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Dry Etching of Al2O3 Thin Films in O2/BCl3/Ar Inductively Coupled Plasma

  • Yang, Xeng;Woo, Jong-Chang;Um, Doo-Seung;Kim, Chang-Il
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.5
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    • pp.202-205
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    • 2010
  • In this study, the etch properties of $Al_2O_3$ thin films deposited by atomic layer deposition were investigated as a function of the $O_2$ content in $BCl_3$/Ar inductively coupled plasma. The experiments were performed by comparing the etch rates and selectivity of $Al_2O_3$ over the hard mask materials as functions of the input plasma parameters, such as the gas mixing ratio, DC-bias voltage, ratio-frequency (RF) power and process pressure. The highest obtained etch rate was 477 nm/min at an RF power of 700 W, $O_2$ to $BCl_3$/Ar gas ratio of 15%, DC-bias voltage of -100 V and process pressure of 15 mTorr. The deposition occurred on the surfaces when the amount of $O_2$ added to the $BCl_3$/Ar gas was too high at a low DC-bias voltage or high process pressure. X-ray photoelectron spectroscopy was used to investigate the chemical reactions on the etched surface.

Low-Temperature Solution Process of Al-Doped ZnO Nanoflakes for Flexible Perovskite Solar Cells

  • Nam, SeongSik;Vu, Trung Kien;Le, Duc Thang;Oh, Ilwhan
    • Journal of Electrochemical Science and Technology
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    • v.9 no.2
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    • pp.118-125
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    • 2018
  • Herein we report on the selective synthesis and direct growth of nanostructures using an aqueous chemical growth route. Specifically, Al-doped ZnO (AZO) nanoflakes (NFs) are vertically grown on indium tin oxide (ITO) coated flexible polyethylene terephthalate (PET) sheets at low temperature and ambient environment. The morphological, optical, and electrical properties of the NFs are investigated as a function of the Al content. Furthermore, these AZO-NFs are integrated into perovskite solar devices as the electron transport layer (ETL) and the fabricated devices are tested for photovoltaic performance. It was determined that the doping of AZO-NFs significantly increases the performance metrics of the solar cells, mainly by increasing the short-circuit current of the devices. The observed enhancement is primarily attributed to the improved conductivity of the doped AZO-NF, which facilitates charge separation and reduces recombination. Further, our flexible solar cells fabricated through this low temperature process demonstrate an acceptable reproducibility and stability when exposed to a mechanical bending test.

Oxidation behavior of CaO added Mg and Mg-Al alloys (CaO을 첨가한 Mg 및 Mg-Al 합금의 산화거동)

  • Ha, Seong-Ho;Lee, Jin-Kyu;Jung, Seung-Boo;Kim, Young-Jig;Jo, Hyung-Ho;Kim, Shae-K.
    • Journal of Korea Foundry Society
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    • v.27 no.3
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    • pp.126-130
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    • 2007
  • Oxidation behavior of CaO added Mg and Mg-5Al alloys was investigated. At $500^{\circ}C$, oxidation rate of pure Mg was abruptly increased, while that of CaO added Mg was remarkably reduced with increasing CaO content. As a result of surface analysis by AES, there was the thin oxide layer mixed with MgO and CaO in CaO added Mg. Oxidation behavior of CaO added Mg was similar to that of Ca added Mg. Oxidation rate of 0.6CaO added Mg-5Al alloy was much lower than that of Mg-5Al alloy at $500^{\circ}C$ and both alloys showed the linear weight change at $400^{\circ}C$.

Pharmacognostical Evaluation of an Antioxidant Plant - Acorus calamus Linn

  • Govindarajan, Raghavan;Agnihotri, Adarsh Kumar;Khatoon, Sayyada;Rawat, Ajay Kumar Singh;Mehrotra, Shanta
    • Natural Product Sciences
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    • v.9 no.4
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    • pp.264-269
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    • 2003
  • The rhizome of Acorus calamus Linn. is commonly known as "Vacha" in indigenous systems of medicine. It is distributed in marshy tracts of Kashmir, Sirmaur (Himachal Pradesh), Manipur and the Naga hills. It is regularly cultivated in Koratagere Taluk in Karnataka and other parts of India. This study deals with the detailed pharmacognostical evaluation of the dried rhizomes of Acorus calamus collected from DehraDun (Uttaranchal), Lucknow (Uttar Pradesh). The commercial sample procured from Delhi market was also evaluated to observe the difference between collected and market samples. Dried rhizome is vertically compressed, pale yellow to dark brown and occasionally orangish brown in colour. Transverse section showed two distinct region with scattered, concentric vascular bundles surrounded by fibrous bundle sheath. Some vascular bundles just beneath the endodermis devoid of bundle sheath. Though the botanical and physico-chemical characters of all the samples were quite similar but some variations were observed in High Performance Thin Layer Chromatography (HPTLC) fingerprint profile, the essential oil content and total percentage of asarone which was found to be highest in Lucknow and lowest in Delhi market sample. These variations may be explained due to some edaphic factors or storage conditions. An attempt was also made to test antioxidant activity (in vitro) and it was found to be 88% at 0.2 g/ml concentration.

