• 제목/요약/키워드: Concentration Transition

검색결과 626건 처리시간 0.03초

대기 중에서 가스상 유기염소계 살충제의 반감기 (Half lives of Gaseous Organochlorine Pesticides in Atmosphere)

  • 최민규;천만영
    • Environmental Analysis Health and Toxicology
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    • 제22권2호통권57호
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    • pp.177-184
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    • 2007
  • Gaseous organochlorine pesticides (OCPs : heptachlor epoxide, p, p'-DDE, ${\gamma}-HCH,\;{\alpha}-chlordane,\;{\gamma}-chlordane$ and trans-nonachlor) concentration was measured using PUF high volume sampler from June, 2000 to June, 2002 in the semi-rural atmosphere. The OCPs concentration in atmosphere, which is estimated by the slope (m) of Clausius-Clapeyron equation and phase-transition energy $({\Delta}H)$, was influenced by revolatilization from environmental matrix (soil, water and tree leaves) and a long range transportation of air mass. But the former affected OCPs concentration more than the latter. The degradation rate constants (k) of OCPs calculated using multiple regression analysis and revised standard temperature method were in good agreement each other. The value of k of ${\gamma}-HCH$ was very low as -0.0007, but the range of k of other components were $-0.00l8{\sim}-0.0038$. The half-life $({\tau})$ which was calculated by k of ${\gamma}-HCH$ was 2.6 years-the longest one, but that of heptachlor epoxide was in 0.5 year-the shortest one. $({\tau})\;of\;{\alpha}-chlordane,\;{\gamma}-chlordane$ and trans-nonachlor in technical chlordane was 1.0, 1.1 and 0.7 year respectively.

헬륨 기체분류의 정상적 비정상적 거동에 관한 연구 (A Study on Steady and Unsteady Behavior of Helium Jet in the Stationary Atmosphere)

  • 김봉곤;서용권;하종률;권순석
    • 한국자동차공학회논문집
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    • 제1권3호
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    • pp.34-45
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    • 1993
  • This study aims to analyze the mixing characteristics of hydrogen considered as a new fuel for internal combustion engines. As the physical property of helium gas is similar to that of hydrogen, helium gas was used in this study. To analyze the steady and unsteady behavior of jet, helium gas was injected into the stationary atmosphere at the normal temperature and pressure. Concentration of helium gas in the center of jet flow is in inverse proportion with axial distance from the nozzle tip. This agrees with the free jet theory of Schlichting. The relative equation for dimensionless concentration to radial/axial distance the axial distance of potential core region, the cone angle a of the jet flow and the relative equation for arriving distance of the front of jet flow to the lapse of time are obtained. But free jet theory of Schlichting in the dimensionless concentration is not in agreement with the present experimental results of the distance of the radial direction. It needs more study. When the arrival frequency of jet flow is used as a parameter, the transition area changing from unsteady flow area into steady flow area becomes gradually wider downstream, but its ratio for the whole unsteady flow area gradually decreases.

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III-V 화합물 자성 반도체의 강자성체 천이온도에 관한 연구 (Ferromagnic Transitition Temperature of Diluted Magnetic III-V Based Semiconductor)

  • 이화용;김송강
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 연구회
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    • pp.143-147
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    • 2001
  • Ferromagnetism in manganese compound semiconductors open prospects for tailoring magnetic and spin-related phenomena in semiconductors with a precision specific to III-V compounds. Also it addresses a question about the origin of the magnetic interactions that lead to a Curie temperature(Tc) as high as 110 K for a manganese concentration of just 5%. Zener's model of ferromagnetism, originally suggested for transition metals in 1950, can explain Tc of $Ga_{1-x}Mn_x$ As and that of its IT-VI counterpart $Zn_{1-x}Mn_x$ Te and is used to predict materials with Tc exceeding room temperature, an important step toward semiconductor electronics that use both charge and spin. In this article, we present not only the experimental result but calculated Curie temperature by RKKY interaction. The problem in making III-V semiconductor has been the low solubility of magnetic elements, such as manganese, in the compound, since the magnetic effects are roughly proportional to the concentration of the magnetic ions. Low solubility of magnetic elements was overcome by low-temperature nonequilibrium MBE{molecular beam epitaxy) growth, and ferromagnetic (Ga,Mn)As was realized. Magnetotransport measurements revealed that the magnetic transition temperature can be as high as 110 K for a small manganese concentration.

