• Title/Summary/Keyword: Contamination process

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Fabrication of Hierarchical Nanostructures Using Vacuum Cluster System

  • Lee, Jun-Young;Yeo, Jong-Souk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.389-390
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    • 2012
  • In this study, we fabricate a superhydrophobic surface made of hierarchical nanostructures that combine wax crystalline structure with moth-eye structure using vacuum cluster system and measure their hydrophobicity and durability. Since the lotus effect was found, much work has been done on studying self-cleaning surface for decades. The surface of lotus leaf consists of multi-level layers of micro scale papillose epidermal cells and epicuticular wax crystalloids [1]. This hierarchical structure has superhydrophobic property because the sufficiently rough surface allows air pockets to form easily below the liquid, the so-called Cassie state, so that the relatively small area of water/solid interface makes the energetic cost associated with corresponding water/air interfaces smaller than the energy gained [2]. Various nanostructures have been reported for fabricating the self-cleaning surface but in general, they have the problem of low durability. More than two nanostructures on a surface can be integrated together to increase hydrophobicity and durability of the surface as in the lotus leaf [3,5]. As one of the bio-inspired nanostructures, we introduce a hierarchical nanostructure fabricated with a high vacuum cluster system. A hierarchical nanostructure is a combination of moth-eye structure with an average pitch of 300 nm and height of 700 nm, and the wax crystalline structure with an average width and height of 200 nm. The moth-eye structure is fabricated with deep reactive ion etching (DRIE) process. $SiO_2$ layer is initially deposited on a glass substrate using PECVD in the cluster system. Then, Au seed layer is deposited for a few second using DC sputtering process to provide stochastic mask for etching the underlying $SiO_2$ layer with ICP-RIE so that moth-eye structure can be fabricated. Additionally, n-hexatriacontane paraffin wax ($C_{36}H_{74}$) is deposited on the moth-eye structure in a thermal evaporator and self-recrystallized at $40^{\circ}C$ for 4h [4]. All of steps are conducted utilizing vacuum cluster system to minimize the contamination. The water contact angles are measured by tensiometer. The morphology of the surface is characterized using SEM and AFM and the reflectance is measured by spectrophotometer.

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Fabrication of 5,000V, 4-Inch Light Triggered Thyristor using Boron Diffusion Process and its Characterization (Boron 확산공정을 이용한 5,000V, 4인치 광 사이리스터의 제작 및 특성 평가)

  • Park, Kun-Sik;Cho, Doohyung;Won, Jongil;Lee, Byungha;Bae, Youngseok;Koo, Insu
    • The Transactions of the Korean Institute of Power Electronics
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    • v.24 no.6
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    • pp.411-418
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    • 2019
  • Light-triggered thyristors (LTTs) are essential components in high-power applications, such as HVDC transmission and several pulsed-power applications. Generally, LTT fabrication includes a deep diffusion of aluminum as a p-type dopant to form a uniform p-base region, which needs careful concern for contamination and additional facilities in silicon semiconductor manufacturing factories. We fabricated 4-inch 5,000 V LTTs with boron implantation and diffusion process as a p-type dopant. The LTT contains a main cathode region, edge termination designed with a variation of lateral doping, breakover diode, integrated resistor, photosensitive area, and dV/dt protection region. The doping concentration of each region was adjusted with different doses of boron ion implantation. The fabricated LTTs showed good light triggering characteristics for a light pulse of 905 nm and a blocking voltage (VDRM) of 6,500 V. They drove an average on-state current (ITAVM) of 2,270 A, peak nonrepetitive surge current (ITSM) of 61 kA, critical rate of rise of on-state current (di/dt) of 1,010 A/㎲, and limiting load integral (I2T) of 17 MA2s without damage to the device.

