• Korean Chemical Engineering Research
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• v.53 no.4
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• pp.407-411
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• 2015

Dense ceramic membranes have been prepared using the commercial perovsikite $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$, powders synthesized by the solid state reaction method. The as-synthesized powders were compressed into disks with 1.0 mm of thickness and the disk was sintered at $1,100^{\circ}C$ for 2 hr. The oxygen permeation flux of $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ membrane increased with the increasing temperature and oxygen partial pressure. The activation energy for oxygen permeation was increased with the increasing oxygen partial pressure. Oxygen permeation flux at $950^{\circ}C$ were measured at various flow rates of feed and sweep gas. It has been demonstrated that oxygen permeability increased at elevated flow rates of both gases, but the sweep gas is more influential.

• Journal of Hydrogen and New Energy
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• v.24 no.1
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• pp.44-49
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• 2013

Hydrogen penetration into a metal leads to damages and mechanical degradations and its content measurement is of importance. For a precise measurement, a sample preparation procedure must be optimized through a series of studies on sample washing and drying. In this study, two-step washing with organic solvents and thermal soaking in inert gas were tried with a rod-shaped, API X65 steel sample. The samples were machined from a steel plate and then washed in acetone and etyl-alcohol for 5 minute each and dried with compressed air. After then, the samples were thermally soaked in a home-made nitrogen gas chamber during 10 minute at different heat gun temperatures from 100 to $400^{\circ}C$ and corresponding temperature range in the soaking chamber was from 77 to $266^{\circ}C$ according to the temperature calibration. Hydrogen residue in the samples was measured with a hot extraction system after each soaking step; hydrogen residue of $0.70{\pm}0.12$ wppm after the thermal soaking at $77^{\circ}C$ decayed with increase of the soaking temperature. By adopting the heat transfer model, decay behavior of the hydrogen residue was fitted into an exponential decay function of the soaking temperature. Saturated value or lower bound of the hydrogen residue was 0.36 wppm and chamber temperature required to lower the hydrogen residue about 95% of the lower bound was $360^{\circ}C$. Furthermore, a thermal desorption spectroscopy was done for the fully soaked samples at $360^{\circ}C$. Weak hydrogen peak was observed for whole temperature range and it means that hydrogen-related contaminants of the sample surface are steadily removed by heating. In addition, a broad peak found around $400^{\circ}C$ means that parts of the hydrogen residue are irreversibly trapped in the steel microstructure.

• Journal of the Korean Institute of Gas
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• v.14 no.6
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• pp.15-20
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• 2010

Compressed Natural Gas (CNG) buses have been supplied since the year 2000 in order to resolve severe atmospheric pollution in metropolitan area and contributed on the improvement of urban atmospheric environment. However, it is indispensible to take an adequate measure to guarantee the safety of CNG vehicles because of the possibility of huge fire accident. A receptacle, connecting device between high pressure fuel supply tank and fuel line, plays an important role in CNG supply system. In recent, leakage of CNG from receptacles has been reported. So, the concern about the security and reliability of receptacles has been arisen. Therefore, a lot of efforts to prevent leakage are invested among researchers and the durability of this component should be guaranteed despite repeated operation. This research has performed durability tests of a CNG receptacle regarding the repeated usage, extreme chattering, and continuous full flow test. Although a receptacle used for CNG vehicle satisfies validation requirements in the test results, it has been found that failure in the function of leakage prevention in a receptacle could take place in the case of prolonged exposure to high supply pressure in common quick charging environment on site.

• Fire Science and Engineering
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• v.18 no.2
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• pp.57-67
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• 2004

The results of the risk assessing on general buses, consisting mainly of diesel-fueled buses, show that the frequency of the instantaneous release is 1.4${\times}$10$^{-3}$ /bus/year, from which the probability of the formation of fireball as a sub event becomes 1.7${\times}$104, and show that the leakage from the CNG-fueled buses is 0.002 event/year. Also, the frequency of gradual release due to a crack is estimated at 3.7${\times}$10$^{-3}$ /buses/year, and a subsequent probability at which this could lead to a jet flame as a sub event is 1.2${\times}$10$^{-3}$ This corresponds to 0.04event/year for the CNG-fueled buses. Dividing all the fired casualties by the running distance of diesel-fueled buses, the risk is 0.091 fire fatalities per 100-million miles. And the total fire risk fur CNG buses is approximately 0.17 per 100-million miles of travel. This means that CNG buses is twice or more dangerous than diesel buses. After all CNG buses are more susceptible to the major fires. In the aspect of the reliability of this study, generic models and the failure data used in assessing the risks of CNG buses are appropriate. However, more accurate physics-based models and databases should be supplemented with this study to provide the better results.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.123-133
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• 2023

