• Journal of Life Science
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• v.8 no.4
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• pp.421-425
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• 1998

The antifungal activity of polygodial, which was isolated from Polygonum hydropiper used as a hot spice in Japan, was investigated through measuring its MICs and against food-contaminants including 4 strains of Saccharomyces cerevisiae, 3 strains of Zygosaccharomyces species, and 5 strains of Aspergillus species. All yeast-like fungi exhibited strong antifungal susceptivilities with MICs and MFCs below 3.13${\mu}g$/ml. Strains of Aspergillu species showed moderate with MIC of 25-50${\mu}g$/ml and MFC of 50-100${\mu}g$/ml. However these strains to sorbic acid, as already known, revealed very weak with MICs of 200-800${\mu}g$/ml and MFCs above 1600${\mu}g$/ml. In addition, effects of various pHs and temperatures on the antifungal activity of polygodial were tested against S. cerevisiae. At $4^{\circ}C$, the fungicidal activity of polygodial gradually increased with incubation time and reached the maximum(MFC of 3. 13${\mu}g$/ml) in 5 hours. At temperatures in the range of 30-$45^{\circ}C$, the activity of polygodial increased in proportion to temperature rise and in particular at $45^{\circ}C$ was possible with the concentration of 0.1${\mu}g$/ml. mOn the other hand, medium pH was also identified to affect the antifungal activity of polygodial. Namely, compared to neutral (pH7), acidic(pH 3) and basic(pH 9) medium synergized its activity (MIC and MFC) to 8- and 2- fold, respectively.

• Journal of the Korea Organic Resources Recycling Association
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• v.10 no.2
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• pp.132-139
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• 2002

This study was carried out to investigate the effects of aging and soil texture on composting of diesel-contaminated soil. The soils used for this study were silt loam and sand. Target contaminant, diesel oil, was spiked at 10,000mgTPH/kg of dry soil. Aging times of diesel-contaminated soils were 15days and 60days, respectively. Fresh diesel-contaminated soil was also investigated. Moisture content was controlled to 70% of soil field capacity. Mix ratio of soil to sludge was 1:0.3 as wet weight basis. Temperature was maintained at $20^{\circ}C$ Volatilization loss of TPH was below 2% of initial concentration. n-Alkanes lost by volatilization were mainly by the compounds of C10 to C17. Diesel in contaminated soil was mainly removed by biodegradation mechanism. First order degradation rate constant of TPH in sandy soil was ranged from 0.081 to 0.094/day, which is higher than that in silt loam(0.056-0.061/day). From fresh to 60day-aged soils, there was little difference of TPH biodegradation rate between the soils. Carbon recovery ranged from 0.61 to 0.89. TPH degradation rate was highly correlated with $CO_2$ production rate.

• Environmental Analysis Health and Toxicology
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• v.12 no.3_4
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• pp.31-41
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• 1997

Public concerns about hazardous health effect from the exposure to organic by-products of the chlorination have been increased. There are numerous studies reporting that chlorination of drinking water produces numerous chlorinated organic by-products including THMs, HAAs, HANs. Some of these products are known to be animal carcinogens. The purpose of this study was to estimate health risk of DBPs by chlorinated drinking water ingestion in Seoul based on methodologies that have been developed for conducting risk assessment of complex-chemical-mixture. The drinking water sample was collected seperately at six water treatment plant in Seoul at March, April, 1996. In tap water of households in Seoul, DBPs were measured wilfh the mean value of 36.6 $\mu$g/L. Risk assessment processes,. which include processes for the estimation of human cancer potency using animal bioassay data and calculation of human exposure, entail uncertainties. In the exposure assessment process, exposure scenarios with various assumptions could affect the exposure amount and excess cancer risk. The reference dose of haloacetonitriles was estimated to be 0.0023 mg/kg/day by applying dibromoacetonitrile NOAEL and uncertainty factor to the mean concentration. In the first case, human excess cancer risk was estimated by the US EPA method used to set the MCL (maximum contaminant level). In the second and third case, the risk was estimated for multi-route exposure with and without adopting Monte-Carlo simulation, respectively. In the second case, exposure input parameters and cancer potencies used probability distributions, and in the third case, those values used point estimates (mean, and maximum or 95% upper-bound value). As a result, while the excess cancer risk estimated by US EPA method considering only direct ingestion tended to be underestimated, the risk which was estimated by considering multi-route exposure without Monte-Carlo simulation and then using the maximum or 95% upper-bound value as input parameters tended to be overestimated. In risk assessment for Trihalomethanes, considering multi-route exposure with adopting Monte-Carlo analysis seems to provide the most reasonable estimations.

