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A Study on the Thermal Stability of an Al2O3/SiON Stack Structure for c-Si Solar Cell Passivation Application (결정질 실리콘 태양전지의 패시베이션 적용을 위한 Al2O3/SiON 적층구조의 열적 안정성에 대한 연구)

  • Cho, Kuk-Hyun;Chang, Hyo Sik
    • Journal of the Korean Ceramic Society
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    • v.51 no.3
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    • pp.197-200
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    • 2014
  • We investigated the influence of blistering on $Al_2O_3$/SiON stacks and $Al_2O_3$/SiNx:H stacks passivation layers. $Al_2O_3$ film provides outstanding Si surface passivation quality. $Al_2O_3$ film as the rear passivation layer of a p-type Si solar cell is usually stacked with a capping layer, such as $SiO_2$, SiNx, and SiON films. These capping layers protect the thin $Al_2O_3$ layer from an Al electrode during the annealing process. We compared $Al_2O_3$/SiON stacks and $Al_2O_3$/SiNx:H stacks through surface morphology and minority carrier lifetime after annealing processes at $450^{\circ}C$ and $850^{\circ}C$. As a result, the $Al_2O_3$/SiON stacks were observed to produce less blister phenomenon than $Al_2O_3$/SiNx:H stacks. This can be explained by the differences in the H species content. In the process of depositing SiNx film, the rich H species in $NH_3$ source are diffused to the $Al_2O_3$ film. On the other hand, less hydrogen diffusion occurs in SiON film as it contains less H species than SiNx film. This blister phenomenon leads to an increase insurface defect density. Consequently, the $Al_2O_3$/SiON stacks had a higher minority carrier lifetime than the $Al_2O_3$/SiNx:H stacks.

Characteristics of Hardness and Wear-Resistance of Plasma-Nitrided and Nitrocarburized Carbon Steels (플라즈마질화 및 침질탄화처리한 탄소강의 경도와 내마모특성)

  • Kim, M.K.;Jung, B.H.;Park, H.S.;Lee, B.C.;Shin, S.H.;Lee, J.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.2
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    • pp.166-173
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    • 1999
  • Commercial carbon steels containing 0.2~0.55 wt.----C were plasma-nitrided or plasma nitrocarburized at $550^{\circ}C$ for 21.6Ks using $H_2-N_2$ or $H_2-N_2$-CO mixed gas respectively. The characteristics of hardening and wear-resistance of each treatment were studied and compared. And also microstructure of nitrided layer and nitrides formed in compound layer near surface were studied. All plasma-nitrided steels investigated showed remarkable increase of surface hardness with the increase of carbon content. But nitrocarburized steels resulted in higher surface-hardness than plasma-nitrided steels, which means that nitrocarburized has higher surface-hardening effect. Plasma-nitrided steels showed hardness increase in through-thickness direction near surface. And also nitrocarburized steels showed similar hardness distribution in through-thickness direction to that of plasma-nitrided steel. However, nitrocarburized steels had higher cross-sectional maximum-hardness than plasma-nitrided steels as much as 100Hv. Wear test showed that the amount of specific wear was reduced by both plasma-nitriding and nitrocarburized, showing that the amount of specific wear was not related to the hardness. But non-treated specimen showed that the amount of specific wear was related to the hardness.

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Vertical Variation of Sediment Structure and Geochemical Characteristics of Core Sediment in Nakdong River Midstream (낙동강 중류의 주상퇴적물에서 나타나는 퇴적 구조와 지화학적 특성의 수직적 변화)

  • Kim, Shin;Lee, Kyu Yeol;Kim, Ju Eon;Lee, Kwon Chul;Ahn, Jung Min;Lee, Injung;Jung, Kang Young;Im, Tae Hyo
    • Journal of Korean Society on Water Environment
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    • v.31 no.3
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    • pp.304-312
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    • 2015
  • In this study, we tried to determine the vertical variation of sediment structure and geochemical characteristics, core sediment was collected in the Nakdong River midstream on August, 2014. Core sediment mainly composed of sand (51.48%) and silt (46.21%) and coarsing upward changed from sM to mS facies. IL and TOC were decreased from lower to upper layer. C/N ratio was lower than 10 so the organic matters were originated from underwater creatures and C/S ratio was decreased from lower to upper layer. Heavy metal (Al, Fe, Zn, Cr, Pb, Ni, Cu, Cd) content were decreased from lower to upper layer and seriously polluted condition is not. These results are thought to be due to the effect of natural and anthropogenic in the fluctuation of flow.

