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Utrastructural Analysis of the Delignification Behaviour in P-Cresol-Water Solvent Pulping (크레졸-물 용매펄프화의 탈리그닌에 관한 초미세구조적 분석)

  • Kim, Chang-Keun;Jo, Byoung-Muk
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.1
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    • pp.60-71
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    • 1992
  • To investigate the delignification behaviour in solvolysis pulping process, Populus alba ${\times}$ glandulosa H. and Pinus Kuraiensis S. et Z. were cooked with p-cresol and vater solvent(2:8, 5:5, 8:2 v/v) at $175^{\circ}C$ for 9 cooking time levels(20, 40, 60, 80, 100, 120, 140, 160, 180, min). Pulp yield, residual lignin content, de lignification rate, decarborhydration rate were determined. Delignification behaviours were analyzed by TEM. 1. The p-cresol-water solvent cooking of P. alba ${\times}$ glandulosa showed good delignification at the solvent system which the mixture ratio of p-cresol and water were 2:8(v/v), while the cooking of P. koraiensis with the p-cresol and water mixture ratio of 5:5 was no good. 2. P. alba ${\times}$ glandulosa showed three step-delignification phenomena at the solvent system which the mixture ratio of p-cresol and water were 2:8(v/v) anti 5:5(v/v). But P. koraiensis showed a first order delignification reaction at the same mixture ratio of p-cresol and water solvent system. 3. In TEM micrograph obtained for the solvent system which the mixture ratio of p-cresol and water was 5:5(v/v), the partial delignification of the cell corner of P. alba ${\times}$ glandulosa and P. koraiensis were observed at 60min. of cooking time. Complete delignification at the cell corner of P. alba ${\times}$ glandulosa was observed at 160min. and that of P. koraiensis was observed of 180min. of cooking time. 4. In optical microscopic observation, fiber separation of P. alba ${\times}$ glandulosa occured at 120min. and that of P. koraiensis began at 140min. of cooking time. 5. At the solvent system which the mixture ratio of p-cresol and water was 5:5(v/v), middle layer on secondary wall($S_2$) and cell corner of P. alba ${\times}$ glandulosa were more selectively delignified than primary wall(P) and outer layer on secondary wall($S_1$). However P. koraiensis did not showed any difference in delignification between cell wall layers and cell corner.

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Effect of Fluoride and Laser on Artificial Caries-like Lesion Formation in Bovine Enamel (불소 및 레이저가 우치법랑질의 인공우식병소에 미치는 영향)

  • Kim, Jae-Gon;Baik, Byeong-Ju;Ju, Hoon;Yun, Hyun-Du
    • Journal of the korean academy of Pediatric Dentistry
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    • v.24 no.3
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    • pp.660-677
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    • 1997
  • The purpose of this study was to examine the morphological characteristics and combined effects of fluoride application and laser irradiation on artificial caries-like lesion formation in bovine enamel. Enamel specimens were divided into five experiment group and placed in no-treatment(group C), APF application alone(group F), laser irradiation alone(group L), APF application before laser irradiation (group FL), and APF application after laser irradiation(group LF) on artificial caries-like lesion. Sound enamel was used as a control group. The ultrastructural changes and physical effects of the fluorided and lased enamel has been investigated by using SEM, enamel solubility and microhardness test as well as distributions of calcium, phosphorus and fluoride in internal enamel by using EPMA. The following results were obtained. 1. In the all experiment groups, the amounts of dissolved calcium of enamel surfaces significantly decreased according to increasing exposure time of acid solution than control group(P<0.001). Group L showed higher than that group FL and LF in 30 and 60min(P<0.05). 2. The microhardness values of enamel surface in the control group was highest than that in the other experiment groups. Group F, L, FL and LF were significantly increased than group C(P<0.001). The enamel surface treated with APF produced deposites of numerous small globules and lased enamel showed a cracker-like appearance with microcrack and small pore. Numerous deposits were infiltrated in the fissured portion of enamel treated with APF after laser irradiation. 4. In the case of APF application alone, the elevation of the fluoride profile can be seen within $5{\mu}m$ of the outermost layer and a similar profile observed in the specimen treated with APF before laser irradiation. However, the specimen treated with APF after laser Irradiation showed a large elevation within $10{\mu}m$ of the outermost layer of the enamel. 5. The higher Ca/P ratios were observed in $10{\mu}m$ depth of lased and fluorided enamel when compared to the sound and carious enamel. The fluoride content decreased rapidly with distance from enamel surface, in the group F, fluoride concentration was significantly higher than that in the group C, L, FL, LF and control group according to increasing enamel depth (P<0.05).

