• Title/Summary/Keyword: Concentration boundary layer

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Study of the Reaction between the Dielectric and the Electrode during the Manufacturing of the Ceramic Capaciitor (요업콘덴사 제조에 있어서의 과전체와 전기물질간의 반응검사)

  • 김기호
    • Journal of the Korean Ceramic Society
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    • v.21 no.1
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    • pp.60-66
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    • 1984
  • During the metallization in the manufacturing of the ceramic capacitor at the boundary layer between Pd or Pt electrode and $BaTiO_3$-dielectric reactions were analysed. For the study of the reaction Electron Spin Resonance (ESR) Method was used. With the aid of ESR an increased of the concentration of the paramagnetic $Ti^{3+}$-Centers on the metallizing process could be seen. It meaned a reduction effect although the metallization was accomplished under oxidation atmosphere. Therefore it could be regarded as a reaction at the boundary layer. In order to investigate the reaction ad double octahedral model was compared and the increase of the $Ti^{3+}$-concentration was studied.

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Generation of Microcellular Foams in Viscoelastic Polymer Solutions (점탄성 폴리머 용액에서의 초미세 폼의 생성)

  • Kang, Sung-Lin;Kim, Ki-Young;Kwak, Ho-Young
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.174-179
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    • 2004
  • The growth of the critical size bubble by diffusion process in viscoelastic medium was treated by an integral method for the concentration boundary layer adjacent to the bubble wall. In this study, we obtained a set of the first order time dependent equations to obtain bubble radius and gas pressure inside the bubble simultaneously. The calculated final cell sizes depending on the initial saturation pressure are in close agreement with the observed ones. The governing equations developed in this study may be used in polymer processing of microcellular foams.

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A Study on the Realization of the High Efficiency LCD Photoresist Removal Technology (고효율 LCD 감광막 제거기술 구현 연구)

  • Son, Young-Su;Ham, Sang-Yong;Kim, Byoung-Inn;Lee, Sung-Hwee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.11
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    • pp.977-982
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    • 2007
  • The realization of the photoresist(PR) removal method with vaporized water and ozone gas mixture has been studied for the LCD TFT array manufacturing. The developed PR stripper uses the water boundary layer control method based on the high concentration ozone production technology. We develop the prototype of PR stripper and experiment to find the optimal process parameter condition like as the ozone gas flow/concentration, process reaction time and thin boundary layer formation. As a results, we realize the LCD PR strip rate over the 0.4 ${\mu}m/min$ and this PR removal rate is more than 5 times higher than the conventional immersion type ozonized water process.

A Study on the Pollutant Dispersion over a Mountain Valley Region (I) : Wind Tunnel Experiments (산악 계곡지형에서의 오염확산에 관한 연구(I) :풍동실험)

  • Yoo Seong-Yeon;Shim Woo-Sup;Kim Seogcheol
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.11
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    • pp.1050-1059
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    • 2005
  • Heat and $SF_6$ gas dispersions over a complex terrain were investigated using wind tunnel. The wind speed, temperature and concentration profiles were measured for the 1/1000 scale complicated terrain model in an Eiffel type boundary layer wind tunnel with test section of 2.5m in height and 4.5m in width. The scale model was mounted on the top of a plate which can rotate with respect to the approaching wind. Dispersion processes from a continuous emission source driven by various wind direction were investigated, including plume climbing over the steep up-slope of the mountain and down-spreading toward the lower level of the valley. Extensive dispersion experiment data (wind speeds and concentration profiles) were provided for verification and validation of dispersion models. Under the identical flow and emission conditions, the independently measured profiles of the temperature and $SF_6$ concentration showed an excellent agreement which ensured the credibility of the results.

Double-Diffusive Convection Due to Heating from Below in a Rotating Cylindrical Cavity (회전하는 원통형밀폐용기내의 아랫면가열에 의한 이중확산대류에 관한 실험적 연구)

  • 강신형;이태홍;이진호
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.7
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    • pp.1731-1740
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    • 1995
  • Experimental investigations have been made to study the double-diffusive nature of convection of an initially stratified salt-water solution due to heating from below in a rotating cylindrical cavity. The objective is to examine the flow phenomena and the heat transfer characteristics according to the changes in temperature gradient, concentration gradient and rotating velocity of cavity. Thermal and solutal boundary conditions at side wall are adiabatic and impermeable, respectively. The top and bottom plate are maintained each at constant temperature and concentration. The cavity is put into a state of solid body rotation. Like the stationary case, the types of initially-formed flow pattern are classified into three regimes depending on the effective Rayleigh number and Taylor number; stagnant flow regime, single mixed-layer flow regime and successively formed multi-mixed layer flow regime. At the same effective Rayleigh number, the number of initially-formed mixed layer and its growth rate decrease as the effect of rotation increases. The temperature and concentration profiles are both uniform in each layer due to convective mixing in the layered-flow regime, but look both liner in stagnant flow regime and single mixed-layer flow regime. At the interface between adjacent layers, the temperature changes smoothly but the concentration changes rapidly.

