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Effects of Chain Extender and Inorganic Filler on the Properties of Semi-Rigid Polyurethane Foams (반경질 폴리우레탄 발포체의 물성에 대한 사슬 연장제와 무기 충전제의 영향)

  • Cha, Gook-Chan;Song, Jeom-Sik;Lee, Suk-Min;Mun, Mu-Seong
    • Polymer(Korea)
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    • v.34 no.1
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    • pp.8-13
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    • 2010
  • The physical properties of polymeric foams depend on the density of foams, physical properties of base polymers, the content of open cells, and cell structures including the size and its distribution, the shape of cell, and the thickness of skin layer. The foam density is affected by the chemistry of raw materials, the concentration of crosslinking agent and the blowing agent as well as the operating parameters during production process. In this study, the basic formulations of foams are composed of polyester polyol, MDI, amine catalyst, tin catalyst, silicone surfactant, and water. Cross-linking density of polyurethane was increased by using chain extenders. Also, the mechanical properties of polyurethane foam were improved by using the inorganic fillers (silica 1,2 and talc 1,2) having different $SiO_2$ contents and particle sizes. We investigated the properties of modulus, tensile strength, compressive strength and hardness of foams obtained by changing kind of inorganic filler and chain extender, and observed the distribution of inorganic filler as well as variation of cell size within the foams by electron microscopy.

Characteristics of tungsten nitride films deposited by reactive sputtering method (Reactive sputtering 방법으로 증착된 W nitride 박막의 특성)

  • 이연승;이원준;나사균;이윤직;임관용;황정남
    • Journal of the Korean Vacuum Society
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    • v.11 no.1
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    • pp.22-27
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    • 2002
  • We investigated the crystal structure, resistivity, and chemical states change of the tungsten nitride $(WN_x)$ films prepared by reactive sputtering method with various $N_2$ flow ratios. Crystal structures of $WN_x$ films deposited at the $N_2$ flow ratios of 20%, 40%, and 60% were bcc $\beta$-W, amorphous, and fcc $W_2$N, respectively. Surface roughness of $WN_x$ film was smallest when the $WN_x$ film is amorphous. After the air exposure of $WN_x$ films, $WO_3$ layer was formed at the surface of all samples. Both the nitrogen content of $WN_x$ film and the binding energy of W $4f_{7/2}$ peaks increased with increasing $N_2$ flow ratio. However, after $Ar^+$ ion etching, the shift of W $4f_{7/2}$ peaks was not observed with $N_2$ flow ratio due to the amorphization of the $WN_x$ film surface. The resistivity of $WN_x$ films increased with increasing $N_2$ flow ratio.

Studies on quality control of domestic Morus alba Linne (국내산 상지(桑枝)의 품질관리 연구)

  • Park, Yu Mi;Beak, Mi Eun;Lee, Young Jong;Won, Jae Hee
    • The Korea Journal of Herbology
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    • v.31 no.3
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    • pp.71-75
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    • 2016
  • Objectives : Mori Ramulus is a young branch of Morus alba Linne, which has been used as traditional medicines for antidiarrhea, antibacteria, and antihypertension in Korea. With the basis on these medicinal activities, it is registered at the Korean Herbal Pharmacopoeia. The standard for quality control in use, however, is not yet validated.Methods : We experiment on heavy metals test, TLC, loss on drying, ash, acid-insoluble ash, contents of ethanolsoluble extracts and contents of oxyresveratrol by using the 15 samples of Mori Ramulus which are collected domestically. We tested items according to the General Test, processes and apparatus, Crude Drugs Test of KP(2011).Results : Purity test(Heavy metals) showed contents for Pb, As, Hg, and Cd range of 0.1~1.1 ppm, 0.0~0.2 ppm, 0.00~0.01 ppm, and 0.00~0.02 ppm. Identification test(Thin layer chromatography) was on comparing with morucine standard solution in Rf value, all samples showed morucine spot (dark blue, Rf : 0.3) as same as Rf value of morucine-standard solution. Loss on drying was ranged from 5.1 to 8.9 %, ash and acid-insoluble ash were between the range 3.0~6.3% and 0.3~0.8%. Contents of ethanol-soluble extracts was ranged from 6.2 to 12.0%. Content of oxyresveratrol was ranged from 0.01 to 0.16 % based on the oxyresveratrol standard curve.Conclusions : We sincerely hope that this study will be contributed to the standardization and quality control of Korean herbal medicines.

Effect of XPS and Polyethylene Aggregates in Model Tests for Prevention of Frost Heave in Railroad Track (철도에서의 동상방지를 위한 모형시험에서 XPS 및 PE골재의 설치 효과)

  • Kim, Donggwan;Yoon, Yeowon;Kim, Youngchin
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.10
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    • pp.5-13
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    • 2014
  • In this research, in order to study insulation effect of commercial XPS and recycled PE aggregates for prevention of frost heave in the roadbed of railroad track from the freezing temperature, model tests were carried out in the large freezing room. For this, thermal conductivities were measured for various dry densities, water contents, temperatures and mixing ratios of PE aggregates. From the tests, it can be seen that thermal conductivities of roadbed decrease with the increase of the ratio of mixed PE aggregates. However it was sensitive to the changes of temperature and water content due to the amount of water in the voids. From the model test of railroad track, it can be seen that the time to reach $0^{\circ}C$ was longer for XPS than that for the PE aggregates. Also the test shows best insulation effect can be achieved when XPS board was installed above the PE aggregate layer rather than the opposite order.

