• Title/Summary/Keyword: Concentration coefficient

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Numerical analysis of chromium deposition through the SOFC cathode channel (고체 산화물 연료전지의 공기극 유로내 크롬 피독에 관한 전산해석)

  • Park, Joon-Guen;Bae, Joong-Myeon;Lee, Shin-Ku;Nabielek, Heinz
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.372-375
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    • 2006
  • SOFC is a high temperature fuelcell with many advantages, but it also have several demerits. One of the Issues is cathode poisoning of Cr coming from stainless steel interconnects. Diffusion process of Cr evaporated from the surface of interconnect steel was calculated by using CFD technique to understand factors for Cr deposition. It has been cleared that factors concerned in Cr deposition and how they affect Cr deposition. Major variables for Cr deposit ion are diffusion coefficient, air velocity and temperature If diffusion coefficient decreases, Cr concentration increases in the air but decreases on the cathode surface. Increasing in air velocity, Cr concentration decreases in the air and on the cathode surface. Increase in temperature leads to rising Cr concentration on the cathode surface because of diffusion coefficient increment.

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A Study on the Chemical characteristics of Anion Components and Metallic Elements of PM10 in Miryang and Changwon (밀양·창원지역의 PM10 중 음이온 성분 및 금속성분의 화학적 특성에 관한 연구)

  • Suh Jeong-Min;Jeon Bo-Kyung;Choi Kum-Chan
    • Journal of Environmental Science International
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    • v.13 no.12
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    • pp.1049-1058
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    • 2004
  • PM10 concentration of total 48 samples collected from 4 sites (the root of Miryang University, Sangnam township Office in Miryang. the root of Changwon elementary school, and Junam reservoir in Changwon) turned out to range from 42.29 to 69.49{\mu}g/m^{3}$, and the average concentration was the root of Changwon elementary school $(69.49{\mu}g/m^{3})$>the root of Miryang university $(58.59{\mu}g/m^{3})$>Junam reservoir $(43.56{\mu}g/m^{3})$>Sangnam township Office $(42.29{\mu}g/m^{3}).> In particular, Junam reservoir, the Clean Area, had a slightly higher value than Sangnam township Office. It was thought although the site was plane and windy without pollutants around. it had a higher concentration value influenced by external factors including bigger population and a northeasterly wind due to a newly-established industrial complex nearby. As for water-soluble ions among PM10 particle collected in Miryang and Changwon area, SO42- accounted for $50{/%}$ and NO3-, was $35{\%}$, and the concentration order was S042->N03->Cl->F-. As for the average concentration of metallic components among PM10 particle collected in Miryang and Changwon area. the root of Changwon elementary school had the AI concentration, Fe concentration and Zn concentration 4 times, 3 times and 1.5 times that of Junam reservoir, respectively. The root of Miryang University had the AI concentration 2 times that of Sangnam township Office, and had Fe concentration and Zn concentration $1.2\~1.5$ times those of Sangnam township Office. When it comes to the relation between metallic elements and meteorological factors in Changwon area, the highest coefficient of correlation was between temperature and humidity with 0.92, and temperature and wind speed turned out in the reverse correlation. The coefficient of correlation between Al and Cr was as high as 0.78. Among metallic elements, the coefficient of correlation between Cu and Pb, Cd, Al were 0.84, 0.85, 0.79, respectively. It is thought that the high coefficient of correlation between Cu and Pb is ascribed to busy traffic and wind in the urban areas, Sammun-dong and Gagok-dong in Miryang. Meanwhile, the coefficients of correlation between Fe and Cu, Al, Zn, Cd, Pb were in the reverse correlation. These coefficients of correlation are attributed to the difference in pollutant sources, rather than difference in pollutant and non-pollutant.

