• Journal of the Korea Organic Resources Recycling Association
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• v.9 no.2
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• pp.37-44
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• 2001

This study was carried out to evaluate the effects of initial concentration and moisture content on removal of phenol in soil. Texture of soil used was sandy loam. Air was supplied at the rate of $31{\ell}/m^3$(soil)/min. Initial phenol concentrations of contaminated-soils were about 700mg/kg and 1,200mg/kg(as dry weight basis), respectively. Low phenol concentration (about 700mg/kg) was degraded more rapidly than high concentration (about 1,200mg/kg). After phenol concentration of 1,200mg/kg was decreased to about 700mg/kg, its degradation was similar to the case of initial phenol concentration of about 700mg/kg. Phenol degradationrate rate of 15% soil moisture content was higher than that of 20%.

• Journal of the Korean earth science society
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• v.28 no.1
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• pp.112-122
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• 2007

It is known that coal-derived fly ashes have the unique chemical composition and mineralogical characteristics. Since iron oxides in coal fly ash are enriched with heavy metals, the subsurface media including soils, underground water, and sea water are highly likely contaminated with heavy metals when the heavy metals are leached from fly ashes by water-fly ash interactions. The purpose of this study was to investigate how indigenous bacteria affect heavy metal leaching and mineralogy in fly ash slurry during the fly ash-seawater interactions in the ash pond located in Dangjin seashore, Korea. The average pH of ash pond seawater was 8.97 in nature. Geochemical data showed that microbial activity sharply increased after the 7th day of the 60-day course batch experiments. Compared with other samples including autoclaved and natural samples, ${SO_4}^{2-}$ was likely to decrease considerably in the fly ash slurry samples when glucose was added to stimulate the microbial activity. Geochemical data including Eh/pH, alkalinity, and major and trace elements showed that the bacteria not only immobilize metals from the ash pond by facilitating the chemical reaction with Mn, Fe, and Zn but may also be able to play an important role in sequestration of carbon dioxide by carbonate mineral precipitation.

• Journal of Korea Soil Environment Society
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• v.1 no.2
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• pp.91-101
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• 1996

In recent years, phytoremediation, the use of plants to detoxify hydrocarbons, has been a promising new area of research, particularly in situ cleanup of large volumes of slightly contaminated soils. There is increasing need for a mathematical model that can be used as a predictive tool prior to actual field implementation of such a relatively new technique. Although a number of models exist for solute-plant interaction in the vegetated zone of soil, most of them have focused on ionic nutrients and some metals. In this study, we developed a mathematical model for simulation of bioremediation of hydrocarbons in soil, associated with plant root systems. The proposed model includes root interactions with soil-water and hydrocarbons in time and space, as well as advective and dispersive transport in unsaturated soil. The developed model considers gas phase diffusion and liquid-gas mass exchanges. For simulation of temporal and spatial changes in root behavior on soil-water and with hydrocarbons, time-specific distribution of root quantity through soil was incorporated into the simulation model. Hydrocarbon absorption and subsequent uptake into roots with water were simulated with empirical equations. In addition, microbial activity in the rhizosphere, a zone of unique interaction between roots and soil microorganisms, was modeled using a biofilm theory. This mathematical model for understanding and predicting fate and transport of compound in plant-aided remediation will assist effective application of plant-aided remediation to field contamination.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.2
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• pp.71-76
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• 2011

