• Title/Summary/Keyword: Contamination process

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Heat Treatment of Carbonized Photoresist Mask with Ammonia for Epitaxial Lateral Overgrowth of a-plane GaN on R-plane Sapphire

  • Kim, Dae-sik;Kwon, Jun-hyuck;Jhin, Junggeun;Byun, Dongjin
    • Korean Journal of Materials Research
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    • v.28 no.4
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    • pp.208-213
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    • 2018
  • Epitaxial ($11{\bar{2}}0$) a-plane GaN films were grown on a ($1{\bar{1}}02$) R-plane sapphire substrate with photoresist (PR) masks using metal organic chemical vapor deposition (MOCVD). The PR mask with striped patterns was prepared using an ex-situ lithography process, whereas carbonization and heat treatment of the PR mask were carried out using an in-situ MOCVD. The heat treatment of the PR mask was continuously conducted in ambient $H_2/NH_3$ mixture gas at $1140^{\circ}C$ after carbonization by the pyrolysis in ambient $H_2$ at $1100^{\circ}C$. As the time of the heat treatment progressed, the striped patterns of the carbonized PR mask shrank. The heat treatment of the carbonized PR mask facilitated epitaxial lateral overgrowth (ELO) of a-plane GaN films without carbon contamination on the R-plane sapphire substrate. Thhe surface morphology of a-plane GaN films was investigated by scanning electron microscopy and atomic force microscopy. The structural characteristics of a-plane GaN films on an R-plane sapphire substrate were evaluated by ${\omega}-2{\theta}$ high-resolution X-ray diffraction. The a-plane GaN films were characterized by X-ray photoelectron spectroscopy (XPS) to determine carbon contamination from carbonized PR masks in the GaN film bulk. After $Ar^+$ ion etching, XPS spectra indicated that carbon contamination exists only in the surface region. Finally, the heat treatment of carbonized PR masks was used to grow high-quality a-plane GaN films without carbon contamination. This approach showed the promising potential of the ELO process by using a PR mask.

Application of Soil's Self-Decontamination Ability to Contaminated Ground (흙의 자체정화능력을 이용한 오염된 토양정화)

  • Jeong, Jin-Seob;Jhung, Jhung-Kwon;Kim, Tae-Hyung;Fang, Hsai-Yang
    • Journal of Korean Society on Water Environment
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    • v.22 no.4
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    • pp.632-638
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    • 2006
  • There are numerous approaches available to cleanup a contaminated surface and subsurface ground currently in use, however, these methods all classify the decontamination after the contamination has penetrated into the soil masses and is costly. Unlike these approaches, in this study, utilization of soil's self-decontamination ability by rearranging and preplanning of the topographical features and surface and subsurface drainage systems for the potential contamination sites before or during contamination process has been considered as an another cleanup method. Step by step explanations on why and how to develop the self-decontamination procedure is proposed in detail. Two examples are presented including contaminated saltwater intrusion along a coastal region and control or prevention of radioactive toxic radon gas ($^{222}Rn$) in residential areas. The effectiveness of the proposed systems to these two examples using the soil's self-decontamination ability is well illustrated.

The Dyeing Properties and Antibiosis of Fabrics Dyed with Agastache rugosa Extract (배초향 추출액을 이용한 염색포의 염색성 및 항균성)

