• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.547-552
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• 2003

In mold machining, there are many concave machining regions where chatter and tool deflection occur since MRR (material removal rate) increases as curvature increases even though cutting speed and depth of cut are constant. Boolean operation between stock and tool model is widely used to compute MRR in NC milling simulation. In finish cutting, the side step is reduced to about 0.3mm and tool path length is sometimes over 300m. so Boolean operation takes long computation time and includes much error if the resolution of stock and tool model is larger than the side step. In this paper, curvature of CL(cutter location) surface and side step of tool path is used to compute the feedrate for constant MRR machining. The data structure of CL surface is Z-map generated from NC tool path. The algorithm to get local curvature from discrete data was developed and applied to compute local curvature of CL surface. The side step of tool path was computed by point density map which includes cutter location point density at each grid element. The feedrate computed from curvature and side step is inserted to new tool path to regulate MRR. The resultants wire applied to feedrate optimization system which generates new tool path with feedrate from NC codes for finish cutting. The system was applied to speaker mold machining. The finishing time was reduced to 12.6%. tool wear was reduced from 2mm to 1.1mm and chatter marks and over cut on corner were removed.

• Geotechnical Engineering
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• v.12 no.2
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• pp.85-94
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• 1996

Model pile tests, using a calibration chamber in which the stress state and the relative density can be controlled, were performed in order to study the effects of pile diameter on the plugging rate and bearing capacity of open-ended pile. The model piles used in the test series were devised so that the bearing capacity of an open-ended pile could be measured out into three components. The test results showed that fully plugging depth of an open -ended pile increased with increase in pile diameter and soil density. Moreover, it was found that unit plug capacity decreased with increase in pile diameter, though the penetration ratio or plugging rate of piles was constant. However, the existing formulae for estimation of plug capacity give plug capacity which is constant or increased with increase in pile diameter, when penetration ratio or plugging rate of piles is equal. Thus, it is proposed that the effect of pile diameter as well as plugging rate on bearing capacity of pile must be considered in plug capacity estimation.

• Polymer(Korea)
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• v.26 no.4
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• pp.422-430
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• 2002

The kinetics of polycondensation of bishydroxyethyl naphthalate has been studied in the range of 241 -$260^{\circ}C$ using antimony trioxide catalyst. The reaction was performed in a batch reactor and the concentration of reaction mixture was measured with HPLC. The activation energy values of forward and reverse reaction determined from molecular species model were found to be 19.7 and 31.4 kcal/mole, respectively, and the equilibrium constants were in the range of 1.4-2.0, which were larger than that of polycondensation of PET and varied to some degree with temperature. It was confirmed by applying the Flory's distribution function that the reaction rate of the hyroxyethyl group does not depend on the molecular size. By applying functional group model, we observed that there was few difference between the activation energy of the forward reaction and that of reverse reaction, therefore the equilibrium constant has almost constant value of 1.4. The rate constants obtained from functional group model was about 3-4 times larger than that from molecular species model, which showed that both model explains the reaction system well. Although the molecular species model should predict the concentration of as many as ten molecules, it fits for the experimental results well.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2002.05a
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• pp.104-109
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• 2002

In this paper, a statistical analysis of fatigue crack growth behavior under constant amplitude loads has been carried out. Fatigue crack growth tests were conducted on sixteen pre-cracked compact tension (CT) specimens of the pressure vessel (SPV50) steel in controlled identical load and environmental conditions. The assessment of the statistical distribution of fatigue crack growth experimental data obtained from SPV50 steel was studied and also the correlation of the parameter C and m in the Paris-Erdogan law was discussed. The probability distribution function of fatigue crack growth life seems to follow the 3-parameter Weibull. The fatigue crack growth rate seems to follow the 3-parameter Weibull and the log-normal distribution. The coefficient of variation (COV) of fatigue crack growth life was observed to decrease as the crack grows. A strong negative linear correlation exists between the coefficient C and the exponent m in Paris model. Fatigue crack growth rate data shows a normal distribution for both m and logC.

• Bulletin of the Korean Chemical Society
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• v.31 no.10
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• pp.2877-2883
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• 2010

The folding kinetics of $WT^*$ ubiquitin variant with valine to alanine mutation at sequence position 26 (HubWA) was studied by stopped-flow fluorescence spectroscopy. While unfolding kinetics showed a single exponential phase, refolding reaction showed three exponential phases. The semi-logarithmic plot of urea concentration vs. rate constant for the first phase showed v-shape pattern while the second phase showed v-shape with roll-over effect at low urea concentration. The rate constant and the amplitude of the third phase were constant throughout the urea concentrations, suggesting that this phase represents parallel process due to the configurational isomerization. Interestingly, the first and second phases appeared to be coupled since the amplitude of the second phase increased at the expense of the amplitude of the first phase in increasing urea concentrations. This observation together with the roll-over effect in the second folding phase indicates the presence of intermediate state during the folding reaction of HubWA. Quantitative analysis of Hub-WA folding kinetics indicated that this intermediate state is on the folding pathway. Folding kinetics measurement of a mutant HubWA with hydrophobic core residue mutation, Val to Ala at residue position 17, suggested that the intermediate state has significant amount of native interactions, supporting the interpretation that the intermediate is on the folding pathway. It is considered that HubWA is a useful model protein to study the contribution of residues to protein folding process using folding kinetics measurements in conjunction with protein engineering.

