• Title/Summary/Keyword: Concentration and Dispersion

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Analysis of Behavior Characteristics of Instantaneous Input of Pollutant in River (하천에 순간 유입된 오염물질의 거동 특성 분석)

  • Yoon, Sei-Eui;Ko, Jae-Hyung;Kim, Soo-Youl
    • Journal of Korea Water Resources Association
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    • v.36 no.4
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    • pp.575-586
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    • 2003
  • In case of continuous input of a pollutant, dispersion characteristics do not change much with changing dispersion coefficient, but that of an instantaneous input is very sensitive to the changes of dispersion coefficient. The characteristics of behavior of instantaneous input of a pollutant at the downstream of Han river were analyzed in this paper Field measurement of hydraulic and water quality factors at the downstream of Han river were conducted at low flow condition. The hydraulic factors were used to estimate the longitudinal dispersion coefficient, and the reasonable empirical equations for longitudinal dispersion coefficient at the downstream of Han river were suggested. The measured concentrations of BOD were closely matched with the calculated ones from RMA-4 model. In case of instantaneous input, range of dispersion, transport pathway and the traveltimes of the first and maximum concentration with variation of the longitudinal dispersion coefficients and water levels of downstream boundary were evaluated in this paper.

Suspension Polymerization with Hydrophobic Silica as a Stabilizer II. Preparation of Polystyrene Composite Particles Containing Carbon Black (소수성 실리카를 안정제로 하는 현탁중합 II. 카본블랙을 함유하는 폴리스티렌 복합체 입자의 합성)

  • Park, Moon-Soo
    • Polymer(Korea)
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    • v.30 no.6
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    • pp.505-511
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    • 2006
  • We tried to prepare polystyrene composite particles containing carbon black by suspension polymerization with water as a reaction medium. Hydrophobic silica was selected as a stabilizer and oil-soluble azobisisobutyronitrile (AIBN), as an initiator. All polymerization reactions were carried out at a fixed temperature of $75^{\circ}C$. Stabilizer concentration was varied from $0.17{\sim}3.33wt%$ compared to water, where particles with $7.96{\mu}m$ in average diameter were obtained at 1.57 wt% of stabilizer. Increase in divinylbenzene concentration, as a crosslinking agent, from $0.1{\sim}1.0 wt%$ compared to monomer exhibited a large increase in average particle diameter Incorporation of 1wt% of carbon black compared to monomer produced an increase in average diameter It is speculated that viscosity lower than that necessary to induce even dispersion of carbon black particles led to poor dispersion, and as a result, large particles. For a styrene mixture containing 3 wt% carton black compared to monomer, enhanced dispersion due to an increase in carbon black concentration reduced average particle diameters. For styrene mixtures containing 1 and 3 wt% carbon black compared to monomer, preparticles before polymerization and polymer composite particles after polymerization showed a similar tendency towards particle formation. When carbon black concentration compared to monomer was increased to 5 and 7 wt%, styrene mixtures exhibited a large increase in viscosity and thus better dispersion of carbon black particles, which led to a decrease in preparticle diameters. However, these particles experienced agglomeration in the polymerization process, and polystyrene composite particles increased in average diameter.

Modeling flow and scalar dispersion around Cheomseongdae

  • Kim, Jae-Jin;Song, Hyo-Jong;Baik, Jong-Jin
    • Wind and Structures
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    • v.9 no.4
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    • pp.315-330
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    • 2006
  • Flow and scalar dispersion around Cheomseongdae are numerically investigated using a three-dimensional computational fluid dynamics (CFD) model with the renormalization group (RNG) $k-{\varepsilon}$ turbulence closure scheme. Cheomseongdae is an ancient astronomical observatory in Gyeongju, Korea, and is chosen as a model obstacle because of its unique shape, that is, a cylinder-shaped architectural structure with its radius varying with height. An interesting feature found is a mid-height saddle point behind Cheomseongdae. Different obstacle shapes and corresponding flow convergences help to explain the presence of the saddle point. The predicted size of recirculation zone formed behind Cheomseongdae increases with increasing ambient wind speed and decreases with increasing ambient turbulence intensity. The relative roles of inertial and eddy forces in producing cavity flow zones around an obstacle are conceptually presented. An increase in inertial force promotes flow separation. Consequently, cavity flow zones around the obstacle expand and flow reattachment occurs farther downwind. An increase in eddy force weakens flow separation by mixing momentum there. This results in the contraction of cavity flow zones and flow reattachment occurs less far downwind. An increase in ambient wind speed lowers predicted scalar concentration. An increase in ambient turbulence intensity lowers predicted maximum scalar concentration and acts to distribute scalars evenly.