• The Journal of Engineering Geology
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• v.18 no.2
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• pp.127-136
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• 2008

Geophysical survey for establishing a wide site for the distribution of water content, wetting front infiltration due to the rainfall, and distribution of groundwater level has been performed by using 8round penetration radar (GPR) method, electrical resistivity method, and so on. On the other hand, a narrow area survey was performed to use a permittivity method such as time domain reflectometry, frequency domain reflectometry, and amplitude domain reflectometry methods for estimating volumetric water content, soil density, and concentration of contaminant in surface and subsurface. The permittivity methods establish more corrective physical parameters than different found survey technologies mentioned above. In this study for establishment of infiltration behaviors for wetting front in the unsaturated soil caused by an artificial rainfall, soil physical parameters for volumetric water content, pore water pressure, and pore air pressure were measured by FDR measurement device and pore water pressure meter which are installed in the unsaturated weathered granite soil with different depths. Consequently, the authors were proposed to a new establishment method for analyzing the variations of volumetric water content and wetting front infiltration from the responses of infiltrating pore water in the unsaturated soil.

• Journal of Soil and Groundwater Environment
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• v.11 no.3
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• pp.59-65
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• 2006

Reductive dechlorination of chlorophenols by nickel coated iron was investigated to understand the feasibility of using Ni/Fe for the in situ remediation of contaminated groundwater. Zero valent iron (ZVI) was amended with Ni(II) ions to form bimetal (Ni/Fe). Dechlorination of 4-chlorophenol and formation of intermediates was studied using Ni/Fe. Effects of initial contaminant concentration, bimetal loading, presence of humic acid, and solution chemistry were also evaluated. Experimental results showed that Ni/Fe bimetal was so effective that more than 95% of 4-CP degradation was achieved within 240 minutes. Pseudo first-order rate constant for the dechlorination reaction was well correlated with bimetal loading. Humic acid competed for the reactive sites on the nickel coated iron with chlorophenols, lowering the dechlorination efficiency. No significant changes in solution pH were observed in the dechlorination of chlorophenols with Ni/Fe in the absence of buffer, indicating that reactivity of bimetal (Ni/Fe) could be prolonged. Phenol was found as a dechlorination intermediate of the conversion of 4-chlorophenol compound by Ni/Fe.

• Journal of Soil and Groundwater Environment
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• v.19 no.3
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• pp.33-38
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• 2014

This study was performed to evaluate the applicability of pump and treat technology as well as to identify the changes of groundwater level by continuous pumping at the petroleum contaminated site. A total of 9 monitoring wells were installed at the site and the contaminant concentrations, TPH, benzene, toluene, ethylbenzene and xylene, of groundwater were measured. With the results of the groundwater monitoring, a total of 9 wells were set up for pumping contaminated groundwater in 3 locations. The waste water treatment facility with a capacity of $10m^3/hr$ was installed in the site and operated for about 1 year. The concentrations of the contaminated groundwater from the 3 pumping wells were exceeded groundwater regulation for benzene and TPH. However, the effluent concentration of benzene and TPH was under the regulation showing the maximum level of 0.011 mg/L and 1.2 mg/L during the operation periods. Groundwater levels were decreased by continuous pumping and those were not recovered during the operation period. Groundwater levels of PW-1,2, PW-3,4,5,6 and PW-7,8,9 were decreased about 5 m, 0.7 m, 2 m, respectively. The hydraulic conductivity (K) of the region of PW-1,2, PW-3,4,5,6 and PW-7,8,9 was estimated to be $6.143{\times}10^{-5}cm/sec$, $2.675{\times}10^{-5}cm/sec$, $1.198{\times}10^{-4}cm/sec$. Groundwater level was seemed to be affected not by hydraulic conductivity but by morphological effect. These results show that the pump and treat technology has high applicability for the restoration of petroleum contaminated groundwater but needs continuous monitoring to prevent rapid groundwater drawdown.

• Journal of the Korea Organic Resources Recycling Association
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• v.19 no.4
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• pp.74-83
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• 2011

In this study, to estimate the transforming (runoff and leachate) rate of the livestock resources applying to agricultural crop land as fertilizer, field scale test was conducted and the results were obtained as follows. According to results of livestock resources effect to agricultural land, the total amount of harvested crop from testing bed was $0.437kg/m^2$, and nutrient contents were $0.024{\pm}0.006%$ and $0.020{\pm}0.004%$ for N and P, respectively. Dynamics of contaminants in the livestock resources to be supplied to agricultural crop land showed that concentrations were continuously decreased to the level of blank test bed until 60 days of planting. The amount of runoff from farm land showed the tendency to increase according to the increase of rainfall intensity. Run-off ratio of 10mm/h rainfall intensity for agricultural land showed that each contaminant concentration was increased due to rainfall intensity with 8 mm/h, specifically SS showed the highest increase.

