• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2719-2723
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• 2012

A kinetic study is reported for nucleophilic substitution reactions of benzyl 4-pyridyl carbonate 6 with a series of alicyclic secondary amines in MeCN. The plot of pseudo-first-order rate constant ($k_{obsd}$) vs. [amine] curves upward, which is typical for reactions reported previously to proceed through a stepwise mechanism with two intermediates (i.e., a zwitterionic tetrahedral intermediate $T^{\pm}$ and its deprotonated form $T^-$). Dissection of $k_{obsd}$ into the second- and third-order rate constants (i.e., $Kk_2$ and $Kk_3$, respectively) reveals that $Kk_3$ is significantly larger than $Kk_2$, indicating that the reactions proceed mainly through the deprotonation pathway (i.e., the $k_3$ process) in a high [amine] region. This contrasts to the recent report that the corresponding aminolysis of benzyl 2-pyridyl carbonate 5 proceeds through a forced concerted mechanism. An intramolecular H-bonding interaction was suggested to force the reactions of 5 to proceed through a concerted mechanism, since it could accelerate the rate of leaving-group expulsion (i.e., an increase in $k_2$). However, such H-bonding interaction, which could increase $k_2$, is structurally impossible for the reactions of 6. Thus, presence or absence of an intramolecular H-bonding interaction has been suggested to be responsible for the contrasting reaction mechanisms (i.e., a forced concerted mechanism for the reaction of 5 vs. a stepwise mechanism with $T^{\pm}$ and $T^-$ as intermediates for that of 6).

• 대한치과교정학회지
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• 제14권2호
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• pp.187-202
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• 1984

There are evidences that exogenous electric currents are capable of enhancing bone formation and resolution, and that the conversion of the bioelectric response to biochemical activity provides the directional component of orthodontic tooth movement. In addition, evidence has implicated cyclic nucleotides in alveolar bone cellular activation mechanism during orthodontic tooth movement. In view of these evidences, this study was performed to investigate the effects of exogenous electric currents on cyclic nuclotide levels in feline alveolar bone and the possible clinical application of electric currents as an additional orthodontic tool. In the first study, three groups of three adult cats were subjected to application of a constant direct current of $10{\pm}2$ microamperes to gingival tissue near maxillary canine noninvasively for 1, 3, and 7 days respectively. In the second study, three groups of three adult cats each were treated by an electric-orthodontic procedure for 1, 3, and 7 days respectively. The left maxillary (control) canine received an orthodontic force of 80gm alone at time of initiation, while the right maxillary (experimental) canine received combined force-electric stimulation (80gm of force and $10{\pm}2$ microamperes of a constant D.C. currents). Alveola, bone samples were obtain from the mesial (tension and/or cathode) and the distal (compression and/or anode) sites surrounding maxillary canines as well as from contralateral control sites. The samples were extracted, boiled, homogenized, and the supernatants were assayed for cyclic nucleotides (cAMP, cGMP) by a radioimmunoassay method. And also the amount of tooth movement was measured in the second study. On the basis of this study, the following conclusions can be drawn: 1. The fluctuation pattern of cyclic nucleotide levels in alveolar bone treated by exogenous electric currents was similar to that treated by orthodontic force. 2. The cAMP levels in alveolar bone of electrically treated teeth significantly elevated above the control values. And of electrically treated teeth, the values of the anode sites were higher than those of the cathode sites. 9. The cGMP levels in alveolar bone of electrically treated teeth elevated above the control values at the initiation phase of treatment, but dropped below the control values at time of termination. And of electrically treated teeth, the values of the cathode sites were higher than those of the anode sites. 4. The rate of tooth movement in teeth . treated by force-electric combination increased with the length of treatment as compared to that treated by mechanical force alone.