  • Park, Young-Hee
    • Journal of Fashion Business
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    • v.16 no.1
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    • pp.16-25
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    • 2012
  • As the test results for surface color, dyeing durability, antibiosis of cotton fabrics and silk fabrics dyed with Agastache rugosa extract, the following conclusions were obtained. The surface color of all the dyed fabrics was confirmed mostly as a GY system. As the result of chrominance(${\Delta}E_{ab}$) measurement, in the case of cotton fabrics the dyed fabrics treated with $Al_2(SO_4)_3$ mordant showed the highest value and in the case of silk fabrics the non-mordant dyed fabrics showed the highest value. The dyeing durability of test fabrics dyed with Agastache rugosa extract are as follows. As the test results of colorfastness to laundry for cotton dyed fabrics, the discoloration degree showed 1st-2nd grade and the contamination degree showed 4th-5th grade. As the test result of colorfastness to dry cleaning for silk dyed fabrics, the contamination degree showed from 1st to 3rd-4th grade. As the test results of colorfastness to acid artificial perspiration, the discoloration degree showed from 1st to 3rd-4th grade and the contamination degree showed from 3rd to 4th-5th grade. As the test results of colorfastness to alkaline artificial perspiration, the discoloration degree showed from 1st to 4th grade and the contamination degree showed from 3rd to 4th-5th grade. The colorfastness to sunlight showed from 1st to 2nd grade. The colorfastness to rubbing showed from 3rd to 4th-5th grade in dry process and from 2nd-3rd to 4th-5th grade in wet process. As the test results of antibiosis, the decrease rate of germs to virus Klebsiella pneumoniae and Staphylococcus aureus showed at least more than 99% after the wash of 10 times. As the test results of antifungal activity to mycete Trichophyton mentagrophytes and Aspergillus niger, the both cotton and silk dyed fabrics didn't gain the significant antifungal effect.

A Study on the Bacterial Contamination and Antimicrobial Resistance in Expressed Human Milk (수집모유의 미생물오염과 항균제 내성에 관한 연구)

  • Hwang, Kyeong-Mi;Kang, Young-Sil
    • Journal of Korean Biological Nursing Science
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    • v.10 no.2
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    • pp.131-140
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    • 2008
  • Purpose: This study is about safety of the expressed human milk by investigating its bacterial contamination and antibiotic resistance of the microbes in the expressed milk. Methods: The data are collected from the 156 mothers and their newborn infants in NICU of U University Hospital from January 2004 to September 2005. Results: 1) The expressed human milk was contaminated by Staphylococcus epidermidis for 66.7%, Two mixed bacterial strain for 11.5%, Acinetobacter species for 8.0%, Klebsiella species for 4.6%, Staphylococcus aureus for 4.6%. 2) The microbes in the human milk had high resistance to the Antimicrobial agents: 77.5% for Penicillin-G, 66.6% for Oxacillin, and 63.7% for Cephalothin. 3) The distribution of microbes showed a significant depending on the place of the milk expression (p=.020). In particular, mixed bacterial strain was found more in the milks expressed at home than the milk expressed at the hospital. Conclusion: This study shows the importance of systematic education of feeding process in expressed milk: poor management of a breast pump, inadequate hand washing and imperfect breast cleaning explain the reasons of contamination 156 cases.

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Soil Contamination by Heavy Metals in Playgrounds of Kindergartens in Vilnius

  • Valskys, Vaidotas;Ignatavicius, Gytautas;Sinkevicius, Stanislovas;Gasiunaite, Ugne
    • Journal of Environmental Science International
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    • v.25 no.1
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    • pp.11-21
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    • 2016
  • The soil contamination by heavy metals in playgrounds of kindergartens in Vilnius city is analysed in this article. The aim of this research is to investigate and evaluate soil contamination by heavy metals in playgrounds of kindergartens in different territories of Vilnius city. Concentrations of heavy metals were measured using Thermo Fisher Scientific Niton$^{(R)}$ XL2 X-ray fluorescence spectrometer. Maximum allowable and background concentrations that are given in Lithuanian hygiene standard and Lithuania geochemical atlas are used to compare and evaluate concentrations of heavy metals. Concentrations of heavy metals and their spatial distribution were analysed in order to exclude the most contaminated areas relating with different functional areas of the city. Geo-statistical analysis and maps of spatial distribution were developed using IDW interpolator in ArcMap software. Detail soil surveys helps to assess the extent of anthropogenic impact in different parts of the city which can be harmful to the soil ecosystem and human health. Such researches can help to change or select different function for city areas in territorial planning process.

