• Title/Summary/Keyword: Content layer

Search Result 1,666, Processing Time 0.025 seconds

Corrosion of AI-Fe Coatings for Wet-Seal Area in Molten Carbonate Fuel Cells

  • Jun, JaeHo;Jun, JoongHwan;Kim, KyooYoung
    • Corrosion Science and Technology
    • /
    • v.3 no.3
    • /
    • pp.98-101
    • /
    • 2004
  • The corrosion behavior of Al-Fe coatings was studied in the wet-seal atmosphere of molten carbonate fuel cells (MCFC). Fe-8Al, Fe-16Al, Fe-25Al, Fe-36Al, and Fe-70Al (in at.%) specimens were tested in Li/K carbonate at $650^{\circ}C$ by a single cell test and an immersion test. In general, the corrosion resistance of the Al-Fe coatings was enhanced due to the formation of a protective $LiAlO_2$ layer. However, when the Al-Fe coatings didn't have sufficient content of aluminum enough for maintaining the protective layer, the corrosion resistance of the Al-Fe coatings was severely degraded by the growth of non-protective scales like $LiAlO_2$. The test results revealed that the aluminum contents in the coatings should be higher than 25 at.% in order to form and maintain the protective $LiAlO_2$ layers.

Effects of carbonization temperature on pore development in polyacrylonitrile-based activated carbon nanofibers

  • Lee, Hye-Min;An, Kay-Hyeok;Kim, Byung-Joo
    • Carbon letters
    • /
    • v.15 no.2
    • /
    • pp.146-150
    • /
    • 2014
  • In this work, activated carbon nanofiber (ACNF) electrodes with high double-layer capacitance and good rate capability were prepared from polyacrylonitrile nanofibers by optimizing the carbonization temperature prior to $H_2O$ activation. The morphology of the ACNFs was observed by scanning electron microscopy. The elemental composition was determined by analysis of X-ray photoelectron spectroscopy. $N_2$-adsorption-isotherm characteristics at 77 K were confirmed by Brunauer-Emmett-Teller and Dubinin-Radushkevich equations. ACNFs processed at different carbonization temperatures were applied as electrodes for electrical double-layer capacitors. The experimental results showed that the surface morphology of the CNFs was not significantly changed after the carbonization process, although their diameters gradually decreased with increasing carbonization temperature. It was found that the carbon content in the CNFs could easily be tailored by controlling the carbonization temperature. The specific capacitance of the prepared ACNFs was enhanced by increasing the carbonization temperature.

Oxidation Resistance of Al Diffusion Coating Layer on TiAl (TiAl합금의 Al 피복시 Al확산 피복층의 내고온산화성)

  • Lee, C.H.;Choe, J.I.
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.10 no.2
    • /
    • pp.150-156
    • /
    • 1997
  • The effect of variation of pack activators, compositions, temperature and time on the thickness and structure of aluminide coatings formed on the TiAl alloy was studied in one-step packs and two-step packs containing aluminum for the purpose of improvement of oxidation resistance. The thickness of coating layer was increased with increasing $NH_4Cl$ content up to 3wt% and then it was saturated. Oxidation resistance of coating layers carried out at one step pack was superior to that of ones through of two step pack. The improvement of high temperature oxidation resistance was due to the formation of a protective $Al_2O_3$ surface layers and coating the alloys with $TiAl_3$ phase.

  • PDF

Enhancement of Surface Hardness and Corrosion Resistance of AISI 310 Austenitic Stainless Steel by Low Temperature Plasma Carburizing Treatment

  • Lee, Insup
    • Journal of Surface Science and Engineering
    • /
    • v.50 no.4
    • /
    • pp.272-276
    • /
    • 2017
  • The response of AISI 310 type austenitic stainless steel to the novel low temperature plasma carburizing process has been investigated in this work. This grade of stainless steel shows better corrosion resistance and high temperature oxidation resistance due to its high chromium and nickel content. In this experiment, plasma carburizing was performed on AISI 310 stainless steel in a D.C. pulsed plasma ion nitriding system at different temperatures in $H_2-Ar-CH_4$ gas mixtures. The working pressure was 4 Torr (533Pa approx.) and the applied voltage was 600 V during the plasma carburizing treatment. The hardness of the samples was measured by using a Vickers micro hardness tester with the load of 100 g. The phase of carburized layer formed on the surface was confirmed by X-ray diffraction. The resultant carburized layer was found to be precipitation free and resulted in significantly improved hardness and corrosion resistance.

Effect of Air Content on the Heat Transfer Characteristics of Nonwoven Insulating Materials (부직포내 공기함량이 열전달에 미치는 영향)

  • 김희숙;김은애
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.18 no.2
    • /
    • pp.244-251
    • /
    • 1994
  • The purpose of this study was to analyze conductive convective and radiative heat transfer characteristic of the nonwovens were studied by measuring thermal conductance at atmospheric and low air pressure. The results obtained were as follows . 1) As thickness of air layer Increased, overall heat transfer was decreased by reducing conductive and radiative heat trasfer. 2) The conductive and convective heat trasfer by air were in the range of 79~8971 of overall heat transfer. 3) As thickness of nonwoven increased for a given solidity, overall heat trasfer was decresed by increasing total thickness of air layer and by reducing conductive and radiative heat transfer. 4) For a given weight, increasing thickness is more effective than increasing solidity.