• 콘크리트학회논문집
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• 제17권4호
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• pp.513-520
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• 2005

현재 유럽 및 일본의 경우 기둥 및 보 부재에 대한 전단 설계에 있어, 전단기구로서 전단보강근과 주철근의 부착작용을 필요로 하지 않는 아치기구와 전단보강근과 주근의 부착 작용을 필요로 하는 트러스기구를 고려하여, 양자의 합으로 전단내력을 평가하는 방식을 취하고 있다. 이러한 설계 방법은 매우 명료하고, 또한 힘의 평형 조건에 기초하여, 단적으로 부착의 좋고 나쁨 및 전단보강근 양의 대소로 정해지는 상한 값으로 전단 내력을 평가하는 것이 특징이다. 본 연구에서는, 역대칭 휨 모멘트를 받는 철근콘크리트 보 부재에서 단부의 텐션쉬프트 영역 사이를 대상으로 한 주철근의 축 방향 응력(압축, 인장) 및 주근의 직경, 부착길이의 상이함에 기인하는 부착거동의 차이와 트러스 기구와의 관계를 명확히 하는 것을 목적으로, 트러스기구만이 재현 가능한 모델 실험법을 제안하고, 전단보강근의 양, 부재의 축압축 응력의 크기 및 부착 영역 양단의 주철근에 가하는 힘의 크기를 실험 변수로 한 부재 실험을 실시하였다. 실험에서 얻은 결과에 기초하여, 양단부 주철근에 가한 힘의 차이로 인해 발생하는 부착응력 분포의 차이를 고려한 일정 트러스 기구와 부채형 트러스기구를 중첩한 복합 트러스 모델을 제안하였다.

• 한국군사과학기술학회지
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• 제23권5호
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• pp.444-451
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• 2020

This study was conducted to develop the hydraulic brake assembly for MUAV(Medium-altitude Unmanned Aerial Vehicle). The brake assembly has the self-gap adjuster which performs to maintain a constant gap between the piston and the disk, even if the friction pad wore down. The function of adjuster helps to keep the brake-reaction speed constant and prevent the unnecessary abrasion of the wear pad during the life of the brake assembly. The development of the aircraft hydraulic brake assembly with the self-gap-adjuster in this paper is the first ever in South Korea. The concept of the mechanism was defined and the formula which is necessary to calculate the friction force was set up in the paper. The tester was invented for the functional test and the proper operation of the self-gap-adjuster was confirmed through the test. Dynamo tests and flight tests were also carried out to verify the braking performance of the brake assembly.

• 한국안전학회지
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• 제24권5호
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• pp.1-5
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• 2009

NiTiCu alloys can produce a large force per unit volume and operate with a simple mechanism. For this reasons, it has been widely studied for application as a micro actuator. So in this study, one-way and two way shape memory effects of Ti-42.5at%Ni-2.0at%Cu alloys are studied. In the case of one-way shape memory effects, shape memory recoverable stress and strain of this alloys were measured by means of tension and compression tests under constant temperature. The strains by tension and compression stress were perfectly recovered by heating at any testing conditions also shape memory recoverable stress increased to 116 MPa in tension tests and to 260 MPa in compression tests. In the case of two-way shape memory effects, transformation temperatures from thermal cycling under constant uniaxial applied tension and compression loads linearly increased by increasing external loads and their maximum recoverable strain is 3.8% at 100MPa tensile condition and 2.2% at 125 MPa compression condition.

• 한국지반공학회논문집
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• 제23권10호
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• pp.57-64
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• 2007

현재 불포화토에 대한 많은 연구가 진행되어 왔고 최근 들어 많은 연구자들이 불포화지반의 안정성을 보다 합리적으로 판단하고 해석하기 위해 불포화상태를 고려한 연구의 필요성을 제기하여 왔다. 이를 위해서는 흡인력에 대한 전단강도의 증진효과를 정량화하고 이를 안정해석에 적용하는 것이 요구되고 있는 실정이다. 따라서 본 연구에서는 불포화 사질토의 전단강도 특성을 규명하기 일해서 국내에 널리 분포하는 화강풍화토 7가지를 대상으로 불포화 삼축압축시험을 수행하였으며, 결과치를 분석하여 강도특성을 규명하고자 한다.