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Magnetic Properties of Chip Inductors Prepared with V2O5-doped Ferrite Pastes (V2O5 도핑한 페라이트 페이스트로 제조된 칩인덕터의 자기적 특성)

  • Je, Hae-June
    • Journal of the Korean Magnetics Society
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    • v.13 no.3
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    • pp.109-114
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    • 2003
  • The purpose of this study Is to investigate the effect of $V_2$O$_{5}$ addition on the microstructures and magnetic properties of 7.7${\times}$4.5${\times}$1.0 mm sized multi-layer chip inductors prepared by the screen printing method using 0∼0.5 wt% $V_2O_{5}$-doped NiCuZn ferrite pastes. With increasing the $V_2O_{5}$ content, the exaggerated grain growth of ferrite layers was developed due to the promotion of Ag diffusion and Cu segregation into the grain boundaries oi ferrites, which affected significantly the magnetic properties of the chip inductors. After sintering at $900^{\circ}C$, the inductance at 10 MHZ of the 0.5 wt% $V_2O_{5}$-doped chip inductor was 3.7 ${\mu}$H less than 4.2 ${\mu}$H of the 0.3 wt% $V_2O_{5}$-doped one, which was thought to be caused by the residual stress at the ferrite layers increased with the promotion of Ag diffusion and Cu segregation. The quality factor of the 0.5 wt% $V_2O_{5}$-doped chip inductor decreased with increasing the sintering temperature, which was considered to be caused by the electrical resistivity of the ferrite layer decreased with the promotion of Ag/cu segregation at the grain boundaries and the growth of the mean grain size of ferrite due to exaggerated grain growth of ferrite layers.

Trail and Campground Deteriorations, and Their Environmental Changes of Soil and Vegetation in Chiak Mountain National Park (치악산 국립공원의 등산로 및 야영장 훼손과 주변 토양 및 식생환경의 변화)

  • 권태호;오구균;권영선
    • Korean Journal of Environment and Ecology
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    • v.2 no.1
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    • pp.50-65
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    • 1988
  • Trail and campground deteriorations and their environmental changes of soil and vegetation were studied in Guryong district of Mt. Chiak National Park in 1988. The Widths of both the entire trail and the bare portion as the trail condition were significantly greater on the more heavily used trail. and regressions showed the significant positive relationship between slope along the trail and maximum depth of the trail($R^2$=0.35). Deterioration types of trail which had higher frequency for a total of 63 observations were rock exposure(48%), trail deepening(29%) and root exposure(27%) in the high order. And occurence of trail deterioration was considerably influenced by slope along the trail Ecological changes of soil and vegetation of trailsides were not found at a uniform tendency but could be grouped, by the types of user's disturbance. On campsites. tree damage types and their frequencies were basic as a means of which grasp the limits of user's impact. The area with damaged trees on campsite in pine forest were larger than that in mixed forest and the frequency by damage type of trees varied according to the distance from the core of campsite and to the crown layer. Water content, pH and hardness of soil. coverage of lower trees, species and individuals per 100$m^2$, basal areas of upper and middle layer of trees had significant relationship with the distance from campsite to forest. The range influenced by user's disturbance was more than 70-80m, md Staphylea bumalda, Morns bombycis, Stephanandra incisa and Securinega suffruticosa were considered as tolerant species to user's impact.

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Effect of phosphorus application on appearance of algal water bloom and rice yield in rice-barley double cropping system

