• Title/Summary/Keyword: Concentration of Solution

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Study on the Crevice Corrosion Behavior of SS 400 in Marine Environment (해양환경중에서 SS400강재의 간극부식거동에 관한 연구)

  • 임우조;정기철;안석환;윤병두
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2000.11a
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    • pp.1-6
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    • 2000
  • This paper was studied on the crevice corrosion behavior of SS 400 in marine environment. In 0%, 2%, 3.5%, 5% NaCl solution, the aspect of the crevice corrosion and polarization behavior under the crevice corrosion was investigated. And Weight loss rate of SS 400 with crevice and non-crevice was measured according to the NaCl concentration. The main results obtained are as follows : 1) Under crevice corrosion, the corrosion potential become less noble as the concentration of NaCl solution increased. 2) The current density under open circuit potential was high drained as concentration of NaCl solution increased by 3.5% but the concentration increased over 3.5%, the current density was low drained. 3) The weight loss rate of SS400 was increased as concentration of NaCl solution increased by 3.5% but the concentration increased over 3.5%, that of SS400 was decreased.

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Experimental Studies on Limiting Concentration of High Saline Feed Solution in Electrodialysis (전기투석 시스템에서 고농도 수용액의 한계 농축에 대한 연구)

  • Junsu, Jang;Bumjoo, Kim
    • Applied Chemistry for Engineering
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    • v.34 no.1
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    • pp.64-68
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    • 2023
  • The salt concentration process in electrodialysis, which uses electrical energy to enhance ion concentrations in an aqueous electrolyte solution, has been studied on the transfer phenomenon of ions and water molecules over the ion exchange membrane. In this paper, we investigated various parameters for limiting concentration of electrolyte solution and the electroosmosis phenomenon in an electrodialysis system by varying salt concentration of electrolyte solution. The electroosmotic water transport was analyzed by measuring the ions and water fluxes in electrolyte solutions having two different NaCl concentrations (NaCl 2M/4M), and concentration change was observed for various volume ratios of the diluted reservoir to the concentration one As a result, it was found that the higher concentration of the aqueous electrolyte solution, the lower electroosmosis, and the higher volume ratio led to a higher concentration in the dilute reservoir, so the limiting concentration was enhanced and the specific energy consumption decreased.

Formation Behavior of Passive State Film on Stainless Steel for Metallic Ion Concentration in Electropolishing Solution (전해 연마액 금속 이온 농도에 따른 스테인리스 스틸의 부동태 피막 형성 거동)

  • Oh, Jong Su;Kang, Eun-Young;Jeong, Dae-Yong
    • Korean Journal of Materials Research
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    • v.32 no.4
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    • pp.230-236
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    • 2022
  • The formation behavior of a passive state film on the surface of STS304 in electrolytic solution was analyzed to determine its metallic ion composition. The properties of passive state films vary depending on the Fe and Cr ions in the electrolytic solution. It was observed that the passive state film surface became flat and glossy as the concentration of Fe and Cr ions in the electrolytic solution increased. The corrosion resistance property of the passive state film was proportional to the amount of Fe and Cr in the electrolytic solution. An initial passive state film with high Fe concentration was formed on the surface of STS304 during early electrolytic polishing. Osmotic pressure of Fe ions occurs between the passive state film and electrolytic solution due to the Fe ion concentration gradient. The Fe in the passive state film is dissolved into the electrolyte, and Cr fills up the Fe ion vacancies. As a result, a good corrosion-resistant floating film was formed. The more Fe ions in the electrolytic solution, the faster the film is formed, and as a result, a flat passive state film containing a large amount of Cr can be formed.