Effects of Pre-Aging Treatment on the Corrosion Resistance of Low Temperature Plasma Nitrocarburized AISI 630 Martensitic Precipitation Hardening Stainless Steel (저온 플라즈마 침질탄화처리된 마르텐사이트계 석출경화형 스테인리스강의 내식성에 미치는 시효 전처리의 영향)

  • Lee, Insup;Lee, Chun-Ho
    • Journal of Surface Science and Engineering
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    • v.53 no.2
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    • pp.43-52
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    • 2020
  • Various aging treatments were conducted on AISI 630 martensitic precipitation hardening stainless steel in order to optimize aging condition. Aging treatment was carried out in the vacuum chamber of Ar gas with changing aging temperature from 380℃ to 430℃ and aging time from 2h to 8h at 400℃. After obtaining the optimized aging condition, several nitrocarburizing treatments were done without and with the aging treatment. Nitrocarburizing was performed on the samples with a gas mixture of H2, N2 and CH4 for 15 h at vacuum pressure of 4.0 Torr and discharge voltage of 400V. The corrosion resistance was improved noticeably by combined process of aging and nitrocarburizing treatment, which is attributed to higher chromium and nitrogen content in the passive layer, as confirmed by XPS analysis. The optimized condition is finalized as, 4h aging at 400℃ and then subsequent nitrocarburizing at 400℃ with 25% nitrogen and 4% methane gas for 15h at vacuum pressure of 4.0 Torr and discharge voltage of 400V, resulting in the surface hardness of around 1300 HV0.05 and α'N layer thickness of around 11 ㎛ respectively.

The Research for Generating Independent Multimedia Title in Display Environment (재생 환경에 독립적인 멀티미디어 타이틀 생성 방법에 관한 연구)

  • Park, Dae-Hyuck;Kang, Eui-Sun;Hong, Maria;Seo, Jeng-Man;Lim, Young-Hwan
    • Journal of the Korea Society of Computer and Information
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    • v.11 no.1 s.39
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    • pp.55-61
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    • 2006
  • Multimedia title needs player that depends upon operate system. This raises problems of data compatibility and resource consumption by overlapping development of player. To solve problems, we propose a method which produce multimedia title contents to internet document and then display on internet browser. Contents in multimedia title are transcoded to internet pages, having greate quality, based on CSS Layer for spatial synchronization of multimedia data. This method converts existing DB into XML for multimedia title including personal information. Therefore, XML data and resource information is playable by private multimedia player. Consequently, user can display multimedia content without player using internet browser in anytime.

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Study on 3-D Physical Modeling for the Inspection of Tunnel Lining Structure by using Ultrasonic Reflection Method (터널 지보구조 진단을 위한 초음파 반사법을 이용한 3차원 모형실험 연구)

  • 김중열;김유성;신용석;현혜자
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.03a
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    • pp.221-228
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    • 2002
  • Thickness of concrete lining, voids at the back of lining or shotcrete are very important elements for inspecting the safety of tunnels. Therefore, the inspection of tunnel lining structure means to investigate the inner layer boundaries of the structure. For this purpose, seismic reflection survey is the most desirable method if it works in good conditions. However, the conventional seismic reflection method can not be properly used for investigating thin layers in the lining structure. In other words, to detect the inner boundaries, it is desirable for the wavelength of source to be less than the thickness of each layer and for the receiver to be capable of detecting high frequency(ultrasonic) signals. To this end, new appropriate source and receiver devices should be developed above all for the ultrasonic reflection survey. This paper deals primarily with the development of source and receiver devices which are essential parts of field measuring system. Interests are above all centered in both the radiation pattern, energy, frequency content of the source and the directional sensitivity of the receiver. With these newly devised ones, ultrasonic physical modeling has been performed on 3-D physical model composed of bakelite, water-proof and concrete, The measured seismograms showed a clear separation of wave arrivals reflected from each layer boundary. Furthermore, it is noteworthy that reflection events from the bottom of concrete below water-proof could be also observed. This result demonstrates the usefulness of the both devices that can be applied to benefit the ultrasonic reflection survey. Future research is being focus on dealing with at first an optimal configuration of source and receiver devices well coupled to tunnel wall, and further an efficient data control system of practical use.

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A Research for Computation of Bearing Capacity and Settlement of Foundation Considering Scale Effect in Weathered-granite Layer (화강풍화토에서 Scale Effect를 고려한 기초의 지지력 및 침하량 산정에 관한 연구)

  • 박용부;정형식
    • Journal of the Korean Geotechnical Society
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    • v.20 no.1
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    • pp.131-139
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    • 2004
  • When calculating bearing capacity and settlement of actual foundation from plate test result fur design and construction of shallow foundation, scale effect should be considered. But, adequate guide and test result of scale effect were not prepared yet in Korea. So, to analyze the relations of bearing capacity and settlement as the difference of loading plate sizes, model test and field loading test were performed with different loading plate on weathered-granite layer. Model tests were conducted with water content, compaction number, saturated unit weight and plate size(Dl5, 25cm) in soil-box$(2,000\times 2,000\times 1,000mm)$ formed soil layer. Field loading tests were carried out with diameters of loading plate$(D15, 25, 30, 40, 75\times 75, 140\times 210cm)$ on the same soil condition. Finally, we presented the prediction formula of bearing and settlement for computating scale offset in design of shallow foundation through result analysis of load test and numerical simulation on weathered soil and rock.

