• Title/Summary/Keyword: Compositional ratio

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Studies on Effect of S/Se Ratio on the Properties of Cu2ZnSn(SxSe1-x)4 (CZTSSe) Thin Films by Sulfo-Selenization of Stacked Precursor Thin Films (열처리 시 S/Se 분말 비율에 따른 Cu2ZnSnSe4 (CZTSSe) 박막의 합성 및 특성 평가)

  • Gang, Myeng Gil;He, Ming Rui;Hong, Chang Woo;Kim, Jin Hyeok
    • Current Photovoltaic Research
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    • v.2 no.4
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    • pp.177-181
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    • 2014
  • $Cu_2ZnSn(S_xSe_{1-x})_4$ (CZTSSe) absorber thin films were prepared on Mo coated soda lime glass substrates by sulfo-selenization of sputtered stacked Zn-Sn-Cu precursor thin films. The Zn-Sn-Cu precursor thin films were sulfo-selenized inside a graphite box containing S and Se powder using rapid thermal processing furnace at $540^{\circ}C$ in Ar atmosphere with pre-treatment at $300^{\circ}C$. The effect of different S/Se ratio on the structural, compositional, morphological and electrical properties of the CZTSSe thin films were studied using XRD (X-ray diffraction), XRF (X-ray fluorescence analysis), FE-SEM (field-emission scanning electron microscopy), respectively. The XRD, FE-SEM, XRF results indicated that the properties of sulfo-selenized CZTSSe thin films were strongly related to the S/Se composition ratio. In particular, the CZTS thin film solar cells with S/(S+Se)=0.25 shows best conversion efficiency of 4.6% ($V_{oc}$ : 348 mV, $J_{sc}$ : $26.71mA/cm^2$, FF : 50%, and active area : $0.31cm^2$). Further detailed analysis and discussion for effect of S/Se composition ratio on the properties CZTSSe thin films will be discussed.

Effect of Betamethasone on Pulmonary Surfactant Activity in Unilateral Pneumonectomized Rabbits (일측폐장절제가토에 있어서 steroid가 제 II 형 폐포세포의 기능에 미치는 영향)

  • Lee, Suck-Kang;Lee, Young-Man
    • Journal of Yeungnam Medical Science
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    • v.1 no.1
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    • pp.59-66
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    • 1984
  • Although it is well established that steroid is effective for treatment of neonatal respiratory distress syndrome (NRDS), the action mechanism of steroid on NRDS is not well known. Several authors have insisted that steroid increases secretion of pulmonary surfactant from type II pneumocyte, but others have insisted that steroid does not affect the secretory function of the type II pneumocyte. And some authors have suggested that steroid may ca use compositional change of pulmonary surfactant phospholipid. From these aspects, it is desirable to confirm the effect of steroid on (he secretory function of the type II pneumocyte. In order to know the effect of steroid on pulmonary surfactant activity, phospholipid phosphorus of lung lavage was measured and composition of pulmonary surfactant phospholipid of lung lavage was analyzed by thin layer chromatography (TLC) in control (C), pneumonectomized (PN), and pneumonectomized with betamethasone treated (PNS) rabbits. And lung weight and lung weight-body weight ratio were measured in each experimental group also. In PN group, right lung pneumonectomy was performed under general anesthesia with pentobarbital sodium (30mg/kg). On the fifth day after the surgery, the left lung was excised and measured above parameters. In PNS group, pneumonectomy was performed as PN group, and one day after the surgery, betamethasone was injected for four days intramusculary (4mg/day) and rabbits were sacrificed. The experiment yielded following results. PNS group's lung weight was significantly (p<0.01) heavier than C group's, but in comparison with PN group's it showed no significant change. PNS group's L/B ratio was significantly (p<0.05) higher than C group's, but compared with PN group's it showed no significant change. The value of phospholipid phosphorus content of PNS group was significantly (p<0.01) higher than that of C group. Even if the value of phospholipid phosphorus content in PNS group was not significantly higher than that of PN group, it showed increasing tendency compared with that of PN group. And in an analysis of the thin layer chromatogram, quantity (${\mu}mol/gm$ of wet weight lung) of phosphatidylcholine in PNS group decreased significantly (p<0.05) compared with C and PN group. From these results, it may be suggested that though steroid inhibits cellular hyperplasia in the compensatory growing lung, it auguments the secretory function of type II pneumocyte and causes compositional change of pulmonary surfactant phospholipid.

