, Seung Chan;Yang, Won Seog;Jang, Si Sung;Yoo, Hwang Ryong;Hwang, Woon Suk
    • Corrosion Science and Technology
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    • v.5 no.6
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    • pp.218-221
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    • 2006
  • Influence of microstructure on the corrosion property of Mg-Al-Zn alloy was investigated using potentiodynamic polarization experiments, galvanic coupling experiments, and scanning electron microscopy in sodium chloride solutions. Pitting was the most common form of attack in chloride solution, and filiform corrosion was also occurred in AZ91D-T4 alloy. On the contrary, filiform attack in the bulk matrix was predominant corrosion form in AZ91D-T6 alloy, and the number and size of pit were decreased than those of AZ91D-T4 alloy. Galvanic coupling effect between $Mg_{17}Al_{12}$ and matrix was existed, but the propagation of galvanic corrosion was localized only near the $Mg_{17}Al_{12}$ phase in AZ91D-6T alloy. The corrosion resistance of Mg-Al matrix increased with decreasing Al content in the matrix. And, it could be regarded that Al content in the matrix is decreased by precipitation of $Mg_{17}Al_{12}$ during the aging treatment and it decreases the anodic reaction rate of the matrix and galvanic effect in AZ91D-T6 alloy. It could be considered that the composition and microstructure of surface protective layer would be varied by precipitation of $Mg_{17}Al_{12}$ and subsequent decreasing of Al content in the matrix. And it would contribute the corrosion resistance of AZ91D-T6 aging alloy.

Effects of the Wire Net Composition on Flexural Properties of Sawdustboard (철강구성(鐵鋼構成)이 톱밥보오드의 휨성질(性質)에 미치는 영향(影響))

  • Lee, Phil-Woo;Suh, Jin-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.13 no.4
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    • pp.67-72
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    • 1985
  • To improve the bending strength of sawdustboard, verious resin contents of 10, 13, 16, and 19% were applied to the thin shell (face layer) composed with wire net or not. The shell effect of sawdust and wire net composition formed with core sawdustboard were evaluated. Forcusing on the effects of wire net composition and noncomposition including a comparison with chipboard and veneer complyboard, bending properties (Modulus of rupture (MOR), Modulus of elasticity (MOE), Stress at proportional limit ($S_{pl}$). Work to maximum load ($W_{ml}$))were analyzed and discussed. 1. In modulus of rutpute, veneer comply was the highest (621.5 kg/$cm^2$), and next decreasing order was wire net composition (159.1 kg/$cm^2$), chipboard (81.75 kg/$cm^2$), and wire net noncomposition (76.21 kg/$cm^2$) as in modulus of elasticity, work to maximum load, except for stress at proportional limit. 2. The highly significant effects were shown in both wire net composition and noncomposition, at the same time wire net composition exceeded two times of noncomposition throughout resin contents in bending properties. Chipboard was similar to the mean or 16% resin content in noncomposirion. 3. Every board in wire net composition above 10% resin content was beyond 100 kg/$cm^2$ in MOR, minimum allowable strength for structural use according to KS F 3104. In conclusion, the feasibility for improving the bending strength of weak sawdustboard by wire net composed shell was offered.

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