Evaluation of Groundwater Contamination Potential of Pesticides Using Groundwater Ubiquity Score in Jeju Island Soils (Groundwater Ubiquity Score를 이용한 제주도 토양 특성별 농약의 지하수 오염가능성 평가)

  • Hyun, Hae-Nam;Jang, Gong-Man;Oh, Sang-Sil;Chung, Jong-Bae
    • The Korean Journal of Pesticide Science
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    • v.11 no.3
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    • pp.144-153
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    • 2007
  • One of the most recent issues facing the pesticides regulatory process is the assessment of the potential for pesticides to leach through soil and appear in groundwater. Since Jeju island depends on a hydrogeologically vulnerable aquifer system as its principle source of drinking water, it is important to identify which pesticides are the most likely to result in groundwater contamination. The objective of this study was to assess groundwater contamination risk of 21 pesticides (12 insecticides, 6 herbicides and 3 fungicides) in Jeju soils using groundwater ubiquity score (GUS). Considering GUS estimated in 21 representative series of Jeju soils, generally herbicides showed relatively higher leaching potentials and insecticides showed lower leaching potentials. Groundwater contamination risk was higher in the order of bromacil > metolachlor > alachlor > linuron pretilachlor > butachlor for herbicides, carbofuran > ethoprophos > diazinone > dimethoate > penthoate > mecarbam > methidathion > endosulfan > fenitrothion > parathion > chlorpyrifos > terbufos for insecticides, and metalaxyl > chlorothalonil > triadimefon for fungicides. Among the tested pesticides alachlor, metolachlor, bromacil, ethoprophos and carbofuran were classified as the pesticides of very high or high groundwater contamination potential. Although the ranking of the leaching potential was essentially determined on the base of the intrinsic properties of the chemicals and environmental properties, variation of the relative groundwater contamination potentials of each pesticides in different soils were not significant. Therefore, the above ranking of groundwater contamination risk would be applied in most of Jeju soils. To lower the possibility of pesticide contamination of groundwater, the use of those pesticides classified as high or very high leaching potential should be strictly regulated in Jeju Island.

A Study on Plasma Corrosion Resistance and Cleaning Process of Yttrium-based Materials using Atmospheric Plasma Spray Coating (Atmospheric Plasma Spray코팅을 이용한 Yttrium계 소재의 내플라즈마성 및 세정 공정에 관한 연구)

  • Kwon, Hyuksung;Kim, Minjoong;So, Jongho;Shin, Jae-Soo;Chung, Chin-Wook;Maeng, SeonJeong;Yun, Ju-Young
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.3
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    • pp.74-79
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    • 2022
  • In this study, the plasma corrosion resistance and the change in the number of contamination particles generated using the plasma etching process and cleaning process of coating parts for semiconductor plasma etching equipment were investigated. As the coating method, atmospheric plasma spray (APS) was used, and the powder materials were Y2O3 and Y3Al5O12 (YAG). There was a clear difference in the densities of the coatings due to the difference in solubility due to the melting point of the powdered material. As a plasma environment, a mixed gas of CF4, O2, and Ar was used, and the etching process was performed at 200 W for 60 min. After the plasma etching process, a fluorinated film was formed on the surface, and it was confirmed that the plasma resistance was lowered and contaminant particles were generated. We performed a surface cleaning process using piranha solution(H2SO4(3):H2O2(1)) to remove the defect-causing surface fluorinated film. APS-Y2O3 and APS-YAG coatings commonly increased the number of defects (pores, cracks) on the coating surface by plasma etching and cleaning processes. As a result, it was confirmed that the generation of contamination particles increased and the breakdown voltage decreased. In particular, in the case of APS-YAG under the same cleaning process conditions, some of the fluorinated film remained and surface defects increased, which accelerated the increase in the number of contamination particles after cleaning. These results suggest that contaminating particles and the breakdown voltage that causes defects in semiconductor devices can be controlled through the optimization of the APS coating process and cleaning process.