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Plan Composition Expressed in the Architecture of Art Gallery Designed by Louis I. Kahn - Focus on the Yale University Art Gallery Extension - (Louis I. Kahn의 미술관 건축에 나타난 평면구성에 관한 연구 - Yale University Art Gallery Extension을 중심으로 -)

  • Kim, Hong-Bae
    • Korean Institute of Interior Design Journal
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    • v.21 no.3
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    • pp.128-135
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    • 2012
  • The purpose of this study is to investigate and analyze the compositional elements of plan of art museums by selecting architectural works, which have strong symbolic meaning when evaluating value, from architectural works by Louis Kahn. First, the centrality of artworks, which are being displayed at the Yale Art Gallery, is complex. It includes three patterns of Void (spatial) Centrality+Symbolic Centrality+Functional Centrality among the five patterns suggested in this study. Second, the ratio system of interior space, which is expressed in the extension of the Yale Art Gallery, can be classified into the floor and walls. The floor used the square 1:1 ratio system. The ceiling used the grid patterns of equilateral triangles (regular tetrahedrons). It was applying a geometric ratio system when creating forms by using one side as a beam and the other sides as decorations of the ceiling. Third, the contours of interior space, which were expressed in Kahn's works, used the method of forming separate space according to the contouring rule (structural unit) defined by columns, and they were used in constructing the entire space through the integration of separate spaces. Fourth, according to the characteristics that were expressed by artworks displayed within the Yale Art Gallery Extension, the concept of accessibility was not as clear as that of residential buildings, because an approach of respecting existing architecture and context was used, rather than the starting point of interior space, or differentiated circulation, which has the function of a determined position.

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Assessment of Overconsolidation Ratio by Depth of Soft Ground: A Case Study in South Korea (국내 연약지반의 심도별 과압밀비 산정에 관한 사례연구)

  • Lee, Jong-Young;Han, Jung-Geun
    • Journal of the Korean Geosynthetics Society
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    • v.20 no.4
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    • pp.9-18
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    • 2021
  • In this study, the overconsolidation ratio (OCR) of soft clay soil was calculated by conducting an indoor physical experiment and a dynamics test using undisturbed soil samples from a soft clay soil field in South Korea. The OCR by depth was predicted by comparing the experimental results with the existing empirical equations. Methods using the liquidity index and the existing empirical equation by the Naval Facilities Engineering Systems Command (NAVFAC) were examined, and the results were compared with the actual measured values. The method using the liquidity index was found to be suitable for estimating the rough OCR of the ground. However, the effect of drying was not considered for the ground above the groundwater level. Therefore, an equation for the correlation equation between the depth and OCR of each region, including the ground above the groundwater level, was proposed. The proposed equation was applied to the OCR prediction of the adjacent area. The predicted values in the area composed of clay (CL, CH) were found to be in good agreement with the actual values. In the region composed of silt (ML), however, the predicted values were not consistent with the actual values. This suggests that the sedimentation and compositional characteristics, rather than the engineering characteristics of the soil, are important factors that affect the OCR prediction.

A Study on the fluctuation Factors Influenced on the Computation of interior Cost (인테리어 공사비 산정에 영향을 주는 변동요인에 관한 연구)

  • 정재은;권영성
    • Korean Institute of Interior Design Journal
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    • no.16
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    • pp.75-81
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    • 1998
  • With the rise of the economic level and the improvement of the standard of living the size of the interior work is becoming large and specialized, With the recent opening of the domestic interior decoration market the order of the large-scale interior decoration work is actively received and its efficient construction is vigorously made. Accordingly reliability is required in keeping with all the accuracy of computing interior construction expenses systematically is importantly emerging. The estimation sheet written in a kind of process mode and in an area made as the construction expense breakdown mode were statistically treated and analyzed as well as quantity computation breakdown data. In determing the major factors that expert an influence on the factors of changes in construction expenses as well as the compositional ratio of construction work that becomes basic material for developing the cost model of interior decoration work the following conclusion could be made: Improvement should be made to suit the present situation by synthesizing and arranging the data practically used in current interior construction expenses. Required construction expenses for the kind of work common to each construction field are showing a given proportion and the required construction expenses of rather small scale interior construction work tend to be irregular. It is necessary to compute optimal construction expenses by calculating the optimal period of work and working personnel in consideration of the influential factor in each work.

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Quality Characteristics and Optimization of Rice Cookies with Nuts by Response Surface Methodology (반응 표면 분석을 이용한 견과류 첨가 쌀 쿠키의 품질 특성 및 최적화)

  • Jin, So-Yeon;Lee, Eun Ji;Kim, Myung-Hyun
    • Journal of the East Asian Society of Dietary Life
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    • v.24 no.2
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    • pp.208-216
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    • 2014
  • The purpose of this study was the optimization of mixing ratio of rice flour, potato starch and soybean flour baking domestic rice cookies with nuts. Response surface methodology, with a central composite design comprising 5 levels and 3 variables, was used to identify the optimal combination of rice flour ($X_1$), potato starch ($X_2$) and soybean flour ($X_3$). The physical properties of 16 samples were analyzed, including color L (p<0.001), color a, color b (p<0.05), spreadability (p<0.05) and hardness (p<0.05). In sensory evaluations, color (p<0.05), flavor, taste (p<0.05), crunch (p<0.05) and overall quality (p<0.05) were differed significantly among the samples. The optimal compositional ratios were 78.90 g rice flour, 18.96 g potato starch, and 15.90 g the soybean flour in 420 g total weight.

