• Title/Summary/Keyword: Constant potential

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ROOT CHILLING DORMANCY REQUIREMENTS FOR AMERICAN GINSENG (PANAX QUINQUEFOLIUM L) (미국 인삼근의 저온 휴면 요구도)

  • Konsler T.R.
    • Proceedings of the Ginseng society Conference
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    • 1984.09a
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    • pp.49-55
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    • 1984
  • Dormant one-year-old ginseng roots were subjected to a range of stratification temperatures and time to define effective limits to these parameters and to quantify their effect on terminating dormancy. Effective storage temperatures tested ranged from $0^{\circ}C\;to\;9^{\circ}C.$ A low percentage of roots produced tops with as few as 30 days in stratification; however, 75 to 90 days were required for 100 percent emergence. Days to emergence, after planting, decreased with increased days in storage thru the maximum storage time of 120 days. The number of days of dormancy was relatively constant, near 126.5 days, over the range of effective temperatures and acceptable storage times. The minimum period of dormancy was associated with 75 days in storage at $3^{\circ}C.$ Root growth rate, after emergence, was greatest following 105 days of stratification. The frequency distribution of emergence with days in stratification suggests the potential of selecting for strains of ginseng with low chilling needs for satisfying dormancy requirements.

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a-Si:H Photodiode Using Alumina Thin Film Barrier

  • Hur Chang-Wu;Dimitrijev Sima
    • Journal of information and communication convergence engineering
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    • v.3 no.4
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    • pp.179-183
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    • 2005
  • A photodiode capable of obtaining a sufficient photo/ dark current ratio at both forward bias state and reverse bias state is proposed. The photodiode includes a glass substrate, an aluminum film formed as a lower electrode over the glass substrate, an alumina film formed as an insulator barrier over the aluminum film, a hydrogenated amorphous silicon film formed as a photo conduction layer over a portion of the alumina film, and a transparent conduction film formed as an upper electrode over the hydro-generated amorphous silicon film. A good quality alumina $(Al_2O_3)$ film is formed by oxidation of aluminum film using electrolyte solution of succinic acid. Alumina is used as a potential barrier between amorphous silicon and aluminum. It controls dark-current restriction. In case of photodiodes made by changing the formation condition of alumina, we can obtain a stable dark current $(\~10^{-12}A)$ in alumina thickness below $1000{\AA}$. At the reverse bias state of the negative voltage in ITO (Indium Tin Oxide), the photo current has substantially constant value of $5{\times}10^{-9}$ A at light scan of 100 1x. On the other hand, the photo/dark current ratios become higher at smaller thicknesses of the alumina film. Therefore, the alumina film is used as a thin insulator barrier, which is distinct from the conventional concept of forming the insulator barrier layer near the transparent conduction film. Also, the structure with the insulator thin barrier layer formed near the lower electrode, opposed to the ITO film, solves the interface problem of the ITO film because it provides an improved photo current/dark current ratio.

Removal of Heavy Metal Ions by Electrocoagulation for Continuous Use of Fe2+/Fe3+-Mediated Electrochemical Oxidation Solutions

  • Jung, Youn-Su;Pyo, Myoung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.29 no.5
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    • pp.974-978
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    • 2008
  • Removal of heavy metal ions ($Cd^{2+}$ and $Zn^{2+}$) by electrocoagulation (ECG) was investigated in an acidic condition, which is necessary for re-using or discharging the mediated electrochemical oxidation (MEO) media. Effects of various parameters such as electrolytes, current densities, and electrode materials were examined for a metal-contaminated MEO system using $Fe^{2+}/Fe^{3+}$ pairs as a mediator. It was found that ECG with Al electrodes is greatly affected by the presence of $Fe^{2+}$. [$Cd^{2+}$] and [$Zn^{2+}$] remain constant until [$Fe^{2+}$] reaches a certain concentration level (ca. 10 mM). This preferential removal of $Fe^{2+}$ during ECG with Al electrodes is not alleviated by controlling current densities, potential programs, and solution mixing. ECG with Fe electrodes, on the other hand, resulted in relatively fast removal of $Cd^{2+}$ and $Zn^{2+}$ under coexistence of $Fe^{2+}$, indicative of the different role between $Fe^{n+}$ generated from an electrode and $Fe^{2+}$ initially present in a solution. When ECG was performed with Fe electrodes until [$Fe^{n+}$] became the same as the concentration of initially present $Fe^{2+}$, [$Cd^{2+}$] and [$Zn^{2+}$] were reduced to one-tenth of the initial concentrations, suggesting the possibility of a continuous use of the medium for a subsequent MEO process.