Commercial hydrogen fuel cell vehicles are charged by compressing gaseous hydrogen to high pressure and storing it in a storage tank in the vehicle. This process causes the temperature of the gas to rise, to ensure the safety to storage tanks, the temperature is limited. Therefore, a heat transfer model is needed to explain this temperature rise. The heat transfer model includes the convective heat transfer phenomenon, and accurate estimation is required. In this study, the convective heat transfer coefficient in the hydrogen fueling process was calculated and compared using various correlation equations considering physical phenomena. The hydrogen fueling process was classified into the fueling line from the dispenser to the tank inlet and the storage tank in the vehicle, and the convective heat transfer coefficients were estimated according to process parameters such as mass flow rate, diameter, temperature and pressure. As a result, in the case of the inside of the filling line, the convective heat transfer coefficient was about 1000 times larger than that of the inside of the storage tank, and in the case of the outside of the filling line, the convective heat transfer coefficient was about 3 times larger than that of the outside of the storage tank. Finally, as a result of a comprehensive analysis of convective heat transfer coefficients in each process, it was found that outside the storage tank was lowest in the entire hydrogen fueling process, thus dominated the heat transfer phenomenon.

• Journal of the Korean Society for Nondestructive Testing
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• v.36 no.5
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• pp.391-398
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• 2016

Acoustic emission (AE) is one of the most powerful techniques for detecting damages and identify damage location during operations. However, in case of the source location technique, there is some limitation in conventional AE technology, because it strongly depends on wave speed in the corresponding structures having heterogeneous composite materials. A compressed natural gas(CNG) pressure vessel is usually made of carbon fiber composite outside of vessel for the purpose of strengthening. In this type of composite material, locating impact damage sources exactly using conventional time arrival method is difficult. To overcome this limitation, this study applied the previously developed Contour D/B map technique to four types of CNG storage tanks to identify the source location of damages caused by external shock. The results of the identification of the source location for different types were compared.

• Journal of the Korea Convergence Society
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• v.9 no.4
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• pp.137-142
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• 2018

This paper is studied, as basic research for measuring the accurate fuel amount of the CNG tank by using the transmit-receive ultrasonic sensor, the receiving sensitivity according to changed the pressure inside the tank and the contact surface of the ultrasonic sensor is analyzed. Measurement was carried out while changing the contact surface of the tank and the sensor to three shapes of Point, Line, and Surface and charging the pressure in the tank at an interval of 1 bar from 0 bar to 5 bar. Experiment results, as the pressure in the tank increased the tendency of the received signal value of the ultrasonic sensor to decrease was confirmed. As the contact area between the tank and the sensor increased, the value of the received signal increased, but the noise also increased. The results of experiment, it is judged that accuracy can be improved by changing the contact surface of the sensor.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.14 no.2
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• pp.69-74
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• 2005

Since the use of CFC and HCFC refrigerants is to be restricted due to the depletion of ozone layer, this experiment applies the $NH_{3}$ gas to study the performance characteristics from the superheat control for improving the energy efficiency. The experiments are carried out for the condensing pressure of refrigeration system from 1500kPa to 1600kPa by 50kPa and for degree of superheat from $0^{circ}$ to $1^{circ}$ by $10^{circ}$ at each condensing pressure. As a result of experiment, 1) As degree of superheat increased, evaporating pressure of the compressor decreased so equilibrium temperature decreased. And specific volume of refrigerant vapors increased so refrigerant mass flow and heat load of the evaporator decreased. 2) An influence of change of condensing pressure on heat load of the evaporator was insignificant. 3) With the identical degree of superheat, change of compressed temperature was insignificant according to each condensing pressure, so there was little change in enthalpy.4) when the degree of superheat is $0^{circ}$C at each condensing pressure, the refrigeration system has the hi띤est performance.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.4
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• pp.387-394
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• 2013

Hydrogen-compressed natural gas (HCNG) blend has attracted attention as a fuel that can reduce $CO_2$ emissions because it has low carbon content and burns efficiently. An increase in the compression ratio of HCNG engines was considered as one of the methods to improve their efficiency and reduce $CO_2$ emissions. However, a high combustion rate and flame temperature cause abnormal combustion such as pre-ignition or knocks, which in turn can cause damage to the engine components and decrease the engine power. In this study, the performance and knock characteristics with a change in the compression ratio of an HCNG engine were analyzed. The combustion characteristics of HCNG fuel were evaluated as a function of the excess air ratio using a conventional CNG engine. The effects of the compression ratio on the engine performance were evaluated through the same experimental procedures.

• Journal of Energy Engineering
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• v.11 no.3
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• pp.276-282
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• 2002

The process of energy separation in a low Pressure vortex tube with compressed air as a work-ing medium is studied in detail. Experimental data of the temperature of the cold and hot air leaving the vortex tube are presented. The variation of the maximum wall temperature along the inner surface of the vortex tube and the temperature distribution in a vortex tube provide useful information about the location of the stagnation point of the flow field at the axis of the vortex tube. Analysis of the results enabled to find the optimum length of the vortex tube, the optimum shape of the Throttle and the usefulness of the Sleeve. In this study Outer tube is used for the exhaust application. The hot gas flow is turned 180$^{\circ}$and passes the out-side of the vortex tube a second time heating it. From this geometric setup of a vortex tube He effects of energy separation and the prediction of the ignition of Diesel Soot is presented by experimental data.