• Title/Summary/Keyword: Confinement mechanism

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Effect of deposition temperature on the photoluminescence of Si nanocrystallites thin films (증착 온도에 따른 실리콘 나노결정 박막의 광학적 특성변화 연구)

  • Jeon, Kyung-Ah;Kim, Jong-Hoon;Choi, Jin-Back;Lee, Sang-Yeol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.04b
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    • pp.38-41
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    • 2002
  • The variation of photoluminescence(PL) properties of Si thin films was investigated by changing deposition temperatures, Si-rich silicon oxide films on p-type (100) Si substrate have been fabricated by pulsed laser deposition(PLD) technique using a Nd:YAG laser. During deposition, the substrates were kept at the temperature range of room temperature(RT) to $400^{\circ}C$. After deposition, samples were annealed at $800^{\circ}C$ in nitrogen ambient, Strong Blue PL has been observed on RT-deposited Si nanocrystallites. When the deposition temperature was increased over $100^{\circ}C$, PL intensities abruptly decreased. The experimental results show the growing mechanism of Si nanocrystallites by PLD.

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An Experimental Study on the Concrete Filled Circular Steel Columns with D/t (지름두께비를 고려한 콘크리트충전 원형강관기둥에 관한 실험적 연구)

  • 한병찬;임경택;엄철환;연길환;윤석천;정수영
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.10a
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    • pp.215-218
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    • 1995
  • This paper presents an experimental study on the strength and deformation of concrete-filled circular steel short columns. Six specimens of concrete-filled circular short columns were tested under concentric compressive load. For comparsion, three specimens of circular steel short columns were also loaded to failure. The ultimate strength, ductility, and confinement mechanism of columns were compared. In the comparison, the effect of witch-thickness ratio and concrete compressive strength on the behavior of colimns were examed. As a result, the axial load verse axial average strain relationship of concrete-filled circular steel columns was very stable, because of interactions between the concrete and steel, the strength are 13% and 30% larger than the strength extimated by simply superimposed method of the concrete and steel. The ratio of the circumferential to longitudinal strain increment, both measured on the steel suface, was 0.28 up to the longitudinal strain of 0.1%, increases from 0.3 to 0.8 between the strain of 0.1% to 0.3%, and 0.8 beyond the strain of 0.3%

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An In-Situ Optical Study on Silicon Crystallization Process Using an Excimer Laser (Excimer Laser응용 실리콘 결정화 공정에 대한 In-Situ 광학적 연구)

  • Kim, W.J.;Y, C.-Hwan;Park, S.H.;Kim, H.J.
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1407-1411
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    • 2003
  • Due to the heat confinement in the shallow region of the target for a short time scale, pulsed laser annealing has received increasing interest for the fabrication of poly-Si thin film transistors(TFTs) on glass as a low cost substrate in the flat panel displays. The formation and growth mechanisms of poly silicon(poly-Si) grains in thin films are investigated using an excimer laser crystallization system. To understand the crystallization mechanism, the grain formations are observed by FESEM analysis. The optical reflectance and transmittance during the crystallization process are measured using HeNe laser optics. A two-step ELC(Excimer Laser Crystallization) process is applied to enhance the grain formation uniformity.

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An Optical Study on ELC Process of Amorphous Silicon (비정질 실리콘의 ELC 공정에 대한 광학적 연구)

  • 김우진;윤창환;박승호;김형준
    • Laser Solutions
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    • v.6 no.2
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    • pp.9-17
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    • 2003
  • Due to the heat confinement in the shallow region of the target for a short time scale, pulsed laser annealing has received an increasing interest for the fabrication of poly-Si thin film transistors(TFTs) on glass as a low cost substrate in the flat panel displays. The formation and growth mechanisms of poly silicon(poly-Si) grains in thin films are investigated using an excimer laser crystallization system. To understand the crystallization mechanism, the grain formations are observed by FESEM photography. The optical reflectance and transmittance during the crystallization process are measured using HeNe laser optics. A two-step ELC(Excimer Laser Crystallization) process is applied to enhance the grain formation uniformity.

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Nanoconfinement effects of MCM-41 on the thermal decomposition of metal borohydrides

  • Kim, Sanghoon;Song, Hyejin;Kim, Chul
    • Analytical Science and Technology
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    • v.31 no.1
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    • pp.1-6
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    • 2018
  • We used differential scanning calorimetry and a thermogravimetric analysis to investigate the effect of being confined in mesoporous MCM-41 on the decomposition of lithium borohydride and magnesium borohydride when heated. The confinement did not cause a phase transition of the metal borohydrides inside MCM-41, but did lower their decomposition temperature. With the exception of a lowering of the temperature, the decomposition reaction mechanism of the metal borohydrides was nearly the same for both the bulk and confined samples.

