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Tribological behavior of multi-layered diamond-like carbon films (다층 다이아몬드상 카본 필름의 윤활 및 마모 거동)

  • 김명근;이광렬;은광용
    • Journal of the Korean Vacuum Society
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    • v.7 no.1
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    • pp.59-65
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    • 1998
  • Multi-layer diamond-like carbon (DLC) films were deposited by 13.56 MHz r.f. PACVD method. Multi-layer DLC film was composed of 2.5 $mu extrm{m}$ thick pure DLC filml and 0.2$\mu\textrm{m}$ thick Si incorporated DLC (Si-DLC) film as a surface layer. Tribological behaviors of the multi-layer DLC film were investigated with a ball-on-disk type tribometer in ambient atmosphere using AISI 52100 steel ball. Low friction coefficient (<0.1) period increased with increasing the Si content in the surface Si-DLC film. The wear rate after 44,000 cycles and 158,400 cycles were the $2.5\times10^{-8}\sim1.8\times10^{-7}\textrm{mm}^3$/rev. and $7.1\times10^{-9}\sim1.8\times10^{-8}\textrm{mm}^3$/rev.,respectively. The wear rate of the multi-layer DLC film after 158,400 cycles was about 2 times smaller than that of pure DLC films of 2.7 $\mu\textrm{m}$ thickness. This high wear resistance and low friction coefficient was caused by the formation of Si oxide layer on the wear scar surface, as confirmed by the debris composition analysis. It was further shown that this si oxide debris layer on the wear scar surface is formed again even after removing the debris of the steel ball, which maintain the low friction coefficient between multi-layer DLC films and steel ball.

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Structures and Double Layer Performances of Carbons Pyrolized from Carbon Oxides (산화탄소로부터 열분해한 탄소의 구조 및 전기이중층 거동)

  • Kim, Ick-Jun;Yang, Sunhye;Jeon, Min-Je;Moon, Seong-In;Kim, Hyun-Soo;An, Kye-Hyeok
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.522-526
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    • 2007
  • Structural features and electrochemical performances of cokes pyrolized from oxidized cokes were examined, and compared with KOH-activated coke. Needle cokes ($d_{002}=3.5{\AA} $), having a graphene layer structure, were changed to a single phase of graphite oxide after oxidation treatment with an acidic solution having an $NaCLO_3$/needle coke composition ratio of above 7.5, and the inter-layer distance of the oxidized coke was expanded to $6.9{\AA} $ with increasing oxygen content. After heating at $200^{\circ}C$, the oxidized coke was pyrolized to the graphene layer structure with inter-layer distance of $3.6{\AA} $. However, the change of the inter-layer distance of the needle coke was not observed in the KOH activation process. On the other hand, an intercalation of electrolyte ions into the pyrolized coke, observed at first charge, occurred at 1.0 V, in which the value was lower than that of KOH-activation coke. The cell capacitor using pyrolized coke exhibited a lower internal resistance of $0.57{\Omega}$ in 1 kHz, and a larger capacitance per weight and volume of 30.3 F/g and 26.9 F/ml at the two-electrode system in the potential range 0~2.5 V than those of the cell capacitor using KOH-activation of coke. This better electrochemical performance may be associated with structure defects in the graphene layer derived from the process of the inter-layer expansion and shrinkage.

Multimedia documents for user interfaces of cooperative work (공동 작업을 위한 사용자 인터페이스로서의 멀티미디어 문서)

  • 성미영
    • Proceedings of the ESK Conference
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    • 1995.10a
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    • pp.46-55
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    • 1995
  • The multimedia documents becomes the most natural user interface for CSCW(Conputer Supported Cooperative Work) in distributed environment. The objective of this study is to propose a multimedia document architecture and to develop a system that can manage it well. The new architecture is for revisable documents and is the basic layer for hypermedia documents. A good document architecture for CSCW must support pointing, marking, and editing over a part of documents. The user views, version control, and full- content search are also desirable features. In this paper, we discuss the basic concept of a new document architecture for CSCW. We also present the user interfaces for spatio-temporal compositions of multimedia documents.