Screening of Xerosis Inhibitor from Seaweed Extracts Using HaCaT Keratinocyte

  • Yoon, Seung-Je;Khan, Mohammed N.A.;Kang, Ji-Young;Nam, Ju-Hyun;Ahn, Dong-Hyun;Hong, Yong-Ki
    • Journal of Marine Bioscience and Biotechnology
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    • v.4 no.1
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    • pp.31-34
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    • 2010
  • The primary function of the skin is to protect the body from the unwanted environmental influences. The outermost layer of the skin is stratum corneum which consists of corneocytes surrounded by lipid regions. Ceramides covalently bound to keratinocytes are essential for the barrier function of the skin, which can be disturbed in the disease, like xerosis. Xerosis is an abnormal dryness of the skin which reduced the thickness of stratum corneum and ceramide content decreasing with age. In this study, 36 seaweed extracts have been tested for screening of xerosis inhibitory agent by in vitro HaCaT keratinocyte assay. Ishige sinicola and Helminthocladia australis induced the significant amount of ceramide-like substance I in HaCaT keratinocyte among the tested seaweed extracts. Sargassum fulvellum, Chondrus ecellatus and Gigartina tenella also induced the ceramide-like substance I whereas Helminthocladia australis and Pachymeniopsis elliptica induced the ceramide-like II from HaCaT keratinocyte.

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Soil modification by addition of cactus mucilage

  • Akinwumi, Isaac I.;Ukegbu, Ikenna
    • Geomechanics and Engineering
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    • v.8 no.5
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    • pp.649-661
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    • 2015
  • This research provides insight on the laboratory investigation of the engineering properties of a lateritic soil modified with the mucilage of Opuntia ficus-indica cladodes (MOFIC), which has a history of being used as an earthen plaster. The soil is classified, according to AASHTO classification system, as A-2-6(1). The Atterberg limits, compaction, permeability, California bearing ratio (CBR) and unconfined compressive strength of the soil were determined for each of 0, 4, 8 and 12% addition of the MOFIC, by dry weight of the soil. The plasticity index, optimum moisture content, swell potential, unconfined compressive strength and permeability decreased while the soaked and unsoaked CBR increased, with increasing MOFIC contents. The engineering properties of the natural soil, which only satisfies standard requirements for use as subgrade material, became improved by the application of MOFIC such that it meets the standard requirements for use as sub-base material for road construction. The effects of MOFIC on the engineering properties of the soil resulted from bioclogging and biocementation processes. MOFIC is recommended for use as a modifier of the engineering properties of soils, especially those with similar characteristics to that of the soil used in this study, to be used as a pavement layer material. It is more economical and environment-friendly than conventional soil stabilizers or modifiers.

A Study on Preparation and the Standard Recipe of Premixed Gam-Injulmi Rice Cake (Premix 감인절미 제조 및 표준 Recipe에 관한 연구)

  • 김경자;오옥자
    • Journal of the East Asian Society of Dietary Life
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    • v.7 no.1
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    • pp.47-55
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    • 1997
  • This study aims to know what the physicochemical properties and physical properties of the Korean traditional rice cake injulmi made from persimmon powder and glutinous rice(powder), and to come up with a standard recipe of it with the premixed powder of persimmon and glutinous rice. Cooked rice powder with 9 different levels of persimmon in cooling dough(75, 100 and 150${\mu}{\textrm}{m}$ power with each 20, 40, and 60%) was tested for rheological parameters, the rate of swelling, degree of gelatinization, sensory evaluation, and the observation of cross section used to electronmicroscope. 1. sensory evaluation conducted by 20 university students as panelists showed that mixed glutinous rice powder and persimmon powder lost their regular forms. increase in persimmon powder content increased a thin layer of starch granule, presumably due to sugar and fiber in the mixed persimmon powder granule. 3. In cooking the rice cake with 20~60% of persimmon, it showed 6.3 to 5.5 pH. 4. Quantitative description analysis conducted by 20 university student s panelists showed that sample that sample C was preferred among 9 samples. From these results, it was concluded that glutinous rice cake cooked with 20% of persimmon powder was quiet acceptable. Optimum cooking condition for the glutinous rice with persimmon powder rice cake was 30min of cooking time and 25$0^{\circ}C$ of cooking temperature with gas oven.

