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Sorption Equilibria and Transport of Gaseous Chlorinated Organic Solvent in Wet Solid Waste Layer (도시고형폐기물(都市固形廢棄物) 및 토양층(土壤層)에 있어서 비(非)이온성(性) 유해유기화학물질(有害有機化學物質)의 거동(擧動)에 관한 연구(硏究) (습윤고형물폐기물층(濕潤固形物廢棄物層)에 있어서 기체상(氣體相) 유해유기염소화물질(有害有機鹽素化物質)을 주대상(主對象)으로))

  • Lee, Donghoon;Tanaka, Nobutoshi
    • Journal of Korean Society of Water and Wastewater
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    • v.7 no.2
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    • pp.9-23
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    • 1993
  • Emission of hazardous and volatile organic chemicals from solid waste landfill site was become to important issue because of environmental pollution and health risk by such chemicals. Laboratory batch and continuous experiments were conducted respectively to elucidate isothermal sorption behaviors and transport phenomena(by gas through unsaturated solid waste layer) in wet solid waste-gas system. Source separated and size reduced refuse(bulky waste) and incinerated ash were used after controlling water content, and trichloroethylene(TCE) was chosen among many such chemicals because of it's generality among those man-created pollutants. Isothermal TCE sorption equilibria wet solid waste-gas system can be described in linear equation and partition coefficient in this system can be estimated approximately by the simple equation derived from schematic structure of the system. Transport equation modified by instantaneous equilibrium sorption fraction and kinetic sorption rate(overall mass transfer capacity coefficient) simulated well the column experiment results.

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Effects of Cold Rolling Parameters on Sagging Behavior for Three Layer Al-Si/Al-Mn(Zn)/Al-Si Brazing Sheets

  • S.H. Lee;J.S. Yoon;M.S. Kim;D. Jung
    • Transactions of Materials Processing
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    • v.8 no.3
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    • pp.227-227
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    • 1999
  • The effects of intermediate annealing (IA) and the final cold rolling (CR) condition on the microstructure and sagging resistance during brazing were investigated using three layer clad sheets composed of the Al-7.5 wt.%Si alloy (filler, thickness: 10 ㎛)/Al-1.3 wt.%Mn based alloy (core, 80㎛)/Al-7.5 wt.%Si alloy (filler, 10㎛). Also, the effect of 1.2∼2 wt.% Zn addition into the core on the sagging resistance of the clad sheets was determined. It was revealed that all the clad sheets fabricated by the optimum condition (IA at 690 K and CR to 20∼45%) show excellent sagging resistance with a limited erosion due to the formation of a coarsely recrystallized grain structure in the core during brazing. It was also revealed that the recrystallization behavior of the Al-1.3 wt.%Mn based alloy is hardly affected by the addition of 1.2-2 wt.%Zn during the brazing cycle. Therefore, the sagging resistance of the clad sheets is found to be governed not by the Zn content added in the A1-1.3wt.%Mn based core, but by the intermediate annealing and final cold rolling condition.

A Study on Properties of Electrodeposited Nickel-Cobalt Alloy Films from Sulfamate Solution (설파민산 니켈-코발트 합금도금 박막 물성에 대한 실험 연구)

  • Koo, Seokbon;Jeon, Junmi;Lee, Changmyeon;Hur, Jinyoung;Lee, HongKee
    • Journal of Surface Science and Engineering
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    • v.50 no.1
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    • pp.24-28
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    • 2017
  • The electrodeposition of Ni-Co alloy from a sulfamate bath was investigated. The cobalt content in the Ni-Co deposits is more influenced by the temperature or stirring effect than the current density in the process parameters. As cobalt contents in the Ni-Co deposited layer increased from 0 wt.% up to 43 wt.%, hardness value of the layer rised from 400 Hv up to 700 Hv and crystal orientation (111) increased. However, (200) and crystal size significantly reduced. The tensile and yield strength also increased, while the modulus of elasticity showed the maximum value of $10.4N/mm^2$ at 29 wt.%.

Radio environment maps: The survey of construction methods

  • Pesko, Marko;Javornik, Tomaz;Kosir, Andrej;Stular, Mitja;Mohorcic, Mihael
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.8 no.11
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    • pp.3789-3809
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    • 2014
  • Radio environment maps (REMs) and geolocation database represent an important source of information for the operation of cognitive radio networks, replacing or complementing spectrum sensing information. This paper provides a survey of methods for constructing the radio frequency layer of radio environment map (RF-REM) using distributed measurements of the signal levels at a given frequency in space and time. The signal level measurements can be obtained from fixed or mobile devices capable of sensing radio environment and sending this information to the REM. The signal measurements are complemented with information already stored in different REM content layers. The combined information is applied for estimation of the RF-REM layer. The RF-REM construction methods are compared, and their advantages and disadvantages with respect to the spatial distribution of signal measurements and computational complexity is given. This survey also indicates possible directions of further research in indirect RF-REM construction methods. It emphasizes that accurate RF-REM construction methods should in the best case support operation with random and clustered signal measurements, their operation should not be affected by measurements outliers, and it must estimate signal levels comparably on all RF-REM locations with moderate computational effort.

