• Title/Summary/Keyword: Compositions

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Effect of Bath Compositions and Plating Conditions for Decorative Properties of Chromium Deposits using Oxalic Acid (수산을 사용한 크롬도금의 광택성에 미치는 도금액의 조성과 도금조건의 영향)

  • Oh, I.S.;Park, J.D.
    • Journal of Power System Engineering
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    • v.5 no.3
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    • pp.80-87
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    • 2001
  • Decorative properties of chromium depositions from oxalic acid bath containing chromium oxide and ammonium sulfate have been examined over a wide range of bath compositions and plating conditions. The obtained results from this experiment are summarized as follow: The followings were determined as a optimum conditions, bath compositions; $CrO_3\;200{\sim}250\;g/{\ell},\;H_2C_2O_4{\cdot}2H_2O\;500{\sim}700\;g/{\ell},\;(NH_4)_2SO_4\;40{\sim}120\;g/{\ell}$, and operation conditions; pH $2.0{\sim}2.5$, current density $15{\sim}250\;A/dm^2$ at bath temperature range of $30{\sim}80^{\circ}C$. Bright chromium deposits were obtained over a wide range of ammonium sulfate concentration and bath temperature. Decorative property for chromium deposition was adopted to apply stoichiometric ratio of $CrO_3$ concentration and $H_2C_2O_4{\cdot}2H_2O$.

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Study on Combustion Characteristics of the Opposed Flames for Different Oxidant Compositions by Considering the Non-gray Radiation by the Gas Mixtures (비회색 혼합가스 복사를 고려한 산화제의 성분 변화에 따른 대향류화염의 연소 특성 연구)

  • Park, Won-Hee;Jo, Bum-Jin;Park, Jong-Hyuk;Kim, Tae-Kuk
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1341-1346
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    • 2004
  • Detailed flame structures of the opposed flames formed for different oxidant compositions are studied numerically. The detailed chemical reactions are modeled by using the CHEMKIN code. Only the $CO_{2}$ and $H_{2}O$ are assumed to participate by absorbing the radiative energy while all other gases are assumed to be transparent. The discrete ordinates method and a narrow band based WSGGM with a gray gas regrouping technique are applied for modeling the radiative transfer through non-homogeneous and non-isothermal combustion gas mixtures generated by the opposed flow flames. The results show that the different radiation model can cause different results for flame structures and the WSGGM with gray gas regrouping is successful in modeling the opposed flames with non-gray gas mixture. The results also show that a reasonable information on the flame structure can be obtained from the modeling by considering different chemical compositions of the oxidant.

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Prediction of Impact Life Time in Solder Balls of the Board Level Flip Chips by Drop Simulations (낙하해석을 통한 보드 레벨 플립칩에서의 솔더볼 충격수명에 관한 연구)

  • Jang, Chong Min;Kim, Seong Keol
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.23 no.3
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    • pp.237-242
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    • 2014
  • Recently much research are has been done into the compositions of lead-free solders. As a result, there has been a rapid increase in the number of new compositions. In the past, the properties of these new compositions were determined and verified through drop-impact tests. However, these drop tests were expensive and it took a long time to obtain a result. The main goal of this study was to establish an analytical method capable of predicting the impact life-time of a new solder composition for board-level flip chips though the application of drop simulations using LS-DYNA. Based on the reaction load obtain with LS-DYNA, the drop-impact fracture cycles were predicted. The study was performed using a Sn-3.0Ag-0.5Cu solder (305 composition). To verify the reliability of the proposed analytical method, the results of the drop-impact tests and life-time analysis were compared, and were found to be in good agreement. Thus, the new analytical method was shown to be very useful and effective.

