• Carbon letters
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• 제5권4호
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• pp.164-169
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• 2004

Carbon-ceramic composites refer to a special class of carbon based materials which cover the main drawbacks of carbon, particularly its proneness to air oxidation, while essentially retaining its outstanding properties. In the present paper, the authors report the results of a systematic study made towards the development of C-SiC-$B_4C$ composites, which involves the effects of compositional parameters, namely, carbon-to-ceramic and ceramic-to-ceramic ratios, on the oxidation behaviour as well as other characteristics of these composites. The C-SiC-$B_4C$ composites, heat-treated to $1400^{\circ}C$, have shown that their oxidation behaviour at temperatures of 800~$1200^{\circ}C$ depends jointly on the total ceramic content and the SiC : $B_4C$ ratio. Good compositions of C-SiC-$B_4C$ composites exhibiting zero weight loss in air at temperatures of 800~$1200^{\circ}C$ for periods of 4~9 h, have been identified. Composites with these compositions undergo a weight gain or a maximum weight loss of less than 3% during the establishment of a protective layer at the surface of carbon in a period of 1~6 h. Significant improvement in the strength of C-SiC-$B_4C$ composites has been observed which increases with an increase in the total ceramic content and also with an increase in the SiC : $B_4C$ ratio.

• 응용통계연구
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• 제36권5호
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• pp.473-488
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• 2023

국내 대표 관광지인 강원도는 관광수요가 일부 지역에만 편중되어 있어 지역별로 다른 관광추이를 보인다. 따라서 각 지자체의 관광 활성화 방안 수립과 지역간 균형발전을 위해 각 지역의 관광 특성을 파악하고, 연도별 관광패턴을 비교하는 것이 중요하다. 본 논문에서는 최근 4년간의 강원도 관광 자료를 이용하여 지역을 군집화하고, 군집별 관광패턴을 Jeon 등 (2021)이 제안한 비유클리디안 가법모형으로 분석하였다. 이때, 연령대에 따른 방문자 수 비율과 방문지 유형에 따른 내비게이션 검색 수 비율을 공변량으로 하고, 업종별로 구분된 관광지출액 비율을 반응 변수로 하였다. 모형의 추정을 위해 평활역접합 방법과 성분별 띠폭 선택법을 이용하였다. 그리고 삼각 도표를 통해 추정된 모형을 시각화하고, 군집별로 적합 오차에 대한 예측 오차비율을 비교하여 연도별 관광패턴 변화를 확인하였다.

• 한국세라믹학회지
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• 제52권4호
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• pp.253-263
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• 2015

Ordinary Portland cement is a widely favored construction material because of its good strength and durability and its reasonable price; however, spalling behaviour during fire exposure can be a serious risk that can lead to strength degradation or collapse of a building. Geopolymers, which can be synthesized by mixing aluminosilicate source materials such as metakaolin and fly ash, and alkali activators, are resistant to fire. Because the chemical composition of geopolymers controls the properties of the geopolyers, geopolymers with various Si:Al ratios were synthesized and evaluated as fire resistant construction materials. Rejected fly ash generated from a power plant was quantitatively analyzed and mixed with alkali activators to produce geopolymers having Si:Al ratios of 1.5, 2.0, and 3.5. Compressive strength of the geopolymers was measured at 28 days before and after heating at $900^{\circ}C$. Geopolymers having an Si:Al ratio of 1.5 presented the best fire resistance, with a 44% increase of strength from 29 MPa to 41 MPa after heating. This material also showed the least expansion-shrinkage characteristics. Geopolymer mortar developed no spalling and presented more than a 2 h fire resistance rating at $1,050^{\circ}C$ during the fire testing, with a cold side temperature of $74^{\circ}C$. Geopolymers have high potential as a fire resistant construction material in terms of their increased strength after exposure to fire.

• Ocean and Polar Research
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• 제32권2호
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• pp.165-175
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• 2010