• Applied Chemistry for Engineering
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• v.35 no.1
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• pp.23-28
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• 2024

Cesium is a potential toxic contaminant due to its high solubility, which allows it to easily penetrate the human body and potentially induce cancer or DNA mutations. In this study, oxygen functional groups were introduced on activated carbons (ACs) by ozone treatment to enhance the cesium adsorption capacity. As the ozone treatment time increased, the oxygen content on the ACs surface increased. Subsequently, the electrostatic interaction between ACs and cesium enhanced, resulting in higher cesium ion adsorption efficiency across all samples. In particular, the sample treated with ozone for 7 minutes at an internal ozone concentration of 50000 ppm had roughly 12% greater oxygen functional group content and the highest cesium removal effectiveness (97.6%). Meanwhile, samples treated for 5 minutes showed a 0.3% cesium removal rate difference compared to those treated for 7 minutes, which was caused by the surface chemical similarity of the two samples due to the reactive characteristics of ozone gas. However, the cesium adsorption performance of ozonated activated carbon seems to be mainly influenced by the amount of oxygen functional groups introduced to the surface, although the specific surface area and pore structure of the activated carbon are also important.

• Journal of radiological science and technology
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• v.38 no.2
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• pp.163-170
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• 2015

The interest of the people in the radioactive contamination of the water has increased significantly and the study about analysis and management of radioactive materials are being actively conducted. And monitoring spots have been expanded to the range of public water as well as drinking water by publishing the rule of drinking water quality standards and examination in the Environmental Enforcement Ordinance No. 553 of Korea. In this study, US EPA was investigated as the foreign advanced cases and the way that is appropriate for the Korea was sought by analyzing investigate radionuclide, interval and management. As a result, in the selection part of investigate radionuclide, geological survey, status of nuclear power plants and the presence of the use of artificial radionuclides of the Korea should be investigated and additionally after the selection of a few radionuclides, the systems should be extended to cover all possible radionuclides by considering radioactive pollution levels in humans may be exposed due to the annual drinking water. In the part of the investigate interval, the concept(MCL, DL) should be set up for preventing concentration detection of above MCL and it needs to the maintenance and management. For example, when the concentration is more than MCL, it should be investigated on a quarterly and when the concentration is lower than MCL, it should be investigated to each different interval and management. And the US EPA divided the management area and make the roadmap for managing drinking water. The each classified area has been organized to match the state budget and labor force and the individual data have been managed effectively by HPGe, the NaI, TLD and so on.

• Journal of Wetlands Research
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• v.18 no.3
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• pp.275-281
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• 2016

This study was conducted to analyze the runoff characteristics of the highway depending on the number of vehicles and to provide the installation proposal of an NPS pollution reduction facility. There were a total of 5 monitoring sites used for the study namely, Gyeongbu, Seohaean, Honam and Tongyeoung Dageon highway. Monitoring events started from 2006 until 2015 having a total of 44 storm events. According to monitoring statistics, the average antecedent dry days (ADD) and rainfall was 6.2 days and 19.2 mm, respectively. The Gyeongbu Highway (H-4) was recorded having the highest Average Daily Traffic and Catchment Area (ADT/CA) with $49.4car/day{\cdot}m^2$ while other site were less than $10car/day{\cdot}m^2$. The average concentration of the NPS pollutants generated from monitoring sites were 63.5 mg/L(TSS), 24.9 mg/L(BOD), 3.35 mg/L(TN), 0.63 mg/L(TP) and 298 ug/L(Total Zn). This exhibited lower values in comparison to the remarks of highway related runoff EMC values published in Korea. Moreover, through the results of the correlation analysis between the contaminant concentration and ADT/CA, $R^2$ value of SS showed the highest correlation with 585. Through the correlation equation between ADT/CA and EMC of TSS, when there is 73.7 mg/L of TSS EMC found from a domestic highway, ADT/CA ratio is normally $13car/day{\cdot}m^2$. Therefore, in a case of more than 13 cars passing through a certain area, the area can be considered and present as the point of generation of nonpoint source pollutants. Also, in this study, since it considered a unit area ADT indicated in previous studies, it was determined that it has a high applicability and utilization in generalized units than conventional study which were conventionally done.