A Review on Identification Methods for TCE Contamination Sources using Stable Isotope Compositions (안정동위원소 조성을 이용한 TCE 오염원 규명방법 소개)

  • Park, Youngyun;Lee, Jin-Yong;Na, Won Jong;Kim, Rak-Hyeon;Choi, Pil Sung;Jun, Seong-Chun
    • Journal of Soil and Groundwater Environment
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    • v.18 no.3
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    • pp.1-10
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    • 2013
  • This study was performed to summarize application of ${\delta}^{13}C$, ${\delta}^{37}Cl$ and ${\delta}D$ of trichloroethylene (TCE) to studies on environmental forensic field regarding identification of TCE sources and evaluation of contribution of TCE to groundwater using data collected from literatures. ${\delta}^{13}C$, ${\delta}^{37}Cl$ and ${\delta}D$ of TCE give some information regarding sources of TCE because they show specific value according to manufacturing method. Also, TCE do not show a significant isotopic fractionation owing to adsorption and dilution. The isotopic fractionation mainly occurs by biodegradation. In addition, isotopic fractionation factor for TCE is different according to a kind of microorganism participated in biodegradation. However, the isotopic data of TCE have to be applied with chemical compositions of TCE and other hydrogeologic factors because isotopic fractionation of TCE is influenced by various factors.

A Comparative Study on the Chemical Compositions of Precipitations in Sungnam City of Kyunggi Province, Inchon City, Kangneung City of Kangwon Province, and Chongwon-gun of Chungbuk Province (경기도 성남시, 인천시, 강원도 강릉시, 충북 청원군 강수의 화학적 성분에 관한 비교 연구)

  • Park, Kuk-Tae;Moon, Gyung-Eon;Heo, Jeong-Goo;Hong, Hyun-Bok
    • Journal of Environmental Science International
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    • v.4 no.3
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    • pp.133-133
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    • 1995
  • A comparative study on the chemical compositions of precipitations from February 1993 to April 1993 in Sungnam city of Kyunggi province, Inchon city, Kangneung city of Kangwon province, and Chongwon-gun of Chungbuk province has been performed. The metal cation and anion concentrations were measured by atomic absorption spectrometer and ion liquid chromatography, respectively. pH/Ion meter and direct nesslerization method were used for the concentration measurements of $H^+$ and $NH^{4+}$ ions, respectively. The quantitative orders of the cation and anion average concentrations, correlation coefficients between the ion concentrations, and pH values are used for chemical analysis on the environmental pollution and pollutant sources in the urban, surburban, seaside, and rural areas of the Korean Peninsula.

A Study on the Heated Edible Oils(II) -Flow Properties and Changes of Fatty Acid Compositions on the Rice Bran Oil- (가열식용유(加熱食用油)에 관(關)한 연구(硏究)(II) -미(米)강유(油)의 유동성(流動性)과 지방산변화(脂肪酸變化)에 관(關)해서-)

  • Kim, Eun-Ae;Jeong, Tae-Myoung;Kim, Haeng-Ja;Park, Jea-Ok
    • Journal of Nutrition and Health
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    • v.11 no.1
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    • pp.33-37
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    • 1978
  • The effect of heating time (0 to 30 hours at $180{\pm}5^{\circ}C$) on the change of flow properties, fatty acid compositions and some other characteristics such as acid value, iodine value, peroxide value and density of purified edible rice bran oil were observed. flow properties were measured with Maron-Belner type capillary viscometer. Newtonian motion was observed in non-heated oil and the oil heated for 5 hours but non-Newtonian motion was observed in the oil heated for more than 10 hours and at high shear stress. The fatty acid compositions were analyzed by gas liquid chromatography and all the components of fatty acids were reduced in amounts with extention of heating time. The acid value, peroxide value and density were increased but iodine value were decreased with extension of heating time.

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Studies on the Composition of Green and Roast Coffee bean (커피생두(生豆)(Green Coffee)와 볶은 커피두(豆)(Roast Coffee)의 성분(成分)에 관(關)한 연구(硏究))

  • Choi, Min-Kang;Lee, Yong-Ock;Ko, Young-Su
    • Journal of Nutrition and Health
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    • v.11 no.1
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    • pp.9-16
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    • 1978
  • A Comparison of the analysis of the green and roast coffee of Arabica and Robusta compositions and regular instant coffee has been investigated by chromatography. The coffee oil were obtained by extracting the green and roast coffee with ethyl ether by soxhlet methood. Instant coffee samples were accurately weighted into 100ml beaker (ca. 0.5g regular coffee and 1.5g decaffeinated coffee) and add ca. 50ml water, heat and boil, remove from heat, and mechanically stried ca. 15min. and filtered of one sample and another sample were without filtrated and proceed with liquid chromatographic separation. The fatty acid compositions of green and roast coffee were compared by gas liquid chromatography and general chemical compositions of sample were analysed. Some similarities between green and roast coffee fatty acids were found in the case of green and roast coffee of both kinds acid methyl esters. They contained stearic, oleic, linoleic, and unknown fatty acid, and palmitic ana linoleic acid were rich.