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Surface Graft Copolymerization of Acrylamide onto Polyacrylonitrile (아크릴아미드의 PAN에 대한 표면 그라프트 공중합에 관한연구)

  • 최재혁;김한도
    • Textile Coloration and Finishing
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    • v.5 no.2
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    • pp.144-148
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    • 1993
  • To increase the moisture content and thereby to reduce the static charge of polyacrylonitrile (PAN), thin layer surface photografting of acylamide (AAm) onto PAN fabrics by using benzophenone as a initiator with a mixtured solvent was carried. The effects of reaction conditions such as monomer, initiator concentrations, UV irradiation time and immersion time of fabrics on grafting were investigated. The percent grafting slightly increased with increasing monomer concentration, benzophenone concentration up to limiting value and thereafter decreased or level offed. The percent grafting was significantly increased with increasing irradiation and immersion times. The moisture regain increased with increasing the percent grafting. The static charge decreased with increasing the percent grafting.

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High efficacy PDP

  • Oversluizen, G.;Dekker, T.;Gillies, M. F.;Zwart, S.T. de
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.339-342
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    • 2003
  • Main PDP panel efficacy improvement factors are discussed. A large panel efficacy improvement can be obtained through a combination of discharge efficiency improvement and phosphor improvement. Important design elements are a high Xe-content gas mixture, the application of a $TiO_2-layer$, and a new green phosphor with little saturation at high VUV-load. In a 4-inch color test panel with a conventional stripe-type cell configuration a white efficacy of 4.4 lm/W and a luminance of 5000 $cd/m^2$ is obtained for sustaining at 250V in addressed condition.

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Tribological Behavior of the Alumina Reinforced with Unidirectionally Oriented SiC whiskers (일방향성 배열을 가잔 SiC whisker에 의해 강화된 알루미나 복합체의 마모마찰 특성)

  • 간태석;임대순;한병동
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1998.10a
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    • pp.25-29
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    • 1998
  • Sliding wear test and surface characterization techniques such as micro-Raman spectroscopy were employed to determine the effect of whisker content and orientation on the friction and wear behavior of SiC whisker reinforced alumina. Composites containing unidirectionally oriented whiskers were fabricated by novel technique Addition of SiC whiskers up to 20 vol.% lowered the friction and improved wear resistance. The results of this study indicated that highly disordered graphite and size of the layer behind the whiskers were responsible for variation of wear rate and friction coefficient.

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The Study of Nano-Mechanical Properties of TiAlSiN Coating Layer with Nitrogen Content (질소 함량에 따른 TiAlSiN 코팅층의 나노 기계적 특성 평가)

  • Gang, Bo-Gyeong;Choe, Yong;Baek, Yeol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.255-255
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    • 2015
  • 나노압침방법을 적용하여 arc ion plating을 통해 제조된 TiAlSiN 코팅층의 질소 함량에 따른 나노 기계적 특성을 평가하였다. 코팅층의 질소 함량은 28~30 [at.%] 이었다. 코팅층에는 AlN, TiSi, $Al_5Ti_3$, $Ti_3AlN$, $Al_5Ti_2$ 상이 형성되었다. 질소 함량이 더 작은 코팅층의 나노경도, 마찰계수, 피로한계의 값이 높아짐을 알 수 있었다.

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A.C. Impedance Properties of HA/Ti Compound Layer coated Ti-30Ta-(3~15)Nb Alloys (Ti-30Ta-(3~15)Nb 합금에 HA/Ti 복합 코팅한 표면의 교류임피던스 특성)

  • Jeong, Y.H.;Lee, H.J.;Moong, Y.P;Park, G.H.;Jang, S.H.;Son, M.K.;Choe, H.C.
    • Journal of Surface Science and Engineering
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    • v.41 no.5
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    • pp.181-188
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    • 2008
  • A.C. impedance properties of HA/Ti compound layer coated Ti-30Ta-($3{\sim}15$)Nb alloys have been studied by electrochemical method. Ti-30Ta binary alloys contained 3, 7, 10 and 15 wt% Nb were manufactured by the vacuum furnace system. And then specimen was homogenized at $1000^{\circ}C$ for 24 hrs. The sample was cut and polished for corrosion test and coating. It was coated with HA/Ti compound layer by magnetron sputter. The non-coated and coated morphology of Ti alloy were analyzed by X-ray diffractometer (XRD), energy X-ray dispersive spectroscopy (EDX) and filed emission scanning electron microscope (FE-SEM). The corrosion behaviors were investigated using A.C. impedance test (PARSTAT 2273, USA) in 0.9% NaCl solution at $36.5{\pm}1^{\circ}C$. Ti-30Ta-($3{\sim}15\;wt%$)Nb alloys showed the ${\alpha}+{\beta}$ phase, and $\beta$ phase peak was predominantly appeared in the case of increasingly Nb contents. The microstructures of Ti alloy were transformed from needle-like structure to equiaxed structure as Nb content increased. From the analysis of coating surface, HA/Ti composite surface uniformed coating layer with 750 nm thickness. The growth directions of film were (211), (112), (300) and (202) for HA/Ti composite coating on the surface after heat treatment at $550^{\circ}C$, whereas, the growth direction of film was (110) for Ti coating. The polarization resistance ($R_p$) of HA/Ti composite coated Ti-alloys were higher than those of the Ti and HA coated samples in 0.9% NaCl solution at $36.5{\pm}1^{\circ}C$. Especially, corrosion resistance of Ti-Ta-Nb system increased as Nb content increased.