• Tunnel and Underground Space
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• v.13 no.2
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• pp.100-107
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• 2003

Deformation is found by an external force in the rock which has internal stress. So, deformation is increased in time what is stressed under constant load. Rock materials collapse suddenly in a long period when the creep rate increases slightly. So mechanical deformability of the ground is an essential condition for determination of long term safety in structures. The result of analysis in 40%, 50%, 60%, 70% of constant load in creep test, strain velocity constants $\alpha$ and ${\gamma}$ increase with load increasement. Griggs equation is more exact than Li and Xia, Singh equation, and G$_2$of a flow constant by Burger's model decreases with stress increasement, but η$_1$,η$_2$and G$_1$ manifest irregularly in this study.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.32 no.2A
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• pp.195-202
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• 2007

A differential space-frequency block code - orthogonal frequency division multiplexing (SFBC-OFDM) scheme as a multiple-input multiple-output (MIMO) transmission technique for next-generation digital multimedia broadcasting (DMB) is proposed in this paper. A linear decoding method for differential SFBC, which performs comparably to the ML decoding method, is derived for the cases of two or four transmit antennas. A simple table lookup method is proposed to improve the efficiency of the encoding/decoding process of DSFBC for the case of non-constant modulus constellations. A DMB MIMO channel model, developed by extending the 3GPP MIMO model to fit DMB environments, is used to compare BER performances of differential space block code schemes for various channel environments. Simulation results show that the differential SFBC-16QAM scheme using either four transmit antennas with one receive antenna or two transmit antennas with two receive antennas achieves a performance gain of 12dB than that of the conventional DQPSK scheme, even with a data rate twice faster.

• Journal of the Korean Society for Precision Engineering
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• v.15 no.10
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• pp.113-119
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• 1998

Ship structures and aircraft structures are consisted of thin sheet alloy, so it is very important to understand the characteristics of fatigue crack propagation of that material and to establish the data base. The data for fatigue crack propagation behavior scatter very much even under identical experimental conditions with constant loading. The behavior of fatigue crack propagation under regular and irregular cyclic loadings is known to be highly affected by complicated factors such as plastic zone developed at the vicinity of crack tip and reduction of cross sectional area. In this paper, the controlled stress amplitude and overload fatigue crack propagation tests have been conducted to investigate the effect of varying factors such as plastic zone size near the crack tip and area reduction factor (AF) on the fatigue crack propagation behavior A better simulation of fatigue crack propagation behavior is found to be obtainable by using Wheeler and Willenborg models with AF effect.

• Macromolecular Research
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• v.9 no.3
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• pp.164-170
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• 2001

Recently in order to describe the complex rheological behavior of polymer melts with long side branches like low density polyethylene, new constitutive equations called the pom-pom equations have been derived by McLeish and Larson on the basis of the reptation dynamics with simplified branch structure taken into account. In this study mathematical stability analysis under short and high frequency wave disturbances has been performed for the simplified differential version of these constitutive equations. It is proved that they are globally Hadamard stable except for the case of maximum constant backbone stretch (λ = q) with arm withdrawal s$\_$c/ neglected, as long as the orientation tensor remains positive definite or the smooth strain history in the now is previously given. However this model is dissipative unstable, since the steady shear How curves exhibit non-monotonic dependence on shear rate. This type of instability corresponds to the nonlinear instability in simple shear flow under finite amplitude disturbances. Additionally in the flow regime of creep shear flow where the applied constant shear stress exceeds the maximum achievable value in the steady now curves, the constitutive equations will possibly violate the positive definiteness of the orientation tensor and thus become Hadamard unstable.

• Bulletin of the Korean Chemical Society
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• v.19 no.2
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• pp.218-222
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• 1998

Removal of Cd(Ⅱ), Zn(Ⅱ) and Cu(Ⅱ) from aqueous solutions using the adsorption process on magadiite has been investigated. It was found that the removal percentage of metal cations at equilibrium increases with increasing temperature, and follows the order of Cd(Ⅱ) > Cu(Ⅱ) > Zn(Ⅱ). Equilibrium modeling of adsorption showed that the adsorptions of Cd(Ⅱ), Cu(Ⅱ), and Zn(Ⅱ) were fitted to Langmuir isotherm. Kinetic modeling of the adsorption showed that first order reversible kinetic model fitted to experimental data. From kinetic model and equilibrium data, the overall rate constant (k) and the equilibrium constant (K) for the adsorption process were calculated. The overall rates of adsorption of metal ions follow the order of Cd(Ⅱ) > Cu(Ⅱ) > Zn(Ⅱ). From the results of thermodynamic analysis, standard Gibbs free energy (ΔG°), standard enthalpy (ΔH°), and standard entropy (ΔS°) of adsorption process were calculated.