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Studies on the Biological and Chemical Properties of Musty Ginseng Root and its Causal Mechanism (적변삼의 생물.화학적 특성과 그 발생원인에 관하여)

  • 정영륜;오승환
    • Journal of Ginseng Research
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    • v.9 no.1
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    • pp.24-35
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    • 1985
  • Rusty root of ginseng has been known as one of the limiting factors in ginseng production in Korea. An attempt was, therefore, made to elucidate biological and chemical natures of the rusty root, and the redox Potential of the ginseng cultivated soils were measured and compared with diseased and non-diseased soils. Reddish discoloration was most frequently observed on the epidermis of ginseng root and the pigments were accumulated in all epidermal cells of the diseased lesions. The lower the redox potential of the ginseng cultivated soil was, the more severe the rusty root was observed. Fe content in the diseased epidermis was 3 times higher than that of healthy one. Organic acids such as oxalic, malonic, succinic, and citric acids were also higher in the mss root than in the healthy one. Thin layer chromatogram of phenolic acid fractions obtained from the epidermal cells of the rusty root of ginseng exhibited 3 to 4 unidentified substances not found in the healthy root. Also lignification of the epidermal cells and the activity of phenylalanine ammonia lyase were greater in the rusty root than the healthy root. Colony formation and conidia production of F. solani, And mycelial growth and sclerotium formation of Sclerotinia sp. isolated from ginseng root were suppressed in a nutritionally minimal medium supplemented with water extract of rusty ginseng root epidermis. It is, therefore, suggested that rusty root of ginseng is caused by unfavorable rhizosphere environmental stress or stresses resulting abnormal metabolism in the root as a selfdefence mechanism of non-specific resistance responses.

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Neighboring Cage Fish Farming Affecting Water and Seabed Quality of the Jordanian Northern Gulf of Aqaba, Red Sea

  • Mohammad, Al-Zibdah;Firas, Oqaily;Tariq, Al-Najjar;Riyad, Manasrah
    • Ocean Science Journal
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    • v.43 no.1
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    • pp.9-16
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    • 2008
  • Environmental qualities of coastal water and bottom sediment were assessed at Jordan's northernmost tip of Gulf of Aqaba to evaluate possible impacts of the bordering fish pen cages in Eilat. Results showed significant differences between surface and bottom water in the chemical and physical variables in the different months of the year (2004-2005). Chlorophyll a was also significantly higher in bottom water when compared to that of the offshore water. Nitrate and ammonia were significantly higher in bottom water than the surface water at each individual station. The upper 2 cm of sediment sample recorded higher values of total phosphorus and organic matter. Seasonality affected the content of total phosphorus, organic matter, redox potential and color especially at the sediment layer below 3 cm of the sediment core. The present investigation showed slight modification of water and sediment qualities but no clear sign of eutrophication was observed. However, to maintain sustainability of healthy environmental conditions at the northern tip of Gulf of Aqaba potentials of any possible environmental risks arising from the fish farms or any other coastal investment should be carefully considered.

Adhesion Characteristic and Porosity Change of Alkali Silicate Impregnant of Concrete (Silicate계 콘크리트 함침제 도포에 따른 부착특성 및 공극변화)

  • Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu;Lim, Young-Chul
    • Journal of the Korean Ceramic Society
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    • v.47 no.4
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    • pp.276-282
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    • 2010
  • There are the impregnating layer formation by surface protective materials or impregnants and the adhesion method by polymer, FRP sheet or steel plate in the surface protective method of concrete structure. The surface impregnation method by impregnants improves the durability of concrete structure by modifying the structure of the concrete surface and also have a merit that can be shortly applied in place without the decrease of concrete surface appearance and is easily applied again. This study is interested in manufacturing the concrete surface impregnants including lithium and potassium silicate for the repair of the exposed concrete and the color concrete requiring the advanced function in view of the concrete appearance. The durability and porosity properties was tested for the review of application. The result of this study show that the effective content of silicate ranges 5 to 20% and the separate application of the first impregnant and the second impregnant is effective for the optimum performance. The adhesion in tension is slightly increased but the reinforcement of concrete substrate is slight. So, the concrete impregnant of this study is more desirable for the improvement of durability rather than the reinforcement.