현장 규모 biobarrier의 수리학적 특성과 기초 설계

  • 최영화;오재일;왕수균;배범한
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.426-430
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    • 2003
  • Subsurface biobarrier technology has potential applications to contain contaminated groundwater and/or to degrade toxic pollutants in groundwater. Effective biobarrier formation is need to assess of hydrogeologic characteristics and to conduct practical operation strategies and design based on this prior to design biobarrier. Thus, in this study, we examined hydrogeologic characteristics in biobarrier construction site. Hydraulic conductivities which calculated from slug test data have shown difference with each well as 1.20$\times$10$^{-3}$ -6.00$\times$10$^{-5}$ cm/sec. Tracer test is a method in which concentration of tracer solution during withdrawal in each well by vacuum extraction system is measured with time. Tracer solution was continuously injected by constant head tank. Measured tracer concentration versus time data were fitted to analytical solution of convection dispersion equation (CDE). The fitting data of CDE to the measured data at each extraction well yielded were 0.61cm/min(pore velocity), 5.38$\textrm{cm}^2$/min(dispersion coefficient) for discharge rate of 0.47 1/min and 1.75cm/min(pore velocity), 36.34$\textrm{cm}^2$/min(dispersion coefficient) for discharge rate of 0.93 1/min. As a result, we acquired fundamental parameters which need to design biobarrier and operation strategies.

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Quantitative Dispersion Evaluation of Carbon Nanotubes Reinforced Polymer Nano-composites (탄소나노튜브 첨가 고분자 나노복합재료의 정량적 분산도 평가)

  • Lee, Sang-Bok;Jeong, Bo-Hwa;Yi, Jin-Woo;Lee, Won-Oh;Um, Moon-Kwang
    • Polymer(Korea)
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    • v.35 no.1
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    • pp.60-65
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    • 2011
  • In order to maximize the performance of polymer nano-composites, it is essential to understand an effect of a dispersion state on material properties as well as to achieve highly dispersed composites. In this work, a simple quantitative approach to evaluate the degree of dispersion was suggested for carbon nanotube (CNT) embedded polymer nano-composites. Through UV-visible spectroscopy analysis, the transmittance of nano-composites was measured at various dispersion states and it was found that the transmittance reduced as the dispersion state of CNT improved. Based on the results, an effective concentration factor for quantitative evaluation of dispersion state was introduced into the Beer-Lambert transmittance law. The proposed method and parameter to evaluate the degree of dispersion were verified by analyzing the transmittances at different dispersion states of CNT, concentrations of CNT and sample thicknesses.

The Dispersion Stability of $\alpha-Fe_2O_3$ Particulate Soil in the Anionic/Nonionic Mixed Surfactant Solution (음/비이온계 혼합계면활성제 용액에서 $\alpha-Fe_2O_3$ 입자의 분산안정성)

  • 정선영;강인숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.6
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    • pp.854-861
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    • 2004
  • To estimate dispersion stability of particles in anionic and nonionic surfactant mixed solution, suspending power was examined as functions of duration time of suspension, ionic and nonionic surfactant mixed ratio, surfactant concentration, kinds of electrolyte, ionic strength and mole numbers of oxyethylene additions to nonionic surfactant using $\alpha$-Fe$_2$O$_3$ particle as the model of particulate soil. The suspending power of anionic and nonionic surfactant mixed solution was relatively higher than that of anionic and nonionic surfactant single solution regardless of solution concentration. The suspending power was gradually decreased with increasing duration time of suspension. In the absence of electrolyte, the effect of surfactant concentration on suspending power was small but in solution with electrolyte, suspending power was lowest at 1 % surfactant concentration. With 1${\times}$10$^{-3}$ ionic strength and polyanionic electrolyte in solution, the suspending power was high but effects of oxyethylene mole number to nonionic surfactant on suspending power was small. Generally the suspending power was gradually increased with decreasing the particle size. Hence the suspending power was inversely related to the particle size.

