• Title/Summary/Keyword: Constant rate

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과망간산을 이용한 지하수내 TCE 제거효과 평가

  • Yang Seung-Gwan;Go Seok-O
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.53-56
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    • 2005
  • A Laboratory study was conducted to evaluate the kinetics of oxidation of trichloroethylene (TCE) in groundwater by potassium permanganate $(KMnO_4)$, Consumption of permanganate by TCE and aquifer materials was also evaluated to obtain an appropriate injection rate of $KMnO_4$. TCE degradation by $KMnO_4$ in the absence of aquifer material showed effective with pseudo-first order rate constant, $k_{obs}=1.8110^{-3}\;s^{-1}\;at\;KMnO_4=500mg/L$. TCE oxidation by $KMnO_4$ was found to be second order reaction and the rate constant, $k=0.65{\pm}0.08\;M^{-1}s^{-1}$, was independent of pH changes. $KMnO_4$ consumption rate by groundwater sampled from field site was not significant, indicating that groundwater containing negligible amount of dissolved organic matter does not have any influence on the $KMnO_4$ degradation. Meanwhile, aquifer materials from field site were actively reacted with permanganate, resulting in the significant consumption of $KMnO_4$. It might be attributed to the existence of metal oxides in aquifer materials, Based on the rate constants obtained from this study, appropriate injection rate of permanganate and TCE removal rate in groundwater could be estimated.

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Crystallization Behavior and Electrical Properties of BNN Thin Films by IBSD Process

  • Lou, Jun-Hui;Jang, Jae-Hoon;Lee, Hee-Young;Cho, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.960-964
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    • 2004
  • [ $Ba_2NaNb_5O_{15}$ ](BNN) thin films have been prepared by the ion beam sputter deposition (IBSD) method on Pt coated Si substrate at temperature as low as $600^{\circ}C$ XRD, SEM were used to investigate the crystallization and microstructure of the films. It was found that the films were crack-free and uniform in microstructure. The electric properties of thin films were carried out by observation of D-E hysteresis loop, dielectric constant and leakage current. It was found the deposition rate strongly influenced the phase formation of the films, where the phase of $BaNb_2O_6$ was always formed when the deposition rate was high. However, the single phase (tungsten bronze structure ) BNN thin film was obtained with the deposition rate as low as $22{\AA}/min$. The remanent polarization Pr and dielectric constant are about 1-2 ${\mu}C/cm^2$ and $100\sim200$, respectively. It was also founded the electric properties of thin films were influenced by the deposition rate. The Pr and dielectric constant of films increased with the decrease of deposition rate. The effects of annealing temperature and annealing time to the crystallization behavior of films were studied. The crystallization of thin film started at about $600^{\circ}C$. The adequate crystallization was gotten at the temperature of $650^{\circ}C$ when the annealing time is 0.5 hour or at the temperature of $600^{\circ}C$ when the annealing time is long as 6 hours.

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Study on the Single Bubble Growth During Nucleate Boiling at Saturated Pool (포화상태 풀비등시 단일기포의 성장에 관한 연구)

  • Kim Jeongbae;Lee Han Choon;Oh Byung Do;Kim Moo Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.2 s.233
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    • pp.169-179
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    • 2005
  • Nucleate boiling experiments on heating surface of constant wall temperature were performed using R113 for almost saturated pool boiling conditions. A microscale heater array and Wheatstone bridge circuits were used to maintain a constant wall temperature condition of heating surface and to measure the heat flow rate with high temporal and spatial resolutions. Bubble images during the bubble growth were taken as 5000 frames per second using a high-speed CCD camera synchronized with the heat flow rate measurements. The bubble growth behavior was analyzed using the new dimensionless parameters for each growth regions to permit comparisons with previous experimental results at the same scale. We found that the new dimensionless parameters can describe the whole growth region as initial and later (thermal) respectively. The comparisons showed good agreement in the initial and thermal growth regions. In the initial growth region including surface tension controlled, transition and inertia controlled regions as divided by Robinson and Judd, the bubble growth rate showed that the bubble radius was proportional to $t^{2/3}$ regardless of working fluids and heating conditions. And in the thermal growth region as also called asymptotic region, the bubble showed a growth rate that was proportional to $t^{1/5}$, also. Those growth rates were slower than the growth rates proposed in previous analytical analyses. The required heat flow rate for the volume change of the observed bubble was estimated to be larger than the heat flow rate measured at the wall. Heat, which is different from the instantaneous heat supplied through the heating wall, can be estimated as being transferred through the interface between bubble and liquid even with saturated pool condition. This phenomenon under a saturated pool condition needs to be analyzed and the data from this study can supply the good experimental data with the precise boundary condition (constant wall temperature).