• 대한기계학회논문집A
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• 제21권7호
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• pp.1058-1072
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• 1997

A head-neck complex dummy, for measuring brain pressure and reaction force in the cervical spine was developed for experimental study related in injury mechanism. Dummy comprised aluminium-casted head with water filled cavity for simulating brain and mechanical neck assembled with six motion segments. Several kinds of experiments (compression, bending, cyclic modulus, relaxation and constant velocity profile) for the developed mechanical neck showed that this neck model is biomechanically reliable compared with in-vitro test results. As an application of developed head-neck complex dummy, shock absorbing properties of protective helmet was chosen. The experiments showed that the maximum pressure increment of brain after impact was tolerable compared with the guide line for mild brain injury pressure (25psi). Constrast to this results, the reaction force in the neck was high enough to produce failure in the cervical spine.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.816-821
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• 2005

The cycloid reducer has very high efficiency, high ratios, high stiffness and small size, in comparison with a conventional gear mechanism, which makes it an attractive candidate for limited space and precision application such as industrial robot. There are several publications on analysis and design of the cycloid reducer, however, it was assumed that the contact stiffness of pin rollers and cycloid disk is constant regardless of their contact geometry. Moreover, the torsional stiffness of the cycloid reducer couldn't be calculated due to the assumption. In this paper, we present a new procedure of calculating torsional stiffness of the cycloid reducer using Hertz contact theory. First, conventional force analysis of the cycloid reducer is briefly reviewed. Then, iterative numerical calculation procedure of the contact stiffness is proposed based on the Hertz contact theory where the contact stiffness depends on the contact force. In addition, total torsional stiffness of the cycloid reducer is estimated considering its rolling element bearing stiffness. The torsional stiffness of the cycloid reducer is dominated by the rolling element bearing stiffness since the contact stiffness of the cycloid disk is too large.

• 대한기계학회논문집
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• 제13권4호
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• pp.708-716
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• 1989

본 연구의 목적은 고속도 카메라로 촬영된 순간사진들로부터 액주면의 파장, 진폭, 파의 진행속도 및 교란의 성장속도 등을 측정하여 액주의 분열에 미치는 기류 및 액량의 효과를 구하였고, 또 이것을 선행 연구자들의 이론 및 실험과 비교분석하여 액주의 분열 기구를 밝히는 데 있다.

• 대한기계학회논문집A
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• 제22권4호
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• pp.868-878
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• 1998

There are recently increasing needs for precision XYZ-stage in the fields of nanotechnology, specially in AFMs(Atomic Force Microscope) and STMs(Scanning Tunneling Microscope). Force measurements are made in the AFM by monitoring the deflection of a flexible element (usually a cantilever) in response to the interaction force between the probe tip and the sample and controlling the force neasyred constant topography can be obtained. The power of the STM is based on the strong distance dependence of the tunneling current in the vacuum chamber and the current is a feedback for the tip to trace the surface topography. Therefore, it is required for XYZ-stage to position samples with nanometer resolution, without any crosscouples and any parasitic motion and with fast response. Nanometer resolution is essential to investigate topography with reasonable shape. No crosscouples and parasitic motion is essential to investigate topography without any shape distortion. Fast response is essential to investigate topography without any undesirable interaction between the probe tip and sample surface ; sample scratch. To satisfy these requirements, this paper presents a novel XYZ-stage concept, it is actuated by PZT and has a monolithic flexible body that is made symmetric as possible to guide the motion of the moving body linearly. PZT actuators have a very fast response and infinite resolution. Due to the monolithic structure, this XYZ-stage has no crosscouples and by symmetry it has no parasitic motion. Analytical modeling of this XYZ-stage and its verification by FEM modeling are performed and optimal design that is to maximize 1st natural frequencies of the stage is also presented and with that design values stage is manufactured.