Stability Improvement of Esomeprazole Magnesium Dihydrate Enteric-Coated Tablet by Adding Alkalizing Agents (에스오메프라졸 마그네슘 이수화물을 함유하는 장용성 제제의 안정성 개선)

  • Cho, Young Ho;Jeon, Hyo Bin;Lee, Jong-Hwa;Lee, Gye Won
    • KSBB Journal
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    • v.32 no.2
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    • pp.108-116
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    • 2017
  • Omeprazole, a benzimidazole derivative, suppresses gastric acid secretion by inhibiting $H^+/K^+$ ATPase in gastric parietals cells, and by reducing $H^+$ concentration. To improve stability of esomeprazole magnesium dihydrate (ESMD), enteric-coated preperation was composed of core tablet, subcoating and enteric coating layer. We were evaluated in vitro dissolution characteristics between test and reference ESMD preparation and stability. We could prepare enteric-coated formulation of ESMD by controlling disintegrating agent and coating ratio which could rapidly dissolved in neutral or alkali medium. The formulation D5 with crospovidone of 1.25% and coating ratio of 16.25% had a similar dissolution behavior compare to reference preparation. Difference factor ($f_1$) and similarity factor ($f_2$) were 0~15 and 50~100 and there was no significant difference in bioequivalence between formulations. The content and dissolution rate of formulation D5 were $96.54{\pm}0.21$ and $78.56{\pm}0.87%$ without change of color in accelerated condition ($40^{\circ}C$, RH 75%, high density polyethylene (HDPE) container) for 6 months. This study concluded that our enteric coated preparation of ESMD could be an useful method to improve stability of unstable drug without direct contact with coating material.

Behavior of Geosynthetic Reinforced Wall with Heat Induce Drainage Method During Rainfall (열유도 토목섬유 배수공법이 적용된 보강토 옹벽의 강우시 거동 특성)

  • Shin, Seung-min;Sin, Chun-won;Yoo, Chung-Sik
    • Journal of the Korean Geosynthetics Society
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    • v.15 no.1
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    • pp.11-19
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    • 2016
  • This paper presents the results of a scale model test to the effect of heat exchanger drainage method in retaining wall of weathered granite soil. Purpose to rise in the temperature of the heat wires inside the weathered granite soil is preventing the collapse of the retaining wall and drainage smoothly moved to the drainage layer. Especially using a spray gun to simulate the rainfall since the rainfall drainage work is important for the rainfall effect on soil, find the difference about displacement of the retaining wall, change of volume water content, drainage, earth pressure and change in the strain of the geosynthetic was effected to heat exchanger within the soil. The result from applying the heat exchanger method decreased the earth pressure and displacement of the wall and increased drainage of water.

Sedimentary Facies and Processes in the Ulleung Basin and Southern East Sea (동해남부해역과 울릉분지의 퇴적상과 퇴적작용)

  • Lee, Byoung-Kwan;Kim, Seok-Yun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.40 no.3
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    • pp.160-166
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    • 2007
  • The coarse deposit with a lower mud content adjacent to the shelf of the southern East Sea is probably a "relict" sediment deposited in response to a lower stand of sea level during the Pleistocene. The sediment that developed on the slope and in the deep sea was river-borne primarily and was secondarily reworked or redistributed by the Tsushima Warm Current from the East China Sea. The clay mineralogy of the area suggests various sources of fine-grained sediment from adjacent rivers, the Korea Strait, volcanic material from Ulleung Island, and the Japan coast. Massive sand, bioturbated mud, homogeneous mud, and laminated mud were the dominant facies found in the core sediments from the study area. The massive sand was mainly volcanic ash from an eruption on Ulleung Island (9300 yr BP) and consisted of colorless pumiceous glass and a black scoriaceous type. The sedimentation rates on the slope, based on the Ulleung-Oki ash layer, were about 10cm/ky higher than in the basin. Other than the coarse-grain sediment, the mean size of the fine sediment dominating the bioturbated and homogeneous muds in the basin and the laminated mud on the slope was 6-10 phi. This indicates a difference in the major sedimentary process: hemipelagic sedimentation in the Ulleung Basin and mass flow deposition, such as turbidite, on the slope of the southern East Sea.