Effects of Salinity, Temperature and Food Type on the Uptake and Elimination Rates of Cd, Cr, and Zn in the Asiatic Clam Corbicula fluminea

  • Lee, Jung-Suk;Lee, Byeong-Gweon
    • Ocean Science Journal
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    • v.40 no.2
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    • pp.79-89
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    • 2005
  • Laboratory radiotracer experiments were conducted to determine assimilation efficiencies (AE) from ingested algal food and oxic sediment particles, uptake rates from the dissolved phase, and the efflux rates of Cd, Cr and Zn in the Asiatic clam Corbicula fluminea. Among three elements, AE from both algal and sediment food was greatest for Cd, followed by Zn and Cr. The AEs of tested elements from algal food (Phaeodactylum tricornutum) were consistently higher than those from sediments at a given salinity and temperature. The influence of salinity (0, 4 and 8 psu) and temperature (5, 13 and $21^{\circ}C$) on the metal AEs was not evident for most tested elements, except Cd AEs from sediment. The rate constant of metal uptake from the dissolved phase $(k_u)$ was greatest for Cd, followed by Zn and Cr in freshwater media. However, in saline water, the $(k_u)$ of Zn were greater than those of Cd. The influx rate of all tested metals increased with temperature. The efflux rate constant was greatest for Cr $(0.02\;d^{-1})$, followed by Zn $(0.010{\sim}0.017\;d^{-1})$ and $Cd\;(0.006\;d^{-1})$. The efflux rate constant for Zn in clam tissues depurated in 0 psu $(0.017\;d^{-1})$ was faster than that in 8 psu $(0.010\;d^{-1})$. Overall results showed that the variation of salinity and temperature in estuarine systems can considerably influence the metal bioaccumulation potential in the estuarine clam C. fluminea. The relatively high Cd accumulation capacity of C. fluminea characterized by the high AE, high dissolved influx rate and low efflux rate, suggested that this clam species can be used as an efficient biomonitor for the Cd contamination in freshwater and estuarine environments.

Time Constant Control Method for Hopfield Neural Network based Multiuser Detector of Multi-Rate CDMA system (시정수 제어 기법이 적용된 Multi-Rate CDMA 시스템을 위한 Hopfield 신경망 기반 다중 사용자 검출기)

  • 김홍열;장병관;전재춘;황인관
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.28 no.6A
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    • pp.379-385
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    • 2003
  • In this paper, we propose a time constant control method for sieving local minimum problem of the multiuser detector using Hopfield neural network for synchronous multi-rate code division multiple access(CDMA) system in selective fading environments and its performance is compared with that of the parallel interference cancellation(PIC). We also assume that short scrambling codes of 256 chip length are used an uplink, suggest a simple correlation estimation algorithm and circuit complexity reduction method by using cyclostationarity property of short scrambling code.It is verified that multiuser detector using Hopfield neural network more efficiently cancels multiple access interference(MAI) and obtain better bit error rate and near-far resistant than conventional detector.

Dynamic Characteristics of Pintle Nozzle about Changes of Chamber Boundary Condition (연소실 경계조건 변화에 따른 핀틀 노즐의 동특성 연구)

  • Jeong, Kiyeon;Kang, Dong-Gi;Lee, Daeyeon;Choi, Jaesung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.5
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    • pp.22-31
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    • 2018
  • In this study, numerical simulations were performed to determine the dynamic characteristics of a pintle nozzle, with changes to the chamber boundary conditions. To apply movement, to the pintle, the nozzle and pintle were created separately by an auto-grid generation program using an overset grid method. The chamber boundary conditions were selected between a constant mass-flow rate condition and a propellant burn-back condition. The pressure and thrust characteristics of the constant mass-flow rate condition were determined by changing the ratio of the mass-flow rate in the inlet. The propellant burn-back condition was considered by formulation of the combustion rate. The burn-back conditions represented nonlinear phenomena, unlike the constant mass flow rate, and a small flow rate resulted in a large change in the chamber pressure.