Synthesis and Characterization of Silver Nanofluid Using Pulsed Wire Evaporation Method in Liquid-Gas Mixture (액상/기상중 전기선 폭발법을 이용한 은 나노유체의 제조 및 특성평가에 관한 연구)

  • Kim, Chang-Kyu;Lee, Gyoung-Ja;Rhee, Chang-Kyu
    • Korean Journal of Materials Research
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    • v.19 no.9
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    • pp.468-472
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    • 2009
  • The silver nanofluids were synthesized by the pulsed wire evaporation (PWE) method in a liquid-gas mixture. The size and microstructure of nanoparticles in the deionized water were investigated by a particle size analyzer (PSA), transmission electron microscope (TEM), and scanning electron microscope (SEM). Also, the synthesized nanofluids were investigated in order to assess the stability of dispersion of nanofluid by the zetapotential analyzer and dispersion stability analyzer. The results showed that the spherical silver nanoparticle formed in the deionized water and mean particle size was about 50 nm. Also, when explosion times were in the range of 20$\sim$200 times, the absolute value of zeta potential was less than -27 mV and the dispersion stability characteristic of low concentration silver nanofluid was better than the high concentration silver nanofluid by turbiscan.

A Study on the Sensitivity Analysis of Line Source Air Quality Models (移動汚染源에 대한 大氣擴散模型의 感應度 分析에 관한 硏究 (HIWAY2, PAL, CALINE3 模型을 對象으로))

  • 김선태;김병태;김정욱
    • Journal of Korean Society for Atmospheric Environment
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    • v.5 no.1
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    • pp.1-10
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    • 1989
  • The sensitivity analysis is a method to quantify to what extent the output of a model changes with the values of input parameters. This will lead to increase model accuracy through measurement validation. Three line source air quality models, HIWAY 2, PAL, and CALINE 3 were selected for this study. The input parameters analysed included wind speed, wind direction, stability, emission rate, mixing height, receptor distance, initial dispersion coefficient, surface roughness, and averaging time. It turned out that PAL model generally showed higher concentration than other two models, and that between CALINE 3 and HIWAY 2, CALINE 3 showed higher concentration than HIWAY 2 model near the line sources, but beyond a certain downwind distances HIWAY 2 model showed higher concentration. The modesl were very sensitive to wind speed especially in the range of 0 $\sim$ 1 m/s and to wind direction near the parallel wind to streets. In case of emission rate, the output concentration was directly proportional to these input parameters. And the sensitivity of the input parameters such as stability, mixing height, initial dispersion coefficient, surface roughness, and averaging time were not very significant.

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An Effect of Heat Input on Thermal Storage for Horizontal Thermal Storage Tank with Heat pipe (열 파이프용 수평 축열조에서의 열 입력이 축열에 미치는 영향)

  • 최우석;박이동;김철주;황영규
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1995.05a
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    • pp.69-76
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    • 1995
  • The horizontal thermal storage tank with heat pipe which is suitable for the sensible heat storage system is able to store a hot water from the heat source such as heating pad efficiently and to supply a hot water to load rapidly. Therefore Arrangement of heating pad affects thermal flow and thermal storage efficiency. So, if effective arrangement is decided for condition of constant number of heating pad, the more rapid thermal flow effect and higher thermal storage efficiency is obtainable by active heat transfer. In this experiments, number of heating pad is ranged from three, five and nine, and when number of heating pad is constant, arrangement are two types of concentration-type and dispersion-type. As a result, for the case of concentration-type of heating pad, strong entrainment take place in horizontal thermal storage tank with heat pipe by active heat transfer and in the constant number of heating pad, the concentration-type has the higher efficiency with about 5∼6% than the dispersion-type. Therefore, when heating pad is equipted to horizontal thermal storage tank with heat pipe, concentration-type of heating pad is an efficient design in constant number. of heating pad.

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A study on high ozone concentration in Shiwha.Banwol industry complex using photochemical air pollution model- Analysis of meteorological characteristics - (시화.반월단지지역의 고농도 오존일에 대한 광화학모델 적용 연구 - 기상특성에 대한 분석 -)

  • An, Jae-Ho
    • Journal of the Korean Solar Energy Society
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    • v.31 no.5
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    • pp.47-59
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    • 2011
  • The purpose of this paper is to simulate the high ozone concentration in Shiwha Banwol indusrial complex. High pollution episodes (ozone alert) of this area are the results of geographical location and its air pollutants emission. This research has used meteorological model (RAMS) and photochemical air pollution Model (CIT model). As first step of the evaluate of this combined model system simulations are done in terms of meteorological characteristics like wind fields, PBL-height, etc.. Numerical simulations are carried out with real meteorological synoptic data on June. 24-25, 2010. In comparison with real measurement and another research the model reflects well local meteorological phenomena and shows the possibility to be utilized to analyse the pollutant dispersion over irregular terrain region. The high ozone concentration is deeply correlated to the ambient air temperature, wind speed and solar radiation. Local meteorological phenomena like sea-land breeze impact on horizontal dispersion of ozone. This analysis of meteorological characteristics can, in turn, help to predict their influences on air quality and to manage the high ozone episodes.