• Korean Journal of Materials Research
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• v.31 no.6
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• pp.320-324
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• 2021

Effects of growth variables and post-growth annealing on the optical, structural and electrical properties of magnetron-sputtered Ga_0.04Mg_0.10Zn_0.86O films are characterized in detail. It is observed that films grown from pure oxygen plasma showed high resistivity, ~10² Ω·cm, whereas films grown in Ar plasma showed much lower resistivity, 2.0 × 10^-2 ~ 1.0 × 10^-1 Ω·cm. Post-growth annealing significantly improved the electrical resistivity, to 4.3 ~ 9.0 × 10^-3 Ω·cm for the vacuum annealed samples and to 1.3 ~ 3.0 × 10^-3 Ω·cm for the films annealed in Zn vapor. It is proposed that these phenomena may be attributed to the improved crystalline quality and to changes in the defect chemistry. It is suggested that growth within oxygen environments leads to suppression of oxygen vacancy (Vo) donors and formation of Zn vacancy (V_Zn) acceptors, resulting in highly resistive films. After annealing treatment, the activation of Ga donors is enhanced, Vo donors are annihilated, and crystalline quality is improved, increasing the electron mobility and the concentration. After annealing in Zn vapor, Zn interstitial donors are introduced, further increasing the electron concentration.

• Journal of Sensor Science and Technology
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• v.30 no.6
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• pp.369-375
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• 2021

In this study, heterogeneous ZnO/CNTF composites were developed to improve the NO₂-sensing response, facilitated by the self-heating property. Highly conductive and mechanically stable CNTFs were prepared by a wet-spinning process assisted by the liquid crystal (LC) behavior of CNTs. Metal-organic frameworks (MOFs) of ZIF-8 were precipitated on the surface of the CNTF (ZIF-8/CNTF) via one-pot synthesis in solution. The subsequent calcination process resulted in the formation of the ZnO/CNTF composites. The calcination temperatures were controlled at 400, 500, and 600 ℃ in an N₂ atmosphere to confirm the evolution of the microstructures and NO₂-sensing properties. Gas sensor characterization was performed at 100 ℃ by applying a DC voltage to induce Joule heating through the CNTF. The results revealed that the ZnO/CNTF composite after calcination at 500 ℃ (ZnO/CNTF-500) exhibited an improved response (R_air/R_gas = 1.086) toward 20 ppm NO₂ as compared to the pristine CNTF (R_air/R_gas = 1.063). Selective NO₂-sensing properties were demonstrated with negligible responses toward interfering gas species such as H₂S, NH₃, CO, and toluene. Our approach for the synthesis of MOF-driven ZnO/CNTF composites can provide a new strategy for the fabrication of wearable gas sensors integrated with textile materials.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.36 no.6
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• pp.415-421
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• 2023

In this study, the piezoresistive properties of cementitious composites enhanced with carbon nanotubes for improved electrical conductivity were analyzed using a deep learning-based transformer algorithm. Experimental execution was performed in parallel for acquisition of training data. Previous studies on mixture design, specimen fabrication, chemical composition analysis, and piezoresistive performance testing are also reviewed in this paper. Notably, specimens in which fly ash substituted 50% of the binder material were fabricated and evaluated in this study, in addition to carbon nanotube-infused specimens, thereby exploring the potential enhancement of piezoresistive characteristics in conductive cementitious materials. The experimental results showed more stable piezoresistive responses in specimens with fly-ash substituted binder. The transformer model was trained using 80% of the gathered data, with the remaining 20% employed for validation. The analytical outcomes were generally consistent with empirical measurements, yielding an average absolute error and root mean square error between 0.069 to 0.074 and 0.124 to 0.132, respectively.

• Journal of the Korean institute of surface engineering
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• v.56 no.5
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• pp.299-308
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• 2023

In this study, phosphorus (P)-doped nickel cobaltite (P-NiCo₂O₄) and nickel-cobalt layered double hydroxide (P-NiCo-LDH) were synthesized on nickel (Ni) foam as a conductive support using hydrothermal synthesis. The thermal properties, crystal structure, microscopic surface morphology, chemical distribution, electronic state of the constituent elements on the sample surface, and electrical properties of the synthesized P-NiCo₂O₄ and P-NiCo-LDH samples were analyzed using thermogravimetric analysis-differential scanning calorimetry (TGA-DSC), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). The P-NiCo₂O₄ electrode exhibited a specific capacitance of 1,129 Fg^-1 at a current density of 1 Ag^-1, while the P-NiCo-LDH electrode displayed a specific capacitance of 1,012 Fg^-1 at a current density of 1 Ag-1. When assessing capacity changes for 3,000 cycles, the P-NiCo₂O₄ electrode exhibited a capacity retention rate of 54%, whereas the P-NiCo-LDH electrode showed a capacity retention rate of 57%.