Effects of Fly Ash Supplementation on the Corn, Rye and Alfalfa Yields by Fertilization of Livestock Waste Composting (석탄회 처리 가축분뇨 퇴비가 옥수수, 호맥 및 알팔파의 생산성에 미치는 영향)

  • 고영두;김재황;김두환;유성오;고병구;이수칠;이종찬;김삼철
    • Journal of Animal Environmental Science
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    • v.5 no.1
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    • pp.63-72
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    • 1999
  • This study was carried out to improve utilization of fly ash. Each animal waste was mixed with fly ash and composted This compost used at forage crops with corn, rye and alfalfa to examine to examine the fertilized efficiency and investigated productivity of forage crops, composition of this copmost and effect of fly ash on soil characteristics and composition. Content of organic matte, P2O5, K2O, CaO, MgO, Mn and B at the soil, which is given fly ash, increased. After the test crops were harvested, pH of the soil was maintained about 7 and contents of organic matter, phosphoric aicd, K, Mg, and B was increased at the soil of used fly ash. As fly ash was mixed, each DM yield of corn and rye was increased 10∼13% and 14∼21% especially alfalfa was increased 35% at the soil which is mixed fly ash with cage layer manure. As fly ash was mixed, each Crude protein (CP) of corn and rye was increased 6∼17% and about 29%, especially, as fly and cage layer manure was mixed CP of alfalfa was increased 33%. In conclusion, as fly ash is mixed with anlmal waste and use at forage crops, It makes the soil good and improve the productivity of forage crops.

Experimental Investigation of Clay Fly Ash Bricks for Gamma-Ray Shielding

  • Mann, Harjinder Singh;Brar, Gurdarshan Singh;Mann, Kulwinder Singh;Mudahar, Gurmel Singh
    • Nuclear Engineering and Technology
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    • v.48 no.5
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    • pp.1230-1236
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    • 2016
  • This study aims to determine the effect of fly ash with a high replacing ratio of clay on the radiation shielding properties of bricks. Some interaction parameters (mass attenuation coefficients, half value layer, effective atomic number, effective electron density, and absorption efficiency) of clay fly ash bricks were measured with a NaI(Tl) detector at 661.6 keV, 1,173.2 keV, and 1,332.5 keV. For the investigation of their shielding behavior, fly ash bricks were molded using an admixture to clay. A narrow beam transmission geometry condition was used for the measurements. The measured values of these parameters were found in good agreement with the theoretical calculations. The elemental compositions of the clay fly ash bricks were analyzed by using an energy dispersive X-ray fluorescence spectrometer. At selected energies the values of the effective atomic numbers and effective electron densities showed a very modest variation with the composition of the fly ash. This seems to be due to the similarity of their elemental compositions. The obtained results were also compared with concrete, in order to study the effect of fly ash content on the radiation shielding properties of clay fly ash bricks. The clay fly ash bricks showed good shielding properties for moderate energy gamma rays. Therefore, these bricks are feasible and eco-friendly compared with traditional clay bricks used for construction.

Oxidation Behavior of $Ni_xFe_{1-x}(OH)_2$ in $C\Gamma$-containing Solutions

  • Chung, Kyeong Woo;Kim, Kwang Bum
    • Corrosion Science and Technology
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    • v.2 no.3
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    • pp.148-154
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    • 2003
  • The addition of Ni leads to the formation of protective rust layer on steel and subsequently high corrosion resistance of steel in $Cl^-$-containing environment. $\alpha$-FeOOH, $\beta$-FeOOH, $\gamma$-FeOOH and $Fe_3O_4$ are formed mainly on steels exposed to $Cl^-$-containing environment. As the first work of this kind, this study reports the influence of Ni on the oxidation behavior of $Ni_xFe_{1-x}(OH)_2$ in $Cl^-$-containing solution at two different pH regions(condition I under which the solution pH is allowed to decrease and condition I under which solution pH is maintained at 8) where $\gamma$-FeOOH and $Fe_3O_4$ are predominantly formed, respectively, upon oxidation of $Fe(OH)_2$, In the presence of Ni(II) in the starting solution, the formation of $\beta$-FeOOH was facilitated and the formation of $\gamma$-FeOOH was suppressed with increasing Ni(II) content and with increasing oxidation rate of Fe(II). Ni(II) was found to have $Fe_3O_4$-suppressing effect under condition II.