Numerical Analysis of the Two-Dimensional Pollutant Dispersion Over Hilly Terrain (산지 내 오염물질 확산의 2차원 수치해석)

  • 김현구;이정묵
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.5
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    • pp.383-396
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    • 1997
  • Numerical prediction of the pollutant dispersion over a two-dimensional hilly terrain is presented. The dispersion model used in the present work is based on the gradient diffusion theory and the finite-volume method on a non-orthogonal boundary-fitted grid system. The numerical model is validated by comparing the results with the available experimental data for the flat-floor dispersion within a turbulent boundary-layer. The numerical error analysis is performed based on the guideline of Kasibhatla et al.(1988) for the elevated-source dispersion in the flat-floor boundary layer having a power-law velocity and linear eddy-diffusivity profile. The influences of the two-dimensional hilly terrain on the dispersion from a continuously released source are numerically investigated by changing the emission locations and heights. It is found that the distributions of ground-level concentration are strongly influenced by the source location and the emission height. Hence, the terrain amplification factor is greatly enhanced when the pollutant source is located within a flow separation region. Dispersion from a source of short duration is also simulated and the duration time of the pollutant is compared at several downstream locations on a hilly terrain. The results of the numerical prediction are applied to the evaluation of environmental impacts due to the automobile exhausts at the seashore highway with a parallel mountain range.

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Evolution of Interfacial Microstructure in Alumina and Ag-Cu-Zr-Sn Brazing Alloy (알루미나/Ag-Cu-Zr-Sn 브레이징 합금계면의 미세조직)

  • Kim, Jong-Heon;Yoo, Yeon-Chul
    • Transactions of Materials Processing
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    • v.7 no.5
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    • pp.481-488
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    • 1998
  • The active metal brazing was applied to bond Alumina and Ni-Cr steel by Ag-Cu-Zr-Sn alloy and the interfacial microstructure and reaction mechanism were investigated. Polycrystalline monoclinic $ZrO_2$ with a very fine grain of 100-150 nm formed at the alumina grain boundary contacted with Zr segregation layer at the interface. The $ZrO_2$ layer containing the inclusions and cracks were developed at the boundary of inclusion/$ZrO_2$ due to the difference in specific volume. The development of $ZrO_2$ at the interface was successfully explained by the preferential penetration of $ZrO_2$ at the interface was successfully explained by the preferential penetration of Zr atoms a higher concentration of oxygen and a high diffusion rate of Al ions into molten brazing alloy.

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Evaluation of the Effect of Regional Pollutants and Residual Ozone on Ozone Concentrations in the Morning in the Inland of the Kanto Region

  • Kiriyama, Yusuke;Shimadera, Hikari;Itahashi, Syuichi;Hayami, Hiroshi;Miura, Kazuhiko
    • Asian Journal of Atmospheric Environment
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    • v.9 no.1
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    • pp.1-11
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    • 2015
  • Increasing ozone concentrations are observed over Japan from year to year. One cause of high ozone concentration in the Kanto region, which includes areas inland from large coastal cities such as metropolitan Tokyo, is the transportation of precursors by sea breezes. However, high ozone concentrations are also observed in the morning, before sea breezes approach inland areas. In this point, there would be a possibility of residual ozone existing above the nocturnal boundary layer affects the ozone concentration in the following morning. In this study, we utilized the Weather Research and Forecasting model and the Community Multiscale Air Quality model to evaluate the effect of regional precursors and residual ozone on ozone concentrations over the inland Kanto region. The results show that precursors emitted from non-metropolitan areas affected inland ozone concentrations more than did precursors from metropolitan areas. Moreover, calculated results indicate downward transportation of residual ozone, resulting in increased concentration. The residual ozone was also affected by precursors emitted from non-metropolitan areas.

Characteristics of Ozone Advection in Vertical Observation Analysis Around Complex Coastal Area (연직관측자료를 통한 복잡 연안지역의 오존 이류특성)

  • Lee, Hwa-Woon;Park, Soon-Young;Lee, Soon-Hwan;Leem, Heon-Ho
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.1
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    • pp.57-74
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    • 2009
  • In order to clarify the vertical ozone distribution in planetary boundary layer of coastal area with complex terrain, an observation campaign was carried out around Gwangyang Bay with dense pollutant emission sources during two days from June, 4 2007. For this observation are Radiosonde, SODAR(SOnic Detection And Ranging) and Tethered ozone sonde were employed. The surface meteorological and photochemical observation data provided by AWS (Automatic Weather System) and AQMS (Air Quality Monitoring System) were also applied for analysis. Synoptic condition is strongly associated with lower level ozone distribution in complex terrain coastal area. Since mesoscale circulation induced by difference of characteristics of land and sea and orographic forcing is predominant under calm synoptic condition, vertical distribution of ozone is complicate and vertical ozone concentration greatly fluctuated. However in second day when synoptic influence become strong, ozone concentration in lower levels is vertically uniform regardless of observation level. This results in vertical observation indicates that vertical ozone distribution is often determined by synoptic condition and also affects surface ozone concentration.

A Study on the Behaviors of Several Layers in a Solar Pond (태양연못안의 각 층의 거동에 관한 연구)

  • 박희용;임경빈
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.2
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    • pp.304-313
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    • 1987
  • The behaviors of layers developed in a solar pond were studied by experimental and analytical methods. An experimental solar pond heated from below was constructed and operated at the net heat fluxes of 110 and 160W/m$^{2}$ and at the initial salt concentration gradients of 18.2, 27.3 and 36.4%/m. The thicknesses, growth rates, temperature and salt concentration in the top and the bottom mixed layers, the diffusive layer and the upper and the lower interfacial boundary layers were measured. The shadowgraph technique was used in order to observe all layer formation and an electroconductivity-temperature probe consisting of four electrodes was fabricated and used in measuring the salt concentration. Based on the experimental results, a model for the solar pond was developed and the governing equation and the assumptions were established. The governing equations were solved by the numerical method. The calculated results obtained from the analysis were compared with the experimental results.