Dietary lipid biomarkers (fatty acids, fatty alcohols, and sterols) in adult specimens were analyzed to compare and understand the feeding ecology of the euphausiid, Euphausia pacifica, from three geographically and environmentally diverse Korean waters (Yellow Sea, East China Sea, and East Sea). Total lipid content of E. pacifica from Korean waters was about 10% dry weight (DW) with a dominance of phospholipids (>46.9% of total lipid content), which are known as membrane components. A saturated fatty acid, C16:0, a monounsaturated fatty acid, C18:1(n-9), and two polyunsaturated fatty acids, C20:5(n-3) and 22:6(n-3), were most abundant (>60% of total fatty acids) in the fatty acid composition. Some of the fatty acids showed slight differences among regions although no significant compositional changes of fatty acids were detected between these regions. Phytol, originating from the side chain of chlorophyll and indicative of active feeding on phytoplankton, was detected all samples. Trace amounts of various fatty alcohols were also detected in E. pacifica. Specifically, krill from the Yellow Sea showed relatively high amounts of longchain monounsaturated fatty alcohols (i.e. 20:1 and 22:1), generally found in herbivorous copepods. Three different kinds of sterols were detected in E. pacifica. The most dominant of these sterols was cholest-5-en-$3{\beta}$-ol (cholesterol). The lipid compositions and ratios of fatty acid trophic markers are indicative of herbivory in E. pacifica from the Yellow Sea and East Sea (mainly feeding on dinoflagellates and diatoms, respectively). The lipid compositions and ratios of fatty acid trophic markers are indicative of carnivory or omnivory in E. pacifica from the East China Sea, mainly feeding on microzooplankton such as protozoa. In conclusion, lipid biomarkers provide useful information about krill feeding type. However, further analyses and experiments (i.e. gut content analysis, in situ grazing experiment, etc.) are needed to better understand the feeding ecology of E. pacifica in various marine environments.

• 한국표면공학회지
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• 제38권5호
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• pp.202-206
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• 2005

Nitriding treatments were conducted on tool steel (SKD 61) at a temperature of $500^{\circ}C$ for 5 hr using high vacuum direct current (DC) plasma, with ammonia and argon as source gases. The structural and compositional changes produced in the nitrided layers by applying different ratios of Ar to $NH_{3}\;(n_{Ar}/n_{NH3}) were investigated using glancing x-ray diffraction (GXRD), optical microscopy, atomic force microscopy (AFM), micro-Vickers hardness testing, and pin-on-disc type tribometer. Nitriding case depths of around of $50{\mu}m$ were produced, varying slightly with different ratios of $n_{Ar}/n_{NH3}. It was found that the specimen surface hardness was 1150 Hv with $n_{Ar}/n_{NH3}=1, increasing to a maximum value of 1500 Hv with $n_{Ar}/n_{NH3}=5. With a further increase in ratio to $n_{Ar}/n_{NH3}=10, the surface hardness of the specimen reduced slightly to a value of 1370 Hv. These phenomena were caused by changes of the crystallographic structure of the nitride layers, i.e the $\gamma'-Fe_{4}N$ phase only was observed in the sample treated with $n_{Ar}/n_{NH3}$=1, and the intensity of the $\gamma'-Fe_{4}N$ phase were reduced but new phase of $\varepsilon'-Fe_{3}N$, which was known as a high hardness, with increasing $n_{Ar}/n_{NH3}. Also, the relative weight loss of counterface of the pin-on-disc with unnitrided steel was 0.2. And that of nitrided steel at a gas mixture ($n_{Ar}/n_{NH3}) of 1, 5, 7, and 10 was 0.4, 0.7, 0.6, and 0.5 mg, respectively. This means that the wear resistance of the nitrided samples could be increased by a factor of 2 at least than that of unnitrided steel.

• Current Photovoltaic Research
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• 제11권3호
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• pp.67-74
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• 2023

The earth-abundant element-based Cu₂ZnSn(S,Se)₄ (CZTSSe) thin film solar cells (TFSCs) have attracted greater attention in the photovoltaic (PV) community due to their rapid development in device power conversion efficiency (PCE) >13%. In the present work, we demonstrated the fine-tuning of the bandgap in the CZTSSe TFSCs by altering the sulfur (S) to the selenium (Se) chalcogenide ratio. To achieve this, the CZTSSe absorber layers are fabricated with different S/(S+Se) ratios from 0.02 to 0.08 of their weight percentage. Further compositional, morphological, and optoelectronic properties are studied using various characterization techniques. It is observed that the change in the S/(S+Se) ratios has minimal impact on the overall Cu/(Zn+Sn) composition ratio. In contrast, the S and Se content within the CZTSSe absorber layer gets altered with a change in the S/(S+Se) ratio. It also influences the overall absorber quality and gets worse at higher S/(S+Se). Furthermore, the device performance evaluated for similar CZTSSe TFSCs showed a linear increase and decrease in the open circuit voltage (V_oc) and short circuit current density (J_sc) of the device with an increasing S/(S+Se) ratio. The external quantum efficiency (EQE) measured also exhibited a linear blue shift in absorption edge, increasing the bandgap from 1.056 eV to 1.228 eV, respectively.