Load-carrying capacity of geosynthetic encased stone columns (지오그리드 보강 스톤컬럼 공법의 하중 지지 특성)

  • Yoo, Chung-Sik;Kim, Sun-Bin;Lee, Dae-Young;Park, Sun-Joon
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.03a
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    • pp.396-404
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    • 2009
  • This paper presents the results of numerical investigation on support mechanism of geogrid-encased stone columns for use in soft ground. A number of cases were analyzed using a axial- and 3D stress-pore pressure coupled model that can effectively model construction sequence and drainage as well as reinforcing effects of geogrid-encased stone columns. The results indicated that the geogrid encasement tends to significantly improve the load carrying of a stone column. Also revealed was that such a confinement effect depends on encasement length and stiffness of geogrid. It is also shown that there exist critical encasement length and stiffness of geogrid for a given condition.

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New Trends in GaAs Epitaxial Techniques (GaAs 에피 성장 기술의 최근 연구 동향)

  • Park, Seong-Ju;Cho, Keong-Ik
    • Electronics and Telecommunications Trends
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    • v.3 no.4
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    • pp.3-12
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    • 1988
  • Epilayer growing process has been recognized as a key technology for successful GaAs based devices and integrations. These may include HEMT, multiple quantum well structures, band gap engineering, and quantum confinement heterostructures. The fabrication of epilayers in these devices must meet very stringent requirements in terms of crystallinity, composition, film thickness and interface quality. In particular, the quality of interfaces is getting more important because the film thickness, and flatness, roughness and stability at interface of ultrathin films cause critical effects on the device performance. This article reviews the current status of modern epitaxial techniques which have been developed in the last few years. First, the new techniques PLE, GI, MEE, TSL based on MBE technique will be reviewed and their technical importance will be stressed. Secondly, MOMBE, GSMBE, CBE which combine the advantages of MBE and MOCVD will also be discussed. Thirdly, the new sophisticated epitaxial technique, ALE, of which mechanism is totally different from others, will also be reviewed. Finally, areas which should be exploited more extensively to accomplish these techniques will be addressed.

An Experimental Study on the High-Strength Concrete Shear Wall using Rectangular Steel Tubes (각형강관을 사용한 고강도 콘크리트 전단벽체에 대한 실험적 연구)

  • 최기봉;조순호;김명준;오종환
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.04a
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    • pp.460-467
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    • 1997
  • Compared to normal-strength concrete, high-strength concrete has the lower lateral expansion capacity caused by the higher elastic modulus and the lower internal crack characteristic. Therefore, the effect of the lateral confining action of hoops appears slowly and also in inefficient Nevertheless. it has been reported that the strength and deformation capacity of high-strength concrete is improved by well-distributed hoops. Due to that argument, this investigation has been compared and analyzed by the experimental works on the deformation capacity and the confinement mechanism of high-strength concrete shear wall of the high-rise building reinforced by rectangular steel tubes and rectangular hoops at both edges of the shear wall.

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Analysis on Transition between Index- and Bandgap-guided Modes in Photonic Crystal Fiber

  • Hong, Kee Suk;Lim, Sun Do;Park, Hee Su;Kim, Seung Kwan
    • Journal of the Optical Society of Korea
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    • v.20 no.6
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    • pp.733-738
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    • 2016
  • We calculate optical properties of guided modes of a hybrid-guiding photonic crystal fiber. The design and modeling of such hybrid-guiding PCF is made by replacing air holes with inserts of high refractive index material layer by layer in order. The optical properties such as mode intensity profile, mode dispersion, optical birefringence, confinement loss, and chromatic dispersion during transition of the guiding mechanism are analyzed and discussed. The guided modes in the hybrid-guiding region are also compared with those of reference index-guiding and bandgap-guiding photonic crystal fibers.

Facile and Room Temperature Preparation and Characterization of PbS Nanoparticles in Aqueous [EMIM][EtSO4] Ionic Liquid Using Ultrasonic Irradiation

  • Behboudnia, M.;Habibi-Yangjeh, A.;Jafari-Tarzanag, Y.;Khodayari, A.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.1
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    • pp.53-56
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    • 2009
  • At room-temperature, a facile, seedless, and environmentally benign green route for the synthesis of star like PbS nanoclusters at 7 min in aqueous solution of 1-ethyl-3-methylimidazolium ethyl sulfate, [EMIM] [$EtSO_{4}$], room-temperature ionic liquid (RTIL), via ultrasonic irradiation is proposed. The X-ray diffraction studies display that the products are excellently crystallized in the form of cubic structure. An energy dispersive X-ray spectroscopy (EDX) investigation reveals the products are extremely pure. The absorption spectra of the product exhibit band gap energy of about 4.27 eV which shows an enormous blue shift of 3.86 eV that can be attributed to very small size of PbS nanoparticles produced and quantum confinement effect. A possible formation mechanism of the PbS nanoparticles using ultrasonic irradiation in aqueous solution of the RTIL is presented.