Effect of Alumina Content on the Hot Corrosion of SiC by NaCl and Na2SO4 (NaCl과 Na₂SO₄에 의한 SiC 고온 부식에 미치는 Alumina 첨가량의 영향)

  • 이수영
    • Journal of the Korean Ceramic Society
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    • v.28 no.8
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    • pp.625-625
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    • 1991
  • The specimens for the corrosion test were made by hot-pressing of SiC power with 2 wt% Nl2O3 and 10wt% Al2O3 additions at 2000℃ and 2050℃. The specimens were corroded in 37 mole% NaCl and 63 mole% Na2SO4 salt mixture at 1000℃ up to 60 min. SiO2 layer was formed on SiC and then this oxide layer was dissolved by Na2O ion in the salt mixture. The rate of corrosion of the specimen containing 10 wt% Al2O3 was slower than that of the specimen containing 2 wt% Al2O3. This is due to the presence of continuous grain boundary phase in the specimen containing 10 wt% Al2O3. The oxidation of SiC produced gas bubbles at the SiC-SiO2 interface. The rate of corrosion follows a linear rate law up to 50 min. and then was accelerated. This acceleration is due to the disruption oxide layer by the gas evolution at SiC-SiO2 interface. Pitting corrosion has found at open pores and grain boundaries.

A Study on the Magnetic Properties and Microstructures of Mn-Ir/Ni-Fe/Zr Muti layers with Various Compositions, Thicknesses and Base Pressures (Mn-Ir의 조성과 두께 및 초기진공도에 따른 Mn-Ir/Ni-Fe/Zr 다층막의 자기적특성과 미세구조 연구)

  • 노재철;최영석;이경섭;김용성;서수정
    • Journal of the Korean Magnetics Society
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    • v.9 no.3
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    • pp.166-172
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    • 1999
  • The magnetic properties between Mn-Ir antiferromagnetic layer and Ni-Fe ferromagnetic layer have been investigated in Mn-Ir/Ni-Fe/Zr on Si wafer formed by magnetron sputtering. Mn-Ir was sputtered from Ir chips and Mn target using D.C. power, Ni-Fe and Zr were deposited from Ni-Fe and Zr targets using D.C. power under Ar atmosphere. We studied the dependence of the magnetic properties on Ir content of Mn-Ir layer for Mn-Ir/Ni-Fe bilayer, and obtained the highest $H_ex$ of 219 Oe and the low $H_c$ of 30 Oe. And then focused on the effect of base pressure for Mn-Ir containing multilayers. Our experimental data showed that if the base pressure is higher than $3.0{\times}10^{-6}\;Torr$, the exchange anisotropy of Mn-Ir/Ni-Fe/Zr disappeared probably due to the grain refining of Mn-Ir film. In addition we have studied the dependence of Zr buffer on magnetic properties of Mn-Ir/Ni-Fe/Zr multilayers, and observed that Zr buffer about (111) texture and lower $H_c$ of Mn-Ir/Ni-Fe/Zr multilayer.

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Ecological Characteristics of Sub-Alpine Coniferous Forest on Banyabong in Mt. Jiri (지리산 반야봉 아고산 침엽수림의 생태적 특성)

  • Cho, Min-Gi;Chung, Jae-Min;Im, Hyo-In;Noh, Il;Kim, Tae-Woon;Kim, Chung-Yeol;Moon, Hyun-Shik
    • Journal of Climate Change Research
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    • v.7 no.4
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    • pp.465-476
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    • 2016
  • This study was conducted to elucidate the ecological characteristics of sub-alpine coniferous forest on Banyabong, Mt. Jiri. Soil pH was 4.20. The contents of organic matter, total N, available P and CEC were 14.15%, 0.43%, 10.1 ppm and $17.17cmol^+/kg$, respectively. Sub-alpine coniferous forest had a relatively soil moisture content with 22.9%. According to the results of importance value analysis, Picea jezoensis (42.7) and Abies koreana (34.0) for tree layer, Rhododendron schlippenbachii (25.5) for subtree layer and Tripterygium regelii (18.4) and Rhododendron mucronulatum (16.6) for shrub layer were high, respectively. Shannon's diversity ranged from 0.3560 to 1.050. Evenness and dominance ranged from 0.398 to 0.733 and 0.267 to 0.601, respectively. A. koreana population had a reverse J-shaped DBH distribution, while P. jezoensis population had a normal DBH distribution. Height growth according to DBH of A. koreana was higher than that of P. jezoensis, which indicate than A. koreana have more effective water use efficiency than P. jezoensis. Annual mean tree ring growth of P. jezoensis and A. koreana showed up 1.792, 1.652, 1.389 mm/yr and 2.081, 1.921, 1.576 mm/yr for small, middle and large diameter tree, respectively.