Stratigraphy of Late Quaternary Core Sediments and Comparative Study of the Tephra Layers from the Northwestern Ulleung Basin of the East Sea (울릉분지 북서부 해역의 코어퇴적물에 대한 제4기 후기 테프라 층서 및 테프라층 비교 연구)

  • 김일수;박명호;류병재
    • Economic and Environmental Geology
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    • v.36 no.3
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    • pp.225-232
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    • 2003
  • Three piston cores. obtained from the northwestern Ulleung Basin of the East Sea, are analyzed to study the tephrostratigraphy of the late Quaternary core sediments and to reveal the comparative characteristics of the tephra layers. The cores consist mainly of the muddy sediments that are partly interbedded with lapilli tephra and ash layers. The muds are further divided into hemipelagic and turbiditic mud facies. The hemipelagic facies is dominated by bioturbated mud and crudely laminated mud, whereas the turbiditic facies includes mainly thinly laminated mud and homogeneous mud, and often alternates with non-turbiditic muds. According to microscopic observation and EDX analysis, three tephra layers of the Ulleung-Oki (U-Oki; ca. 9.3 ka), Aira-Tanzawa (AT: ca. 22~24.7 ka) and Ulleung-Yamato (U-Ym; ca. 25~33 ka) are identified in the study cores. Among these, the U-Oki and U-Ym layers, originating from the Ulleung Island, consist mainly of massive-type glass shards with alkali feldspar. Both of the tephra layers contain a lower content of SiO$_2$ (57~66.5 wt.%) and a higher content of Na$_2$O+K$_2$O (11~16 wt.%) than the AT layer (SiO$_2$=75~78.5 wt.%, Na$_2$O+K$_2$O=6.5~9 wt.%) that consists of typical plane-type and/or bubble-wall glass grains. Compared with that of the U-Ym layer, a sedimentary facies of the U-Oki layer is very thick and contains three stratigraphic units, probably due to relatively large and different supplies of pyroclastic sediments. Thus, the eruption of Ulleung Volcano (ca. 7,300 B.C.) is thought to have had a more powerful effect on depositional environment than the U-Ym eruption.

Recovery of Covalently Linked Fatty Acid Monolayer on the Hair Surface Using Biomimetic Lipid (생체모사 지질을 이용한 모발 표면에 공유 결합된 지방산 단분자층의 회복)

  • Kim, Ei-Suk;Son, Seong-Kil;Lee, Cheon-Koo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.38 no.2
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    • pp.139-145
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    • 2012
  • There is a unique type of fatty acid in the hair surface. 18-methyleicosanoic acid (18-MEA) is an unusual anteiso fatty acid covalently linked to the outermost surface of hair cuticle. A layer of 18-MEA is located in the upper ${\beta}$-layer of the CMC that is responsible for the low surface energy and low friction resistance of the hair's outer surface. The high mobility of 18-MEA molecule facilitates spreading of extraneous lipid by decreasing interfacial shear strength. In this study, we introduced N-hydroxyl succinimidyl ester functional group to the one end of C10 - 40 isoalkyl acid for regenerating hair surface with covalently bound fatty acid layer. The re-hydrophobicization of hair surface has been investigated by contact angle measurement. The inner moisture content of hair at different levels of humidity (40, 55, 70 %RH) was measured by electric moisture analyzer. Treatment with Hydroxysuccinimidyl C10 - 40 Isoalkyl Acidate (HCIA) was supposed to make hair surface smoother by filling the cracks between cuticles with covalently bound fatty acid monomolecular layer like cuticle glue. This glue effect was also confirmed with line profile of AFM images. Therefore, the moisture and structural components of inner hair were not easily flown out and the optimum moisture content could be kept constantly though the outside humidity level was changed. The lateral force microscopy (LFM) by using atomic force microscope showed that the friction force of hair surface treated with HCIA was decreased. It also showed the constantly sustained friction value even after shampooing repeated 15 times.