Effect of horizontal joints on structural behavior of sustainable self-compacting reinforced concrete beams

  • Ibrahim, Omar Mohamed Omar;Heniegal, Ashraf Mohamed;Ibrahim, Khamis Gamal;Agwa, Ibrahim Saad
    • Advances in concrete construction
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    • v.10 no.5
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    • pp.455-462
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    • 2020
  • This study investigated the effect of horizontal casting joints on the mechanical properties and structural behavior of sustainable self-compacting reinforced concrete beams (SCRCB). The experimental research consisted of two stages. The first stage used four types of concrete mixtures which were produced to indicate the effects of cement replaced with cement waste at 0%, 5%, 10%, and 15% by weight of cement content on fresh concrete properties of self-compacting concrete (SCC) such as, passing ability, filling ability, and segregation resistance. In addition, mechanical properties such as compressive, tensile, and flexural strength were also studied. The second stage selected the best mixture from the first stage and studied the effect of horizontal casting joints on the structural behavior of sustainable SCRCBs. The effect of horizontal casting joints on the mechanical properties and structural behavior were at the 25%, 50%, 75%, and 100% of sample height. Load deflection, failure mode, and theoretical analysis were studied. Results indicated that the incorporation of replacement with cement waste by 5% to 10% led to economic and environmental advantages, and the results were acceptable for fresh and mechanical properties. The results indicated that delaying the time for casting the second layer and increasing the cement waste in concrete mixtures had a great effect on the mechanical properties of SCC. The ultimate load capacity of horizontal casting joints reinforced concrete beams slightly decreased compared with the control beam. The maximum deflection of casting joint beams with 75% of samples height is similar with the control beam. The experimental results of reinforced concrete beams were substantially acceptable with the theoretical results. The failure modes obtained the best forced casting joint on the structural behavior at 50% height of casting in the beam.

The Effect on the Lipid Metabolism of Tsaiya Ducks When High Levels of Choline or Methionine are Added to the Ducks' Diet

  • Lien, T.F.;Jan, D.F.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.7
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    • pp.1090-1095
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    • 1999
  • In order to minimize the occurrence of fatty liver, this study investigated how adding a high level of dietary choline or methionine affected the lipid metabolism of Tsaiya ducks. Feeding trials were conducted with sixty Tsaiya ducks during their growing period, when they were 8-12 weeks old, and during their laying period, 10-14 weeks after the onset of laying when they were 26-30 weeks old. The ducks were randomly assigned to one of three groups: a control group (basal diet), a group in which methionine was added to the basal diet, and a group in which choline was added to the basal diet. The levels of methionine and choline added were twice as high as the levels recommended by the NRC for layer-type chickens. Experimental results indicated that adding choline to the basal diet of growing ducks significantly (p<0.05) increased their body weight, while adding methionine significantly (p<0.05)reduced their body weight. Adding either choline or methionine reduced the ducks' liver fat content in both the growing and the laying periods (p<0.05). Ducks receiving added methionine or choline in their diets displayed enhanced egg production (p<0.05). Adding choline increased serum triacylglycerol (TG) in the laying period (p<0.05). Adding either choline or methionine did not significantly (p>0.05) affect the t-globulin level. Adding methionine increased the activity of liver malic dehydrogenase in both the growing and the laying periods, and increased fatty acid synthetase in the laying period (p<0.05). While adding choline markedly (p>0.05) increased VLDL and apo B in both the growing and the laying periods, it decreased HDL and apo A in the laying period (p<0.05). This study found that adding a high level of choline to the basal diets of Tsaiya ducks in both the growing and the laying periods had beneficial effects. Furthermore, adding methionine affected the lipid metabolism of Tsaiya ducks to a lesser extent than adding choline.

Effects of Supplementary Mineral Methionine Chelates (Zn, Cu, Mn) on the Performance and Eggshell Quality of Laying Hens

  • Lim, H.S.;Paik, I.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.12
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    • pp.1804-1808
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    • 2003
  • A layer experiment was conducted to determine the effects of supplementary methionine chelates (Cu, Zn and Mn), individual or in combination, on laying performance, eggshell quality, gizzard erosion, and IgG level of serum for 8 weeks. Five hundred 96-wk-old force molted ISA Brown layers were assigned to five dietary treatments. Basal diet was formulated to meet or exceed the nutrients requirements listed in NRC (1994). Five experimental diets were control, Zn-methionine chelate (Zn-Met) supplemented, Cumethionine chelate (Cu-Met) supplemented, Zn-Mn-methionine chelate (Zn-Mn-Met) supplemented and Zn-Mn-Cu-Met supplemented diet. Each treated diet was supplemented with respective mineral(s) at the level of 100 ppm in the form of methionine chelate. Egg production was increased by Cu-Met supplementation but decreased by Zn-Met supplementation. Egg weight was significantly (p<0.05) lower in Cu-Met treatment than those of the control and Zn-Met treatment. Specific gravity of eggs and eggshell strength were highest and soft egg production was lowest in Cu-Met treatment. Gizzard erosion index was significantly increased by supplementation of Cu-Met, Zn-Mn-Met or Zn-Mn-Cu-Met. Zinc content in liver significantly increased by Zn-Met, but not by Zn-Mn-Cu-Met treatment. In conclusion, 100 ppm Cu in Cu-Met chelate improved laying performance and eggshell quality but also increased gizzard erosion index. Supplementation of Zn-Met or its combination with other mineral chelates had no beneficial effects on laying performance and eggshell quality.