• Title/Summary/Keyword: Contact formation

검색결과 856건 처리시간 0.03초

Electrochemical Properties of Lithium Sulfur Battery with Silicon Anodes Lithiated by Direct Contact Method

  • Kim, Hyung Sun;Jeong, Tae-Gyung;Kim, Yong-Tae
    • Journal of Electrochemical Science and Technology
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    • 제7권3호
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    • pp.228-233
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    • 2016
  • It is hard to employ the carbon materials or the lithium metal foil for the anode of lithium sulfur batteries because of the poor passivation in ether-based electrolytes and the formation of lithium dendrites, respectively. Herein, we investigated the electrochemical characteristics of lithium sulfur batteries with lithiated silicon anode in the liquid electrolytes based on ether solvents. The silicon anodes were lithiated by direct contact with lithium foil in a 1M lithium bis(trifluoromethane sulfonyl) imide (LiTFSI) solution in 1,2-dimethoxyethane (DME) and 1,3-dioxolane (DOL) at a volume ratio of 1:1. They were readily lithiated up to ~40% of their theoretical capacity with a 30 min contact time. In particular, the carbon mesh reported in our previous work was employed in order to maximize the performance by capturing the dissolved polysulfide in sulfur cathode. The reversible specific capacity of the lithiated silicon-sulfur batteries with carbon mesh was 1,129 mAh/g during the first cycle, and was maintained at 297 mAh/g even after 50 cycles at 0.2 C, without any problems of poor passivation or lithium dendrite formation.

Streptomyces levendulae의 원형질체와 원형질체 융합에 대한 미세구조 (Ultrastructural Studies for Protoplasts and Protoplast Fusion in Streptomyces lavendulae)

  • 하영칠;홍순우;유진철;임헌만
    • 미생물학회지
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    • 제24권3호
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    • pp.197-203
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    • 1986
  • Streptomyces lavendulae에서 생성된 원형질체 및 원형질체 융합과정에 대한 미세구조 및 행태학적 관찰을 투과 전자현미경과 주사전자현미경을 사용하여 행하였다. 생성된 원행질체들은 고장액에서 대체로 안정하였으나 간혹 변형된 원형질체들이 관찰되었다. 원형질체 융합은 접촉지역 융합지역, 분리지역 형성과정을 차례로 거치면서 선행되는 것이 관찰되었다. 이러한 사실은 세포막 구조의 변화와 이원형의 소실에 의하여 뒷받침이 될 수 있으으로 이러한 변화들을 융합과정에서의 각 단계로 해석하는 것이 가능하리라 사료된다.

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급속응고한 Ag-Sn-In 합금의 미세조직에 미치는 Misch Metal의 영향 (The Effect of Misch Metal on the Microstructure of Rapidly solidified Ag-Sn-In Alloys)

  • 장대정;남태운
    • 한국전기전자재료학회논문지
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    • 제20권6호
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    • pp.561-565
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    • 2007
  • Because of a good wear resistance and a stable contact resistance, Ag-CdO is widely used as electrical contact material. But, the Cd-oxide mainly exists as a coarse particle and adversely affected to environment. As a reason, $Ag-SnO_2$ alloy has been developed. The Sn-oxide maintains stable and fine particle even at high temperature. In order to investigate the effect of Misch metal (Mm) additional that affects the formation of the oxide and the formation of fine matrix Ag, we studied the microstructures and properties of Ag-Sn-In(-Mm) material fabricated by rapid solidification process. The experimental procedure were melting using high frequency induction, melt spinning, and internal oxidation. The Mm addition makes Ag matrix more fine than no Mm addition. The reason is that the addition of Misch metal decreased a latent heat of fusion of alloy, as a result the rapid solidification effect of alloy is increased. The maximum hardness shows at 0.3 wt%Mm. after that the hardness is decreased until 0.4 wt% Mm, but still larger than no Mm addition alloy. At 0.5 wt% Mm alloy, the precipitation of Misch metal causes a decrease of hardness than no Mm addition alloy.

Coupled temperature-displacement modeling to study the thermo-elastic instability in disc brakes

  • Ramkumar, E.;Mayuram, M.M.
    • Coupled systems mechanics
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    • 제1권2호
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    • pp.165-182
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    • 2012
  • Macroscopic hot spots formed due to the large thermal gradients at the surface of the disc brake rotor, make the rotor to fail or wear out early. Thermo-elastic deformation results in contact concentration, leading to the non uniform distribution of temperature making the disc susceptible to hot spot formation. The formation of one hot spot event will predispose the system to future hot spotting at the same location. This leads to the complete thermo-elastic instability in the disc brakes; multitude parameters are responsible for the thermo elastic instability. The predominant factor is the sliding velocity and above a certain sliding velocity the instability of the brake system occurs and hot spots is formed in the surface of the disc brake. Commercial finite element package ABAQUS(R) is used to find the temperature distribution and the result is validated using Rowson's analytical model. A coupled analysis methodology is evolved for the automotive disc brake from the transient thermo-elastic contact analysis. Temperature variation is studied under different sliding speeds within the operation range.