A prediction of indoor pollutant concentration using method mass transfer coefficient in multi-layered building materials (복합 건축자재의 물질전달계수를 이용한 실내 오염물질 농도 예측방법)

  • Kim, Chang Nam;Lee, Yun Gyu;Leigh, Seung Bok;Kim, Tae Yeon
    • KIEAE Journal
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    • v.7 no.5
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    • pp.53-58
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    • 2007
  • In order to predict the indoor air pollutant, the VOCs emission rate is used through small chamber in the design process. However, the small chamber method has limitations as the convective mass transfer coefficient, the most important factor when predicting VOCs contamination of indoor air, is different between the small chamber result and the measured data in the actual building. Furthermore, the existing studies which analyzed mass transfer coefficient in the small chamber were directed on the small chambers developed at the time and FLEC(Field and Laboratory Emission Cell), thus, are different from the current small chamber which has been changed with improvements. The purpose of this study is to determine the emission rate of pollutant in multi-layered building materials, and predict the indoor pollutant concentration through the CFD(Computational of Fluid Dynamics) and CRIAQ2 based on the mass transfer coefficient on singled-layered building material by using the current small chamber widely used in Korea. Futhermore, this study used the new convective mass transfer coefficient(hm') which indicates the existing convective mass transfer coefficient(hm) including VOC partition coefficient(k). Also, formaldehyde was selected as target pollutant.

Wear Debris Concentration Measurement by Laser Beam Attenuation (광감쇄를 이용한 마모입자의 농도 측정)

  • 강기호;손정영;전형욱;윤의성;안효석
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1990.11a
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    • pp.58-62
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    • 1990
  • The size and concentration of wear debris in lubricating oil often reveal the operating condition of the rotating machinery. To evaluate the possible application of light attenuation measurement for the estimation of wear debris concentration in the lubricating oil, the light transmittance through the lubricating oil cell contaminated with various concentrations of diatomite particles was measured, the attenuation coefficient was estimated from the transmittance measurement and the coefficients were compared with those obtained from the scattering theory. The comparision showed good agreements between them. It is also noted that the experimentally determined attenuation coefficient showed almost linear relation with particle weight concentrations for the concentrations within the range of 2000 ppm. For the case of 0 ppm weight concentration of diatomite particles in the lubricating oil cell, the thickness of the cell required to give $100 \mu W$ light attenuation is 7.75 mm. This result indicates that the light attenuation method will be one of the possible candidates of machine failure diagnostic sensors for the estimation of wear debris concentration in the lubricating oil.

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Molecular dynamics study of Al solute-dislocation interactions in Mg alloys

  • Shen, Luming
    • Interaction and multiscale mechanics
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    • v.6 no.2
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    • pp.127-136
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    • 2013
  • In this study, atomistic simulations are performed to study the effect of Al solute on the behaviour of edge dislocation in Mg alloys. After the dissociation of an Mg basal edge dislocation into two Shockley partials using molecular mechanics, the interaction between the dislocation and Al solute at different temperatures is studied using molecular dynamics. It appears from the simulations that the critical shear stress increases with the Al solute concentration. Comparing with the solute effect at T = 0 K, however, the critical shear stress at a finite temperature is lower since the kinetic energy of the atoms can help the dislocation conquer the energy barriers created by the Al atoms. The velocity of the edge dislocation decreases as the Al concentration increases when the external shear stress is relatively small regardless of temperature. The Al concentration effect on the dislocation velocity is not significant at very high shear stress level when the solute concentration is below 4.0 at%. Drag coefficient B increases with the Al concentration when the stress to temperature ratio is below 0.3 MPa/K, although the effect is more significant at low temperatures.

Dispersion of Nonconservative Contaminants Accidentally Released into Natural Streams (사고에 의하여 자연하천으로의 방류된 비보존성 오염물질의 종확산)

  • Jo, Seong-U;Jeon, Gyeong-Su
    • Journal of Korea Water Resources Association
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    • v.34 no.4
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    • pp.289-301
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    • 2001
  • A fractional step finite difference model for the longitudinal dispersion of nonconservative pollutants is applied to the Nakdong River to simulate the phenol spill accident which occurred on March, 1971. Prior to the dispersion calculation, the flow conditions are simulated to provide inputs to the dispersion model. An unsteady flow model based on Preissmann's four-point scheme is used for this purpose. Sensitivities of the dispersion calculation to empirical equations for dispersion coefficient and to the first-order decay coefficient are analyzed. The time to peak concentration at a downstream location is significantly different depending on the formula for the dispersion coefficient. Although the decay coefficient does not affect the shape of the temporal concentration distribution, the concentration values depend on the decay coefficient verb significantly. An optimization technique is used to calibrate the dispersion model as well as the flow model. The time to the peak concentration is simulated for major positions of water intake along the Nakdong River.