• The Journal of the Korea institute of electronic communication sciences
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• v.19 no.1
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• pp.39-46
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• 2024

In this study, GTZO(Ga-Ti-Zn-O) thin films were deposited at various working pressures (1~7mTorr) by RF magnetron sputtering to examine the structural, electrical, and optical properties. All GTZO thin films exhibited c-axis preferential growth regardless of working pressure, the GTZO thin film deposited at 1mTorr showed the most excellent crystallinity having 0.38˚ of FWHM. The average transmittance in the visible light region (400~800nm) showed 80% or more regardless of the working pressure. We could observed the Burstein-Moss effect that carrier concentration decrease with the increase of working pressure and thus the energy band gap is narrowed. Figure of merits of GTZO thin film deposited at 1mTorr showed the highest value of 9.08 × 103 Ω-1·cm-1, in this case resistivity and average transmittance in the visible light region were 5.12 × 10-4 Ω·cm and 80.64%, respectively.

• Applied Chemistry for Engineering
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• v.23 no.4
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• pp.372-376
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• 2012

Carbon nanotubes (CNT) are considered as one of ideal nano-fillers in the field of composites with their excellent electrical, mechanical, and thermal properties. Therefore CNT composites are increasingly used in fabricating conductive materials, structural materials with high strength and low weight, and multifunctional materials. The main problem of the CNT composites is difficulty in the dispersion of CNT in the polymer matrix. In this study multi-walled carbon nanotubes (MWNT) were pretreated by the physical process utilizing a wrapping method. After the pretreatment polymer/MWNT nanocomposites were prepared by melt processing. The effect of functionalization MWNT by wrapping with styrene acrylonitrile (SAN) on the mechanical and electrical properties of acrylonitrile butadiene styrene resin (ABS)/MWNT composites was studied by comparing the properties of ABS mixed with the neat MWNT. Electrical and mechanical properties of ABS/MWNT nanocomposites were studied as a function of the functionalization and content of MWNT. The tensile strength of the ABS/MWNT nanocomposites increased, but the impact strength decreased. The polymer wrapping in ABS system has little effect on the improvement of electrical properties.

• Geophysics and Geophysical Exploration
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• v.15 no.4
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• pp.177-189
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• 2012

Evaluation of three-dimensional ore body modeling has been performed by applying the geostatistical integration technique to multiple geophysical (electrical resistivity, MT) and geological (borehole data, physical properties of core) information. It was available to analyze the resistivity range in borehole and other area through multiple geophysical data. A correlation between resistivity and density from physical properties test of core was also analyzed. In the case study results, the resistivity value of ore body is decreased contrast to increase of the density, which seems to be related to a reason that the ore body (magnetite) includes heavy conductive component (Fe) in itself. Based on the lab test of physical properties in iron mine region, various geophysical, geological and borehole data were used to provide ore body modeling, that is electrical resistivity, MT, physical properties data, borehole data and grade data obtained from borehole data. Of the various geostatistical techniques for the integrated data analysis, in this study, the SGS (sequential Gaussian simulation) method was applied to describe the varying non-homogeneity depending on region through the realization that maintains the mean and variance. With the geostatistical simulation results of geophysical, geological and grade data, the location of residual ore body and ore body which is previously reported was confirmed. In addition, another highly probable region of iron ore bodies was estimated deeper depth in study area through integrated modeling.