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Effects of Intake Gas Compositions on the Performance of Diesel Engine (흡기 조성 변화가 디젤기관의 성능에 미치는 영향)

  • Kim, S.W.;Lee, J.K.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.2 no.2
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    • pp.49-58
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    • 1994
  • A study on the performance of a Diesel engine with various intake gas compositions other than that of air are performed experimentally. In this study, the concentrations of each of oxygen, nitorgen, carbon dioxide, and argon are changed and their effects on the performance of the engine are investigated parametrically. The experiments are performed at constant engine speed condition, and main measured parameters are cylinder pressure, intake gas compositions, fuel consumption rate. Increase of oxygen concentration up to 24% improved the performance of the engine generally. The adverse effect was observed when the oxygen concentration was increased over 24%. Increase of carbon dioxide concentration degraded the performance of the engine, mainly due to the lower specific heat ratio of carbon dioxide. Adding argon gas to the intake gas improved the overall performance. Finally, it is found that two most influencing factors affecting the performance of the Diesel engine in this study of intake gas composition variation are ignition delay and specific heat ratio of the intake gas.

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A Study on the Materials Characteristics of High Tensile Strength Steel(SM570) Plates (고장력(SM570)강재의 재료특성에 관한 연구)

  • Im, Sung Woo;Ko, Sang Ki;Ha, Dong Woo;Oh, Sang Hoon;Chang, In Hwa
    • Journal of Korean Society of Steel Construction
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    • v.12 no.6
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    • pp.649-659
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    • 2000
  • In this study, the chemical compositions and mechanical properties of high tensile strength steel plates in accordance with their thickness are quantitatively estimated, that are steel plates SM570 to be purposed to use in building structure. Test results of steel plates SM570 are compared with those of steel plates SS400 and steel plates SM490 mostly using building structure. It is found that chemical compositions, carbon equivalent, parameter of welding crack susceptibility, yield strength, tensile strength, elongation, and impact strength have satisfied the prescribed value in KS code for all case of thickness.

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Preparation of Silica Films by Sol-Gel Process (졸-겔 법을 이용한 실리카 박막의 제조)

  • 이재준;김영웅;조운조;김인태;제해준;박재관
    • Journal of the Korean Ceramic Society
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    • v.36 no.9
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    • pp.893-900
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    • 1999
  • Silica films were prepared on Si single crystal substrates by sol-gel process using TEOS as starting materials. Films were fabricated by a spin coating technique. Sol solutions were prepared by varying the compositions of CH3OH, H2O and DMF with fixed molar ratio of TEOS=1, HCl=0.05(mol). Wetting behavior viscosity of solutions gelation time thickness of films and cracking behavior were investigated with the various solution compositions. Wetting behaviors of solutions depended on the solution compositions mixing method and mixing rate. The optimum composition of sol was TEOS : DMF ; CH3OH: H2O :HCl=1:2:4:4:0.05(mol) and the mixing rate of solution was optimized at 1 ml/min. Viscosity of solutions were controlled by choosing a reaction time(elapsed time after mixing) at a room temperature so that we could get up to 800nm thick film The surface roughness was getting poor when thickness of films was thicker than 500nm. Thickness of coated films were increased with decreasing amount of CH3OH. The best surface roughness was obtained at the content of CH3OH 4 mol. The shortest gelation time was obtained with the content of CH3OH 8 mol. Crack-free filkms were fabricated when sintered at 500$^{\circ}C$ for 1 hr with heating rate of 0.6$^{\circ}C$/min.

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