  • Hwang, Jae-Bok;Bae, Hee-Soo;Park, Tae-Seon;Choi, In-Bae
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.233-233
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    • 2017
  • Algal communities are important to maintain the aquatic ecosystems function. Algae have short life cycles, they respond quickly to environmental change and their diversity and density can indicate and the quality of their habitat. The bloom forms before the rice seedings have emerged, it may present a physical barrier that prevents the seedlings from penetrating the floodwater. Wind may also move the algal bloom, pushing the young plants beneath the surface. Another harmful action develops when the water dries up and the algae form a layer at the bottom of the field. The layer envelops the seedlings, which are not yet deeply rooted, and drag them to the surface when the water is let in again. Soil utilization pattern can be the mail facter affecting soil physico-chemical properties, especially in soil phosphorus (P). Solid content of the algae culture solution increased with the increase in the nitrogen rather the phosphors concentration. Phosphoric acid was treated with conventional treatments (100-0%, before transplanting time-tillering stage), 50-50%, 0-100%, and un-treated. The herbicide was treated on the 7 DAT (day after transplanting). Green algae samples were collected 20 DAT. Total phosphoric acid was the highest at 0.06 in 50-50% treatment in 20 DAT. The amount of green algae was about twice (9.8 mg/20ml) that of un-treated. Total number of green algae was 54 species(Green algae 35 species, Euglena 9 species, Stone wheel 10 species). Among the phosphoric acid treatment methods, the number of occurrences of green algae were the highest with 39 species in 0-100%, followed by 50-50%, 28 species, conventional treatments, 22 species, non-treatment, 18 species, respectively. Rice Yield was not significantly different by phosphoric treatment time, but slightly higher than un-treated. The maximal algal biomass was observed about 2weeks or 1 month after transplanting; the subsequent decrease of the biomass was related to the consumption by grazers and to a deficient light under the rice canopy. Maximal algal growth was observed just before tillering. To estimate the suitable method of phosphorus application in puddled-soil drill seeding of rice, available phosphorus appearance of algal water bloom, and rice yield were investigated in paddy soil of rice-barley double cropping system.

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Light Conditions and Characteristics of Leaves and Fruit at Different Canopy Positions in Slender-spindle 'Hongro' Apple Trees (세장방추형 '홍로' 사과나무의 수관 부위별 수광상태와 잎 및 과실의 특성)

  • Song, Ju-Hee;Kang, In-Kyu;Choi, Dong Geun
    • Horticultural Science & Technology
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    • v.32 no.4
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    • pp.440-447
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    • 2014
  • For this analysis, canopies of slender-spindle 'Hongro'/M9 apple trees were divided into 4 positions: upper, lower, exterior, and interior parts. The photosynthetic rate was highest in the external part of the upper canopy of the tree, where it was 4.5 times higher than in the internal part of the lower canopy. This difference was closely associated with differences in light penetration based on canopy position. Analysis of leaf growth characteristics showed that the leaves situated in the internal part of the canopy were larger and thinner than those in the external part of the canopy. The difference in leaf thickness was mainly due to thickness of the primary layer of palisade tissues (68.5 and $110.3{\mu}m$ for internal and external leaves, respectively). Fruit weight and quality were closely related to the extent of light penetration. Fruit weight, soluble solid content, and red skin color were higher in the fruits from the external part of the canopy. Thus, fruit maturity was delayed in the internal part of canopy. The fruit skin and wax layer were thicker in fruits from the internal canopy than in those from the external canopy. Therefore, our results indicate a need for improved light penetration in internal parts of the canopy and for split harvesting depending on maturity at different canopy positions.

Use-friendly Active Packaging of Powdered Infant Formula in Single-serve Portion Augmented with Anti-oxidative Function (산화억제 가능성과 사용편의성을 가진 일회성 조제분유 포장)

  • Lee, Hye Lim;An, Duck Soon;Lee, Dong Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.25 no.3
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    • pp.95-99
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    • 2019
  • In the modified atmosphere packaging of powdered infant formula, the oxygen inside the package may cause its quality deterioration and needs to be minimized for quality preservation. A way of oxygen scavenger inclusion in the single-serve package without contacting the product was devised for removing oxygen residing initially and permeating through the seal layer during the storage. A polyethylene/pulp multi-layer porous filter bag of 5 × 7 cm containing 13 g of powdered infant formula was packaged in an 8 × 9 cm size aluminium laminated film package with a Fe-based oxygen scavenger of 1.8 g. After nitrogen flushed packaging, the active packages were stored at 30℃ for 254 days with periodical quality measurement. The active package could remove the initial residual oxygen of 1.4% completely and maintain absence of oxygen for the whole storage, which contributed to reduced oxidation observed in lower product peroxide value compared to that of the product in the control package. There was no influence of packaging treatment on content of 5-hydroxymethylfurfural, reaction product of initial nonenzymatic browning. The devised oxygen-scavenging single-serve package showed a potential to improve the preservation of infant formula powder and extend the shelf life.