  • PDF

Water Chemistry Profiles under Korean White Pine (Pinus koraiensis S. et Z.) Stand (잣나무 임분에 있어서 강우수질의 이동 특성)

  • Jin Hyun-O;Chung Doug-Young;Lee Choong-Hwa
    • Korean Journal of Agricultural and Forest Meteorology
    • /
    • v.1 no.2
    • /
    • pp.110-118
    • /
    • 1999
  • This experiment was conducted to characterize the vertical transport trend of dissolved elements through throughfall, stemflow, effluent from Ao layer, and leachate out of soil profile on Pinus koraiensis stand in Experimental Forest of Kyunghee University, located in Kwangju, Kyunggi province for 12 months from July, 1998 to Jun, 1999. In addition, we investigated the content of dissolved elements and the factors influencing the water chemistry concentrations separately collected from the field. Water movement in the process of throughfall and stemflow from precipitation, and rainfall leached from Ao layer into soil water was governed by concentration of through fall, precipitation, rainfall intensity, seasonal variation, and other factors. Also, smaller changes of pH in soil water than that of dissolved elements in soil water could contribute buffer capacity, as well as balancing the concentration between cations and anions.

  • PDF

Characteristics of Microstructure of Hardfacing Layer of Stellite 6 with Mo Addition (몰리브덴을 첨가하여 PTAW법으로 육성된 Stellite 6합금의 미세조직 특성평가)

  • 신종철;김재수;이덕열;양재웅;윤진국;노대호;이종권
    • Journal of Surface Science and Engineering
    • /
    • v.35 no.4
    • /
    • pp.241-248
    • /
    • 2002
  • Hardfacing layers of Stellite 6 alloy with different molybdenum content are deposited on AISI 1045 carbon steel using plasma transferred arc welding (PTAW). The properties of the hardfacing layer are investigated in order to clarify the effect of molybdenum addition to the cobalt-base alloy. With an increase in molybdenum contents, the size of Cr-rich carbides in the interdendritic region is abruptly refined, but volume fraction of the carbide slightly increases. Also, with an increase of Mo, $M_{6}$ C type carbides are formed instead of Cr-rich $M_{7}$ $C_{3}$ type carbided, and this microstructural change enhanced the mechanical properties of Stellite 6 alloy.

Surface hardening and enhancement of Corrosion Resistance of AISI 310S Austenitic Stainless Steel by Low Temperature Plasma Nitrocarburizing treatment.

  • Lee, Insup
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2012.11a
    • /
    • pp.175-177
    • /
    • 2012
  • A corrosion resistance and hard nitrocarburized layer was distinctly formed on 310 austenitic stainless steel substrate by DC plasma nitrocarburizing. Basically, 310L austenitic stainless steel has high chromium and nickel content which is applicable for high temperature applications. In this experiment, plasma nitrocarburizing was performed in a D.C. pulsed plasma ion nitriding system at different temperatures in $H_2-N_2-CH_4$ gas mixtures. After the experiment structural phases, micro-hardness and corrosion resistance were investigated by the optical microscopy, X-ray diffraction, scanning electron microscopy, micro-hardness testing and Potentiodynamic polarization tests. The hardness of the samples was measured by using a Vickers micro hardness tester with the load of 100 g. XRD indicated a single expanded austenite phase was formed at all treatment temperatures. Such a nitrogen and carbon supersaturated layer is precipitation free and possesses a high hardness and good corrosion resistance.

  • PDF

Hydrogen Effects on Diamond-like Carbon as the LC alignment Layer of FFS mode

  • You, Jae-Geon;Kim, Sung-Ju;Gwag, Jin-Seog;Lee, Hyun-Kyung;Lee, Dae-Kyu;Ahn, Jun-Yong;Jun, Jung-Mok;Lee, Jung-Yeal
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2005.07a
    • /
    • pp.349-352
    • /
    • 2005
  • In this paper, we have investigated the hydrogen effects on Diamond-like Carbon (DLC) as an LC alignment layer of the FFS mode. By change of a Hydrogen content in the DLC sputtering process, the image sticking and electro-optic characteristics of Black-White panel with DLC / IB technology were examined.

  • PDF

Geotextiles Horizontal Drain between Earth Fills and Natural Soft Ground (토목섬유를 사용한 무처리 연약지반과 성토사이의 수평배수층)

  • Lee, Hyoung-Kyu;Kong, Kil-Yong;Kim, Hyun-Tae
    • Magazine of the Korean Society of Agricultural Engineers
    • /
    • v.44 no.4
    • /
    • pp.129-138
    • /
    • 2002
  • This paper presents a study on the discharge capacity of geotextiles as a horizontal drain layer placed between the layers of earth fill and natural soft ground. Required discharge capacity of geotextiles as drain layers estimated by consolidation analysis is proportional to the consolidation coefficient of the ground soils and the width of the earth fills. The field discharge capacity of the geotextiles are measured by the hydraulic transmissivity test. And the results show wide variation according to the material characteristics of geotextiles, water content of the soils, vertical pressure, and etc. For the short horizontal drain length, geotextile filter mat can be used for the horizontal drain layer. And f3r the long drain($25{\sim}55m$), it is used for the drain together with Bord Drain.