• Elastomers and Composites
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• v.34 no.5
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• pp.383-390
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• 1999

Functionally graded polyurethane elastomers PUEs/grad. Poly(dimethylammoninum ethylacrylate bromide)(PDMAEA) were prepared by the method of electrophoresis. Results of elemental analysis showed that concentration of PDMAEA had gradient across the thickness(2mm) of the base PUEs. The modified PUEs(PUEs/grad. PDMAEA) containing high concentration of PDMAEA displayed low degree of swelling in benzene which was poor solvent for PDMAEA, and high degree of swelling in water which was good solvent. For the each layer of modified PUEs, glass transition temperature, dynamic storage modulus were stooled by DSC, Rheovibron DDV-IIC dynamic viscoelastomer. The chemomechanical properties of modified PUEs was explored by the electric-stimulus.

• Transactions of the Korean hydrogen and new energy society
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• v.7 no.1
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• pp.71-79
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• 1996

Yttrium thin film, 580nm thick, was prepared by electron beam evaporation. Film was hydrogenated room temperature upto 40 bar hydrogen pressure, without any activation process. Hydrogen concentration was determined by a quartz-crystal microbalance(QCM) method. YH2.9 sample was made without any pulverization. Electrical resistance was measured by four-point DC method in the temperature range between room temperature and 30K for various hydrogen concentration, x=0 to 2.9 of YHx sample. Temperature dependent resistance of YH2.9 shows low temperature minimum at 105K, the metal-semiconductor transition at 260K, and a hystersis above 210K.

• Journal of ILASS-Korea
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• v.7 no.4
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• pp.42-49
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• 2002

In this study, quantitative measurement of nitric oxide concentration distributions were investigated in the laminar CH4/O2/N2 premixed flame by laser-induced fluorescence (LIF). The NO A-X (0,0) vibrational band around 226nm was excited using a XeCl excimer-pumped dye laser. Selecting an appropriate NO transition minimizes interference from Rayleigh scattering and O2 fluorescence. The measurements were taken in CH4/O2/N2 premixed flame with equivalence ratios varying from $1.0{\sim}1.6$, and a fixed flowrate of 5slpm. NO was found to produce primarily between an inner premixed and an outer nonpremixed flame front, and total NO concentration is raised when equivalence ratios increase. These results suggest that prompt NO is likely to contribute to NO formation in CH4/O2/N2 premixed flame. Furthermore, this trend was well matched with previous works.

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.422-427
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• 2000

Propagation characteristics of tribrachial flames have been investigated experimentally in both two-dimensional and axisymmetric counterflows. Mixture fraction gradient at stoichiometric location is controlled by varying equivalence ratios at the two nozzles, one of which maintains rich while the other lean premixture. Tribrachial flames propagating through these mixtures are investigated. The propagation speed of tribrachial flames in two-dimensional counterflow decreases with fuel concentration gradient and has much higher speed than the maximum speed predicted previously in two-dimensional mixing layers. From an analogy with premixed flame propagation, this excessively large propagation speed can be attributed to the tribrachial flame propagating with respect to burnt gas. Corresponding maximum speed in the limit of small mixture fraction gradient is estimated and extrapolated experimental results substantiate this limiting speed. As mixture fraction gradient approaches zero, a transition in propagation characteristics occurs, such that the propagation speed of tribrachial flame approaches stoichiometric laminar burning velocity with respect to burnt gas. Similar behavior has been obtained for tribrachial flames propagating in axisymmetric counterflow.

• Korean Journal of Crystallography
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• v.11 no.3
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• pp.151-156
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• 2000

Yb/YAG single crystals were grown from the melt composition of Y/sub 1-x/Yb/sub x/)₃Al/sub 5/O/sub 12/ where x equal to 5, 10, 15, 20, 25, 33, 50, 75 and 100 at % by floating zone method. Optimum growth parameters to get high quality single crystals were 3.5 mm/h of growth rate and 20 rpm of rotation rate under the N₂ atmosphere. After the growth, color of crystals was appeared with pale blue due to the lack of oxygen, but it was disappeared after annealing at 1450℃ for 2 hr. Absorption coefficients were linearly increased depending on the concentration of Yb/sup 3+/ ions. Broad emission band was measured in the range of 1020 to 1050 nm with the peak intensity at 1031 nm and 1051 nm because of ²F/sub 5/2/(1)→²F/sub 7/2/(3) and ²F/sub 5/2/(1)→²F/sub 7/2/(4) transition respectively. When Yb/sup 3+/ ions were substituted with high rates, there were tendency to decrease the measured fluorescent lifetime for Yb ions depending on the concentration of Yb/sup 3+/ ions.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.7 no.1
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• pp.20-29
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• 1995