• 동아시아식생활학회지
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• 제24권2호
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• pp.208-216
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• 2014

The purpose of this study was the optimization of mixing ratio of rice flour, potato starch and soybean flour baking domestic rice cookies with nuts. Response surface methodology, with a central composite design comprising 5 levels and 3 variables, was used to identify the optimal combination of rice flour ($X_1$), potato starch ($X_2$) and soybean flour ($X_3$). The physical properties of 16 samples were analyzed, including color L (p<0.001), color a, color b (p<0.05), spreadability (p<0.05) and hardness (p<0.05). In sensory evaluations, color (p<0.05), flavor, taste (p<0.05), crunch (p<0.05) and overall quality (p<0.05) were differed significantly among the samples. The optimal compositional ratios were 78.90 g rice flour, 18.96 g potato starch, and 15.90 g the soybean flour in 420 g total weight.

• Mass Spectrometry Letters
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• 제9권3호
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• pp.81-85
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• 2018

In this study, the chemical composition of bacterial melanin isolated from the Streptomyces glaucescens strain was elucidated by ultra-high-resolution Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry. Ultra-high-resolution mass profiles of the microbial melanin product were acquired using a 15 Tesla FT-ICR mass spectrometer in positive and negative ion modes via electrospray ionization to obtain more complete descriptions of the molecular compositions of melanin-derived organic constituents. A mass resolving power of 500,000 (at m/z 400) was achieved for all spectra while collecting 400 scans per sample with a 4 M transient. The results of this analysis revealed that the melanin pigment isolated from S. glaucescens predominantly exhibits CHON and CHO species, which belong to the proteins class of compounds, with the mean C/O and C/N ratios of 4.3 and 13.1, thus suggesting that the melanin could be eumelanin. This analytical approach could be utilized to investigate the molecular compositions of a variety of natural or synthetic melanins. The compositional features of melanins are important for understanding their formation mechanisms and physico-chemical properties.

• Asian-Australasian Journal of Animal Sciences
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• 제20권6호
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• pp.989-993
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• 2007

A lactose-hydrolyzed milk with low sweetness was developed using nanofiltration. Raw milk was treated with 0.03% ${\beta}$-galactosidase at $4^{\circ}C$ for 24 h to hydrolyze lactose partially. The resultant lactose-hydrolyzed milk containing 0.43% lactose was then concentrated using a nanofiltration membrane to reach concentration factor of 2.13. The concentration factors and coefficients of retention of milk components in nanofiltration were determined. The concentration factor of milk fat was 2.20 which was the highest of the milk components. The coefficient of retention of calcium and riboflavin was 0.96 and 0.76, respectively. However, the coefficient of retention of glucose, galactose, and sodium was 0.21, 0.15, and 0.22, respectively. Raw milk was treated with 0.1% ${\beta}$-galactosidase at $4^{\circ}C$ for 40 h to hydrolyze lactose fully and then concentrated to reach a concentration factor of 1.6 by using nanofiltration. The concentrated milk was reconstituted with water. The lactose-hydrolyzed milk had sweetness similar to milk. The compositional ratios of crude protein, calcium, sodium, and riboflavin of lactose-hydrolyzed nanofiltrated milk to those of raw milk were 99%, 97%, 77%, and 80%, respectively. This study showed that nanofiltration of lactose-hydrolyzed milk to remove galactose and glucose did not cause significant loss of calcium. The lactose-hydrolyzed nanofiltrated milk contained 0.06% lactose and had sweetness similar to milk.

• 한국추진공학회지
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• 제5권1호
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• pp.49-59
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• 2001

경사기능재료(FGM)는 일반적으로 세라믹스나 금속과 같은 서로 다른 재료로 이루어져 있다. FGM의 성질은 조성구배, 미세조직, 기공율에 의해 변화가 일어난다. 본 연구에서는 입방체 AlN/Al-$Al_3$Ti FGM은 분말야금공정으로 제조하였고 그 특성을 관찰하였다. Al에 서로 다른 Mg와 Ti 분말을 steel 몰드에 조성구배를 폭넓게 하여 적층, 혼합하였다. 소결온도와 Mg의 양을 점점 증가시킴으로써 형성된 AlN의 양도 더 증가하였다. AlN과 $Al_3$Ti는 조성구배를 XRD 분석, 광학현미경으로 조직을 관찰하였으며 미소경도시험을 행하였다.