A Case Study on Learning of Fundamental Idea of Calculus in Constant Acceleration Movement (등가속도 운동에서 미적분의 기본 아이디어 학습 과정에 관한 사례연구)

  • Shin Eun-Ju
    • Journal of Educational Research in Mathematics
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    • v.16 no.1
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    • pp.59-78
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    • 2006
  • As a theoretical background for this research, the literatures which focus on the rationale of teaching and learning of connecting with mathematics and science in calculus were investigated. And teaching and learning material of connecting with mathematics and science in calculus was developed. And then, based on the case study using this material, the research questions were analyzed in depth. Students could understand mean-velocity, instant-velocity, and acceleration in the experimenting process of constant acceleration movement. Also Students could understand fundamental ideas that instant-velocity means slope of the tangent line at one point on the time-displacement graph and rate of distance change means rate of area change under a time-velocity graph.

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EFFECTS OF WATERY VAPOR CONCENTRATION ON DROPLET EVAPORATION IN HOT ENVIRONMENT

  • Lee, M.J.;Kim, Y.W.;Ha, J.Y.;Chung, S.S.
    • International Journal of Automotive Technology
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    • v.2 no.3
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    • pp.109-115
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    • 2001
  • A study has been conducted to clarify the effect of watery vapor concentration in hot ambient on droplet evaporation. Droplets of water, ethanol, n-hexadecaneand n-heptane were used in this experimental study. Ambient conditions are fixed at 470 K in temperature, 0.1 MPa in pressure and 2 m/s in velocity of ambient air. Watery vapor concentration was changed 0%~40% by 10% by add water to air. To obtain the time histories of droplet diameter after exposed in ambient, a suspended droplet in hot and humid ambient stream was synchronized with a back flash light, and enlarged droplet images were taken by a CCD camera. The evaporation rate constant of water droplet decreases slightly with the vapor concentration because diffusion velocity reduction of droplet vapor occurs on the surface. The values of ethanol and n-heptane droplet actively increase by effect that water from condensation of vapor flows into the droplet. The evaporation rate constant of n-hexadecane which has higher boiling point than water increases within around 30% of the concentration.

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Phosphate removal efficiency and the removal rate constant by particle sizes of converter slag and conditions of the wastewater (전로슬래그의 입도 크기 및 폐수의 조건 변화에 따른 인산염 제거효율과 제거 속도상수에 관한 연구)

  • Lee, Sang Ho;Hwang, Jeong Jae
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.6
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    • pp.841-849
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    • 2012
  • The effluent quality of phosphorus is strengthened by the national standard to conserve water resources to lessen the eutrophication threat. The soluble phosphate in the wastewater effluent can be removed using the converter slag as solid waste produced through the steel making process. The experiments for removal efficiencies and removal constants were performed for this research with the artificial wastewater following several different conditions, particle size, phosphate concentration and initial pH. The correlation coefficients of Freundlich adsorption isothem were 0.9505 for $PS_A$, 0.9183 for $PS_B$, respectively. The removal efficiency was 87-94 % for $PS_A$ and 90-96 % for $PS_B$ respectively. The pH of the wastewater was elevated to pH 11.8 for the initial pH 8.5, phosphate removal efficiency was the highest as 84 % ~ 98 %. In case of 10 mg/L of the intial phosphate, the removal efficiency was 96 ~ 98 %. The more initial pH increases, the higher the reaction rate constant is.

Experimental Study on the Thermal Storage Efficiency Through Variable Porous Mainfolds in a Test Storage Tank (실험 저장조내의 유입구 형상변화에 따른 열 저장효율에 관한 실험적 연구)

  • Pak, Ee-Tong;Hwang, Sung-Il;Choi, Young-Il
    • Solar Energy
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    • v.9 no.3
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    • pp.37-43
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    • 1989
  • This paper dealt with thermal storage efficiency due to difference ($T_{\infty}-Ti$) between the mean temperature of water in the storage tank [$0.5m{\times}0.5m{\times}1.0m$] and the temperature of water flowing into the tank, flow rate of water flowing into the tank and shape of porous manifold which water flow into the tank through. As results of experiments; (1) When the flow rate was constant and the diameter of porous section decreased by 8mm, 6mm, and 4mm, the thermal storage efficiency increased. (2) When the diameter of porous section was constant and the difference ($T_{\infty}-Ti$) between the mean temperature of water in the storage tank and the temperature of water flowing into the tank increased by -30, -20, -10, 5, 10, 15 ($^{\circ}C$), the thermal storage efficiency increased. (3) When the($T_{\infty}-Ti$) was constant and the flow rate decreased by 0.8, 0.4, 0.25(LPM), the thermal storage efficiency increased. (4) When the shape of porous section was rigid, the thermal storage efficiency was the most effective, and with establishing flexible porous section or mesh, the effective thermal storage efficiency was obtained.

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