Determination of the pH of Iso-Selectivity of the Interfacial Diffusion Layer of Fe

  • Ha, Heon Young;Kwon, Hyuk Sang
    • Corrosion Science and Technology
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    • v.7 no.1
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    • pp.40-44
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    • 2008
  • Passive metal forms an interfacial diffuse layer on the surface of passive film by its reaction with $H^+$ or $OH^-$ ions in solution depending on solution pH. There is a critical pH, called pH point of iso-selectivity ($pH_{pis}$) at which the nature of the diffuse layer is changed from the anion-permeable at pH<$pH_{pis}$ to the cation-permeable at pH>$pH_{pis}$. The $pH_{pis}$ for a passivated Fe was determined by examining the effects of pH on the thickness of passive film and on the dissolution reaction occurring on the passive film under a gavanostatic reduction in borate-phosphate buffer solutions at various pH of 7~11. The steady-state thickness of passive film formed on Fe showed the maximum at pH 8.5~9, and further the nature of film dissolution reaction was changed from a reaction producing $Fe^{3+}$ ion at $pH\leq8.5$ to that producing $FeO_2{^-}$ at $pH\geq9$, suggesting that the $pH_{pis}$ of Fe is about pH 8.5~9. In addition, the passive film formed at pH 8.5~9, $pH_{pis}$, was found to be the most protective with the lowest defect density as confirmed by the Mott-Schottky analysis. Pitting potential was decreased with increasing $Cl^-$ concentration at $pH\leq8.5$ due probably to the formation of anion permeable diffuse layer, but it was almost constant at $pH\geq9$ irrespective of $Cl^-$ concentration due primarily to the formation of cation permeable diffuse layer on the film, confirming again that $pH_{pis}$ of Fe is 8.5~9.

Development of Polymeric Human Jelly Phantom for Hyper-Thermic Therapy by High Frequency Magnetic Field (고주파 자기장을 이용한 온열요법 치료용의 젤리형 고분자 모의인체)

  • Choi, Chang-Young;Kim, Byung-Hun;Hwang, Young-Jun;Kim, Oh-Young
    • Polymer(Korea)
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    • v.32 no.1
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    • pp.90-93
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    • 2008
  • We developed a variety of polymeric jelly phantoms that can be used in hyperthermia using an electromagnetic wave as an auxiliary cancer therapy. Particularly, using an appropriate material composed of polyethylene, deionized water, and sodium chloride, jelly phantoms for brain was prepared. Also, their electrical properties were characterized by measuring the dielectric constant and conductivity. As the results, overall electrical values of the phantoms decreased with increasing the amount of the components of the materials, excepted for sodium chloride. Additionally, storage characteristics of the phantoms showed a sustainable stability up to 6 months. Based on the experimental results, it can be proposed that jelly phantoms containing a ferro-magnetic particle could be a potential material for cancer therapy following the further study on the temperature elevation effect and the evaluation of electromagnetic properties of the materials.

Low-temperature crystallization of high-dielectric (Ba,Sr)$TiO_3$ thin films for embedded capacitors

  • Cho, Kwang-Hwan;Kang, Min-Gyu;Kang, Chong-Yun;Yoon, Seok-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.03a
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    • pp.21-21
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    • 2010
  • (Ba,Sr)$TiO_3$ (BST) thin film with a perovskite structure has potential for the practical application in various functional devices such as nonvolatile-memory components, capacitor, gate insulator of thin-film transistors, and electro-optic devices for display. Normally, the BST thin films derived from sol-gel and sputtering are amorphous or partially crystalline when processed below $600^{\circ}C$. For the purpose of integrating BST thin film directly into a Si-based read-out integrated circuit (ROIC), it is necessary to process the BST film below $400^{\circ}C$. The microstructural and electrical properties of low-temperature crystallized BST film were studied. The BST thin films have been fabricated at $350^{\circ}C$ by UV-assisted rapidly thermal annealing (RTA). The BST films are in a single perovskite phase and have well-defined electrical properties such as high dielectric constant, low dielectric loss, low leakage current density, and high breakdown voltage. Photoexcitation of the organics contained in the sol-gel-derived films by high-intensity UV irradiation facilitates elimination of the organics and formation of the single-crystalline phase films at low temperatures. The amorphous BST thin film was transformed to a highly (h00)-oriented perovskite structure by high oxygen pressure processing (HOPP) at as low as $350^{\circ}C$. The dielectric properties of BST film were comparable to (or even better than) those of the conventionally processed BST films prepared by sputtering or post-annealing at temperature above $600^{\circ}C$. When external pressure was applied to the well-known contractive BST system during annealing, the nucleation energy barrier was reduced; correspondingly, the crystallization temperature decreased. The UV-assisted RTA and HOPP, as compatible with existing MOS technology, let the BST films be integrated into radio-frequency circuit and mixed-signal integrated circuit below the critical temperature of $400^{\circ}C$.