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Investigation of Linear Viscoelastic Properties of Xanthan-Carob Mixture in Sol and Gel States

  • Yoon, Won-Byong;Gunasekaran, Sundaram
    • Food Science and Biotechnology
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    • 제18권3호
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    • pp.618-623
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    • 2009
  • Synergistic interactions between xanthan (X) and carob (C) were investigated by studying the linear viscoelastic behavior of X, C, and X/C mixtures at sol and gel states. At the solution state, storage modulus (G') dominates the linear viscoelastic properties of X/C mixtures. The gelation temperature (52 to $57^{\circ}C$) was weakly dependent on the xanthan fraction (${\phi}x$) in the mixture. The ${\phi}x$ also had a strong effect on G' until ${\phi}x=0.5$. The elastic active network concentration (EANC) of X/C gels was estimated from the pseudo-equilibrium modulus. The EANC for systems with ${\phi}x=0.25$, 0.5, 0.75, and 1 at 1% total concentration was 2.3, 4.4, 4.1, and 0.32 (${\times}10^{-3}\;mol/m^3$), respectively. The maximum synergistic effect was observed at about ${\phi}x=0.5$. The G' at the transition state of X/C mixed gel was proportional to ${\omega}^{3/2}$ at ${\omega}$>${\omega}_{tr}$ (the onset transition frequency) compared to the theoretical limit of ${\omega}^{1/2}$.

Relationship between Carrier Concentration and Superconducting Transition Temperature in Bi-Sr-Ca-Cu-O Superconductor

  • Kim, Myung Chul;Park, Soon Ja
    • 분석과학
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    • 제5권2호
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    • pp.223-228
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    • 1992
  • 초산염(acetate)을 출발원료로 하여 $Bi_2Sr_2Ca_2Cu_3Oy$계 단일상 고온초전도체를 합성하려 하였으며 그 초전도상의 형성과정을 초전도전이온도 $T_c$ 및 전하나르게 농도와의 상관관계로부터 설명하고자 하였다. 초전도전이온도 $T_c$는 전기저항밀도 및 자화율을 측정하여 결정하였다. 시료로는 상기의 초전도체 출발조성물의 하소분말에 대해 $850^{\circ}C$, $860^{\circ}C$, 그리고 $870^{\circ}C$에서 40시간 동안 공기 중 열처리한 것을 이용하였다. 전하나르게농도는 홀계수를 측정하여 구하였다. 열처리과정 중의 초전도체 형성과정을 세라믹벌크내에 형성된 초전도체의 양 및 전하나르게농도 분포의 상관관계로부터 설명하였다.

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추진제용 PEG, PCP의 바인더 특성연구 (A Study on the PEG and PCP Binder for Propellant)

  • 홍명표;류문삼;임유진
    • 한국추진공학회지
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    • 제2권3호
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    • pp.70-79
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    • 1998
  • 고에너지 및 무연 추진제의 바인더 중 프리폴리머로 PEG 및 PCP가 널리 사용되어왔다. 본 연구에서는 PEG 프리폴리머에 PCP0260 및 PCP1270을 혼합 사용한 경우와 PCP0260, PCP1270, PEG만을 각각 단독으로 사용한 경우에 또 가소제로는 BTTN/DEGDN, BTTN/TMETN계를 사용하여 PEG/ PCP의 함량 변화, Pl/Po의 함량 변화에 대한 점도 변화를 온도에 따라서 고찰하였고, 경화된 바인더로는 PEG/PCP의 함량 변화, Pl/Po의 함량 변화에 따라 기계적 특성, 유리전이 온도를 고찰하였다. 그 결과 PCP의 함량이 증가함에 따라 점도는 상승하나, 유리전이 온도가 낮아지므로 저온물성이 좋아지며, 기계적 특성이 우수한 장점을 지니고 있다. 또한 TMETN은 DEGDN에 비하여 유리전이 온도 및 점도의 상승을 보이는 단점을 나타내고 있다.