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Correlation analysis of solar radiation and meteorological parameters on high ozone concentration (태양복사 및 기상요소의 고농도 오존형성에 대한 상관성 분석)

  • An, Jae Ho
    • KIEAE Journal
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    • v.12 no.6
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    • pp.93-98
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    • 2012
  • The concerns on high ozone concentration phenomenon is significantly growing in Seoul metropolitan area including the industry complex area, like Shiwha Banwol area. The aims of this research is the analysis of relationship between high concentrations of $O_3$ and solar radiation parameters in atmosphere. The understanding of the effects of solar radiation intensity, humidity, high air temperature on ozone concentration in a day is very useful to provide a direction for reducing of the high ozone concentration to a local government or a metropolitan government. The correlation analysis between maximum ozone concentration and various meteorological parameters in 2009 - 2011 carried out using IBM's SPSS program. The results showed that the mean correlations coefficient (R) between daily Ozone maximum and solar radiation resulted R = 0.64 during 2011. May - September in 10 air pollution stations. In case of correlations between daily ozone maximum and relative humidity showed negative correlation R = -0.61. The correlation analysis with mean air temperature during 1-3 PM resulted R = 0.29. This low correlation coefficient could be corrected by using of categorized data of ozone concentration. The daily maximum ozone concentration is more dependent on peak solar radiation and high air temperature during 1-3 PM than its simple daily maximum values. The results of this research would be used to develop the high ozone alert system around Seoul metropolitan area. This correlation analysis could be partially integrated to prediction of ozone peak concentration in connection with other methods like classification and regression tree(CART).

Adaptive Estimation of Hairy Root Mass Using Conductometry

  • Kim, Ji-Hyeon;Yoo, Young-Je
    • Journal of Microbiology and Biotechnology
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    • v.13 no.5
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    • pp.641-646
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    • 2003
  • An accurate and efficient method for measuring the mass of hairy roots using conductometry is established. A conductivity equation expressed in terms of the concentration of the ion species in the medium is suggested. By using this equation, the effect of the individual ions on the total conductivity can be quantitatively analyzed. An equation for the in situ estimation of the cell growth coefficient for determining the mass of hairy roots is established based on measurements of the nitrogen concentration and conductivity during cultivation. The proposed equation does not require preliminary experiments to determine the cell growth coefficient. Instead, the physiological characteristics of the plant species are reflected by introducing the cellular nitrogen content. Since the cell growth coefficient is determined by measuring the major ionic nutrient concentrations, it is more effective to express the dynamics of an actual culture system. This improved method for determining the mass of hairy roots was successfully utilized in a fed-batch culture system.

Numerical Simulation of Growth/Decay of Algae using Equivalent Tracking Method of Decay Coefficient (감쇠계수 등가추적법을 이용한 조류 생장/소멸 수치모의)

  • Park, Inhwan;Kim, Sung Hoon;Song, Chang Geun
    • Journal of the Korean Society of Safety
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    • v.33 no.4
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    • pp.78-83
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    • 2018
  • Previous researches on the analysis of algae concentration were restricted to applying single-valued decay coefficient during simulation period, and the accuracy as well as the applicability were severely challenged. In this study, an equivalent tracking method of decay coefficient was proposed by introducing the time-series decay coefficients and restart option. Dye module in EFDC model was employed to route the temporal variation of Chl-a concentration. It was shown that the simulation results can be significantly improved up to 46% when the equivalent tracking method was activated.

Effect of $Cl_2$ Gas Concentration of the Surface Modified TiC on the Tribological Properties (TiC표면개질에서 $Cl_2$ 가스농도가 tribology 특성에 미치는 효과)

  • Bae, Heung-Taek;Lim, Dae-Soon;Na, Byung-Chul
    • Tribology and Lubricants
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    • v.23 no.6
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    • pp.261-265
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    • 2007
  • Carbide-derived carbon coating has been synthesized by low temperature treatment of TiC disk with $H_2/Cl_2$ mixture gases. A variety of physical measurements indicated that Ti was extracted and carbon layer was formed by exposure of $Cl_2$ gas. The $I_D/I_G$ ratio increased with increasing $Cl_2$ gas concentration. Wear coefficient and frictional coefficient varied with $Cl_2$ gas concentration. When the $Cl_2$ gas concentration decreased to 3.3 vol%, the friction coefficient approach a minimum. The results showed that degree of graphite crystallinity and variation of porosity due to the $Cl_2$ gas content were responsible for different tribology performance.