Determination and Variation of Core Bacterial Community in a Two-Stage Full-Scale Anaerobic Reactor Treating High-Strength Pharmaceutical Wastewater

  • Ma, Haijun;Ye, Lin;Hu, Haidong;Zhang, Lulu;Ding, Lili;Ren, Hongqiang
    • Journal of Microbiology and Biotechnology
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    • v.27 no.10
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    • pp.1808-1819
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    • 2017
  • Knowledge on the functional characteristics and temporal variation of anaerobic bacterial populations is important for better understanding of the microbial process of two-stage anaerobic reactors. However, owing to the high diversity of anaerobic bacteria, close attention should be prioritized to the frequently abundant bacteria that were defined as core bacteria and putatively functionally important. In this study, using MiSeq sequencing technology, the core bacterial community of 98 operational taxonomic units (OTUs) was determined in a two-stage upflow blanket filter reactor treating pharmaceutical wastewater. The core bacterial community accounted for 61.66% of the total sequences and accurately predicted the sample location in the principal coordinates analysis scatter plot as the total bacterial OTUs did. The core bacterial community in the first-stage (FS) and second-stage (SS) reactors were generally distinct, in that the FS core bacterial community was indicated to be more related to a higher-level fermentation process, and the SS core bacterial community contained more microbes in syntrophic cooperation with methanogens. Moreover, the different responses of the FS and SS core bacterial communities to the temperature shock and influent disturbance caused by solid contamination were fully investigated. Co-occurring analysis at the Order level implied that Bacteroidales, Selenomonadales, Anaerolineales, Syneristales, and Thermotogales might play key roles in anaerobic digestion due to their high abundance and tight correlation with other microbes. These findings advance our knowledge about the core bacterial community and its temporal variability for future comparative research and improvement of the two-stage anaerobic system operation.

Estimation and Characteristics of Atmospheric Deposition Flux of Polycyclic Aromatic Hydrocarbons (PAHs) into the Masan and Haengam Areas of Korea (마산과 행암 지역으로 유입되는 다환방향족탄화수소(PAHs)의 대기 침적 플럭스 산정과 특성)

  • Lee Su-Jeong;Moon Hyo-Bang;Choi Min-kyu
    • Journal of Environmental Science International
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    • v.15 no.2
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    • pp.121-131
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    • 2006
  • Atmospheric bulk (wet and dry) samples were monthly collected in Masan and Heangam areas of Korea, to assess the deposition flux and seasonal variation of polycyclic aromatic hydrocarbons (PAHs). Deposition fluxes of PAHs in bulk samples were determined using gas chromatography coupled to mass spectrometer detector (GC/MSD). Particle deposition fluxes from Masan and Haengam areas varied from 13 to $87\;g/m^2/year$ and from 5 to $52\;g/m^2/year$, respectively. PAHs deposition fluxes in atmospheric bulk samples in Masan and Haengam areas ranged from 135 to $464\;{\mu}g/m^2/year$ and from 62.2 to $194\;{\mu}g/m^2/year$, respectively. Atmospheric deposition fluxes of particles and PAHs in this study were comparable to or slightly lower values than those from different locations in Korea and other countries. PAHs profiles of atmospheric deposition bulk samples showed slightly different from two sampling areas, however the predominant species of PAHs were similar. Indeno (1,2,3-c,d)pyrene, benzo(g,h,i)perylene, phenanthrene compounds were the most detected PAHs in deposition bulk samples. Carcinogenic PAHs occupied the contribution of approximately $30-40\%$ of the total PAHs deposition fluxes. The non-metric multi-dimensional scaling (MDS) was used, to assess the differentiation of PAHs source between two sampling areas. The result suggests that PAHs contamination sources were different according to the location and season surveyed. There was no an apparent relationship between the PAHs deposition flux against temperature and rainfall amount, even though summer season with the highest temperature and the largest amount of precipitation showed the lowest PAHs deposition flux. Benzo(e)pyrene/benzo(a)pyrene ratio indicated that the photo-degradation process was one of important factors to the seasonal variation of PAHs with the lower deposition fluxes.

