• Journal of Powder Materials
• /
• v.26 no.5
• /
• pp.395-404
• /
• 2019

Aluminum nitride (AlN) has excellent electrical insulation property, high thermal conductivity, and a low thermal expansion coefficient; therefore, it is widely used as a heat sink, heat-conductive filler, and heat dissipation substrate. However, it is well known that the AlN-based materials have disadvantages such as low sinterability and poor mechanical properties. In this study, the effects of addition of various amounts (1-6 wt.%) of sintering additives $Y_2O_3$ and $Sm_2O_3$ on the thermal and mechanical properties of AlN samples pressureless sintered at $1850^{\circ}C$ in an $N_2$ atmosphere for a holding time of 2 h are examined. All AlN samples exhibit relative densities of more than 97%. It showed that the higher thermal conductivity as the $Y_2O_3$ content increased than the $Sm_2O_3$ additive, whereas all AlN samples exhibited higher mechanical properties as $Sm_2O_3$ content increased. The formation of secondary phases by reaction of $Y_2O_3$, $Sm_2O_3$ with oxygen from AlN lattice influenced the thermal and mechanical properties of AlN samples due to the reaction of the oxygen contents in AlN lattice.

• Composites Research
• /
• v.35 no.1
• /
• pp.47-51
• /
• 2022

In order to efficiently control the heat generation of electronic devices, many research has been conducted on thermally conductive composite materials. In this study, milled carbon fiber was dispersed in four solvent to investigate the relationship of carbon fiber alignment according to dispersion by solvents, and carbon fiberreinforced composite material(CFRP) was manufactured using vacuum filtration. To evaluate the arrangement of CFRP the arrangement of the prepared specimen was observed under an optical microscope, and thermal conductivity was measured by Laser Flash Analysis. The Through-plane thermal conductivity of CFRP using NMP and Ethanol was 10.79 W/mK and 10.57 W/mK respectively, which were improved by 218% and 209% compared to the In-plane thermal conductivity. The high viscosity of the solvent greatly affects the shear of the fluid, and it seemed to determine the alignment of the filler.

• Journal of the Microelectronics and Packaging Society
• /
• v.28 no.4
• /
• pp.73-77
• /
• 2021

Flexible electrodes for wearable devices have been actively studied in not only achieving mechanical/electrical stability, but also providing various functionalities for extending its industrial application. In this study, a flexible carbon/PDMS composite is prepared by addition of carbon black (CB) as a conductive filler, and effect of CB with different contents on electrical properties of the composite was investigated for the application of flexible electrodes, temperature sensor and heater. With increase of CB contents, resistivity of the carbon/PDMS was increased, and excellent durability was observed, confirmed by repetitive stretching deformation test. Resistance increase of the carbon/PDMS with temperature reveals the property of positive temperature coefficient, which can be applied for temperature sensor. Also, joule heating on the carbon/PDMS was observed when electrical potential was applied, indicating the applicability of the carbon/PDMS for heater.

• Composites Research
• /
• v.22 no.3
• /
• pp.44-54
• /
• 2009

In this paper, we proposed a numerical model the complex permittivity for the E-glass fabric/epoxy composite laminate containing electrical conductive carbon black. The model is based on the percolation theory and for the composites over than the percolation threshold and in higher frequency band in that the AC conductivity is fully proportional to the frequency. The measurement for the complex permittivity wasperformed at the frequency band of 0.5 GHz $\sim$ 18.0 GHz using a vector network analyzer with a 7 mm coaxial air line. The proposed model is composed of the numerical equations of the scaling law used in percolation theory and constants obtained from experiments to quantify the model itself. The model describes the complex permittivity as the function of frequency and filler concentration. The model was verified by being compared with the measurements.

• Korean Chemical Engineering Research
• /
• v.54 no.3
• /
• pp.410-418
• /
• 2016

In this study, we prepared electrically conducting composites using epoxy resin of diglycidyl ether of bisphenol A (DGEBA) as a matrix, triethylenetetramine (TETA) as a hardener and nickel powder or multi-walled carbon nanotubes (MWCNTs) grafted with $-NH_2$ groups (MWCNT-$NH_2$) as electrically conducting fillers. Electrical conductivity of composite films were measured by coating on the slide glass with a doctor blade. We measured modification reactions of MWCNT and reaction of MWCNT-$NH_2$ with DGEBA epoxy resin by fourier transform infrared spectrometer (FTIR), thermogravimetric analyzer (TGA) and elemental analyzer (EA). Morphology of composites was investigated by scanning electron microscope (SEM) and sheet resistances of composites were measured by 4-point probe. We found $(9.87{\pm}1.09){\times}10^4{\Omega}/sq$ of sheet resistance for epoxy composite containing both 40 wt% nickel powder and 0.5 wt% of MWCNT-$NH_2$ as fillers, equivalent to epoxy composite containing 53.3 wt% nickel powder only as a filler.

• Journal of the Microelectronics and Packaging Society
• /
• v.23 no.3
• /
• pp.51-56
• /
• 2016

To fabricate a copper (Cu)-based fine conductive filler having antioxidation property, submicron silver (Ag)-coated Cu particles were fabricated and their antioxidation property was evaluated. After synthesizing the Cu particles of $0.705{\mu}m$ in average diameter by a wet-reduction process, Ag-coated Cu particles were fabricated by successive Ag plating using ethylene grycol solvent. Main process parameters in the Ag plating were the concentration of reductant (ascorbic acid), the injection rate of Ag precursor solution, and the stirring rate in mixed solution. Thus, Ag plating characteristics and the formation of separate fine pure Ag phase were observed with different combinations of process parameters. As a result, formation of the separate pure Ag phase and aggregation between Ag-coated Cu particles could be suppressed by optimization of the process parameters. The Ag-coated Cu particles which were fabricated using optimal conditions showed slight aggregation, but excellent antioxidation property. For example, the particles indicated the weight gain not exceeding 0.1% until $225^{\circ}C$ when they were heated in air at the rate of $10^{\circ}C/min$ and no weight gain until 75 min when they were heated in air at $150^{\circ}C$.