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Depositing Rate of Electroless Nickel Plating Bath Contained Triethanolamine as a Complexing Agent (트리에탄올아민을 錯化劑로 사용한 無電解니켈鍍金浴의 析出速度에 관한 硏究)

  • Yeo, Woon-Kwan
    • Journal of Surface Science and Engineering
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    • v.18 no.4
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    • pp.153-163
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    • 1985
  • In the electroless nickel plating bath which contained nickel sulfate, sodium hypophosphite, boric acid and triethanolamine, effect of their concentration on the rate of deposition was tested by gravimetric method and polarization method. The polarization method that polarize small range of voltage anodicaly and cathodicaly at the mixed potential in the electroless plating bath can calculate mixed current (depositing rate) from $i_{mp}=\frac {i}{\eta}\;\frac{RT}{nF}\;or\;i_{mp}=\frac{i}{\eta}\;\frac{1}{2.3}(\frac{b_a\;\;b_c}{b_c+b_a})$ Where $i_{mp}$ is the depositing current, i is the polarized current, ${\eta}$ is the polarized voltage, $b_a\;and\;b_c$ are the Tafel slop of anodic and cathodic polarization curves respectively. The calculated mixed current ($i_{mp}$) is proportional to the depositing rate obtained by gravimetric method and corresponded mostly to the real depositing rate by multifying supplementary constant. The polarization method can be used for founding inclination of reaction on various concentration of each composition. Decreasing or increasing concentration of triethanolaminc as a complexing agent , the depositing rate is decreased and when the bath contained 25-50mL/L of triethanoloamine, the depositing rate is increased. The depositing rate is increased with increasing the concentration of boric acid, and when the bath contained 0.5M of boric acid, the depositing rate is increased abruptly. The optimum composition of the electroless nickel bath was estimated 0.1M of nickel sulfate, 0.25M of sodium hypophosphite, 0.5M of boric acid, and 25-50mL/L of triethanalamine.

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Optimal Design of Process-Inventory Network under Cycle Time and Batch Quantity Uncertainties (이중 불확실성하의 공정-저장조 망구조 최적설계)

  • Suh, Kuen-Hack;Yi, Gyeong-Beom
    • Journal of Institute of Control, Robotics and Systems
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    • v.16 no.3
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    • pp.305-312
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    • 2010
  • The aim of this study is to find an analytic solution to the problem of determining the optimal capacity of a batch-storage network to meet demand for finished products in a system undergoing joint random variations of operating time and batch material loss. The superstructure of the plant considered here consists of a network of serially and/or parallel interlinked batch processes and storage units. The production processes transform a set of feedstock materials into another set of products with constant conversion factors. The final product demand flow is susceptible to joint random variations in the cycle time and batch size. The production processes have also joint random variations in cycle time and product quantity. The spoiled materials are treated through regeneration or waste disposal processes. The objective function of the optimization is minimizing the total cost, which is composed of setup and inventory holding costs as well as the capital costs of constructing processes and storage units. A novel production and inventory analysis the PSW (Periodic Square Wave) model, provides a judicious graphical method to find the upper and lower bounds of random flows. The advantage of this model is that it provides a set of simple analytic solutions while also maintaining a realistic description of the random material flows between processes and storage units; as a consequence of these analytic solutions, the computation burden is significantly reduced. The proposed method has the potential to rapidly provide very useful data on which to base investment decisions during the early plant design stage. It should be of particular use when these decisions must be made in a highly uncertain business environment.

Effects of Operating Parameters on Ozone Production by Plasma Gun for Ballast Water Treatment (밸러스트 수 처리를 위한 Plasma Gun의 오존생성에 미치는 운전변수의 영향)

  • Lee, Hyeon-Don;Kim, Jong-Oh;Chung, Jae-Woo
    • Journal of Navigation and Port Research
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    • v.34 no.3
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    • pp.205-211
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    • 2010
  • Effects of operating parameters on electrical properties and ozone generation of Plasma Gun for ballast water treatment were investigated in a laboratory scale experiment. Electrical discharges and ozone generation initiated with applying voltages higher than discharge onset value. Ozone concentration was almost linearly increased with the increase of applied voltage. The optimum electrode gap distance which gave the optimum energy efficiency of ozone generation was 1.95 mm in the experimented apparatus. The effect of inner electrode material on the electrical energy transfer was negligible, however, the difference of electrical and thermal conductivities between electrode materials significantly influenced the ozone generation. In a constant geometrical structure, the electrical energy density played an important role in the ozone generation. The increase of oxygen content in the feeding gas enhanced the ozone generation by lowering ionization potential and promoting ozone source.

Three-Dimensional Vibration Analysis of Thick Shells of Revolution (두꺼운 축대칭 회전쉘의 3차원적 진동해석)

  • 강재훈;양근혁;장경호
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.15 no.3
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    • pp.399-407
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    • 2002
  • A three-dimensional method of analysis is presented for determining the free vibration frequencies and mode shapes of hollow bodies of revolution (i.e., thick shells), not limited to straight line generators or constant thickness. The middle surface of the shell may have arbitrary curvatures, and the wall thickness may vary arbitrarily. Displacement components$U_\Phi, U_z, U_\theta$ in the meridional, normal and circumferential directions, respectively, are taken to be sinusoidal in time, periodic in$\theta$, and algebraic polynomials in the$\Phi$and z directions. Potential(strain) and kinetic energies of the entire body are formulated, and upper bound values of the frequencies are obtained by minimizing the frequencies. As the degrees of the polynomials are increased, frequencies converge to the exact values. Novel numerical results are presented for two types of thick conical shells and thick spherical shell segments having linear thickness variations. Convergence to four digit exactitude is demonstrated for the first five frequencies of both types of shells. The method is applicable to thin shells, as well as thick and very thick ones.