A Study on the Natural Uranium Contamination Measuring Technology (천연우라늄 오염에 관한 방사선/능 측정기술 연구)

  • 정운수;홍상범;서범경;박진호;조용우;조성원;이정민
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.407-417
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    • 2004
  • This study is to verify radiation detection method by using $\alpha$-spectroscopy and ${\gamma}$-spectroscopy for concretes and components which will be generated during the decommissioning of the uranium conversion plant. Components and inside walls of the building were contaminated with natural uranium materials. Some parts of the stainless steel pipes and concretes of the walls were sampled and analyzed their alpha and gamma activities respectively. Alpha and gamma activities are well matched each other in the range of high activity region to 0.01 Bq/g and gamma activities are over estimated comparing alpha activities corresponded in below 0.005 Bq/g region for the natural uranium of AUC sample. The $^{238}U$ originated from natural products of conversion process could be distinguished by measuring $^{214}Pb$ or $^{214}Bi$ and $^{234}Th$ or $^{234m}Pa$. Uranium contaminations mainly are in the wall surface of the plant. Decontamination process of generating wastes which can be reached tp background level gamma activities measured by gamma spectroscopy can also be used to conservative assessment data.

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Improvement of Pressurized MF Pretreatment in MF/RO Process for Reuse (하수방류수 재이용 MF/RO 공정에서 가압식 MF의 전처리 성능 향상 방안 연구)

  • Na, Yumee;Park, Yong-Min;Lee, Yang-Woo;Kim, Won Kyong;Kim, Ji-Tae;Cho, Il-Hyoung
    • Membrane Journal
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    • v.24 no.5
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    • pp.350-357
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    • 2014
  • Pressurized MF membranes are used to remove suspended solid and colloidal materials of wastewater treatment plant effluent as the pretreatment of RO in reuse water production process. Membrane operation data and pollutants removal efficiency are investigated using 100 t/d scale pilot plant in J wastewater treatment plant located in Namyangju city. 40 LMH flux of pressurized MF membrane are obtained in various turbidity and temperature condition. Coagulation of dissolved organic enables flux improvement of MF from 40 LMH to 60 LMH. Pressure drop of 1st RO elements rapidly increased after long-term pause, which is because the complex contamination of organic matter and ionic substances of pluming systems.

Analysis of Attrition Rate of Y2O3 Stabilized Zirconia Beads with Different Microstructure and Mechanical Properties (고에너지 분쇄 매체 지르코니아 Beads의 미세구조 및 기계적 특성에 따른 마모율 분석)

  • Kim, Jung-Hwan;Yoon, Sae-Jung;Hahn, Byung-Dong;Ahn, Cheol-Woo;Yoon, Woon-Ha;Choi, Jong-Jin
    • Korean Journal of Materials Research
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    • v.28 no.6
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    • pp.349-354
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    • 2018
  • Particle size reduction is an important step in many technological operations. The process itself is defined as the mechanical breakdown of solids into smaller particles to increase the surface area and induce defects in solids, which are needed for subsequent operations such as chemical reactions. To fabricate nano-sized particles, several tens to hundreds of micron size ceramic beads, formed through high energy milling process, are required. To minimize the contamination effects during high-energy milling, the mechanical properties of zirconia beads are very important. Generally, the mechanical properties of $Y_2O_3$ stabilized tetragonal zirconia beads are closely related to the mechanism of phase change from tetragonal to monoclinic phase via external mechanical forces. Therefore, $Y_2O_3$ distribution in the sintered zirconia beads must also be closely related with the mechanical properties of the beads. In this work, commercially available $100{\mu}m-size$ beads are analyzed from the point of view of microstructure, composition homogeneity (especially for $Y_2O_3$), mechanical properties, and attrition rate.