A theoretical model for film condensation of a vapor including a relatively lighter noncondensable gas on a horizontal tube has been formulated on the basis of the conservation laws and other fundamental physical principles. The model is applied to the prediction of the condensation heat transfer characteristics for the Freon vapor in the presence of air on a horizontal tube. Calculated results for the mean heat transfer coefficient, which is shown to depend strongly on the bulk concentration of air, are in good agreement with the available experimental results for a range of operating conditions. The distributions of physical quantities along the surface of tube are also calculated, such as the boundary layer thickness and local heat transfer coefficient. The present model is readily reduced to the Nusselt model as the bulk concentration of air decreases to zero. Therefore, the transition from the condensation of pure vapor to that of vapor-air mixture occurs continuously not abruptly.

• Journal of the Korea Institute of Military Science and Technology
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• v.7 no.2 s.17
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• pp.109-117
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• 2004

We synthesized energetic prepolymer(2-nitrato ethyl oxirane, NEO) for plastic-bonded explosive and measured its thermodynamic parameters. 2-Nitrato ethyl oxirane(NEO) as a monomer was synthesized from 4-butene-ol, the first-step was preparation of 1-nitrate-3-butene and second-step was synthesized 2-nitrate-ethyl oxirane from 1nitrate-3-butene and then polymerized by cationic ring opening polymerization. The unreacted monomer concentration was measured by GC. The thermodynamic parameters were obtained from the ceiling temperature(Tc) values of 1 mole monomer at each reaction temperature. We varied feed rate of monomer, concentration of initiator and monomer to control molecular weight and polydispersity of perpolymer(NEO). Number average molecular weight(Mn), polydispersity(PD), and glass transition temperature(Tg), viscosity of prepolymer(NEO) were 2000, 1.07, $-55^{\circ}C$ and 300 poise respectively.

• Journal of the Korean Society for Precision Engineering
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• v.7 no.2
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• pp.113-123
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• 1990

To study deleterious effects of contaminants contained in lubricating systems, the effects of fine alumina particle concentration and size on the critical failure load, friction and wear characteristic were examined on boundary lubrication condition using the four ball machine. The following conclusions are deduced: The abrasive is found to cause a transition from mild wear to severe wear at less severe conditions than with clean oil. In mild wear region the friction and wear increase with particle size and concentration, but in severe wear region do not exhibit any definite trend. In relation to film thinckness there is a threshold of particle size beyond which the failure load no longer decreases with particle size.

• Journal of Animal Environmental Science
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• v.7 no.1
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• pp.45-56
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• 2001

The following statistics are the results of a survey that analyzed the classification of livestock area and spatial mobility based upon the number of livestock and an area of 151 towns and cities from 1975 to 1995. 1. As a results of analysis about the degree of location concentration using C.V., Korean native cattles (HanWoo) and swines are becoming more centralized while dairies and chickens are becoming decentralized. 2. 49 regions, that is 32.5%, were classified as growing regions, 30 regions (19.9%) were stagnant regions and 72 regions (47.7%) were withering regions. The classification was based upon the calculation according to the numbers of converted grown animals and growth index. Kyonggi-do and Chungchongnam-do, specifically, took up 26.6% and 24.5% of the developing regions which shows that these two regions are the dominant regions for livestock. 3. Kyongsangbuk-do and Chungchongnam-do play significant roles for overall livestock, and Chollanam-do is considering a transition from swines to Korean native cattles and Kyongsangbuk-do is shifting from Korean native cattles to swines.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.162-163
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• 2021

To prepare the waterborne silicone acrylic resin coatings, acrylic resin was prepared by a radical polymerization. Glass transition temperature(Tg) of the acrylic copolymer was fixed at 30℃ and the contents of tertiary amine monomer(DMAEMA), were varied to be 5, 10, 15 and 20 wt%, hydroxyl monomer, and carboxyl monomer were fixed 10 wt%, and 4 wt% respectively. γ-Glycidoxypropyltrimethoxysilane(GPTMS) containing epoxy group was used for curing agents. The eqivalent ratio of amine to epoxy was 1:1. The prepared coatings exhibited excellent adhesion to various substrates, and various physical properties of the coatings were satisfactory. The gloss retension and color difference were improved at low tertiary amine concentration. The coatings containing 10wt% tertiary amine concentration have especially good weather resistant properties.