가솔린 엔진오일의 사용에 따른 기계적 성질의 변화에 관한 연구 (The Changes of Mechanical Properties of Used Oil in Gasoline Engine)

  • 강석춘;신성철;김동길;노장섭
    • Tribology and Lubricants
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    • 제9권2호
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    • pp.36-48
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    • 1993
  • This study is concerned with the changes (deterioration) of the mechanical properties of used oil in the gasoline engine. The analysed properties of used oil were friction, antiwear, wear debris, load-carrying ability and the formation of surface film. From this study, it was found that the oil used in engine was deteriorated to increase the wear and fricion and decrease the load-carrying ability as the running distance of oil was increased. Also the main cause of deterioration was related to the formation of the protective film on the contact zone. When the film was composed with rich additives (sulfur), this could properly protect contact zone from the increase of wear and friction. But as oil was deteriorated, it could not form such a film and therefore the protective ability of sliding surface diminished.

Characterization and Optimization of the Contact Formation for High-Performance Silicon Solar Cells

  • Lee, Sung-Joon;Jung, Won-Cheol;Han, Seung-Soo;Hong, Sang-Jeen
    • 동굴
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    • 제82호
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    • pp.5-7
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    • 2007
  • In this paper, p-n junction formation using screen-printed metalization and co-firing is used to fabricate high-efficiency solar cells on single- crystalline silicon substrates. In order to form high-quality contacts, co-firing of a screen-printed Ag grid on the front and Al on the back surface field is implemented. These contacts require low contact resistance, high conductivity, and good adhesion to achieve high efficiency. Before co-firing, a statistically designed experiment is conducted. After the experiment, a neural network (NN) trained by the error back-propagation algorithm is employed to model the crucial relationships between several input factors and solar cell efficiency. The trained NN model is also used to optimize the beltline furnace process through genetic algorithms.

SEM Tribosystem에 의한 TiN피막의 미시적 마모형태의 천이 조건 (Transition Condition of Microscopic Wear Mode for TiN Coating by SEM Tribosystem)

  • 문봉호
    • 한국기계가공학회지
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    • 제10권3호
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    • pp.100-107
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    • 2011
  • To evaluate the wear characteristics of very thin ceramic coated layer, it is very important to investigate its wear process in great detail. An effective method for investigating the wear of a thin layer is the observation of wear process in microscopic detail, using in-situ system. In this study, based on the SEM Tribosystem as in-situ system, the microscopic wear mode of TiN coatings was investigated in repeated sliding. Consequently, four modes were revealed for TiN coatings: Ploughing, powder formation, flake formation and coating delimitation. Sc(Severity of contact) can clarify transition condition of those microscopic wear modes.

볼 충격을 받는 유리의 콘크랙형성에 대한 경계조건의 영향 (The Effects of Boundary Condition in Cone Crack Formation of Soda-lime Glass by Ball Impact)

  • 김문생;허진;이현철;김호종
    • 대한기계학회논문집A
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    • 제27권6호
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    • pp.981-986
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    • 2003
  • In order to investigate the possibility of processing of brittle material by ball impact, the effects of boundary conditions about impact damage of soda-lime glass by small spheres were evaluated experimentally. It was investigated that crack appearance developed in soda-lime glass with boundary conditions of without sealing, single-sealing and double-sealing by impact velocity. The double-sealing was most effective in the development of perfect cone than other boundary condition. In case of double-sealing condition, PVC and Polyurethane sealing were more effective in producing a perfect cone formation than other sealing materials. The impact velocity range over which perfect cones were formed was influenced by both the contact area and diameter of impact particle.

Low Temperature Dissociation of SiOx by Gold

  • 이경재;양미현;쿠마르 요게쉬;임규욱;강태희;정석민
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.140.1-140.1
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    • 2013
  • The native silicon-oxide (SiOx) layer at the metal/Silicon interface acts as an electrical resistance to the metal contact of devices. Various methods are proposed for removing this layer, such as sputtering before metal contact formation or high temperature annealing. We studied the chemical evolution of the Au/SiOx/Si system during the annealing at $500^{\circ}C$ using a spatially resolved photoelectron emission method. Scanning photoelectron emission microscopy (SPEM) and core level spectra from local area of the sample show the inhomogeneous oxidation and formation of silicide of Au, as well as valence band spectra reveals the role of Au atoms during the dissociation process of SiOx.

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두 가지 타입의 CuPC FET 전극 구조에서의 전기적 특성 (Electrical Properties of CuPc FET Using Two-type Electrode Structure)

  • 이원재;이호식
    • 한국전기전자재료학회논문지
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    • 제24권12호
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    • pp.988-991
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    • 2011
  • We fabricated a copper phthalocyanine (CuPc) based field-effect transistor with different device structure as a bottom and top contact FET. Also, we used a $SiO_2$ as a gate insulator and analyzed using a current-voltage (I-V) characteristics of the bottom and top contact CuPc FET device. In order to discuss the channel formation, we were observed the capacitance-gate voltage(C-V) characteristics of the bottom and top contact CuPc FET device.