In this study, a heavy metal stabilization treatment using waste resource stabilizing agents was utilized on army firing range soil contaminated with Pb and Cu. Both calcined oyster shells (COS; 5% w/w) and waste cow bone (WCB; 3% w/w) were applied for a wet-curing duration of 28 days. Following the stabilization treatment, the process efficiency was evaluated by various extraction methods for Pb and Cu. Neutral and weak acid extraction methods, such as water soluble extraction and SPLP, did not show positive results for heavy metal stabilization with very low leachability. On the other hand, TCLP and 0.1 N HCl extraction showed that the stabilizing agents significantly reduced the amount of the heavy metals leached from the soil, which strongly supports that the treatment efficiency is positively evaluated in acidic leaching conditions. Specifically, in the 0.1 N HCl extraction, the reduction efficiencies of Pb and Cu leaching were 99.9% and 83.9%, respectively. From the sequential extraction results, a difference between Pb and Cu stabilization was observed, which supports that Pb stabilization is more effective due to the formation of insoluble Pb complexes. This study demonstrates that the application of waste resources for the stabilization of heavy metals is feasible.

• Korean Journal of Environmental Agriculture
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• v.25 no.3
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• pp.257-261
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• 2006

Zerovalent iron (ZVI) has been recently used for environmental remediation of soils and groundwaters contaminated by chlorinated organic compounds. As a new approach to improve its reductive activity and stability, zerovalent iron-montmorillonites (ZVI-Mt) complex are synthesized by simple process. Therefore, this study was carried out to elucidate the characteristics of ZVI-Mt complex and to investigate degradation effects of fungicide chlorothalonil. The XRD patterns of ZVI-Mt complex showed distinctive peaks of ZVI and montmorillonite. In ZVI-Mt complex, the oval particles of ZVI were partly surrounded by montmorillonite layers that could prevent ZVI surface oxidation by air. The degradation ratio of chlorothalonil after 60 min exhibited 71% by ZVI and 100% by ZVI-Mt complex. ZVI-Mt21 complex exhibited much higher and faster degradation ratio of chlorothalonil compare to that of ZVI or ZVI-Mt11 complex. Also, degradation rate of chlorothalonil was increased with increasing ZVI or ZVI-Mt complex content and with decreasing initial solution pH.

• Journal of Soil and Groundwater Environment
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• v.9 no.1
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• pp.39-46
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• 2004

Removal efficiencies for diesel fuel and diesel hydrocarbons ($C_10$∼$C_22$) using microwave-enhanced SVE process were evaluated with dry and moist soil, respectively. Diesel removal rates of microwave-enhanced SVE process were 7 times for dry soil and 1580 times for moist soil as great as those of the SVE process without microwave heating. High dielectric property of water contents may accelerate the absorption of microwave energy into soil and thus vaporized the diesel fuel components drastically. The diesel removals were 67.7∼78.4% for $C_10$ and $C_12$, and 0∼18.5% for $C_14$∼$C_22$ for dry and moist soil with SVE process only. On the other hand, dry soil with microwave-enhanced SVE process showed 89.3∼99.4% removal for $C_10$ to and $C_12$ and 35.6∼67.0% for hydrocarbons over $C_14$. All hydrocarbons ($C_10$∼$C_22$) studied were significantly removed (93.6∼99.8%) for moist soil with microwave-enhanced SVE process.

• Journal of the Mineralogical Society of Korea
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• v.25 no.3
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• pp.155-162
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• 2012

We observed characteristic oxidation and dissolution phenomena induced by dissolved oxygen for mackinawite that is produced via sulfate-reducing bacteria (SRB) living in anaerobic environments such as soils and groundwater. We tried to recognize the role of the sulfide minerals that usually coexist with some stabilized radionuclides (e.g., reduced uranium), which can be reoxidized and redissolved by an oxygen-rich groundwater invaded into a contaminated area. The mackinawite produced by 'Desulfovibrio desulfuricans', a sulfate-reducing bacterium, was conducted to be dissolved for 2 weeks by some oxidants such as 'hydrogen peroxide' and 'sodium nitrite'. Although mineralogical oxidation and dissolution characteristics were different from each other according to the oxidants, the initially oxidized solution was early stabilized through the oxygen consumption by ${\mu}m$-sized sulfide particles and the resultant increase of sulfate in solution. From these results, we can anticipate that the large amount of sulfide minerals generated by SRB can not only repress the anoxic environment to be disturbed by the consumption of oxygen in groundwater, but also contribute to stabilize the reduced/precipitated radionuclides as a buffer material for a long time.