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Effect of reduced energy density of close-up diets on metabolites, lipolysis and gluconeogenesis in Holstein cows

  • Huang, Wenming;Wang, Libin;Li, Shengli;Cao, Zhijun
    • Asian-Australasian Journal of Animal Sciences
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    • 제32권5호
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    • pp.648-656
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    • 2019
  • Objective: An experiment was conducted to determine the effect of reduced energy density of close-up diets on metabolites, lipolysis and gluconeogenesis in cows during the transition period. Methods: Thirty-nine Holstein dry cows were blocked and assigned randomly to three groups, fed a high energy density diet (HD, 1.62 Mcal of net energy for lactation $[NE_L]/kg$ dry matter [DM]), a medium energy density diet (MD, $1.47Mcal\;NE_L/kg\;DM$), or a low energy density diet (LD, $1.30Mcal\;NE_L/kg\;DM$) prepartum; they were fed the same lactation diet to 28 days in milk (DIM). All the cows were housed in a free-stall barn and fed ad libitum. Results: The reduced energy density diets decreased the blood insulin concentration and increased nonesterified fatty acids (NEFA) concentration in the prepartum period (p<0.05). They also increased the concentrations of glucose, insulin and glucagon, and decreased the concentrations of NEFA and ${\beta}-hydroxybutyrate$ during the first 2 weeks of lactation (p<0.05). The plasma urea nitrogen concentration of both prepartum and postpartum was not affected by dietary energy density (p>0.05). The dietary energy density had no effect on mRNA abundance of insulin receptors, leptin and peroxisome proliferator-activated $receptor-{\gamma}$ in adipose tissue, and phosphoenolpyruvate carboxykinase, carnitine palmitoyltransferase-1 and peroxisome proliferator-activated $receptor-{\alpha}$ in liver during the transition period (p>0.05). The HD cows had higher mRNA abundance of hormone-sensitive lipase at 3 DIM compared with the MD cows and LD cows (p = 0.001). The mRNA abundance of hepatic pyruvate carboxy-kinase at 3 DIM tended to be increased by the reduced energy density of the close-up diets (p = 0.08). Conclusion: The reduced energy density diet prepartum was effective in controlling adipose tissue mobilization and improving the capacity of hepatic gluconeogenesis postpartum.

불균일 농도 LPG의 폭발 특성에 관한 연구 (A Study on the LPG Explosion Characteristics of Non-uniform Concentration)

  • 오규형
    • 한국화재소방학회논문지
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    • 제17권4호
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    • pp.111-116
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    • 2003
  • 가로, 세로, 높이가 각각 100cm, 60cm, 45cm로 내용적이 $270\ell$인 폭발 용기를 이용하여 불균일 농도 상태의 LPG-공기 혼합가스의 폭발특성을 측정하였다. 폭발은 vented-explosion과 closed explosion의 조건에서 실시하였다. 실험의 변수로는 점화원의 위치, 노즐직경 및 유속으로, 시료가스를 주입하는 노즐의 직경과 유속을 변화시키면서 용기 내에서의 불균일 혼합정도를 조절하였다. 폭발압력은 strain형 압력센사를 사용하여 측정하였고 폭발화염의 거동은 비디오카메라로 측정하여 분석하였다. 실험결과 유속과 가스 주입 시간이 용기 내 가스 혼합에 중요한 요소임을 알 수 있었으며, 불균일 정도가 심화될 수록 폭발압력과 압력상승속도가 감소하였으나 용기 내 폭발화염의 체류시간은 크게 증가하였으며 이로 인하여 가스 폭발 후 화재로의 전이 위험성이 증가함을 알 수 있었다.

(Bi1⁄2Na1⁄2)1-xCaxTiO3 세라믹스의 압전 특성 및 상전이 거동 (Piezoelectric Properties and Phase Transition behaviors of (Bi1/2Na1/2)1- xCaxTiO3Ceramics)

  • 이용현;조정호;김병익;최덕균
    • 한국세라믹학회지
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    • 제45권5호
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    • pp.263-267
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    • 2008
  • $(Bi_{1/2}Na_{1/2})TiO_3$-based ceramics have been intensively studied as lead-free piezoelectric ceramics. In this study, the piezoelectric properties and phase transition behaviors of BNT based solid solution $(Bi_{0.5}Na_{0.5})_{1-x}Ca_xTiO_3$ ($X=0.01{\sim}0.25$) were investigated. The morphotropic phase boundary(MPB) zone which BNT is transformed from rhombohedral to cubic structure was appeared by adding $CaTiO_3$ with 0.12 mol by the measurement of permittivity and X-ray diffraction. The behavior which ferroelectric BNT with adding $CaTiO_3$ was changed to antiferroelectric and paraelectric state was confirmed by the measurement ofhysterisis loop and depolarization temperature as a function of temperature. As $CaTiO_3$ concentration was increased, the phase transition temperature was decreased. The piezoelectric properties were highest at 0.01 mol of $CaTiO_3$ concentration. The electromechanical coupling factor($K_t$) and mechanical quality factor($Q_m$) were 42% and 254, respectively.