The Physical Properties and Efficiencies of Cu(In,Ga)Se2 Thin Films Depending on the Mo:Na Thickness (Mo:Na 두께에 따른 Cu(In,Ga)Se2 박막의 물성과 효율변화)

  • Shin, Younhak;Kim, Myunghan
    • Korean Journal of Materials Research
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    • v.24 no.3
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    • pp.123-128
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    • 2014
  • To realize high-performance thin film solar cells, we prepared CIGS by the co-evaporation technique on both sodalime and Corning glass substrates. The structural and efficient properties were investigated by varying the thickness of the Mo:Na layer, where the total thickness of the back contact was fixed at 1${\mu}m$. As a result, when the Mo:Na thickness was 300 nm on soda-lime glass, the measured Na content was 0.28 %, the surface morphology was a plate-like compact structure, and the crystallinity by XRD showed a strong peak of (112) preferential orientation together with relatively intense (220) and (204) peaks as the secondary phases influenced crystal formation. In addition, the substrates on soda-lime glass effected the lowest surface roughness of 2.76 nm and the highest carrier density and short circuit current. Through the optimization of the Mo:Na layer, a solar conversion efficiency of 11.34% was achieved. When using the Corning glass, a rather low conversion efficiency of 9.59% was obtained. To determine the effects of the concentration of sodium and in order to develop a highefficiency solar cells, a very small amount of sodium was added to the soda lime glass substrate.

Preparation and Dissolution Characteristics of Sustained Release Pellets Containing Isosorbide Dinitrate (질산 이소소르비드가 함유된 서방형 펠렛의 제조 및 용출 특성)

  • Lee, Gye-Won;Kim, Hak-Hyung;Ryu, Sung-Kyun
    • Journal of Pharmaceutical Investigation
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    • v.38 no.6
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    • pp.381-385
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    • 2008
  • Isosorbide dinitrate is an oral assiatant therapy agent of angina pectoris, myocardial infarction and congestive heart failure. The objective of this study was to formulate sustained release containing isosorbide dinitrate and assess their formulation variables. Pellets were prepared by fluid bed process and consist of drug layer and membrane layer. The pellets were coated with ethylcellulose along with $5{\sim}15%$ of plasticizer such as triacetin and diethyl butylrate. In vitro evaluation study was performed by comparative dissolution test between test and reference isosorbide dinitrate preparation. We could prepare sustained pellets of isosorbide dinitrate by fluid bed process which were reduced process time and had high content. The pellet coated with 1% ethylcellulose and triacetin(l5%) had a similar dissolution behavior compare to reference isosorbide dinitrate preparation controlling initial dissolution and those of dissolution at 30 min were 17.25 and 17.09%, respectively. Difference factor and similarity factor were $0{\sim}15$ and $50{\sim}100$ and there was no significant difference in bioequivalence between formulations. It might be concluded that our sustained release pellet of isosorbide dinitrate could be an alternatively delivery system to reference drug preparation.

The Effects of Gas Compositions During Post Nitriding on the AISI 316L Stainless Steel after Plasma Carburizing

  • Lee, Insup
    • Journal of Surface Science and Engineering
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    • v.48 no.6
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    • pp.269-274
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    • 2015
  • In this experiment, post-nitriding treatment was performed at $400^{\circ}C$ on AISI 316 stainless steel which was plasma carburized previously at $430^{\circ}C$ for 15 hours. Plasma nitriding was implemented on AISI 316 stainless steel at various gas compositions (25% $N_2$, 50% $N_2$ and 75% $N_2$) for 4 hours. Additionally, during post nitriding Ar gas was used with $H_2$ and $N_2$ to observe the improvement of surface properties. After treatment, the behavior of the hybrid layer was investigated by optical microscopy, X-ray diffraction, and micro-hardness testing. Potentiodynamic polarization test was also used to evaluate the corrosion resistance of the samples. Meanwhile, it was found that the surface hardness increased with increasing the nitrogen gas content. Also small percentage of Ar gas was introduced in the post nitriding process which improved the hardness of the hardened layer but reduced the corrosion resistance compared with the carburized sample. The experiment revealed that AISI 316L stainless steel showed better hardness and excellent corrosion resistance compared with the carburized sample, when 75% $N_2$ gas was used during the post nitriding treatment. Also addition of Ar gas during post nitriding treatment degraded the corrosion resistance of the sample compared with the carburized sample.