• Journal of the Korean GEO-environmental Society
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• v.7 no.6
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• pp.13-22
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• 2006

The geotextile have been used in filtration and drainage for over 30 years in many applications of civil and environmental projects. Geotextile tube is compound technology of filtration and drainage property of geotextile. Geotextile have been used for various types of containers, such as small hand-filled sandbags, 3-dimensional fabric forms for concrete paste, large soil and aggregate filled geotextile gabion, prefabricated hydraulically filled containers, and other innovative systems involving containment of soils using geotextile. They are hydraulically filled with dredged materials. It have been applied in coastal protection and scour protection, dewatering method of slurry, and isolation of contaminated material. Recently, geotextile tube technology is no longer alternative construction technique but suitable desired solution. This paper presents the behavior of geotextile tube composite structure by 2-D limit equilibrium and plane strain analysis. 2-D limit equilibrium analysis was performed to evaluate the stability of geotextile tube composite structure for the lateral load and also the plane strain analysis was conducted to determine the design and construction factors. Based on the results of this paper, the three types of geotextile tube composite structure is stable. And the optimum tensile strength of geotextile is 151kN/m and maximum pumping pressure is 22.7kN/m.

• Clean Technology
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• v.12 no.4
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• pp.250-258
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• 2006

CFC compounds such as CFC-113 and 1,1,1-TCE, etc. have been used in various industries due to their excellent chemical stability, thermodynamic characteristics, non-inflammability and anti-corrosiveness. However, in oder to protect the earth environment, "the Montreal Protocol on substances that deplete the ozone layer" was adopted in 1989 for prevention of production and utilization of these CFC compounds and alternative cleaning agent have been required in the industry. The objective of this study is to develop non-aqueous cleaning agents that do not require major change of cleaning system, have excellent cleaning efficiency, are favorable to the environment, are harmless to the human body, and are not generated corrosive materials. In this work, non-aqueous cleaning agents have been formulated with glycol ether series and paraffinic hydrocarbon series with siloxane, and their physical properties and cleaning efficiencies were analyzed and compared with those of regulated materials. As a result of physical properties measurement of the formulated cleaning agents, it is expected that they may have good penetration ability into contaminated materials due to their properties with low density and low surface tension. Measurement of flash point and vapor pressure of the cleaning agents will be helpful for evaluation of their safety and working environment. The experimental results of cleaning flux, solder and grease by the formulated cleaning agents show that their cleaning abilities of soils were good and that there were no residues on the substance after cleaning. Therefore, alternative cleaning agents which have equivalent cleaning ability to regulating materials, good penetration ability and low hazard to human body, have been developed in this work.

• Korean Journal of Microbiology
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• v.33 no.3
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• pp.193-198
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• 1997

Microorganisms capable of producing biosurfactant were isolated from oil-contaminated soils and seawater. Among them, the selected strain SW1 was identified as Pseudomonas sp. by taxonomical characteristic tests, and so tentatively named Pseudomonas sp. SWI. The optimal temperature and initial pH for biosurfactant production were TEX>30^{\circ}C.$ and 7.0, respectively. The optimal medium composilion for the production of biosurfactant by Pseudomonas sp. SW1 were hexadecane of 2.0%, yeast extract of 0.04%, $K_{2}HPO_4$ of 0.02%, $KH_2PO_4$ of 0.03% and $MgSO_4$ center dot $7H_2O$ of 0.04%, respectively. Under the above conditions, minimum wrface tension was 32 mN/m after incubation of 2 days. The biosurfactant was produced during initial stationary phase in the optimal medium. Pseudotnonas sp. SWl utilized various hydrocarbons such as Bunker oils, n-alkanes and branched alkanes as a sole carbon source.