Study on the Soybean Yield as Influenced by Method and Rate of Phosphate Application in Reclaimed Soil (야산(野山) 개간지(開墾地) 토양(土壌)에서 인산시비방법(燐酸施肥方法) 및 시용량(施用量)이 대두수량(大豆收量)에 미치는 영향(影響))

  • Park, Keon-Ho;Chae, Jae-Seok;Hwang, Nam-Yul
    • Korean Journal of Soil Science and Fertilizer
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    • v.16 no.1
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    • pp.56-63
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    • 1983
  • On a newly reclaimed soil, an experiment was carried out for the elucidation of proper rate of phosphorus fertilizer and application method to increase soybean yield in Honam area. 1. The yield was high in whole layer placement of phosphorus fertilizer and low in deep placement. 2. Broadcasting with 15% of phosphate fixation coefficent and whole layer and deep placement of fertilizer with 10% of phosphate fixation coefficent showed maximum yield. 3. Large application of phosphate increased stem diameter and number of blanches and podes. 4. Application of phosphorus fertilizer increased phosphate content in soil from 9 ppm to 48-223 ppm and contents of bases 5. Significant positive correlation was obtained between soybean yield and phosphorus uptake amount.

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Environmental Survey on the Cultivation Ground in the West Coast of Korea 5. Bottom Conditions on a Coastal Farm of Kunsan Areas (서해연안의 양식장 환경조사 5. 군산연안 양식장의 저질환경)

  • Lee Jeong-Yeol;Ryou Dong-Ki
    • Journal of Aquaculture
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    • v.8 no.2
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    • pp.85-98
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    • 1995
  • In Kunsan coastal areas, there are some plans to construct industrial zone and, it will affect physical and chemical parameters of marine environment of the area. As one of many environmental surveys on the aquacultural farm in Korean west coast, the survey on the bottom sediment characteristics of intertidal farm was conducted from May 1992 to April 1993. Dominant grain size was fine sand $(69-98\%)$ and the pH of sediment was ranged of $7.2\~9.1$. Especially the pH increased after embank was constructed. The water holding capacity was $11.1-28.1\%$ and showed high value in silt and clay area. The COD was 1.27 mg/g dry mud and increased after embank was constructed. The total organic matter content ranged of $0.84-8.11\%$ and the DO absorption was $0\~6.56 mg/g$ dry mud. The value of DO absorption showed low in winter and spring, but high in summer and fall. The total nitrogen and the sulfide were rang of $0\~402{\mu}g/g$ dry mud and $0\~122{\mu}g/g$ dry mud respectively. These values were high in summer and winter season, and higher in upper layer than that of lower layer in general.

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Characteristics of transparent dielectric in PbO-B$_2$O$_3$-${SiO_2}-{Al_2}{O_3}$ system and investigation of reaction between dielectric and electrode(ITO) (투명 유전체 PbO-B$_2$O$_3$-${SiO_2}-{Al_2}{O_3}$의 물성 및 전극(ITO)과의 반응성 연구)

  • Lee, Jae-Yeol;Hong, Gyeong-Jun;Kim, Deok-Nam;Kim, Hyeong-Sun;Heo, Jeung-Su
    • Korean Journal of Materials Research
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    • v.11 no.4
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    • pp.305-311
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    • 2001
  • $PbO-B_2O_3-SiO_2-Al_2O_3$, system was investigated for optical, thermal and electrical properties of transparent dielectric. We also studied the reaction between transparent dielectric and transparent electrode(Indium Tin Oxide, ITO) during firing. For the evaluation of properties, dielectrics were prepared under the conditions fired at 520~58$0^{\circ}C$ with 12$\mu\textrm{m}$ thickness. In the reaction between dielectrics and electrode(ITO), In ions diffused into dielectric layer, while Sn ion diffusion was not observed. The coefficient of thermal expansion, the dielectric constant, the glass transition temperature and the transmittance of the dielectric were greatly dependent on PbO content. The increase of the coefficient of thermal expansion and the dielectric constant were monitored by increasing PbO, while the glass transition temperature and the transmittance were decreased. With the increased $Al_2O_3/B_2O_3$ ratio, the coefficient of thermal expansion and the transmittance were decreased, while the dielectric constant was increased. The glass transition temperature did not change significantly.

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