Optimization of Muffin with Opuntia humifusa Powder using Response Surface Methodology (반응표면분석법을 이용한 천년초 분말 첨가 머핀 제조 조건의 최적화)

  • Kim, Soojeong;Jung, Bok-Mi;Joo, Nami
    • The Korean Journal of Food And Nutrition
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    • v.25 no.4
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    • pp.911-921
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    • 2012
  • The objective of this study was to determine the optimum mixing ratio of Opuntia humifusa powder and sugar in the preparation of muffin. The optimal sensory composite recipe was determined by following the central composites for muffin with different levels of Opuntia humifusa powder (A) and sugar (B). The analysis was performed using the response surface methodology, and the sensory evaluation was performed with the data. Ten experimental recipes, including two with reference points in the composition, were selected. The compositional and functional properties were measured, and the physical and sensory values were applied to the mathematical models. Perturbation plots showed the effects of each ingredient on the final product. Measurements showed significant values in lightness (p<0.05), sweetness (p<0.05), hardness (p<0.05), gumminess (p<0.05) and cohesiveness (p<0.01). The sensory measurements showed significant values in color (p<0.05), flavor (p<0.05), appearance (p<0.05), softness (p<0.05) and overall quality (p<0.05). Based on the numerical and graphical methods, the optimal formulation was determined to be 6.10 g of Opuntia humifusa powder and 82.61 g of sugar.

Study on the Thermodynamic Properties and Combustion Information of Natural Gases from Various Producing Districts (산지별 천연가스들의 열 물성치 및 연소 정보 검토)

  • Lee, Chang-Eon;Hyun, Seung-Ho;Hwang, Cheol-Hong;Lee, Sung-Min;Ha, Young-Cheol;Lee, Kang-Jin
    • Journal of the Korean Society of Combustion
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    • v.12 no.1
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    • pp.38-47
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    • 2007
  • The diversification of import districts of natural gas is trying to prepare an increase in the demand and price. The interchangeability of natural gases should be examined prior to supply to gas appliances, although compositional differences among natural gases are not large. The object of this study is to investigate numerically the thermodynamic and transport properties as well as information on combustion of 6 natural gases. Comparing the properties of BOG1 with those of standard gas, the maximum differences of heating value, Wobbe index, air-fuel ratio, and specific heat are 10%, 4%, 10% and 5.54%, respectively. That is, the BOG1 is required careful application. However, all gases except for BOG1 show the similar properties with standard gas. Finally, the combustion information such as flame temperature and burning velocity are examined. These results will provide the useful information related to the interchangeability of various natural gases in practical combustion appliances.

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Taste Response of Electrodes Coated with Polymeric Lipid Membrane (고분자 지질막 전극 센서의 맛 반응 평가)

  • 조용진;박인선;김남수
    • Journal of Biosystems Engineering
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    • v.27 no.3
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    • pp.249-258
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    • 2002
  • The fourteen different electrodes coated with polymeric lipid membrane were evaluated to selectively monitor the sweet, salty, sour and bitter tastes, and umami. The polymeric lipid membrane consisted of the three components, or polymer matrix, plasticizer and electroactive material, the compositional ratio of which was 1:1.25:1. Herein, the 14 different electroactive materials were used. Sucrose, NaCl, citric acid, caffeine and MSG were used as standard materials of sweet, salty, sour and bitter tastes, and umami. The linear responses of each electrode regarding 5 tastes were analyzed by means of the correlation coefficient between electric potential difference and concentration of a taste material when the linearity was based on a linear model and a thermodynamic model, respectively. As fur salty taste, the electrode coated with valinomycin had a selective linearity at the significance level of 0.01. For monitoring sweet taste, the electrode with oleylamine and the electrode with the mixture of tai-n-octylmethylammonium chloride and dioctylphosphate (2:8) showed the significant linearities at the levels of 0.05 and 0.10, respectively.

Preparation of Seleinzed CuInSeS12T Thin Films P-type Conductivity (P형 전기전도도 특성을 갖는 $Selenized CuInse_2$ 박막의 제조)

  • 박성;김선재
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.43 no.2
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    • pp.296-302
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    • 1994
  • Polycrystalline CuInSeS12T thin were prepared by depositing Cu/In layer, which was sequentially sputtered varying the Cu/(Cu+In) mole ratio, on glass substrate and selenizing with selenium metal vapor in a nitrogen atmosphere. Compositional and structural, characterization was carried out by X-ray diffraction (XRD), wavelength-dispersive spectroscopy(WDS), and scanning electron microscope(SEM). Electrical characterization was carried out by the measurements of Hall effect, electrical resistivity. Large indium loss occurs in early stage of the selenization process. The selenized films which had mole ratios larger than 0.28 have chalcopyrite CuInSeS12T phase and these that had less mole ratios have sphalerite phase. The selenized films containing CuS1xTSe phase have Cu-rich CuInSeS12T phase and these that did not contain CuS1xTSe have In-rich CuInSeS12T phase. By optimizing the sputtering conditions,it is possible to fabricate CuInSeS12T thin films which have little secondary phases and an appropriate hole concentration (10S015T ~ 10S016TcmS0-3T) for solar cells.