• Applied Chemistry for Engineering
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• v.26 no.3
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• pp.275-279
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• 2015

Poly(3,4-ethylenedioxythiophene) : poly(styrenesulfonate) (PEDOT : PSS) has attracted a great deal of attention as a transparent conductive material for organic solar cells or organic light-emitting diodes due to its high electrical conductivity, optical transparency, and excellent mechanical flexibility. It is well known that a solvent doping for PEDOT : PSS thin-films significantly increases the conductivity of films. In this paper, the effect of various kinds of solvent doping and post-treatment on the electrical and structural properties of PEDOT : PSS thin-films is investigated. The solvent doping greatly increases the conductivity of PEDOT : PSS thin-films up to 884 S/cm. A further enhancement of the conductivity of PEDOT : PSS thin-films is achieved by the solvent post-treatment which raises the conductivity up to 1131 S/cm. The enhancement is mainly caused by the depletion of insulating PSS and forming conducting PEDOT-rich granular networks. Strong optical absorption peaks at the wavelength of 225 nm of PEDOT : PSS thin-films indicate the depletion of insulating PSS by post-treatment. We believe that the solvent post-treatment is a promising method to achieve highly conductive transparent PEDOT : PSS thin-films for applications in efficient, low-cost and flexible organic devices.

• The Journal of Engineering Geology
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• v.3 no.2
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• pp.125-148
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• 1993

Groundwater flow in fractured rock masses is controlled by combined effects of fracture networks, state of geostafic stresses and crossflow between fractures and rock matrix. Furthermore the scaie dependent, anisotropic properties of hydraulic parameters results mainly from irregular paftems of fracture system, which can not be evaluated properly with the methods available at present. The basic assumpfion of discrete fracture network model is that groundwater flows only along discrete fractures and the flow paths in rock mass are determined by geometric paftems of interconnected fractures. The characteristics of fracture distribution in space and fracture hydraulic parameters are represented as the probability density functions by stochastic simulation. The discrete fracture network modelling was aftempted to characterize the groundwater flow in the vicinity of existing large cavems located in Wonjeong-ri, Poseung-myon, Pyeungtaek-kun. The fracture data of $1\textrm{km}^2$ area were analysed. The result indicates that the fracture sets evaluated from an equal area projection can be grouped into 6 sets and the fracture sizes are distributed in longnormal. The conductive fracture density of set 1 shows the highest density of 0.37. The groundwater inflow into a carvem was calculated as 29ton/day with the fracture transmissivity of $10^{-8}\textrm{m}^2/s$. When the fracture transmissivity increases in an order, the inflow amount estimated increases dramatically as much as fold, i.e 651 ton/day. One of the great advantages of this model is a forward modelling which can provide a thinking tool for site characterization and allow to handle the quantitative data as well as qualitative data.

• Journal of Electrical Engineering and Technology
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• v.6 no.4
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• pp.543-550
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• 2011

Conductive SiC-$ZrB_2$ composites were produced by subjecting a 40:60 (vol%) mixture of zirconium diboride (ZrB2) powder and ${\beta}$-silicon carbide (SiC) matrix to spark plasma sintering (SPS). Sintering was carried out for 5 min in an argon atmosphere at a uniaxial pressure and temperature of 50 MPa and $1500^{\circ}C$, respectively. The composite sintered at a heating speed of $25^{\circ}C$/min and an on/off pulse sequence of 12:2 was denoted as SZ12L. Composites SZ12H, SZ48H, and SZ10H were obtained by sintering at a heating speed of $100^{\circ}C$/min and at on/off pulse sequences of 12:2, 48:8, and 10:9, respectively. The physical, electrical, and mechanical properties of the SiC-$ZrB_2$ composites were examined and thermal image analysis of the composites was performed. The apparent porosities of SZ12L, SZ12H, SZ48H, and SZ10H were 13.35%, 0.60%, 12.28%, and 9.75%, respectively. At room temperature, SZ12L had the lowest flexural strength (286.90 MPa), whereas SZ12H had the highest flexural strength (1011.34 MPa). Between room temperature and $500^{\circ}C$, the SiC-$ZrB_2$ composites had a positive temperature coefficient of resistance (PTCR) and linear V-I characteristics. SZ12H had the lowest PTCR and highest electrical resistivity among all the composites. The optimum SPS conditions for the production of energy-friendly SiC-$ZrB_2$ composites are as follows: 1) an argon atmosphere, 2) a constant pressure of 50 MPa throughout the sintering process, 3) an on/off pulse sequence of 12:2 (pulse duration: 2.78 ms), and 4) a final sintering temperature of $1500^{\circ}C$ at a speed of $100^{\circ}C$/min and sintering for 5 min at $1500^{\circ}C$.