A study on the titanium welding process according to the temperature characteristics of shielding methods (티타늄 용접공정에서 온도특성에 따른 실딩방법에 관한 연구)

  • Chung, Han-Shik;Jeong, Hyo-Min;Lee, Dae-Chul;Lee, Byeong-Yong
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.1
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    • pp.29-34
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    • 2013
  • The welds tent to be weakened if it is exposed to the air during the welding process. In titanium welding with Gas Tungsten Arc Welding, inappropriate colors of the welds, such as purple/red, blue, yellow, gray, white and pink represents that it is contaminated by oxygen and nitrogen in the air. Shielding gases can be used to protect welds from the contamination. In addition, Weld metal and heat affected zone (HAZ) are also shielded from the air when it is cooled down to the room temperature. In this paper, appropriate shielding gases for the shape and form of Trailing Shielding Jig and torch shielding ($13{\sim}20{\ell}/min$), after shielding ($22{\sim}30{\ell}/min$), and back shielding ($25{\sim}30{\ell}/min$) are studied.

Transport of Colloids and Contaminant in Riverbank Filtration (강변여과에서 콜로이드 물질과 오염물의 거동에 관한 연구)

  • Lee Sang-Il;Kim Dae-Hwan;Lee Sang-Sin;You Sang-Yeon
    • Journal of Korea Water Resources Association
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    • v.39 no.6 s.167
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    • pp.511-520
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    • 2006
  • Riverbank filtration is a natural process, using alluvial aquifers to remove contaminants and pathogens in river water for the production of drinking water. In Korea, most of the drinking water is supplied by surface water in-take. However, maintaining the quality of the drinking water becomes more and more difficult due to the increase of contamination. In riverbank filtration, the understanding of contaminant transport is an important task for the production of high quality drinking water and for the maintenance of facilities. In this paper, the transport behavior of hydrophobic organic contaminants is investigated when contaminants coexist with dissolved organic matter (DOM) and bacteria. In the developed model, the aquifer is thought of as a four phase system: two mobile colloidal phases, an aqueous phase, and a stationary solid matrix phase. The model equations are solved numerically for various situations. Results indicate that the presence of colloidal matters can enhance the mobility of contaminant significantly and that partitioning coefficients play an important role in the process.

Problem Findings Regarding the Legal Liability of Soil Contaminated Sites in Korea, and it's Policy Suggestion from a Comparison Study to U. S., U K., Germany, Netherlands, and Denmark's Policies (토양오염지역의 책임에 관한 우리 나라, 미국, 영국, 독일, 네덜란드, 덴마크 법과 제도의 비교 분석 및 우리 나라 정책개선방향)

  • Park, Yong-Ha;Park, Sang-Yeol;Yang, Jae-E.
    • Journal of Environmental Policy
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    • v.3 no.2
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    • pp.31-57
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    • 2004
  • Attempts were made to compare and analyze the policies of the United States, the United Kingdom, the Netherlands, Germany and Denmark concerning Korea's major problems associated with legal liability of the contaminated sites. These countries were chosen from a feasible preliminary analysis of 18 countries of the EU and the U. S. The major problems were revealed based on the analysis of Korean legacy and legislation, which are summarized as follows i) lack of clear detailed technical and legal guidance to determine the responsible party or parties of contaminated sites, ii) no distinction between the strict and non strict legal liability of innocent land owners, iii) no clearly set limit on retroactive legal liability. Comparison of the policies of countries chosen suggested improvements regarding these major problems as follows: i) activating national and international research on soil contamination prevention policy, ii) arranging distinct legal regulation between strict and non strict liability criteria, iii) establishing the limits on innocent and non strict liability, iv) establishing methodology and process of legal liability distribution and compensation, and v) establishing a legal process to redeem any benefit derived from remediation of contaminated sites with the public budget. Our policy suggestions above are not yet conclusive due to a lack of policy implementation simulation. Additional research is needed on aspects of social, economic and long term effects of the proposed policy directions. Nevertheless, application of the policy suggestions of this research would increase the efficacy of Korean policy regarding the survey and remediation of the potentially contaminated sites.

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