Effect of Concentration of Solution and Temperature on Water Flux by Semi-Permeability of Hardened Cement Paste (시멘트경화체의 반투과성에 의한 수분이동에 미치는 용액농도와 환경온도의 영향)

  • 배기선;오상근;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.131-136
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    • 1997
  • It is well known that concrete is typical porous material. We pay attention to Hansen's idea that concrete may be expected to act as semi-permeable membrane, and report the effect of concentration of solution and temperature on water flux in forward osmosis. In order to measuring volume of water flux from distilled water to solution of sodium chloride through hardened cement paste, specially designed apparatus was constructed, and the following result were obtained: (1) hardened cement paste acts as semi-permeable membrane, consequently, water flux in forward osmosis may occur. (2) Rate of water flux is proportion to concentration of dilute solution, and this suggests hardened cement paste is agreeable to the theory of membrane. (3) Effect of temperature on water flux is agreeable to Arrehenius equation and is great.

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Approximated Solution of Model for Three-Phase Fluidized Bed Biofilm Reactor in Wastewater Treatment

  • Choi Jeong-Woo;Min Junhong;Lee Won-Hong;Lee Sang Baek
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.5 no.1
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    • pp.65-70
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    • 2000
  • An approximated analytical solution of mathematical model for the three phase fluidized bed bioreactor (TFBBR) was proposed using the linearization technique to describe oxygen utilization rate in wastewater treatment. The validation of the model was done in comparison with the experimental results. Satisfactory agreement was obtained in the comparison of approximated analytical solution and numerical solution in the oxygen concentration profile of a TFBBR. The approximated solutions for three modes of the liquid phase flow were compared. The proposed model was able to predict the biomass concentration, dissolved oxygen concentration the height of efficient column, and the removal efficiency.

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Measurements of the Diamagnetic Susceptibility of NaCl Aqueous Solution

  • Lee, Seung-Hwan
    • Journal of Navigation and Port Research
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    • v.27 no.6
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    • pp.669-675
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    • 2003
  • Using a SQUID magnetometer, the diamagnetic susceptibility of NaCl aqueous solution was measured with high accuracy in a magnetic field of up to 6 Tat 25$\pm0.05^{\circ}C$. The NaCl concentrations adopted in this experiment were 0 (water), 7.5, 15, 23, 26.2, 26.6 and 100% (crystal) with the concentration error of $\pm$0.04%. Experimental data was compared with the calculated value of susceptibility derived from dependence of the vapor pressure on NaCl concentration As a result, our measured value was almost in accordance with the calculated value. It was found that the diamagnetic susceptibility shows a decrease of approximately 10% within the saturated concentration (26.2%) and that the susceptibility is one of the effective cause for the concentration dependence in the gas-liquid interface deformation of the NaCl solution.

A Study of the Effect of Fluoride to Dental Hard Tissue (불소가 치아 경조직에 미치는 영향에 관한 연구)

  • 이승우
    • Journal of Oral Medicine and Pain
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    • v.5 no.1
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    • pp.1-4
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    • 1980
  • Caries free anterior teeth were rinsed for 10 minutes with 1%, 5% sodium fluoride and 1% stannous fluoride solution three times a day for the period of experiment. And the author measured the concentration of enamel fluoride by means of Mc Cann's Technique. And the results were as follows : 1. There were little difference of enamel fluoride concentration between the teeth treated with 5% sodium fluoride solution. 2. The enamel fluoride concentration shows a tendency of direct proportion in lower concentration of fluoride solution for the period of 10 days. 3. The Enamel fluoride concentration in the group treated with stannous fluoride solution reveals acute elevation in the 5th day of experiment but the trend was not direct proportional in the 10th day of experiment.

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Effects of Diurnal Alternation of Nutrient Solution Salinity on Growth and Fruit Quality of Tomatoes Hydroponically Grown in NFT System (NFT 수경재배시스템에서 주/야 양액농도변환이 토마토의 생육 및 품질에 미치는 영향)

  • Kim Ki-Deog;Lee Eung-Ho;Lee Jae-Wook;Lee Byoung-Yil;Son Jung-Eek;Chun Chang-Hoo
    • Journal of Bio-Environment Control
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    • v.15 no.1
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    • pp.53-68
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    • 2006
  • This experiment was conducted to investigate the effects of diurnal alternation of nutrient solution salinity on growth and fruit quality of tomatoes (Lycoperisicon esculentum cv. 'House momotaro') hydroponically grown in root intercept bag-NFT (RIB-NFT) system. Plant height was the lowest in the high concentration during daytime (6/1 $dS\;m^{-1}$, day/night). Yield was very high in the concentration of 1/1 $dS\;m^{-1}$, it decreased with increasing the concentration of nutrient Yield was higher at low concentration (4/1 $dS\;m^{-1}$) at nighttime compared to the same concentration (4/4 $dS m^{-1}$) at daytime and nighttime, and the reverse (1/4 $dS\;m^{-1}$) was similar to the control (perlite culture). Yield was greatly reduced by higher concentration at daytime than nighttime, and the decrease was alleviated by lower concentration at nighttime. With increasing the concentration of nutrient solution during daytime, sugar content of tomato fruit was increased, but yield was decreased. In the other experiment, tomato plants were hydropoically cultured in NFT system diurnally alternated between Aichi's solution and $Ca(NO_3)_2$ solution. $Ca(NO_3)_2$ solution was supplied for 4 hours from 10:00 to 14:00 at daytime and from 22:00 to 2:00 at nighttime, respectively, and Aichi's solution was supplied for the time except the 4 hours. Ca content of leaves and sugar content of fruit were increased by supplying $Ca(NO_3)_2$ solution at daytime compared to nighttime, but plant growth was greatly suppressed by supplying $Ca(NO_3)_2$ solution with the concentration of 4 $dS\;m^{-1}(4/4^{Ca}\;dS\;m^{-1})$ at nighttime.

Adsorptive Binding of Plasma Proteins to Red Blood Cell Ghosts (플라즈마 단백질의 고스트 적혈구 흡착 특성)

  • 김동욱;차운오
    • KSBB Journal
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    • v.11 no.6
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    • pp.630-635
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    • 1996
  • Blood plasma proteins dissolved in isotonic phosphate-buffered saline were found to be adsorbed to red blood cell ghosts suspended in the solution. This was evidenced by concentration reduction of the plasma proteins in the bulk solution. For initial concentration of 0.1mg/mL immuno globulin, concentration reduction increased from 14% to 45% as the volume fraction of red blood cell ghosts in the solution increased from 5% to 45%. For initial concentration of 0.075mg/mL albumin, the concentration reduction increased from 12% to 47% as the volume fraction of red blood cell ghosts in the solution increased from 5% to 70%. The concentration reduction of plasma proteins in hardened red blood cell ghosts was higher than that in red blood cell ghosts. The number of adsorbed protein molecules per a red blood cell ghost were reduced as volume fraction of the ghosts in the solution increased.

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Prediction of Alkaline Copper Quat (ACQ) Wood Preservative Concentration by Turbidity (탁도에 의한 구리·알킬암모늄화합물계 목재방부제(ACQ)의 농도 예측)

  • Lee, Jong Shin;Kim, Kyoung Tae;Choi, Gwang Sik
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.5
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    • pp.743-749
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    • 2016
  • The concentration control of wood preservatives is necessary to produce a preservative treated wood having a uniform quality. Concentration measurement method of wood preservatives to be easily used in the field has not been developed yet. This study examined the way to estimate the concentration from turbidity of ACQ wood preservative that can be relatively easily measured by using a portable turbidity meter. The addition of phosphoric acid solution in an alkaline ACQ solution having a very low turbidity is created a suspension of the white substance and the turbidity suddenly increased. The optimum amount of addition of the phosphoric acid solution is until the pH of ACQ solution reaches 7, the turbidity of the ACQ solution reaches maximum value. Excessive addition of the phosphoric acid solution results in a turbidity decrease with acidification of the ACQ solution. Also ACQ solution becomes transparent. The high significance was recognized with positive correlation between the concentration and the turbidity of the ACQ solution. From the t-test, The significant difference between the actually measured concentrations and the concentrations predicted by the regression equation for industrial ACQ solutions was not recognized. Thus, it was possible to know that concentration prediction and control of industrial ACQ solution using the turbidity and a regression equation. Therefore, using the regression equation and turbidity is expected to be able to management the concentration of ACQ solution in the industrial field.